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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

(E)-(2-NITROVINYL)BENZENE

Cas:5153-67-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

5153-67-3 C8H7NO2 (E)-2-Nitroethenylbenzene CAS NO.5153-67-3

Cas:5153-67-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(E)-β-Nitrostyrene

Cas:5153-67-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

(E)-2-Nitroethenylbenzene CAS 5153-67-3

Cas:5153-67-3

Min.Order:1 Kilogram

FOB Price: $70.0 / 90.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 5153-67-3 with best quality

Cas:5153-67-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-(2-Nitrovinyl)benzene 5153-67-3

Cas:5153-67-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

(E)-2-Nitroethenylbenzene CAS:5153-67-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

(E)-2-Nitroethenylbenzene CAS:5153-67-3

Cas:5153-67-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-(2-Nitrovinyl)benzene

Cas:5153-67-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-(2-Nitrovinyl)benzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply trans-^b-Nitrostyrene

Cas:5153-67-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

(E)-(2-NITROVINYL)BENZENE

Cas:5153-67-3

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity (E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(E)-2-Nitroethenylbenzene CAS.5153-67-3

Cas:5153-67-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

(E)-2-Nitroethenylbenzene CAS.5153-67-3

Cas:5153-67-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

(E)-2-Nitroethenylbenzene CAS.5153-67-3

Cas:5153-67-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

trans-β-Nitrostyrene

Cas:5153-67-3

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(E)-2-Nitroethenylbenzene CAS.5153-67-3

Cas:5153-67-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

trans-β-Nitrostyrene cas no. 5153-67-3 98%

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzene,[(1E)-2-nitroethenyl]-

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec trans-β-Nitrostyrene 500g

Cas:5153-67-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Trans-beta-nitrostyrene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

(E)-2-Nitroethenylbenzene

Cas:5153-67-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With sulfonic acid amine MCM-41 mesoporous silica nanoparticles at 90℃; for 20h; Temperature;99%
With m-aminobenzoic acid-(L)-phenylglycinol ammonium at 20℃; for 40h;99%
With ammonium acetate In toluene at 100℃; for 22h;99%
nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
Stage #1: 2-nitro-1-phenylethan-1-ol With potassium carbonate In water for 0.25h; Green chemistry;
Stage #2: With hydrogenchloride In water pH=6; Green chemistry;
96%
With H-Y zeolite In toluene for 8h; Heating;93%
With H-Y zeolite In toluene for 8h; Product distribution; Heating; also with other zeolites;93%
styrene
292638-84-7

styrene

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In 1,2-dichloro-ethane at 70℃; for 12h; Kinetics; Reagent/catalyst; Solvent; Concentration; Molecular sieve; Inert atmosphere; stereoselective reaction;95%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In 1,4-dioxane at 80℃; for 1h; Reagent/catalyst; Solvent; Green chemistry; stereoselective reaction;95%
Stage #1: styrene With chloro-trimethyl-silane; copper(ll) sulfate pentahydrate; guanidine nitrate In acetonitrile at 0 - 20℃; Inert atmosphere;
Stage #2: With triethylamine In acetonitrile at 20℃; for 0.5h; Inert atmosphere; stereoselective reaction;
92%
[(E)-2-bromoethenyl]benzene
588-72-7

[(E)-2-bromoethenyl]benzene

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With tetranitromethane In acetonitrile Irradiation;95%
nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

B

(1,3-dinitropropan-2-yl)benzene
117538-84-8

(1,3-dinitropropan-2-yl)benzene

Conditions
ConditionsYield
aminopropyl-functionalized silica at 90℃; for 2h; Product distribution; Further Variations:; Catalysts;A 95%
B 3%
MCM-41-NHMe at 90℃; for 1h;A 81%
B n/a
With azide amine MCM-41 mesoporous silica nanoparticles at 90℃; for 20h;A 42%
B 47%
(E)-3-phenylacrylic acid
140-10-3

(E)-3-phenylacrylic acid

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With copper(II) nitrate In acetonitrile at 110℃; for 8h; Reagent/catalyst; Solvent; Temperature; Sealed tube; Green chemistry; regioselective reaction;94%
With pyridine; Iron(III) nitrate nonahydrate In toluene at 100℃; for 12h; Reagent/catalyst; Solvent;90%
With chloro-trimethyl-silane; copper(II) nitrate trihydrate In acetonitrile at 100℃; for 2h; Reagent/catalyst; stereoselective reaction;89%
nitromethane
75-52-5

