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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Fluoro-4-Nitrophenol

Cas:394-41-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Our Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Factory supply 3-Fluoro-4-nitrophenol CAS 394-41-2 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed

Factory supply 3-Fluoro-4-nitrophenol CAS 394-41-2 with fast delivery

Cas:394-41-2

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Fluoro-4-Nitrophenol

Cas:394-41-2

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% 3-Fluoro-4-nitrophenol 394-41-2 Producer

Cas:394-41-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Fluoro-4-nitrophenol Manufacturer/High quality/Best price/In stock

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3-fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM 394-41-2 3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3-Fluoro-4-nitrophenol 394-41-2

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 394-41-2 with best quality

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phenol,3-fluoro-4-nitro- 394-41-2

Cas:394-41-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 3-Fluoro-4-nitrophenol CAS: 394-41-2

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $142.0 / 148.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

3-Fluoro-4-nitrophenol CAS:394-41-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

3-Fluoro-4-nitrophenol CAS:394-41-2

Cas:394-41-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phenol,3-fluoro-4-nitro-

Cas:394-41-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:394-41-2

Cas:394-41-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Fluoro-4-Nitrophenol

Cas:394-41-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFUCHEM--394-41-2--High purity 3-Fluoro-4-nitrophenol factory price

Cas:394-41-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-Fluoro-4-Nitrophenol

Cas:394-41-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 3-Fluoro-4-nitrophenol Synonyms: 3-Fluoro-4-nitrophenol99%;3-FLUORO-4-NITROPHENOL (POWDER);3-FLUORO-4-NITROPHENOL (SOLID);3-FLUORO-4-NITROPHENOL;3-FLUORO-4-METHYLPYRIDINE;Phenol, 3-fluoro-4-nitro-;3-Fluoro-4-nitrophen;3-Fluoro-4-n

3-Fluoro-4-nitrophenol 394-41-2 C6H4FNO3

Cas:394-41-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

TIANFUCHEM--394-41-2--High purity 3-Fluoro-4-nitrophenol factory price

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 3-Fluoro-4-Nitrophenol CAS No.: 394-41-2 Molecule Formula:C6H3FNO3 Molecule Weight:156.09 Purity: 99.0% Package: 25kg/drum Description:Pale yellow to brown powder Manufacture Standards:Enterprise Standard

Lower Price 3-Fluoro-4-Nitrophenol

Cas:394-41-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

TIANFUCHEM--394-41-2--High purity 3-Fluoro-4-nitrophenol factory price

Cas:394-41-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

TIANFUCHEM--394-41-2--High purity 3-Fluoro-4-nitrophenol factory price

Cas:394-41-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

3-Fluoro-4-nitrophenol

Cas:394-41-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

3-fluorophenol
372-20-3

3-fluorophenol

A

5-fluoro-2-nitrophenol
446-36-6

5-fluoro-2-nitrophenol

B

2-nitro-3-fluorophenol
385-01-3

2-nitro-3-fluorophenol

C

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With nitric acid; acetic acid at 15 - 26℃; for 1.5 - 2h; Product distribution / selectivity;A n/a
B n/a
C 27%
3-fluorophenol
372-20-3

3-fluorophenol

A

5-fluoro-2-nitrophenol
446-36-6

5-fluoro-2-nitrophenol

B

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With sodium nitrate; sulfuric acid
3-fluorophenol
372-20-3

3-fluorophenol

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With sodium nitrate; sulfuric acid
With ferric nitrate In tetrahydrofuran at 42℃;
With nitric acid In water at 8 - 10℃; for 0.5h; Time; Cooling with ice;
3-fluorophenol
372-20-3

3-fluorophenol

sulfuric acid
7664-93-9

sulfuric acid

sodium nitrate

sodium nitrate

A

5-fluoro-2-nitrophenol
446-36-6

5-fluoro-2-nitrophenol

B

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

3-fluoro-4-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranoside
872618-18-3

3-fluoro-4-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranoside

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With human recombinant O-GlcNAcase, wild type In dimethyl sulfoxide at 37℃; Kinetics; aq. phosphate buffer; Enzymatic reaction;
3-fluoro-4-nitrophenyl 2-deoxy-2-difluoroacetamido-β-D-glucopyranoside
1160363-27-8

