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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Mercaptobenzaldehyde CAS 29199-11-9

Cas:29199-11-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

2-Thiosalicylaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzaldehyde,2-mercapto- 29199-11-9

Cas:29199-11-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

2-Mercaptobenzaldehyde CAS:29199-11-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

2-Mercaptobenzaldehyde CAS:29199-11-9

Cas:29199-11-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzaldehyde,2-mercapto-

Cas:29199-11-9

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 29199-11-9 ,2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:10 Kilogram

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Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzaldehyde,2-mercapto-

Cas:29199-11-9

Min.Order:0

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offer2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzaldehyde,2-mercapto-

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzaldehyde,2-mercapto-

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzaldehyde,2-mercapto-

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

2-Mercaptobenzaldehyde Application:2-Mercaptobenzaldehyde

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Other

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DB BIOTECH CO., LTD

best seller Application:API

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Trading Company

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

2-MERCAPTOBENZALDEHYDEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-MERCAPTOBENZALDEHYDE

Cas:29199-11-9

Min.Order:0

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Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

2-Mercaptobenzaldehyde

Cas:29199-11-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SAGECHEM LIMITED

29199-11-9 Application:intermediate

Benzaldehyde, 2-mercapto-

Cas:29199-11-9

Min.Order:0

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Synthetic route

2,2'-dithiodibenzaldehyde
55164-16-4

2,2'-dithiodibenzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With tris-(2-carboxyethyl)-phosphine hydrochloride In dimethyl sulfoxide100%
With triphenylphosphine In methanol; water; N,N-dimethyl-formamide 1.) room temp., 30 min; 2.) ice-water bath, 30 min;80%
With water; triphenylphosphine In methanol; N,N-dimethyl-formamide at 20℃; for 0.5h;80%
o-hydroxymethyl thiophenol
4521-31-7

o-hydroxymethyl thiophenol

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With dihydrogen peroxide In neat (no solvent) at 80℃; for 4h; Green chemistry;100%
Multi-step reaction with 2 steps
1: 54 percent / pyridinium chlorochromate / CH2Cl2 / 4 h / 20 °C
2: 80 percent / triphenylphosphine; water / methanol; dimethylformamide / 0.5 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 54 percent / PCC / CH2Cl2 / 4 h / Ambient temperature
2: 80 percent / Ph3P / dimethylformamide; H2O; methanol / 1.) room temp., 30 min; 2.) ice-water bath, 30 min
View Scheme
2-(2-bromophenyl)-1,3-dioxolan
34824-58-3

2-(2-bromophenyl)-1,3-dioxolan

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Stage #1: 2-(2-bromophenyl)-1,3-dioxolan With magnesium In tetrahydrofuran at 0℃; for 1h; Reflux;
Stage #2: With sulfur In tetrahydrofuran at 20℃;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; water for 2h; Reflux;
91%
thiophenol
108-98-5

thiophenol

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Stage #1: thiophenol With n-butyllithium; N,N,N,N,-tetramethylethylenediamine
Stage #2: N,N-dimethyl-formamide
83%
Stage #1: thiophenol With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane
Stage #2: N,N-dimethyl-formamide In hexane
66%
Stage #1: thiophenol With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane at 0 - 20℃; for 16h; Inert atmosphere;
Stage #2: N,N-dimethyl-formamide In hexane at 0 - 20℃; for 20h; Inert atmosphere;
48%
o-Thioacetoxybenzaldehyde
119011-44-8

o-Thioacetoxybenzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With titanium tetrachloride; zinc In dichloromethane at 25℃; for 0.166667h;82%
o-rhodano-benzaldehyde
85733-65-9

o-rhodano-benzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With sodium hydroxide for 0.0833333h;70%
With sodium sulfide; water das Natriumsalz entsteht;
2-hydroxy-5-phenylcyclohex-1-enecarbaldehyde
1060749-49-6

2-hydroxy-5-phenylcyclohex-1-enecarbaldehyde

mer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III)

mer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III)