nitromethane

benzaldehyde dimethyl acetal
1125-88-8

benzaldehyde dimethyl acetal

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With lepidocricite; water In acetonitrile at 105℃; for 48h; Henry Nitro Aldol Condensation; Inert atmosphere;93%
With phosphotungstic acid immobilized on amine-grafted mesoporous silica at 50℃; for 12h; Inert atmosphere;92%
With sulfonic acid and 3-aminopropyltriethoxysilane functionalized at K10-montmorillonite (SO3H-APTES at K10-MMT) at 90℃; for 2h; Reagent/catalyst; Time; Henry Nitro Aldol Condensation;99.2 %Chromat.
Stage #1: benzaldehyde dimethyl acetal With highly porous and stable acid-base bifunctional metal-organic framework chromium(III) terephthalate containing sulfonic acid and amine groups (MIL-101-NH2-SO3H) In o-xylene at 49.84℃;
Stage #2: nitromethane In o-xylene at 49.84℃; Henry Nitro Aldol Condensation;
nitromethane
75-52-5

nitromethane

benzaldehyde dimethyl acetal
1125-88-8

benzaldehyde dimethyl acetal

A

nitrostyrene
5153-67-3

nitrostyrene

B

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With FeO2H; water In acetonitrile at 105℃; for 48h; Reagent/catalyst; Henry Nitro Aldol Condensation; Inert atmosphere;A 93%
B 6%
With lepidocricite; water In acetonitrile at 80℃; for 12h; Reagent/catalyst; Henry Nitro Aldol Condensation; Inert atmosphere;A 41.6%
B 57%
C8H7NO3

C8H7NO3

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With sodium iodide; tin(ll) chloride In ethanol for 0.116667h; Reflux; Green chemistry;92%
2-phenyl-4,4,6-trimethyltetrahydro-(2H)-1,3-oxazine
31771-33-2

2-phenyl-4,4,6-trimethyltetrahydro-(2H)-1,3-oxazine

nitromethane
75-52-5

nitromethane

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With acetic acid In acetonitrile for 5h; Heating;90%
(1R*,2R*)-1,2-dibromo-2-phenyl-1-nitroethane
3425-99-8, 37887-94-8

(1R*,2R*)-1,2-dibromo-2-phenyl-1-nitroethane

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With 1-methyl-3-pentyl-1H-imidazolium tetrafluoroborate at 130 - 135℃; for 0.05h; microwave irradiation;89%
With dimethyl sulfoxide at 25℃; for 18h;51%
4-methylphenylstyryl sulfide
92550-70-4

4-methylphenylstyryl sulfide

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With tert.-butylnitrite In water at 100℃; for 12h;87%
styrene
292638-84-7

styrene

A

nitrostyrene
5153-67-3

nitrostyrene

B

benzaldehyde
100-52-7

benzaldehyde

C

benzonitrile
100-47-0

benzonitrile

D

acetophenone
98-86-2

acetophenone

E

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With formic acid; sodium nitrite In acetonitrile at 70℃; for 4h; Mechanism; Reagent/catalyst; Solvent; Temperature; Schlenk technique;A n/a
B n/a
C 84%
D n/a
E n/a
nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With CaO modified benzyl bromide at 102℃; for 5h; Reagent/catalyst; Temperature; Henry Nitro Aldol Condensation;A 15.6%
B 82.9%
aminopropyltriethoxysilane on silica-alumina at 100℃; for 6h; Product distribution; Kinetics; Further Variations:; Catalysts;A 99 % Chromat.
B n/a
nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; sodium carbonate In dimethyl sulfoxide at 20℃; for 1.5h; Inert atmosphere; Irradiation;81%
3-nitro-2-phenylpropane-1,1-dicarbonitrile

3-nitro-2-phenylpropane-1,1-dicarbonitrile

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With dmap; di-tert-butyl dicarbonate In toluene at 45 - 50℃;80%
styrene
292638-84-7

styrene

A

nitrostyrene
5153-67-3

nitrostyrene

B

2-isonitroso-1-nitro-2-phenylethane
21205-24-3

2-isonitroso-1-nitro-2-phenylethane

Conditions
ConditionsYield
With tert.-butylnitrite In dimethyl sulfoxide at 32 - 35℃; for 0.5h; Green chemistry;A 7%
B 73%
(Z)-1-Phenyl-2-(trimethylstannyl)aethen
7422-28-8, 17421-57-7, 50849-52-0

(Z)-1-Phenyl-2-(trimethylstannyl)aethen

A

nitrostyrene
5153-67-3

nitrostyrene

B

(Z)-nitrostyrene
15241-23-3

(Z)-nitrostyrene

Conditions
ConditionsYield
With tetranitromethane In dimethyl sulfoxide for 3h; Ambient temperature;A n/a
B 65%
rac-(5S,6R,7S)-5-(4-chlorophenyl)-6-nitro-7-phenyltetrahydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one

rac-(5S,6R,7S)-5-(4-chlorophenyl)-6-nitro-7-phenyltetrahydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one

