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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5-Chloro-o-anisic acid methyl ester (COOCH3=1)

Cas:33924-48-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 33924-48-0 with best quality

Cas:33924-48-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid,5-chloro-2-methoxy-, methyl ester 33924-48-0

Cas:33924-48-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid,5-chloro-2-methoxy-, methyl ester

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzoic acid,5-chloro-2-methoxy-, methyl ester

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

CAS33924-48-0

Cas:33924-48-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Greenutra Resource Inc

Methyl 5-chloro-2-methoxybenzoateAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Methyl 5-chloro-2-Methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Manufacturers

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Methyl-5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl 5-chloro-2-methoxybenzoate, 98%

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Appearance & Physical State White to light yellow crystal powder Density 1.259 Boiling Point 235-240ºC Melting Point 150-152ºC Flash P

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Antimex Chemical Limied

Methyl 5-chloro-2-methoxybenzoateAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Methyl 5-chloro-2-methoxybenzoate cas 33924-48-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methyl 5-chloro-2-methoxybenzoate cas 33924-48-0

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

33924-48-0

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL 5-CHLORO-2-METHOXYBENZOATE

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Trading Company

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Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

Methyl 5-chloro-2-methoxybenzoate

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

5-chloro-2-methoxybenzoic acid methyl ester

Cas:33924-48-0

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%4) We are manufactureAp

Methyl 5-chloro-2-methoxybenzoate manufacturer

Cas:33924-48-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With N-chloro-succinimide; silver hexafluoroantimonate; 1-methylthiotriptycene In 1,2-dichloro-ethane at 20℃; for 2h; Inert atmosphere; Schlenk technique;91%
With sodium persulfate; tris(bipyridine)ruthenium(II) dichloride hexahydrate; sodium chloride In water; acetonitrile at 25℃; for 15h; Irradiation;73 %Spectr.
5-chloro-2-hydroxybenzoic acid
321-14-2

5-chloro-2-hydroxybenzoic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With sodium hydroxide; tetra-(n-butyl)ammonium iodide In dichloromethane; water at 20℃; for 4h;46%
With sodium hydroxide
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water for 4h; Ambient temperature;
Stage #1: 5-chloro-2-hydroxybenzoic acid With sodium hydroxide In water at 37℃; for 0.5h; pH=10;
Stage #2: dimethyl sulfate In water for 3h; pH=10;
methanol
67-56-1

methanol

5-chloro-2-methoxybenzoic acid
3438-16-2

5-chloro-2-methoxybenzoic acid

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With hydrogenchloride
2-methoxy-5-chlorobenzonitrile
55877-79-7

2-methoxy-5-chlorobenzonitrile

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous-alcoholic KOH-solution
2: hydrogen chloride
View Scheme
5-chloro-2-hydroxybenzoic acid
321-14-2

5-chloro-2-hydroxybenzoic acid

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With potassium carbonate; dimethyl sulfate In acetone23.10 g (99%)
p-(5-chloro-2-methoxybenzamidoethyl)-benzenesulfonic acid

p-(5-chloro-2-methoxybenzamidoethyl)-benzenesulfonic acid

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With thionyl chloride In N-methyl-acetamide; benzene
5-chloro-2-hydroxybenzoic acid
321-14-2

5-chloro-2-hydroxybenzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; Reflux; Darkness;
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: triisobutylaluminum; 2,2,6,6-tetramethyl-piperidine; n-butyllithium / tetrahydrofuran; hexane / 3 h / -78 - 20 °C
1.2: 3 h / -78 - 20 °C / 760.05 Torr
2.1: toluene; methanol / Inert atmosphere
View Scheme
5-chloro-2-methoxybenzoic acid
3438-16-2