A

mer-hydrido(1-carbonyl-2-oxo-5-phenylyclohexenediyl)tris(trimethylphosphine)cobalt(III)
210900-83-7

mer-hydrido(1-carbonyl-2-oxo-5-phenylyclohexenediyl)tris(trimethylphosphine)cobalt(III)

B

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
In diethyl ether at -80 - 20℃; for 14h; Mechanism; Inert atmosphere; Schlenk technique;A 69%
B n/a
ethyl 2-sulfanylacetate
623-51-8

ethyl 2-sulfanylacetate

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

A

ethyl benzo[b]thiophene-2-carboxylate
17890-55-0

ethyl benzo[b]thiophene-2-carboxylate

B

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With potassium tert-butylate In ammonia for 180h; Irradiation;A 55%
B 10%
With potassium tert-butylate 1.) NH3, irradiation, 180 min,; Yield given. Multistep reaction. Yields of byproduct given;
2,2'-dithiodibenzaldehyde
55164-16-4

2,2'-dithiodibenzaldehyde

methyl vinyl ketone
78-94-4

methyl vinyl ketone

A

2-formylthiophenol
29199-11-9

2-formylthiophenol

B

3-acetyl-4-hydroxythiochroman

3-acetyl-4-hydroxythiochroman

C

3-acetyl-2H-1-benzothiopyran

3-acetyl-2H-1-benzothiopyran

Conditions
ConditionsYield
With triphenylphosphine In chloroform at 20℃; for 96h;A 9%
B 52%
C 33.5%
2-[(phenylmethyl)thio]benzaldehyde
24852-71-9

2-[(phenylmethyl)thio]benzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Stage #1: 2-[(phenylmethyl)thio]benzaldehyde With aluminum (III) chloride In benzene at 20℃; for 48.5h; Inert atmosphere;
Stage #2: With water In benzene Cooling with ice;
24%
O-(2-formylphenyl) N,N-dimethylcarbamothioate

O-(2-formylphenyl) N,N-dimethylcarbamothioate

A

2-formylthiophenol
29199-11-9

2-formylthiophenol

B

S-(2-formylphenyl) N,N-dimethylthiocarbamate
153511-19-4

S-(2-formylphenyl) N,N-dimethylthiocarbamate

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 230℃; for 15h; Miyazaki-Newman-Kwart rearrangement; Microwave irradiation;A 10%
B n/a
2-mercapto-N-methyl-N-phenylbenzamide
49848-22-8

2-mercapto-N-methyl-N-phenylbenzamide

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With lithium aluminium tetrahydride
N-Formylpiperidine
2591-86-8

N-Formylpiperidine

thiophenol
108-98-5

thiophenol

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine 1.) hexane, a) 0 deg C, 0.5 h, b) RT, 17 h, 2.) hexane, 25 deg C, 18 h; Yield given; Multistep reaction;
Thiosalicylic acid
147-93-3

Thiosalicylic acid

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 96 percent / LiAlH4 / tetrahydrofuran / 20 °C
2: 54 percent / pyridinium chlorochromate / CH2Cl2 / 4 h / 20 °C
3: 80 percent / triphenylphosphine; water / methanol; dimethylformamide / 0.5 h / 20 °C
View Scheme
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Reflux;
Multi-step reaction with 3 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere
2: pyridinium chlorochromate / dichloromethane / 4 h / 20 °C / Inert atmosphere
3: triphenylphosphine / water; N,N-dimethyl-formamide; methanol / 0.5 h / 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 20 °C
2: pyridinium chlorochromate / dichloromethane / 5 h / 20 °C
3: tris-(2-carboxyethyl)-phosphine hydrochloride / dimethyl sulfoxide
View Scheme
Multi-step reaction with 3 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C
2: pyridinium chlorochromate / dichloromethane / 20 °C
3: triphenylphosphine / methanol; N,N-dimethyl-formamide; water / 1 h / 0 - 20 °C
View Scheme
1,2-bis(2-(hydroxymethyl)phenyl)disulfane
35190-71-7