A

nitrostyrene
5153-67-3

nitrostyrene

rac-(5R,6R,7S)-5-(4-chlorophenyl)-6-nitro-7-phenyltetrahydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one

rac-(5R,6R,7S)-5-(4-chlorophenyl)-6-nitro-7-phenyltetrahydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
In dimethyl sulfoxide at 110℃; for 48h;A 15%
B 61%
nitromethane
75-52-5

nitromethane

benzylamine
100-46-9

benzylamine

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With copper(II) choride dihydrate; 3-chloro-benzenecarboperoxoic acid at 0 - 60℃; for 10h; Henry Nitro Aldol Condensation; Inert atmosphere;61%
Cinnamic acid
621-82-9

Cinnamic acid

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; sodium nitrite for 0.133333h; Microwave irradiation;57%
nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

isovaleraldehyde
590-86-3

isovaleraldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

B

(2S,3R)-2-(prop-2-yl)-3-phenylbutanal

(2S,3R)-2-(prop-2-yl)-3-phenylbutanal

C

2-(prop-2-yl)-3-phenylbutanal
1000072-29-6

2-(prop-2-yl)-3-phenylbutanal

Conditions
ConditionsYield
Stage #1: nitromethane; benzaldehyde With O-(tert-butyldiphenylsilyl)-L-tyrosine lithium salt; magnesium sulfate In dichloromethane at 25℃; for 48h;
Stage #2: isovaleraldehyde In dichloromethane at 25℃; for 72h; Michael addition; optical yield given as %ee; enantioselective reaction;
A 50%
B n/a
C n/a
Nitroethane
79-24-3

Nitroethane

benzene
71-43-2

benzene

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver(I) acetate In 1,2-dimethoxyethane; dimethyl sulfoxide at 100℃; for 24h; Glovebox; Schlenk technique; Inert atmosphere; regioselective reaction;50%
styrene
292638-84-7

styrene

A

nitrostyrene
5153-67-3

nitrostyrene

B

phenyl (5-phenyl-4,5-dihydroisoxazol-3-yl)methanone
7064-02-0

phenyl (5-phenyl-4,5-dihydroisoxazol-3-yl)methanone

Conditions
ConditionsYield
With tert.-butylnitrite; manganese(III) triacetate dihydrate In acetonitrile at 20℃; for 5h; Schlenk technique; Inert atmosphere;A 50%
B 5%
trans-2-phenylvinylboronic acid
6783-05-7

trans-2-phenylvinylboronic acid

nitrostyrene
5153-67-3

nitrostyrene

Conditions
ConditionsYield
With dipotassium peroxodisulfate; bismuth (III) nitrate pentahydrate In benzene at 70℃; for 12h; Inert atmosphere;48%
nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

B

(S)-1-phenyl-2-nitroethanol
149495-00-1

(S)-1-phenyl-2-nitroethanol

Conditions
ConditionsYield
With bis(α-ethylphenylamine) cupric chloride In methanol at 20℃; for 72h; Henry reaction; optical yield given as %ee; enantioselective reaction;A 46%
B n/a
styrene
292638-84-7

styrene

A

nitrostyrene
5153-67-3

nitrostyrene

B

2-nitro-1-phenylethyl nitrate

2-nitro-1-phenylethyl nitrate

Conditions
ConditionsYield
With peroxynitrous acid In acetonitrile at 5 - 10℃; for 1h;A 45%
B n/a
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

B

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal
1089665-81-5

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal

C

(2S,3R)-4-nitro-2-(1-phenylmethyl)-3-phenylbutanal
1021394-80-8

(2S,3R)-4-nitro-2-(1-phenylmethyl)-3-phenylbutanal

D

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal
1235612-22-2

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal

Conditions
ConditionsYield
Stage #1: nitromethane; benzaldehyde With O-(tert-butyldiphenylsilyl)-L-tyrosine lithium salt; magnesium sulfate In dichloromethane at 25℃; for 48h;
Stage #2: 3-phenyl-propionaldehyde In dichloromethane at 25℃; for 72h; Michael addition; enantioselective reaction;
A 43%
B n/a
C n/a
D n/a