5-chloro-2-methoxybenzoic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

Conditions
ConditionsYield
In methanol; toluene Inert atmosphere;86.3 mg
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

methyl 2-methoxy-5-sulfamoyl-benzoate
33045-52-2

methyl 2-methoxy-5-sulfamoyl-benzoate

Conditions
ConditionsYield
With sodium sulfamate; copper(I) bromide In tetrahydrofuran at 50℃; for 10h; Temperature; Reflux;96.55%
With sodium aminosulfinate; copper(I) bromide In tetrahydrofuran at 40℃; for 18h; Concentration; Temperature;96.55%
With sodium aminosulfinate; copper(l) chloride In tetrahydrofuran at 40℃; for 8h; Temperature;96.55%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

acetonitrile
75-05-8

acetonitrile

3-(5-chloro-2-methoxyphenyl)-3-oxopropanenitrile
69316-10-5

3-(5-chloro-2-methoxyphenyl)-3-oxopropanenitrile

Conditions
ConditionsYield
Stage #1: acetonitrile With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran; hexane at -78℃; for 0.666667h;
94%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

methyl 2-methoxy-5-(p-methylphenyl)benzoate
1271315-60-6

methyl 2-methoxy-5-(p-methylphenyl)benzoate

Conditions
ConditionsYield
With Ni(Cl){2-(Ph2P)C6H4NCH(Ph)P(O)Ph2} In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25℃; for 24h; Negishi coupling reaction; Inert atmosphere;93%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

3-chloro-6-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic acid methyl ester
1146214-97-2

3-chloro-6-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic acid methyl ester

Conditions
ConditionsYield
With silica-SMAP-Ir(OCH3)(C8H12) In hexane ligand reacted with B-compound in hexane in presence of Ir-complex as catalyst at 25°C for 4 h;85%
With Silica-SMAP-Ir(OMe)(cod) In hexane at 25℃; for 4h; Autoclave; regioselective reaction;85%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

5-chloro-2-methoxybenzoic acid
3438-16-2

5-chloro-2-methoxybenzoic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃;83%
With water; sodium hydroxide In ethanol at 15 - 30℃; for 4h;74.9%
With sodium hydroxide for 16h; Ambient temperature; Yield given;
With sodium hydroxide In 1,4-dioxane
With water at 80℃; for 0.25h;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

(5-chloro-2-methoxyphenyl)methanol
7035-10-1

(5-chloro-2-methoxyphenyl)methanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 2h;73.5%
In tetrahydrofuran
In tetrahydrofuran
With lithium aluminium tetrahydride In tetrahydrofuran for 2h; Heating / reflux;
With lithium aluminium tetrahydride In diethyl ether for 2h; Cooling with ice;
1-Chlorooctane
111-85-3

1-Chlorooctane

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

methyl 2-methoxy-5-octylbenzoate

methyl 2-methoxy-5-octylbenzoate

Conditions
ConditionsYield
With nickel(II) bromide dimethoxyethane; pyridine-2,6-bis(N-cyanocarboxamidine); lithium chloride; zinc In 1-methyl-pyrrolidin-2-one at 80℃; for 23h; Inert atmosphere;59%
pyrrolidine
123-75-1

pyrrolidine

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

(5-chloro-2-methoxyphenyl)(pyrrolidin-1-yl)methanone

(5-chloro-2-methoxyphenyl)(pyrrolidin-1-yl)methanone

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; for 2h;56%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

cyclooctylguanidine sulfate
75230-36-3

cyclooctylguanidine sulfate

N-(5-Chloro-2-methoxy-benzoyl)-N'-cyclooctyl-guanidine; hydrochloride
75230-19-2

N-(5-Chloro-2-methoxy-benzoyl)-N'-cyclooctyl-guanidine; hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; sodium In methanol for 5h; Ambient temperature;55.4%
4-methoxyphenyl triflate
66107-29-7

4-methoxyphenyl triflate

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

methyl 4,4'-dimethoxy-[1,1'-biphenyl]-3-carboxylate

methyl 4,4'-dimethoxy-[1,1'-biphenyl]-3-carboxylate

Conditions
ConditionsYield
With nickel(II) chloride2-methoxyethyl ether; 1,4-di(diphenylphosphino)-butane; 4,4'-di-tert-butyl-2,2'-bipyridine; lithium chloride; palladium dichloride; zinc In 1-methyl-pyrrolidin-2-one; N,N-dimethyl-formamide at 20 - 80℃; for 24h; Ullmann Condensation; Inert atmosphere;45%
1-(imino(4-methylpiperazin-1-yl)methyl)guanidine dihydrochloride

