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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 2-(4-Methylphenyl)pyridine CAS No. 4

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 4467-06-5 with best quality

Cas:4467-06-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 2-p-tolylpyridine Structural formula CAS No. 4467-06-5 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:OLED Intermediates Tr

2-p-tolylpyridine

Cas:4467-06-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Qingdao Beluga Import and Export Co., LTD

2-(4-Methylphenyl)pyridine CAS:4467-06-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2-(4-Methylphenyl)pyridine CAS:4467-06-5

Cas:4467-06-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Pyridine,2-(4-methylphenyl)-

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-(p-Tolyl)pyridine

Cas:4467-06-5

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Pyridine,2-(4-methylphenyl)-

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-(4-methylphenyl)pyridine CAS NO.4467-06-5

Cas:4467-06-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

2-(4-Methylphenyl)pyridine Basic information Product Name: 2-(4-Methylphenyl)pyridine Synonyms: Pyridine, 2-(4-methylphenyl)-;MPHPY;AKOS BAR-0491;2-(P-TOLYL)PYRIDINE;2-(4-METHYLPHENYL)PYRIDINE;2-(4-TOLYL)PYRIDINE;2-(P-TOLYL)PYRIDINE, 97+%;2-(P

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-(p-Tolyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Manufacturers

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-(p-tolyl)pyridine/SAGECHEM/Manufacturer in China

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-(4-Methylphenyl)pyridine cas no. 4467-06-5 98%

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-(p-Toly)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-(p-Tolyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Other

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

2-(4-Tolyl) Pyridine

Cas:4467-06-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents

Pyridine,2-(4-methylphenyl)-

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

2-(4-Methylphenyl)pyridine cas 4467-06-5Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-(4-Methylphenyl)pyridine cas 4467-06-5

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Other

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Hubei Jiutian Bio-medical Technology Co., Ltd

Trimeric sodium phosphate detergent auxiliary agent is a kind of excellent properties, is one of the biggest component of detergent consumption during the production, it has four aspects: 1, chelation of heavy metal ions, heavy metal ions in the wate

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-(p-Tolyl)pyridine 4467-06-5

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

2-(p-Tolyl)pyridine manufacturer

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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NUTROCHEM- MANUFACTURE PLACE

best seller Application:API

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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HWRK Chem

in storeAppearance:liquid Package:5g Application:Organic Chemicals

2-(p-Tolyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Trading Company

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Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

2-(4-Methylphenyl)pyridine

Cas:4467-06-5

Min.Order:0

Negotiable

Type:Other

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Synthetic route

2-chloropyridine
109-09-1

2-chloropyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C32H41N12Ni2O(3+)*3F6P(1-) In tetrahydrofuran at 25℃; for 5h; Inert atmosphere; Schlenk technique;100%
With N-heterocyclic carbene-based nickel(II) complex In tetrahydrofuran at 20℃; for 12h; Kumada reaction;99%
With chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate In tetrahydrofuran at 20℃; for 12h; Kumada-Corriu coupling reaction; Inert atmosphere;99%
2-chloropyridine
109-09-1

2-chloropyridine

para-bromotoluene
106-38-7

para-bromotoluene

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
Stage #1: para-bromotoluene With lithium
Stage #2: With zinc(II) chloride
Stage #3: 2-chloropyridine; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Negishi cross-coupling; Further stages.;
99.5%
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; electrolysis;80%
2-[4-(2-pyridinyl)phenyl]methylenehydrazinecarboxylic acid tert-butyl ester
198904-84-6

2-[4-(2-pyridinyl)phenyl]methylenehydrazinecarboxylic acid tert-butyl ester

A

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

B

N-1-(tert-butoxycarbonyl)-N-2-[4-(pyridine-2-yl)benzyl]hydrazine
198904-85-7

N-1-(tert-butoxycarbonyl)-N-2-[4-(pyridine-2-yl)benzyl]hydrazine

Conditions
ConditionsYield
With hydrogen; triethylamine; 5%-palladium/activated carbon at 40℃; under 760.051 Torr; for 5h;A 0.69%
B 99.17%
With hydrogen; sodium carbonate; 5%-palladium/activated carbon at 40℃; under 760.051 Torr; for 5h;A 0.25%
B 99.16%
With hydrogen; 5%-palladium/activated carbon In methanol at 50℃; under 760.051 Torr; for 5h;A 2.69%
B 97.11%
at 40 - 62℃; under 1520.1 Torr; for 5h; Hydrogen/nitrogen (1/2);A 0.1%
B 97.2%
With hydrogen; 5%-palladium/activated carbon at 5 - 58℃; under 1520.1 Torr; for 5 - 8h; Nitrogen gas;A 2.11%
B 94.41%
2-chloropyridine
109-09-1

2-chloropyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate In tetrahydrofuran at 100℃; for 24h; Suzuki-Miyaura coupling;99%
With potassium phosphate monohydrate; 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate In 1,4-dioxane; 1,3,5-trimethyl-benzene at 135℃; for 24h; Suzuki-Miyaura coupling; Inert atmosphere;98%
With 4-di-tert-butylphosphanyl-1-phenyl-5-(2,6-dimethoxyphenyl)-1H-[1,2,3]triazole; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 100℃; for 12h; Suzuki coupling; Inert atmosphere;97%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate; palladium dichloride In ethanol; water at 80℃; for 0.166667h; Suzuki-Miyaura reaction;99%
With potassium phosphate tribasic heptahydrate; palladium diacetate In isopropyl alcohol at 80℃; for 0.133333h; Suzuki coupling;98%
With potassium phosphate tribasic heptahydrate; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; for 12h; Suzuki cross-coupling reaction;98%
2-chloropyridine
109-09-1