A

nitrostyrene
5153-67-3

nitrostyrene

B

(S)-1-phenyl-2-nitroethanol
149495-00-1

(S)-1-phenyl-2-nitroethanol

C

(R)-2-nitro-1-phenylethanol
145920-96-3

(R)-2-nitro-1-phenylethanol

Conditions
ConditionsYield
With vinyl acetate; Pseudomonas fluorescens amino lipase In hexane; toluene at 30℃; for 48h; Title compound not separated from byproducts;A 40%
B n/a
C n/a
nitromethane
75-52-5

nitromethane

benzaldehyde
100-52-7

benzaldehyde

A

nitrostyrene
5153-67-3

nitrostyrene

B

(S)-1-phenyl-2-nitroethanol
149495-00-1

(S)-1-phenyl-2-nitroethanol

C

(R)-2-nitro-1-phenylethanol
145920-96-3

(R)-2-nitro-1-phenylethanol

Conditions
ConditionsYield
With bis(α-ethylphenylamine) copper acetate In methanol at 20℃; for 72h; Henry reaction; optical yield given as %ee; enantioselective reaction;A 40%
B n/a
C n/a
With bis(α-ethylphenylamine) zinc acetate In methanol at 20℃; for 72h; Henry reaction; optical yield given as %ee; enantioselective reaction;A 32%
B n/a
C n/a
nitrostyrene
5153-67-3

nitrostyrene

2-Phenylnitroethane
6125-24-2

2-Phenylnitroethane

Conditions
ConditionsYield
With magnesium(II) perchlorate; model of NADH grafted on silica matrix In acetonitrile at 65℃; for 120h;100%
With sodium tetrahydroborate; silica gel In chloroform; isopropyl alcohol at 0 - 23℃; for 1.33333h; Inert atmosphere;99%
With hydrogen; tris(triphenylphosphine)rhodium(l) chloride In benzene at 50℃; under 2585.81 Torr; for 14h;98%
nitrostyrene
5153-67-3

nitrostyrene

5-carbamoyl thieno<2,3-b>pyridine
117390-40-6

5-carbamoyl thieno<2,3-b>pyridine

bromo-8 octyl dimethylchlorosilane
125056-17-9

bromo-8 octyl dimethylchlorosilane

2-Phenylnitroethane
6125-24-2

2-Phenylnitroethane

Conditions
ConditionsYield
With magnesium(II) perchlorate; silice (Merck Kieselgel Art.:7734) Product distribution; multistep reaction; 1.) grafting on a silica matrix, reflux, in toluene, 12 h, 2.) reflux, toluene, 5 days. 3.) acetonitrile, 65 deg C, 5 days; reagent quqntity, reaction time varied;100%
nitrostyrene
5153-67-3

nitrostyrene

(1,4-dinitrobutane-2,3-diyl)dibenzene
60947-52-6

(1,4-dinitrobutane-2,3-diyl)dibenzene

Conditions
ConditionsYield
With samarium diiodide; isopropylamine In water100%
With tetraethylammonium tosylate In water; N,N-dimethyl-formamide at 0℃; Electrolysis;71%
With titanium(III) chloride; ammonium acetate In tetrahydrofuran; water at 0℃; for 0.5h;6%
nitrostyrene
5153-67-3

nitrostyrene

diethylzinc
557-20-0

diethylzinc

(1-nitromethyl-propyl)-benzene
119880-63-6, 7796-78-3

(1-nitromethyl-propyl)-benzene

Conditions
ConditionsYield
With chiral (OCHPhCHMeN(i-Pr))PNMe2; copper(I) triflate In hexane; toluene at -30℃; for 3h; Addition;100%
copper(I) 2-(Me2NCH2)-3-(Me3Si)-naphthalene-1-thiolate In diethyl ether; hexane at -20℃; for 4h; Michael addition;98%
With magnesium bromide In diethyl ether for 1h; Ambient temperature;92%
indole
120-72-9

indole

nitrostyrene
5153-67-3

nitrostyrene

3-(2-nitro-1-phenylethyl)-1H-indole
51626-47-2

3-(2-nitro-1-phenylethyl)-1H-indole

Conditions
ConditionsYield
Stage #1: nitrostyrene With 2-[(S)-4-isopropyl-4,5-dihydrooxazol-2-yl]-N-[2-(-4-phenyl-4,5-dihydrothiazol-2-yl)phenyl]benzenamine; zinc trifluoromethanesulfonate In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: indole In toluene at -20℃; for 15h; Friedel Crafts alkylation; Inert atmosphere;
100%
With Zn(2+)*2C6H6NO2S2(1-) In ethanol at 20℃; for 24h; Solvent; Reagent/catalyst;100%
Stage #1: nitrostyrene With (S)-10,10'-bis[(S)-4-isopropyl-4,5-dihydrooxazol-2-yl]-9,9'-biphenanthrene; samarium trifluoromethanesulfonate In chloroform at 20℃; for 0.25h; Inert atmosphere;
Stage #2: indole In chloroform at 20℃; for 18h; Friedel-Crafts alkylation; Inert atmosphere;
99%
1-methylindole
603-76-9