1,2-bis(2-(hydroxymethyl)phenyl)disulfane

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 16 percent / PCC
2: 80 percent / Ph3P / dimethylformamide; H2O; methanol / 1.) room temp., 30 min; 2.) ice-water bath, 30 min
View Scheme
With triphenylphosphine In methanol; water; N,N-dimethyl-formamide for 1h;
2-aminobenzaldehyde
529-23-7

2-aminobenzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) sodium nitrite / 1) sulphuric acid, water, 0 deg C, 2) water, room temp., 1 h, 60 deg C, 30 min
2: 70 percent / sodium hydroxide / 0.08 h
View Scheme
Multi-step reaction with 2 steps
1: Diazotization.durch Umsetzung mit CuCNS
2: sodium sulfide; water / das Natriumsalz entsteht
View Scheme
N-(2-nitro-benzyl)-sulfanilic acid

N-(2-nitro-benzyl)-sulfanilic acid

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
2: Diazotization.durch Umsetzung mit CuCNS
3: sodium sulfide; water / das Natriumsalz entsteht
View Scheme
2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With sodium sulfide
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
With sodium sulfide nonahydrate In N,N-dimethyl acetamide at 80℃; for 0.5h; Inert atmosphere;
Multi-step reaction with 3 steps
1.1: potassium hydroxide / dimethyl sulfoxide / 0.33 h / 20 °C / Inert atmosphere
1.2: 1.5 h / 110 °C / Inert atmosphere
2.1: acetic acid; hydrogen bromide; dimethyl sulfoxide / water / 20 °C / Cooling with ice
3.1: triphenylphosphine / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere
3.2: 0.17 h / Inert atmosphere
View Scheme
salicylaldehyde
90-02-8

salicylaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: potassium carbonate / acetonitrile / 0.17 h / 20 °C / Inert atmosphere
1.2: 24 h / 80 °C / Inert atmosphere
2.1: 1-methyl-pyrrolidin-2-one / 15 h / 230 °C / Microwave irradiation
View Scheme
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: toluene-4-sulfonic acid / toluene / Dean-Stark
2.1: magnesium / tetrahydrofuran / 1 h / 0 °C / Reflux
2.2: 20 °C
2.3: 2 h / Reflux
View Scheme
2-(tert-butylthio)benzaldehyde
65924-65-4

2-(tert-butylthio)benzaldehyde

2-formylthiophenol
29199-11-9

2-formylthiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: acetic acid; hydrogen bromide; dimethyl sulfoxide / water / 20 °C / Cooling with ice
2.1: triphenylphosphine / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere
2.2: 0.17 h / Inert atmosphere
View Scheme
2,2'-dithiodibenzaldehyde
55164-16-4

2,2'-dithiodibenzaldehyde

acrylonitrile
107-13-1

acrylonitrile

A

2-formylthiophenol
29199-11-9

2-formylthiophenol

B

4-hydroxythiochromane-3-carbonitrile

4-hydroxythiochromane-3-carbonitrile

Conditions
ConditionsYield
Stage #1: 2,2'-dithiodibenzaldehyde With triphenylphosphine In tetrahydrofuran at 20℃; for 0.333333h; Inert atmosphere;
Stage #2: acrylonitrile In tetrahydrofuran for 0.166667h; Inert atmosphere;
2-formylthiophenol
29199-11-9

2-formylthiophenol

2,2'-dithiodibenzaldehyde
55164-16-4

2,2'-dithiodibenzaldehyde

Conditions
ConditionsYield
With triethylamine; phenylacetylene; copper(l) iodide In acetonitrile at 20℃; for 8h;100%
With oxygen; SiO2-Cl In dichloromethane at 0℃; for 0.166667h;98%
MoO2Cl2(DMSO)2 In dimethyl sulfoxide at 20℃; for 0.5h;91%
nitrostyrene
5153-67-3

nitrostyrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-3-nitro-2-phenylthiochroman-4-ol
1574615-20-5

