CAS No.41270-80-8,methyl 2-(formylamino)benzoate Suppliers

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methyl formyl anthranilate

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methyl 2-(formylamino)benzoate CAS:41270-80-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality o

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Methyl 2-formamidobenzoate

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Nanjing Raymon Biotech Co., Ltd.

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Methyl N-formylanthranilate

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Synthetic route

: 64-18-6
formic acid

: 134-20-3
2-carbomethoxyaniline

: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
With sulfated polyborate In neat (no solvent) at 70℃; for 0.5h;	92%
at 130℃; im Druckrohr;

: 64-18-6
formic acid

: 87-25-2
2-ethoxycarbonylaniline

: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
With (1-methyl-3-(3-sulfopropyl)-1H-imidazol-3-ium)3[PW12O403-] In neat (no solvent) at 70℃; for 1.5h; Green chemistry;	90%

: 68061-82-5
methyl 2-(methyl(nitroso)amino)benzoate

A: 93-58-3
benzoic acid methyl ester

B: 619-50-1
4-nitrobenzoic acid methyl ester

C: 5807-64-7
diphenic acid dimethyl ester

D: 55676-77-2
dimethyl (1,1'-biphenyl)-2,4'-dicarboxylate

E: 32947-58-3
dimethyl (1,1'-biphenyl)-2,3'-dicarboxylate

F: 75541-61-6
2-(benzoyl-methylamino)benzoic acid methyl ester

G: 134-20-3
2-carbomethoxyaniline

H: 85-91-6
Methyl N-methylanthranilate

I: 7510-49-8
methyl 2-(benzamido)benzoate

J: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
at 220℃; for 0.25h; Sealed tube;	A n/a B n/a C n/a D n/a E n/a F n/a G n/a H n/a I 90% J n/a

...Expand

: 51673-84-8
dimethoxyacetaldehyde

: 134-20-3
2-carbomethoxyaniline

: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
With oxygen; toluene-4-sulfonic acid In 1,4-dioxane at 60℃; for 2h;	60%

: 134-20-3
2-carbomethoxyaniline

: 109-94-4
formic acid ethyl ester

A: 72368-50-4
ethyl 2-(formylamino) benzoate

B: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
With sodium

...Expand

: 134-20-3
2-carbomethoxyaniline

: 109-94-4
formic acid ethyl ester

sodium: sodium

A: 72368-50-4
ethyl 2-(formylamino) benzoate

B: 41270-80-8
N-formylanthranilic acid methyl ester

...Expand

: 50978-45-5
3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide

: 134-20-3
2-carbomethoxyaniline

: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.25h; chemoselective reaction;

: 134-20-3
2-carbomethoxyaniline

: 2258-42-6
Acetic formic anhydride

: 41270-80-8
N-formylanthranilic acid methyl ester

Conditions

Conditions	Yield
In diethyl ether; hexane at 0 - 20℃;

: 41270-80-8
N-formylanthranilic acid methyl ester

: 66715-31-9
o-methoxycarbonylphenylisonitrile

Conditions

Conditions	Yield
With triethylamine; trichlorophosphate In dichloromethane at -30 - 20℃; for 48.5h;	81%
With triethylamine; trichlorophosphate In tetrahydrofuran at 0℃;
With triethylamine; trichlorophosphate In tetrahydrofuran at 0℃;

: 41270-80-8
N-formylanthranilic acid methyl ester

: 514805-22-2
1-(p-toluenesulfonyl)-1,2-heptadiene

: 514805-20-0
2-{Formyl-[(E)-1-(toluene-4-sulfonylmethyl)-hex-1-enyl]-amino}-benzoic acid methyl ester

Conditions

Conditions	Yield
With dmap; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 2h;	60%

: 82721-81-1
1-(p-toluenesulfonyl)-1-heptyne

: 41270-80-8
N-formylanthranilic acid methyl ester

: 514805-20-0
2-{Formyl-[(E)-1-(toluene-4-sulfonylmethyl)-hex-1-enyl]-amino}-benzoic acid methyl ester

Conditions

Conditions	Yield
With dmap; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 2h;	57%

: 131156-26-8
1-(p-toluenesulfonyl)-2-heptyne

: 41270-80-8
N-formylanthranilic acid methyl ester

: 514805-20-0
2-{Formyl-[(E)-1-(toluene-4-sulfonylmethyl)-hex-1-enyl]-amino}-benzoic acid methyl ester

Conditions

Conditions	Yield
With dmap; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 24h;	51%

: 41270-80-8
N-formylanthranilic acid methyl ester

: 474452-37-4
4-[8-(p-toluenesulfonyl)-7-octynyl]-1,2-(methylenedioxy)benzene

: 474452-40-9
2-{[(E)-7-Benzo[1,3]dioxol-5-yl-1-(toluene-4-sulfonylmethyl)-hept-1-enyl]-formyl-amino}-benzoic acid methyl ester