1-methylindole

nitrostyrene
5153-67-3

nitrostyrene

1-methyl-3-(2-nitro-1-phenylethyl)-1H-indole
109811-96-3

1-methyl-3-(2-nitro-1-phenylethyl)-1H-indole

Conditions
ConditionsYield
With Zn(2+)*2C6H6NO2S2(1-) In ethanol at 20℃; for 24h;100%
With 1H-pyrrolo[2,3-b]pyridinium substituted-borate salt In toluene at 0 - 20℃; for 24h;99%
Stage #1: nitrostyrene With (S)-10,10'-bis[(S)-4-isopropyl-4,5-dihydrooxazol-2-yl]-9,9'-biphenanthrene; zinc(II) trifluoroacetate In diethyl ether at 20℃; for 0.25h; Inert atmosphere;
Stage #2: 1-methylindole In diethyl ether at 20℃; Friedel-Crafts alkylation; Inert atmosphere;
99%
nitrostyrene
5153-67-3

nitrostyrene

cycloheptane
291-64-5

cycloheptane

(E)-(2-cycloheptylethenyl)benzene

(E)-(2-cycloheptylethenyl)benzene

Conditions
ConditionsYield
With dibenzoyl peroxide In benzene for 6h; Heating;100%
nitrostyrene
5153-67-3

nitrostyrene

Cyclooctan
292-64-8

Cyclooctan

(E)-β-cyclooctylstyrene

(E)-β-cyclooctylstyrene

Conditions
ConditionsYield
With dibenzoyl peroxide In benzene for 12h; Heating;100%
With di-tert-butyl peroxide; copper diacetate In 1,2-dichloro-ethane at 100℃; Schlenk technique; Inert atmosphere;86%
With di-tert-butyl peroxide; copper In 1,2-dichloro-ethane at 110℃; for 8h; Sealed tube; Inert atmosphere; Schlenk technique;85%
nitrostyrene
5153-67-3

nitrostyrene

cyclohexanone
108-94-1

cyclohexanone

(S)-2-[(R)-2-nitro-1-phenylethyl]cyclohexanone
4591-64-4, 51262-17-0, 51262-18-1, 84025-84-3, 84025-87-6, 84025-83-2

(S)-2-[(R)-2-nitro-1-phenylethyl]cyclohexanone

Conditions
ConditionsYield
With 1-[(S)-2'-methylpyrrolidine]-4-aza-1-azoniabicyclo[2.2.2]octane tetrafluoroborate at 20℃; for 22h; Michael addition; Ionic liquid; optical yield given as %ee; enantioselective reaction;100%
With (S)-6-phenyl-3-[(S)-pyrrolidin-2-ylmethyl]-2-thioxotetrahydropyrimidin-4(1H)-one; water; 4-nitro-benzoic acid In tetrahydrofuran for 18h; Michael reaction; optical yield given as %ee; enantioselective reaction;100%
With 4-nitro-benzoic acid; (S)-6-phenyl-3-[(S)-pyrrolidin-2-ylmethyl]-2-thioxotetrahydropyrimidin-4(1H)-one In tetrahydrofuran; water Product distribution / selectivity; Michael Reaction;100%
nitrostyrene
5153-67-3

nitrostyrene

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

dimethyl [(1S)-2-nitro-1-phenylethyl]malonate

dimethyl [(1S)-2-nitro-1-phenylethyl]malonate

Conditions
ConditionsYield
With calcium p-methoxyphenolate; anti-5,4-diphenyl pyridinebisoxazoline In toluene at -20℃; for 432h; Michael condensation; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;100%
With C34H46N4*Ni(2+)*2Br(1-) In dichloromethane at 4℃; for 16h; Catalytic behavior; Solvent; Michael Addition; enantioselective reaction;99%
With (5,7-bis(trifluoromethyl)-1H-benzoimidazol-2-yl)-9-epiquinine amine In dichloromethane at -20℃; for 40h; asymmetric Michael addition; Inert atmosphere; optical yield given as %ee; enantioselective reaction;98%
Tetrahydro-4H-pyran-4-one
29943-42-8

Tetrahydro-4H-pyran-4-one

nitrostyrene
5153-67-3

nitrostyrene

(R)-tetrahydro-3-((R)-2-nitro-1-phenylethyl)pyran-4-one

(R)-tetrahydro-3-((R)-2-nitro-1-phenylethyl)pyran-4-one

Conditions
ConditionsYield
With 1-[(S)-2'-methylpyrrolidine]-4-aza-1-azoniabicyclo[2.2.2]octane tetrafluoroborate at 20℃; for 17h; Michael addition; Ionic liquid; optical yield given as %ee; enantioselective reaction;100%
With bis(((S)-pyrrolidin-2-yl)methyl) phosphonate dihydrochloride; sodium hydrogencarbonate at 20℃; for 17h; Michael condensation; Ionic liquid; optical yield given as %ee; enantioselective reaction;98%
Stage #1: Tetrahydro-4H-pyran-4-one With N-((S)-1-phenylethyl)-5-((S)-pyrrolidin-2-yl)oxazole-4-carboxamide; acetic acid In neat (no solvent) at 20℃; for 0.0833333h; Michael Addition;
Stage #2: nitrostyrene In neat (no solvent) at 20℃; for 30h; Reagent/catalyst; Michael Addition; stereoselective reaction;
95%
nitrostyrene
5153-67-3