1-(imino(4-methylpiperazin-1-yl)methyl)guanidine dihydrochloride

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

4-(4-methylpiperazin-1-yl)-6-(3-chloro-6-methoxyphenyl)-1,3,5-triazin-2-amine
1620567-89-6

4-(4-methylpiperazin-1-yl)-6-(3-chloro-6-methoxyphenyl)-1,3,5-triazin-2-amine

Conditions
ConditionsYield
With methanol; sodium Reflux;31%
1-(3,4-methylenedioxyphenyl)biquanidine hydrochloride

1-(3,4-methylenedioxyphenyl)biquanidine hydrochloride

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

N-BENZO[1,3]DIOXOL-5-YL-6-(5-CHLORO-2-METHOXYPHENYL)-[1,3,5]TRIAZINE-2,4-DIAMINE
521064-26-6

N-BENZO[1,3]DIOXOL-5-YL-6-(5-CHLORO-2-METHOXYPHENYL)-[1,3,5]TRIAZINE-2,4-DIAMINE

Conditions
ConditionsYield
28%
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

6-(5-chloro-2-methoxy-phenyl)-N-phenyl-[1,3,5]triazine-2,4-diamine
68215-85-0

6-(5-chloro-2-methoxy-phenyl)-N-phenyl-[1,3,5]triazine-2,4-diamine

Conditions
ConditionsYield
With sodium ethanolate In ethanol; water27%
2-acetyl-1-tetralone
17216-08-9

2-acetyl-1-tetralone

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

1-(5-Chloro-2-methoxyphenyl)-3-(1,2,3,4-tetrahydro-1-oxo-2-naphthalenyl)-1,3-propanedione
108506-68-9

1-(5-Chloro-2-methoxyphenyl)-3-(1,2,3,4-tetrahydro-1-oxo-2-naphthalenyl)-1,3-propanedione

Conditions
ConditionsYield
With sodium hydride In 1,2-dimethoxyethane for 6h; Heating;
2-acetyl-6-allylphenol
58621-39-9

2-acetyl-6-allylphenol

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

8-Allyl-2-(5-chloro-2-methoxy-phenyl)-chromen-4-one
198351-09-6

8-Allyl-2-(5-chloro-2-methoxy-phenyl)-chromen-4-one

Conditions
ConditionsYield
With sulfuric acid; sodium hydride 1) THF, reflux, 5 h, 2) THF, MeOH, reflux, 3 h; Yield given. Multistep reaction;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

5-chloro-2-methoxy-phenyl magnesium bromide

5-chloro-2-methoxy-phenyl magnesium bromide

tris-(5-chloro-2-methoxy-phenyl)-methanol

tris-(5-chloro-2-methoxy-phenyl)-methanol

Conditions
ConditionsYield
With diethyl ether
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

5-chloro-2-methoxybenzoic acid ester

5-chloro-2-methoxybenzoic acid ester

2-[2-(5-Chloro-2-methoxy-phenyl)-2-oxo-ethyl]-benzoic acid

2-[2-(5-Chloro-2-methoxy-phenyl)-2-oxo-ethyl]-benzoic acid

Conditions
ConditionsYield
With lithium diisopropyl amide 1) THF, 0 deg C, 60 min, 2) THF; Yield given. Multistep reaction;
tert-butyl phenylcarbamate
3422-01-3

tert-butyl phenylcarbamate

methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

[2-(5-chloro-2-methoxy-benzoyl)-phenyl]-carbamic acid tert-butyl ester

[2-(5-chloro-2-methoxy-benzoyl)-phenyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: tert-butyl phenylcarbamate With tert.-butyl lithium In tetrahydrofuran at -78 - -40℃;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran at -40 - 0℃;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