Conditions

Conditions	Yield
With dmap; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 15h;	26%
With dmap; potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 15h;	26%

: 82721-81-1
1-(p-toluenesulfonyl)-1-heptyne

: 41270-80-8
N-formylanthranilic acid methyl ester

A: 131156-26-8
1-(p-toluenesulfonyl)-2-heptyne

B: 514805-20-0
2-{Formyl-[(E)-1-(toluene-4-sulfonylmethyl)-hex-1-enyl]-amino}-benzoic acid methyl ester

C: 2-(Formyl-{1-[1-(toluene-4-sulfonyl)-meth-(E)-ylidene]-hexyl}-amino)-benzoic acid methyl ester

Conditions

Conditions	Yield
With potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 96h;	A n/a B 16% C 4%

...Expand

: 67-56-1
methanol

: 41270-80-8
N-formylanthranilic acid methyl ester

: 62723-86-8
4-methoxy-1,4-dihydro-benzo[d][1,3]oxazin-2-one

Conditions

Conditions	Yield
(i) (thermolysis), (ii) /BRN= 1098229/; Multistep reaction;

: 64-17-5
ethanol

: 41270-80-8
N-formylanthranilic acid methyl ester

: 62723-87-9
4-ethoxy-1,4-dihydro-benzo[d][1,3]oxazin-2-one

Conditions

Conditions	Yield
(i) (thermolysis), (ii) /BRN= 1718733/; Multistep reaction;

: 41270-80-8
N-formylanthranilic acid methyl ester

: 109072-26-6
2-pentylquinolin-4(1H)-one

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 57 percent / potassium carbonate; DMAP / dimethylformamide; H2O / 2 h / 20 °C 2: 77 percent / LiHMDS / tetrahydrofuran / 1.17 h / -78 °C 3: 68 percent / mercuric chloride; aluminum / methanol; tetrahydrofuran / 1.5 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 4-oxo-2-pentylidene-3-(toluene-4-sulfonyl)-3,4-dihydro-2H-quinoline-1-carbaldehyde

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 57 percent / potassium carbonate; DMAP / dimethylformamide; H2O / 2 h / 20 °C 2: 77 percent / LiHMDS / tetrahydrofuran / 1.17 h / -78 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 3-(2-isocyano-phenyl)-N,N-dimethyl-3-oxo-propionamide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: POCl3; Et3N / tetrahydrofuran / 0 °C 2: magnesium bis(diisopropylamide) / diethyl ether / 0 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 4-hydroxy-quinoline-3-carboxylic acid dimethylamide

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: POCl3; Et3N / tetrahydrofuran / 0 °C 2: magnesium bis(diisopropylamide) / diethyl ether / 0 °C 3: magnesium bis(diisopropylamide) / diethyl ether / 2 h View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 3-(2-isocyano-phenyl)-3-oxo-propionic acid tert-butyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: POCl3; Et3N / tetrahydrofuran / 0 °C 2: magnesium bis(diisopropylamide) / diethyl ether / 0 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 4-hydroxy-quinoline-3-carboxylic acid tert-butyl ester

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: POCl3; Et3N / tetrahydrofuran / 0 °C 2: magnesium bis(diisopropylamide) / diethyl ether / 0 °C 3: magnesium bis(diisopropylamide) / diethyl ether / 2 h View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 106283-19-6
(S)-2-(2-(2-(2-(dimethylamino)benzamido)-N-methylacetamido)-3-methylbutanamido)benzoic acid

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C 3: lithium hydroxide / tetrahydrofuran; water / 8 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-22-8
methyl 2-(2-(2-(2-(dimethylamino)benzamido)-N-methylacetamido)-3-methyl-butanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-25-1
methyl 2-(2-(2-(2-(dimethylamino)benzamido)-N-propylacetamido)-3-methyl-butanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-26-2
methyl 2-(2-(N-benzyl-2-(2-(dimethylamino)benzamido)acetamido)-3-methylbutanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-27-3
methyl 2-(2-(2-(2-(dimethylamino)benzamido)-N-(4-fluorobenzyl)acetamido)-3-methylbutanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-28-4
methyl 2-(2-(n-(4-chlorobenzyl)-2-(2-(dimethylamino)benzamido)acetamido)-3-methylbutanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-29-5
methyl 2-(2-(2-(2-(dimethylamino)benzamido)-N-phenethylacetamido)-3-methylbutanamido)benzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C View Scheme

: 41270-80-8
N-formylanthranilic acid methyl ester

: 1418290-30-8
2-(2-(2-(2-(dimethylamino)benzamido)-N-propylacetamido)-3-methylbutan-amido)benzoic acid

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: trichlorophosphate; triethylamine / dichloromethane / 48.5 h / -30 - 20 °C 2: methanol / 20 h / 20 °C 3: lithium hydroxide / tetrahydrofuran; water / 8 h / 20 °C View Scheme

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