nitrostyrene

tris(allyl)aluminum
18854-66-5

tris(allyl)aluminum

1-nitro-2-phenylpent-4-ene

1-nitro-2-phenylpent-4-ene

Conditions
ConditionsYield
Stage #1: nitrostyrene; tris(allyl)aluminum In diethyl ether at 0℃; for 0.0333333h;
Stage #2: With hydrogen bromide In diethyl ether at 0℃; Further stages.;
100%
nitrostyrene
5153-67-3

nitrostyrene

1-methyl-1-propanethiol
513-53-1

1-methyl-1-propanethiol

C12H17NO2S
1012859-62-9

C12H17NO2S

Conditions
ConditionsYield
In water at 20℃; for 4h; Michael-type addition;100%
nitrostyrene
5153-67-3

nitrostyrene

ethanethiol
75-08-1

ethanethiol

(1-Ethylsulfanyl-2-nitro-ethyl)-benzene
25408-68-8

(1-Ethylsulfanyl-2-nitro-ethyl)-benzene

Conditions
ConditionsYield
In water at 20℃; for 4h; Michael-type addition;100%
nitrostyrene
5153-67-3

nitrostyrene

N-((1S)-1-phenylethyl)hydroxylamine
53933-47-4

N-((1S)-1-phenylethyl)hydroxylamine

C16H18N2O3

C16H18N2O3

Conditions
ConditionsYield
In tetrahydrofuran100%
nitrostyrene
5153-67-3

nitrostyrene

acetone
67-64-1

acetone

(R)-5-nitro-4-phenylpentan-2-one

(R)-5-nitro-4-phenylpentan-2-one

Conditions
ConditionsYield
With (S)-di-tert-butyl 2-{3-[(1S,2S)-2-amino-1,2-diphenylethyl]thioureido}succinate; acetic acid In water; toluene at 20℃; for 48h; Michael reaction; optical yield given as %ee; enantioselective reaction;100%
Stage #1: acetone With ((S)-pyrrolidin-2-yl)methyl phenylcarbamate In toluene at 20℃; for 0.5h; Michael Addition;
Stage #2: nitrostyrene In toluene at 20℃; for 24h; Michael Addition; stereoselective reaction;
93%
With water; O,O-diethyl [(1S,2S)-2-amino-1,2-diphenylethyl]phosphoramidothioate; acetic acid In toluene at 70℃; for 24h; Reagent/catalyst; Solvent; Temperature; Michael Addition; enantioselective reaction;90%
nitrostyrene
5153-67-3

nitrostyrene

isovaleraldehyde
590-86-3

isovaleraldehyde

(2S,3R)-2-isopropyl-4-nitro-3-phenylbutanal

(2S,3R)-2-isopropyl-4-nitro-3-phenylbutanal

Conditions
ConditionsYield
With : H-D-Pro-Pro-Glu supported on polyethyleneglycol-polystyrene (TentaGel resin) In chloroform; isopropyl alcohol at -15℃; for 72h; optical yield given as %ee; enantioselective reaction;100%
With 4-methyl-morpholine; C16H26N4O5 In neat (no solvent) at 20℃; for 72h; stereoselective reaction;96%
With 4-methyl-morpholine; H-D-Pro-L-Pro-L-Glu-NH2*TFA In chloroform; isopropyl alcohol at 20℃; for 48h; optical yield given as %ee; stereoselective reaction;93%
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

nitrostyrene
5153-67-3

nitrostyrene

(2S,3R)-4-nitro-2-(1-phenylmethyl)-3-phenylbutanal
1021394-80-8

(2S,3R)-4-nitro-2-(1-phenylmethyl)-3-phenylbutanal

Conditions
ConditionsYield
With 4-methyl-morpholine; C16H26N4O5 In neat (no solvent) at 20℃; for 24h; stereoselective reaction;100%
With 4-methyl-morpholine; (R)-2-(((2S,3S,4R)-2-((2-carboxyethoxy)methyl)-4-methoxytetrahydro-2H-pyran-3-yl)carbamoyl)pyrrolidin-1-ium 2,2,2-trifluoroacetate In dichloromethane at 20℃; for 22h; Michael Addition; Inert atmosphere; stereoselective reaction;97%
With 4-methyl-morpholine; H-D-Pro-L-Pro-L-Glu-NH2*TFA In chloroform; isopropyl alcohol at 20℃; optical yield given as %ee; enantioselective reaction;94%
nitrostyrene
5153-67-3