(2R,3R,4S)-3-nitro-2-phenylthiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Solvent; Temperature; Reagent/catalyst; Inert atmosphere; enantioselective reaction;99%
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel diacetate In toluene at -40℃; for 15h;99%
1-chloro-4-(2-nitrovinyl)benzene
706-07-0

1-chloro-4-(2-nitrovinyl)benzene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(4-chlorophenyl)-3-nitrothiochroman-4-ol
1574615-21-6

(2R,3R,4S)-2-(4-chlorophenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
3-chloroβ-nitrostyrene
37888-03-2, 3156-35-2

3-chloroβ-nitrostyrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(3-chlorophenyl)-3-nitrothiochroman-4-ol
1574615-26-1

(2R,3R,4S)-2-(3-chlorophenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
4-bromo-β-nitrostyrene
3156-37-4

4-bromo-β-nitrostyrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(4-bromophenyl)-3-nitrothiochroman-4-ol
1574615-27-2

(2R,3R,4S)-2-(4-bromophenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
3-bromo-β-nitro-styrene
115665-95-7, 15795-14-9

3-bromo-β-nitro-styrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(3-bromophenyl)-3-nitrothiochroman-4-ol
1574615-29-4

(2R,3R,4S)-2-(3-bromophenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
4-fluoro-β-nitrostyrene
5153-69-5, 706-08-1

4-fluoro-β-nitrostyrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(4-fluorophenyl)-3-nitrothiochroman-4-ol
1574615-35-2

(2R,3R,4S)-2-(4-fluorophenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
3-nitro-β-nitrostyrene
882-26-8

3-nitro-β-nitrostyrene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2S,3R,4R)-3-nitro-2-(3-nitrophenyl)thiochroman-4-ol
1574615-40-9

(2S,3R,4R)-3-nitro-2-(3-nitrophenyl)thiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
1-methoxy-3-(2-nitrovinyl)benzene
3179-09-7

1-methoxy-3-(2-nitrovinyl)benzene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4S)-2-(3-methoxyphenyl)-3-nitrothiochroman-4-ol
1574615-46-5

(2R,3R,4S)-2-(3-methoxyphenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
1-methyl-3-(2-nitrovinyl)benzene
22568-43-0, 62248-93-5

1-methyl-3-(2-nitrovinyl)benzene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2S,3R,4R)-3-nitro-2-(m-tolyl)thiochroman-4-ol
1574615-52-3

(2S,3R,4R)-3-nitro-2-(m-tolyl)thiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
1-(2-thienyl)-2-nitroethene
34312-77-1

1-(2-thienyl)-2-nitroethene

2-formylthiophenol
29199-11-9

2-formylthiophenol

(2R,3R,4R)-3-nitro-2-(thiophen-2-yl)thiochroman-4-ol
1574615-57-8

(2R,3R,4R)-3-nitro-2-(thiophen-2-yl)thiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel(II) acetate tetrahydrate In toluene at -40 - 20℃; for 15h; Inert atmosphere; enantioselective reaction;99%
3-(2-bromobenzylidene)oxindole
391614-10-1

3-(2-bromobenzylidene)oxindole

2-formylthiophenol
29199-11-9

2-formylthiophenol

2'-(2”-bromophenyl)-4'-hydroxyspiro[indoline-3,3'-thiochroman]-2-one

2'-(2”-bromophenyl)-4'-hydroxyspiro[indoline-3,3'-thiochroman]-2-one

Conditions
ConditionsYield
With 2C2H3O2(1-)*Ni(2+)*C49H45N5 In toluene at -40 - 20℃; for 30h; stereoselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

3-benzylidene-6-chloroindol-2-one
387343-81-9

3-benzylidene-6-chloroindol-2-one

6-chloro-4'-hydroxy-2'-phenylspiro[indoline-3,3'-thiochroman]-2-one

6-chloro-4'-hydroxy-2'-phenylspiro[indoline-3,3'-thiochroman]-2-one

Conditions
ConditionsYield
With 2C2H3O2(1-)*Ni(2+)*C49H45N5 In toluene at -40 - 20℃; for 30h; stereoselective reaction;99%
(E)-1-methoxy-4-(2-nitrovinyl)benzene
3179-10-0, 5576-97-6