3-fluoro-4-nitrophenyl 2-deoxy-2-difluoroacetamido-β-D-glucopyranoside

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With human recombinant O-GlcNAcase, wild type In dimethyl sulfoxide at 37℃; Kinetics; aq. phosphate buffer; Enzymatic reaction;
3-fluoro-4-nitrophenyl 2-deoxy-2-trifluoroacetamido-β-D-glucopyranoside
1160363-28-9

3-fluoro-4-nitrophenyl 2-deoxy-2-trifluoroacetamido-β-D-glucopyranoside

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With human recombinant O-GlcNAcase, wild type In dimethyl sulfoxide at 37℃; Kinetics; aq. phosphate buffer; Enzymatic reaction;
C17H23FN2O8
1200828-97-2

C17H23FN2O8

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With human recombinant O-GlcNAcase, wild type In dimethyl sulfoxide at 37℃; Kinetics; aq. phosphate buffer; Enzymatic reaction;
3-fluoro-4-nitrophenyl-2-deoxy-2-fluoroacetamido-β-D-glucopyranoside
1160363-26-7

3-fluoro-4-nitrophenyl-2-deoxy-2-fluoroacetamido-β-D-glucopyranoside

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With human recombinant O-GlcNAcase, wild type In dimethyl sulfoxide at 37℃; Kinetics; aq. phosphate buffer; Enzymatic reaction;
C6H4FN2

C6H4FN2

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: copper(II) sulfate; sulfuric acid; water / 100 °C
2: nitric acid / water / 0.5 h / 8 - 10 °C / Cooling with ice
View Scheme
meta-fluoroaniline
372-19-0

meta-fluoroaniline

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium nitrite / 1 h / Cooling with ice; Ionic liquid
1.2: 1 h
2.1: copper(II) sulfate; sulfuric acid; water / 100 °C
3.1: nitric acid / water / 0.5 h / 8 - 10 °C / Cooling with ice
View Scheme
2,4-Difluoronitrobenzene
446-35-5

2,4-Difluoronitrobenzene

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium methylate / 5.5 h / 45 °C / Inert atmosphere
2: benzene; aluminum (III) chloride / 11 h / 45 °C
View Scheme
2-fluoro-4-methoxy-1-nitro-benzene
446-38-8

2-fluoro-4-methoxy-1-nitro-benzene

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With aluminum (III) chloride; benzene at 45℃; for 11h;
3-bromo-4-nitrophenol
5470-65-5

3-bromo-4-nitrophenol

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With potassium fluoride In dimethyl sulfoxide at 40℃; for 5h; Temperature;
4-nitro-phenol
100-02-7

4-nitro-phenol

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

Conditions
ConditionsYield
With potassium fluoride; copper
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

4-amino-3-fluorophenol
399-95-1

4-amino-3-fluorophenol

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon In tetrahydrofuran; ethanol at 20℃; for 4.5h;100%
With iron; acetic acid In ethyl acetate for 3h; Heating / reflux;98%
With hydrogen; palladium 10% on activated carbon In ethyl acetate for 4h;97%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

methyl iodide
74-88-4

methyl iodide

2-fluoro-4-methoxy-1-nitro-benzene
446-38-8

2-fluoro-4-methoxy-1-nitro-benzene

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; for 48h; Darkness; Sonication;100%
With potassium carbonate at 20℃;100%
With potassium carbonate In acetone at 20℃; for 14h;99%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

benzyl bromide
100-39-0

benzyl bromide

4-benzyloxy-2-fluoro-1-nitrobenzene
221040-07-9

4-benzyloxy-2-fluoro-1-nitrobenzene

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide100%
With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 24h;97%
With sodium carbonate In N,N-dimethyl-formamide97%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

tert-butylchlorodiphenylsilane
58479-61-1

tert-butylchlorodiphenylsilane

4-(tert-butyl-diphenyl-silanyloxy)-2-fluoro-phenylamine
205700-47-6

4-(tert-butyl-diphenyl-silanyloxy)-2-fluoro-phenylamine

Conditions
ConditionsYield
Stage #1: 3-fluoro-4-nitrophenol; tert-butylchlorodiphenylsilane With 1H-imidazole In DMF (N,N-dimethyl-formamide) at 20℃; for 4h;
Stage #2: With hydrogen; palladium 10% on activated carbon In ethyl acetate under 2068.65 Torr; for 18h;
100%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