nitrostyrene

propionaldehyde
123-38-6

propionaldehyde

(2S,3R)-2-methyl-4-nitro-3-phenylbutanal
475294-87-2

(2S,3R)-2-methyl-4-nitro-3-phenylbutanal

Conditions
ConditionsYield
With : H-D-Pro-Pro-Glu supported on polyethyleneglycol-polystyrene (TentaGel resin) In chloroform; isopropyl alcohol at -15℃; for 17h; optical yield given as %ee; enantioselective reaction;100%
With (S)-2-(triphenylsilyl)pyrrolidine In hexane at -20℃; for 48h; Michael reaction; optical yield given as %de; diastereoselective reaction;97%
With 4-methyl-morpholine; C16H26N4O5 In neat (no solvent) at 20℃; for 24h; stereoselective reaction;96%
nitrostyrene
5153-67-3

nitrostyrene

butyraldehyde
123-72-8

butyraldehyde

(2S,3R)-2-ethyl-4-nitro-3-phenylbutanal

(2S,3R)-2-ethyl-4-nitro-3-phenylbutanal

Conditions
ConditionsYield
With : H-D-Pro-Pro-Glu supported on polyethyleneglycol-polystyrene (TentaGel resin) In chloroform; isopropyl alcohol at -15℃; for 20h; optical yield given as %ee; enantioselective reaction;100%
With 4-methyl-morpholine; (R)-2-(((2S,3S,4R)-2-((2-carboxyethoxy)methyl)-4-methoxytetrahydro-2H-pyran-3-yl)carbamoyl)pyrrolidin-1-ium 2,2,2-trifluoroacetate In dichloromethane at 20℃; for 22h; Michael Addition; Inert atmosphere; stereoselective reaction;97%
With 4-methyl-morpholine; H-D-Pro-L-Pro-L-Glu-NH2*TFA In chloroform; isopropyl alcohol at 20℃; optical yield given as %ee; enantioselective reaction;96%
nitrostyrene
5153-67-3

nitrostyrene

hexanal
66-25-1

hexanal

(+)-(2S)-2-[(R)-2-nitro-1-phenyl-ethyl]-hexanal

(+)-(2S)-2-[(R)-2-nitro-1-phenyl-ethyl]-hexanal

Conditions
ConditionsYield
With : H-D-Pro-Pro-Glu supported on polyethyleneglycol-polystyrene (TentaGel resin) In chloroform; isopropyl alcohol at -15℃; for 19h; optical yield given as %ee; enantioselective reaction;100%
With 4-methyl-morpholine; C16H26N4O5 In neat (no solvent) at 20℃; for 24h; stereoselective reaction;100%
With 4-methyl-morpholine; H-D-Pro-L-Pro-L-Glu-NH2*TFA In chloroform; isopropyl alcohol at 20℃; optical yield given as %ee; enantioselective reaction;98%
nitrostyrene
5153-67-3

nitrostyrene

1-nitro-4-(2-nitrovinyl)benzene
3156-41-0

1-nitro-4-(2-nitrovinyl)benzene

(S)-2-((R)-2-nitro-1-(4-nitrophenyl)ethyl)cyclohexanone

(S)-2-((R)-2-nitro-1-(4-nitrophenyl)ethyl)cyclohexanone

Conditions
ConditionsYield
With (S)-6-phenyl-3-[(S)-pyrrolidin-2-ylmethyl]-2-thioxotetrahydropyrimidin-4(1H)-one; water; 4-nitro-benzoic acid In tetrahydrofuran for 18h; Michael reaction; optical yield given as %ee; enantioselective reaction;100%
nitrostyrene
5153-67-3

nitrostyrene

1,3-dimethylbarbituric acid
769-42-6

1,3-dimethylbarbituric acid

1,3-dimethyl-5-(2-nitro-1-phenylethyl)pyrimidine-2,4,6(1H,3H,5H)-trione

1,3-dimethyl-5-(2-nitro-1-phenylethyl)pyrimidine-2,4,6(1H,3H,5H)-trione

Conditions
ConditionsYield
With 2Zn(2+)*2NO3(1-)*2C3H7NO*2Y(3+)*4C14H11NO3(2-) In ethanol; water at 20℃; for 0.25h; Reagent/catalyst; Michael Addition;100%
With water; diethylamine at 20℃; for 1h; Reagent/catalyst; Time; Michael Addition; Green chemistry;99%
nitrostyrene
5153-67-3

nitrostyrene

6-amino-1,3-dimethylbarbituric acid
104497-09-8

6-amino-1,3-dimethylbarbituric acid

6-amino-1,3-dimethyl-5-(2-nitro-1-phenylethyl)pyrimidine-2,4(1H,3H)-dione
95834-23-4