(E)-1-methoxy-4-(2-nitrovinyl)benzene

2-formylthiophenol
29199-11-9

2-formylthiophenol

A

2-(4-methoxyphenyl)-3-nitro-thiochroman-4-ol

2-(4-methoxyphenyl)-3-nitro-thiochroman-4-ol

B

(2R,3R,4S)-2-(4-methoxyphenyl)-3-nitrothiochroman-4-ol
1574615-43-2

(2R,3R,4S)-2-(4-methoxyphenyl)-3-nitrothiochroman-4-ol

Conditions
ConditionsYield
With 2-{[(1S)-N-{[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl}-1-phenylethanamino]methyl}-4,6-dibromophenol; nickel diacetate In toluene at -40℃; for 15h;A n/a
B 99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-phenylprop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-phenylprop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-phenylthiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-phenylthiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; Solvent; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(4-fluorophenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(4-fluorophenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-2-(4-fluorophenyl)-4-hydroxythiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-2-(4-fluorophenyl)-4-hydroxythiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-3-(4-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

(E)-3-(4-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

((2R,3S,4R)-2-(4-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

((2R,3S,4R)-2-(4-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-fluorophenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-fluorophenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-2-(2-fluorophenyl)-4-hydroxythiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-2-(2-fluorophenyl)-4-hydroxythiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-3-(2-chlorophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

(E)-3-(2-chlorophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

((2R,3S,4R)-2-(2-chlorophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

((2R,3S,4R)-2-(2-chlorophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-3-(2-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

(E)-3-(2-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

((2R,3S,4R)-2-(2-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

((2R,3S,4R)-2-(2-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-3-(3-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

(E)-3-(3-bromophenyl)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)prop-2-en-1-one

((2R,3S,4R)-2-(3-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

((2R,3S,4R)-2-(3-bromophenyl)-4-hydroxythiochroman-3-yl)(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-(trifluoromethyl)phenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-(trifluoromethyl)phenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(2-(trifluoromethyl)phenyl)thiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(2-(trifluoromethyl)phenyl)thiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-2-(3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-oxoprop-1-en-1-yl) Benzonitrile

(E)-2-(3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-oxoprop-1-en-1-yl) Benzonitrile

2-((2R,3S,4R)-3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridine-1-carbonyl)-4-hydroxythiochroman-2-yl)benzonitrile

2-((2R,3S,4R)-3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridine-1-carbonyl)-4-hydroxythiochroman-2-yl)benzonitrile

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-4-(3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-oxoprop-1-en-1-yl)benzonitrile

(E)-4-(3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-oxoprop-1-en-1-yl)benzonitrile

4-((2R,3S,4R)-3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridine-1-carbonyl)-4-hydroxythiochroman-2-yl)benzonitrile

4-((2R,3S,4R)-3-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridine-1-carbonyl)-4-hydroxythiochroman-2-yl)benzonitrile

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(4-nitrophenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(4-nitrophenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(4-nitrophenyl)thiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(4-nitrophenyl)thiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-methoxyphenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(2-methoxyphenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(2-methoxyphenyl)thiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(2-methoxyphenyl)thiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(3-methoxyphenyl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(3-methoxyphenyl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(3-methoxyphenyl)thiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(3-methoxyphenyl)thiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%
2-formylthiophenol
29199-11-9

2-formylthiophenol

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(naphthalen-1-yl)prop-2-en-1-one

(E)-1-(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)-3-(naphthalen-1-yl)prop-2-en-1-one

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(naphthalen-1-yl)thiochroman-3-yl)methanone

(2,3-dihydro-1H-pyrrolo[2,3-b]pyridin-1-yl)((2R,3S,4R)-4-hydroxy-2-(naphthalen-1-yl)thiochroman-3-yl)methanone

Conditions
ConditionsYield
With C31H26F6N4O2 In dichloromethane at 0℃; enantioselective reaction;99%

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