2-fluoro-4-methoxy-1-nitro-benzene
446-38-8

2-fluoro-4-methoxy-1-nitro-benzene

Conditions
ConditionsYield
Stage #1: 3-fluoro-4-nitrophenol With N-ethyl-N,N-diisopropylamine In methanol; acetonitrile at 0℃; for 0.5h;
Stage #2: diazomethyl-trimethyl-silane With methanol In acetonitrile at 20℃; for 18h;
100%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

sodium methylate
124-41-4

sodium methylate

4-nitro-3-methoxyphenol
16292-95-8

4-nitro-3-methoxyphenol

Conditions
ConditionsYield
With potassium carbonate In methanol for 168h; Reflux;100%
Stage #1: 3-fluoro-4-nitrophenol; sodium methylate In methanol at 50℃;
Stage #2: With hydrogenchloride In methanol; water
100%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

t-butyldimethylsiyl triflate
69739-34-0

t-butyldimethylsiyl triflate

1-(tert-butyldimethylsilyl)oxy-3-fluoro-4-nitrobenzene

1-(tert-butyldimethylsilyl)oxy-3-fluoro-4-nitrobenzene

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 16h;100%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

trifluoromethanesulfonic acid 3-fluoro-4-nitrophenyl ester
256935-94-1

trifluoromethanesulfonic acid 3-fluoro-4-nitrophenyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 3h;98%
With triethylamine In dichloromethane; water98%
With triethylamine In dichloromethane at 0 - 20℃; for 18h;85.1%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

(R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane
86940-97-8

(R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane

4-nitro-3-(2,2,4-trimethyl-[1,3]dioxolan-4-ylmethoxy)-phenol
956599-48-7

4-nitro-3-(2,2,4-trimethyl-[1,3]dioxolan-4-ylmethoxy)-phenol

Conditions
ConditionsYield
Stage #1: (R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane With potassium tert-butylate In methylpyrrolidine, 1-; toluene at 25℃; for 0.833333h;
Stage #2: 3-fluoro-4-nitrophenol In methylpyrrolidine, 1-; toluene at 65℃; for 1.5h;
98%
Stage #1: 3-fluoro-4-nitrophenol; (R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane With potassium tert-butylate In toluene; acetonitrile at 65 - 70℃; for 1h;
Stage #2: With hydrogenchloride In water pH=5; Product distribution / selectivity;
2-methoxyethyl methanesulfonate
16427-44-4

2-methoxyethyl methanesulfonate

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

2-methoxy-4-(2-methoxyethoxy)-1-nitrobenzene
625119-89-3

2-methoxy-4-(2-methoxyethoxy)-1-nitrobenzene

Conditions
ConditionsYield
With caesium carbonate In butanone for 19h; Heating / reflux;98%
With caesium carbonate In butanone for 19h; Heating / reflux;98%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

glycine
56-40-6

glycine

N-(5-hydroxy-2-nitrophenyl)-amino acetic acid

N-(5-hydroxy-2-nitrophenyl)-amino acetic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium bicarbonate In ethanol; water98%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

acetic anhydride
108-24-7

acetic anhydride

C8H6FNO4
1044232-35-0

C8H6FNO4

Conditions
ConditionsYield
samarium(III) trifluoromethanesulfonate at 20℃; for 0.166667h;98%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

methylamine
74-89-5

methylamine

3-(methylamino)-4-nitrophenol
14703-79-8

3-(methylamino)-4-nitrophenol

Conditions
ConditionsYield
In water at 85℃; for 5h;98%
In water at 85℃; for 5h;95%
In water at 80℃; for 18h; Sealed tube; Inert atmosphere;84%
In water at 85℃; for 5h;
In water at 80℃; for 18h; Inert atmosphere; Sealed tube;
diethyl sulfate
64-67-5

diethyl sulfate

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

4-ethoxy-2-fluoro-1-nitrobenzene
28987-48-6

4-ethoxy-2-fluoro-1-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 1.5h;98%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