6-amino-1,3-dimethyl-5-(2-nitro-1-phenylethyl)pyrimidine-2,4(1H,3H)-dione

Conditions
ConditionsYield
With 2Zn(2+)*2NO3(1-)*2C3H7NO*2Y(3+)*4C14H11NO3(2-) In ethanol; water at 20℃; for 0.25h; Michael Addition;100%
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

nitrostyrene
5153-67-3

nitrostyrene

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal
1089665-81-5

2-benzyl-2-(2-nitro-1-phenylethyl)ethanal

Conditions
ConditionsYield
With 4-methyl-morpholine; (S)-2-(((2S,3R)-2-((2-carboxyethoxy)methyl)tetrahydro-2H-pyran-3-yl)carbamoyl)pyrrolidin-1-ium 2,2,2-trifluoroacetate In dichloromethane at 20℃; for 19h; Michael Addition; Inert atmosphere; stereoselective reaction;100%
2-methyl-1H-indole
95-20-5

2-methyl-1H-indole

nitrostyrene
5153-67-3

nitrostyrene

2-methyl-3-(2-nitro-1-phenylethyl)-1H-indole
109809-52-1

2-methyl-3-(2-nitro-1-phenylethyl)-1H-indole

Conditions
ConditionsYield
With aminosulfonic acid at 60℃; for 0.5h; Michael addition;99%
Stage #1: nitrostyrene With (S)-10,10'-bis[(S)-4-isopropyl-4,5-dihydrooxazol-2-yl]-9,9'-biphenanthrene; zinc(II) trifluoroacetate In diethyl ether at 20℃; for 0.25h; Inert atmosphere;
Stage #2: 2-methyl-1H-indole In diethyl ether at 20℃; Friedel-Crafts alkylation; Inert atmosphere;
99%
With pyrrolidinium 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate at 50℃; for 12h; Friedel Crafts alkylation;99%
nitrostyrene
5153-67-3

nitrostyrene

ethyl acetoacetate
141-97-9

ethyl acetoacetate

ethyl 2-acetyl-4-nitro-3-phenylbutyrate
72709-62-7

ethyl 2-acetyl-4-nitro-3-phenylbutyrate

Conditions
ConditionsYield
With lithium phenolate; (S)-3,3′-bis[hydroxy(diphenyl)methyl]-1,1′-binaphthalene-2,2′-diol In dichloromethane at 20℃; for 48h; Michael reaction; Inert atmosphere;99%
With triethylamine at 20℃; Michael Addition; Green chemistry;99%
bis(acetylacetonate)nickel(II) In 1,4-dioxane at 90℃; for 17h;98%
nitrostyrene
5153-67-3

nitrostyrene

acetylacetone
123-54-6

acetylacetone

(+/-)-3-(2-nitro-1-phenylethyl)pentane-2,4-dione
72709-61-6

(+/-)-3-(2-nitro-1-phenylethyl)pentane-2,4-dione

Conditions
ConditionsYield
With triethylamine at 20℃; Michael Addition; Green chemistry;99%
With N21,N23-bis(4-bromobenzyl)-2-(((2-(pyridin-3-yl)ethyl)amino)methyl)-5,10,15,20-tetrakis(3,5-ditert-butyl-4-oxo-cyclohexa-2,5-dienylidene)porphyrinogen In ethanol at 20℃; for 16h; Catalytic behavior; Kinetics; Reagent/catalyst; Solvent; Michael Addition; Inert atmosphere;99%
With 1-methyl-3-(2-(piperidin-1-yl)ethyl)-1H-imidazol-3-ium-chloride In neat (no solvent) at 20℃; for 0.5h; Reagent/catalyst; Time; Michael Addition; Sonication;98%
nitrostyrene
5153-67-3

nitrostyrene

diethyl malonate
105-53-3

diethyl malonate

diethyl 2-(3-nitrophenylethyl)malonate
71639-13-9

diethyl 2-(3-nitrophenylethyl)malonate

Conditions
ConditionsYield
With lithium phenolate; (S)-3,3′-bis[hydroxy(diphenyl)methyl]-1,1′-binaphthalene-2,2′-diol In dichloromethane at 20℃; for 48h; Michael reaction; Inert atmosphere;99%
With triethylamine at 20℃; Michael Addition; Green chemistry;99%
With C16H25N5S In tetrahydrofuran at 25℃; for 2h; Michael Addition;96%

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