N-(t-butoxycarbonyl)-4-chloroaniline
18437-66-6

N-(t-butoxycarbonyl)-4-chloroaniline

[4-chloro-2-(5-chloro-2-methoxy-benzoyl)-phenyl]-carbamic acid tert-butyl ester

[4-chloro-2-(5-chloro-2-methoxy-benzoyl)-phenyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: N-(t-butoxycarbonyl)-4-chloroaniline With tert.-butyl lithium In tetrahydrofuran at -78 - -40℃;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran at -40 - 0℃;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

t-butyl<3-(trifluoromethyl)phenyl>-carbamate
109134-07-8

t-butyl<3-(trifluoromethyl)phenyl>-carbamate

A

[2-(5-chloro-2-methoxy-benzoyl)-3-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

[2-(5-chloro-2-methoxy-benzoyl)-3-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

B

[2-(5-chloro-2-methoxy-benzoyl)-5-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

[2-(5-chloro-2-methoxy-benzoyl)-5-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: t-butyl<3-(trifluoromethyl)phenyl>-carbamate With tert.-butyl lithium In tetrahydrofuran at -78 - -40℃;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran at -40 - 0℃;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

tert-butyl (4-(trifluoromethyl)phenyl)carbamate
141940-37-6

tert-butyl (4-(trifluoromethyl)phenyl)carbamate

N-[2-[(5-chloro-2-methoxyphenyl) carbonyl]-4-(trifluoromethyl) phenyl]aminocarboxylic acid, 1,1-dimethylethyl ester
221113-30-0

N-[2-[(5-chloro-2-methoxyphenyl) carbonyl]-4-(trifluoromethyl) phenyl]aminocarboxylic acid, 1,1-dimethylethyl ester

Conditions
ConditionsYield
Stage #1: tert-butyl (4-(trifluoromethyl)phenyl)carbamate With tert.-butyl lithium In tetrahydrofuran at -78 - -40℃;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran at -40 - 0℃;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

tert-butyl (2-(trifluoromethyl)phenylamino)formate
141940-36-5

tert-butyl (2-(trifluoromethyl)phenylamino)formate

[2-(5-chloro-2-methoxy-benzoyl)-6-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

[2-(5-chloro-2-methoxy-benzoyl)-6-trifluoromethyl-phenyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: tert-butyl (2-(trifluoromethyl)phenylamino)formate With tert.-butyl lithium In tetrahydrofuran at -78 - -40℃;
Stage #2: methyl 5-chloro-2-methoxybenzoate In tetrahydrofuran at -40 - 0℃;
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

(2-amino-phenyl)-(5-chloro-2-methoxy-phenyl)-methanone
474088-40-9

(2-amino-phenyl)-(5-chloro-2-methoxy-phenyl)-methanone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: t-BuLi / tetrahydrofuran / -78 - -40 °C
1.2: tetrahydrofuran / -40 - 0 °C
2.1: 3 N HCl / ethanol / Heating
View Scheme
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

(2-amino-5-chloro-phenyl)-(5-chloro-2-methoxy-phenyl)-methanone
474088-58-9

(2-amino-5-chloro-phenyl)-(5-chloro-2-methoxy-phenyl)-methanone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: t-BuLi / tetrahydrofuran / -78 - -40 °C
1.2: tetrahydrofuran / -40 - 0 °C
2.1: 3 N HCl / ethanol / Heating
View Scheme
methyl 5-chloro-2-methoxybenzoate
33924-48-0

methyl 5-chloro-2-methoxybenzoate

2-chloro-N-[2-(5-chloro-2-methoxy-benzoyl)-phenyl]-acetamide
474088-45-4

2-chloro-N-[2-(5-chloro-2-methoxy-benzoyl)-phenyl]-acetamide

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: t-BuLi / tetrahydrofuran / -78 - -40 °C
1.2: tetrahydrofuran / -40 - 0 °C
2.1: 3 N HCl / ethanol / Heating
3.1: pyridine / CH2Cl2
View Scheme

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