2-(chloromethyl)quinoline monohydrochloride
3747-74-8

2-(chloromethyl)quinoline monohydrochloride

2-[(3-fluoro-4-nitrophenoxy)methyl]quinoline

2-[(3-fluoro-4-nitrophenoxy)methyl]quinoline

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 60℃; for 1.5h;98%
Methyl 2-bromopropionate
5445-17-0

Methyl 2-bromopropionate

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

methyl 2-(3-fluoro-4-nitrophenoxy)propionate
868232-59-1

methyl 2-(3-fluoro-4-nitrophenoxy)propionate

Conditions
ConditionsYield
With potassium carbonate In acetone Heating;97%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

4,6-dinitroresorcinol
616-74-0

4,6-dinitroresorcinol

Conditions
ConditionsYield
Stage #1: 3-fluoro-4-nitrophenol With water; potassium hydroxide at 80℃; for 2h;
Stage #2: With sulfuric acid; nitric acid at 30℃; for 1h; Temperature; Reagent/catalyst;
96.4%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

ethyl iodide
75-03-6

ethyl iodide

4-ethoxy-2-fluoro-1-nitrobenzene
28987-48-6

4-ethoxy-2-fluoro-1-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In butanone at 0 - 40℃; reflux;96%
With caesium carbonate In acetonitrile at 50℃;
With potassium carbonate In butanone at 85℃; for 2.5h;
1-bromo-octane
111-83-1

1-bromo-octane

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

2-fluoro-4-octyloxynitrobenzene
187329-15-3

2-fluoro-4-octyloxynitrobenzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; Inert atmosphere; Sonication; Darkness;95%
With potassium carbonate In acetone Heating;
(4RS)-4-hydroxymethyl-2,2,4-trimethyl-1,3-dioxolane
86884-87-9

(4RS)-4-hydroxymethyl-2,2,4-trimethyl-1,3-dioxolane

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

(R,S)-4-nitro-3-(2,2,4-trimethyl-[1,3]dioxolan-4-ylmethoxy)-phenol
956599-27-2

(R,S)-4-nitro-3-(2,2,4-trimethyl-[1,3]dioxolan-4-ylmethoxy)-phenol

Conditions
ConditionsYield
Stage #1: (4RS)-4-hydroxymethyl-2,2,4-trimethyl-1,3-dioxolane; 3-fluoro-4-nitrophenol With potassium tert-butylate In 1-methyl-pyrrolidin-2-one; toluene at 20 - 65℃; for 1.5h;
Stage #2: With acetic acid In 1-methyl-pyrrolidin-2-one; water; toluene Product distribution / selectivity;
95%
trifluoroaceticmethanesulfonic anhydride

trifluoroaceticmethanesulfonic anhydride

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

trifluoromethanesulfonic acid 3-fluoro-4-nitrophenyl ester
256935-94-1

trifluoromethanesulfonic acid 3-fluoro-4-nitrophenyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane; ethyl acetate95%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

2-(bromomethyl)pyridine hydrobromide
31106-82-8

2-(bromomethyl)pyridine hydrobromide

3-fluoro-4-nitrophenyl pyridin-2-ylmethyl ether

3-fluoro-4-nitrophenyl pyridin-2-ylmethyl ether

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 80℃; for 2h;95%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

isopropyl alcohol
67-63-0

isopropyl alcohol

3-isopropoxy-4-nitrophenol
194737-98-9

3-isopropoxy-4-nitrophenol

Conditions
ConditionsYield
Stage #1: isopropyl alcohol With sodium hydride In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: 3-fluoro-4-nitrophenol In tetrahydrofuran for 12h; Reflux;
95%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

N,N-dimethylammonium chloride
506-59-2

N,N-dimethylammonium chloride

3-(dimethylamino)-4-nitrophenol
14703-80-1

3-(dimethylamino)-4-nitrophenol

Conditions
ConditionsYield
With potassium carbonate In water; dimethyl sulfoxide at 100℃;94%
2-methyl-3-bromo-1-propene
1458-98-6

2-methyl-3-bromo-1-propene

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

2-fluoro-4-(2-methylallyloxy)-1-nitrobenzene

2-fluoro-4-(2-methylallyloxy)-1-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 55℃; for 13h;94%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

1-Amino-2-methyl-propan-2-ol
2854-16-2

1-Amino-2-methyl-propan-2-ol

2-fluoro-5-(trifluoromethyl)pyridine
69045-82-5

2-fluoro-5-(trifluoromethyl)pyridine

2-methyl-1-((2-nitro-5-((5-(trifluoromethyl)pyridin-2-yl)oxy)phenyl)amino)propan-2-ol

2-methyl-1-((2-nitro-5-((5-(trifluoromethyl)pyridin-2-yl)oxy)phenyl)amino)propan-2-ol

Conditions
ConditionsYield
Stage #1: 3-fluoro-4-nitrophenol; 1-Amino-2-methyl-propan-2-ol With sodium hydrogencarbonate In 1-methyl-pyrrolidin-2-one at 120℃; for 4h; Inert atmosphere;
Stage #2: 2-fluoro-5-(trifluoromethyl)pyridine With potassium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 4h; Inert atmosphere;
93.5%
Stage #1: 3-fluoro-4-nitrophenol; 1-Amino-2-methyl-propan-2-ol With caesium carbonate; N-ethyl-N,N-diisopropylamine In 1-methyl-pyrrolidin-2-one at 100℃; for 4h;
Stage #2: 2-fluoro-5-(trifluoromethyl)pyridine With caesium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 3h;
1.53 g
Stage #1: 3-fluoro-4-nitrophenol; 1-Amino-2-methyl-propan-2-ol With N-ethyl-N,N-diisopropylamine In 1-methyl-pyrrolidin-2-one at 100℃; for 4h;
Stage #2: 2-fluoro-5-(trifluoromethyl)pyridine With caesium carbonate
1.53 g
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

4-chloro-N-methylpicolinamide
220000-87-3

4-chloro-N-methylpicolinamide

4-(4-amino-3-fluorophenoxy)pyridine-2-carboxylic acid methyl amide
757251-39-1

4-(4-amino-3-fluorophenoxy)pyridine-2-carboxylic acid methyl amide

Conditions
ConditionsYield
Stage #1: 3-fluoro-4-nitrophenol; 4-chloro-N-methylpicolinamide With potassium carbonate In acetonitrile for 4h; Green chemistry;
Stage #2: With iron(III) chloride; hydrazine hydrate; pyrographite In methanol for 3h; Reflux; Green chemistry;
92.5%
With potassium hydroxide for 1.5h;92.4%
methanol
67-56-1

methanol

3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

4-nitro-3-methoxyphenol
16292-95-8

4-nitro-3-methoxyphenol

Conditions
ConditionsYield
With sodium for 12h; Reflux;91%
With sodium methylate for 72h; Reflux;88%
With sodium methylate for 60h; Reflux;2.7 g
Stage #1: methanol; 3-fluoro-4-nitrophenol With sodium for 24h; Reflux;
Stage #2: With hydrogenchloride; water In ethyl acetate pH=1;
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

phenylboronic acid
98-80-6

phenylboronic acid

2-fluoro-1-nitro-4-phenoxy-benzene
28987-53-3

2-fluoro-1-nitro-4-phenoxy-benzene

Conditions
ConditionsYield
With copper diacetate; triethylamine In dichloromethane at 20℃; Molecular sieve; Inert atmosphere;91%
With copper diacetate; triethylamine In dichloromethane at 20℃; Molecular sieve; Inert atmosphere;91%
With copper diacetate; trimethylamine In dichloromethane at 20℃; for 16h; Molecular sieve; Inert atmosphere;21%
With copper diacetate; trimethylamine In dichloromethane at 20℃; for 16h; Inert atmosphere; Molecular sieve;21%
3-fluoro-4-nitrophenol
394-41-2

3-fluoro-4-nitrophenol

3-(chloromethyl)-1-methyl-1H-pyrazole hydrochloride

3-(chloromethyl)-1-methyl-1H-pyrazole hydrochloride

3-((3-fluoro-4-nitrophenoxy)methyl)-1-methyl-1H-pyrazole

3-((3-fluoro-4-nitrophenoxy)methyl)-1-methyl-1H-pyrazole

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In acetonitrile at 60℃; for 8h;90.2%

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