2-chloropyridine

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With Ni(Cl){2-(Ph2P)C6H4NCH(Ph)P(O)Ph2} In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25℃; for 24h; Negishi coupling reaction; Inert atmosphere;99%
With C38H34Br2N4Ni2P2 In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 90℃; for 12h; Reagent/catalyst; Negishi Coupling; Inert atmosphere; Schlenk technique;99%
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 6h; Inert atmosphere; Schlenk technique; Heating;99%
With C21H18N8Ni2O(2+)*2F6P(1-) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 20 - 80℃; Negishi coupling reaction;98%
trimethylpyridin-2-ylammonium iodide
33675-27-3

trimethylpyridin-2-ylammonium iodide

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C38H34Br2N4Ni2P2; potassium iodide In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 65℃; for 12h; Reagent/catalyst; Concentration; Inert atmosphere; Schlenk technique;99%
With C32H26ClN2NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 85℃; for 12h; Inert atmosphere;97%
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 90℃; for 8h; Negishi coupling reaction; Inert atmosphere;87%
2-Cyanopyridine
100-70-9

2-Cyanopyridine

p-MeC6H4-MnCl
192887-48-2

p-MeC6H4-MnCl

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With dichlorobis(trimethylphosphine)nickel In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Inert atmosphere;99%
2-fluoropyridine
372-48-5

2-fluoropyridine

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
Stage #1: 2-fluoropyridine; p-tolylzinc(II) chloride With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 25 - 100℃; for 10h; Schlenk technique; Inert atmosphere;
Stage #2: p-tolylzinc(II) chloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 100℃; for 10h; Inert atmosphere; Schlenk technique;
99%
2-pyridyl dimethylsulfamate
1282034-09-6

2-pyridyl dimethylsulfamate

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C38H34Br2N4Ni2P2 In tetrahydrofuran at 35℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;99%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-tolylmagnesium chloride
696-61-7

4-tolylmagnesium chloride

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C36H52Br2N4NiSi In tetrahydrofuran at 70℃; for 24h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique;99%
2-(4-methylphenyl)pyridine N-oxide
33421-24-8

2-(4-methylphenyl)pyridine N-oxide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With ammonium chloride; zinc In tetrahydrofuran at 22 - 38℃; for 0.583333h;98%
With palladium on activated charcoal; ammonium formate In methanol at 20℃;95%
With methanol; palladium 10% on activated carbon; ammonium formate at 20℃; Inert atmosphere;95%
With tetrahydroxydiboron In N,N-dimethyl-formamide; acetonitrile at 20℃; for 0.166667h;151 mg
2-chloropyridine
109-09-1

2-chloropyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

A

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

B

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With C68H72Cl2N6NiP2 In diethyl ether at 25℃; for 12h; Kumada coupling reaction; Inert atmosphere;A 98%
B n/a
2-bromo-pyridine
109-04-6

2-bromo-pyridine

trimethyl((5-methyl-2-(p-tolyl)-1,3,2-dioxaborinan-5-yl)methoxy)silane
1352708-10-1

trimethyl((5-methyl-2-(p-tolyl)-1,3,2-dioxaborinan-5-yl)methoxy)silane

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol at 100℃; for 18h; Suzuki Coupling; Inert atmosphere;96%
2-methoxypyridine
1628-89-3

2-methoxypyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With (IPr)Ni(π-allyl)Cl In tetrahydrofuran at 60℃; for 12h; Kumada Cross-Coupling; Inert atmosphere;95%
With C68H72Cl2N6NiP2 In tetrahydrofuran at 25℃; for 24h; Inert atmosphere;91%
With bis(1,5-cyclooctadiene)nickel (0); C23H28N4 In tetrahydrofuran; m-xylene at 60℃; for 4h; Kumada Cross-Coupling; Inert atmosphere; Sealed tube;54%
With dichlorobis(trimethylphosphine)nickel In tetrahydrofuran at 23℃; for 15h;
2-chloropyridine
109-09-1

2-chloropyridine

potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With N-methyl-2-phenyl-3-(dicyclohexylphosphino)-1H-indole; palladium diacetate; triethylamine; sodium t-butanolate In water at 100℃; for 18h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;95%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

pyridin-2-yl sulfurofluoridate
127827-58-1

pyridin-2-yl sulfurofluoridate

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium carbonate In ethanol; water at 35℃; for 3h; Suzuki Coupling; chemoselective reaction;95%
para-bromotoluene
106-38-7

para-bromotoluene

C22H22InN5*Cl3Li3

C22H22InN5*Cl3Li3

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 80℃; Inert atmosphere; Schlenk technique;95%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With nickel(II) fluoride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 60℃; for 16h; Inert atmosphere;93%
With C16H16Cl2CoN8(1+)*F6P(1-) In tetrahydrofuran at 20℃; for 2h; Kumada-Corriu cross-coupling;92%
With [Ni(1-(1-ethyl-benzimidazol-2-ylmethyl)-3-mesitylimidazolin-2-ylidene)2][Cl]2; sodium acetate In tetrahydrofuran at 20℃; Kumada-Corriu coupling reaction; Inert atmosphere;
para-bromotoluene
106-38-7

para-bromotoluene

2-(trimethylsilyl)pyridine
13737-04-7

2-(trimethylsilyl)pyridine

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With potassium fluoride; copper(l) iodide; palladium diacetate; catacxium A In N,N-dimethyl-formamide at 90℃; for 12h; Hiyama coupling; Inert atmosphere;92%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

p-tolylboronic pinacol ester
195062-57-8

p-tolylboronic pinacol ester

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With tricyclohexylphosphine-copper chloride; sodium t-butanolate In toluene at 100℃; for 15h; Reagent/catalyst; Inert atmosphere; Sealed tube;92%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In neat (no solvent) at 110℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;77%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

para-bromotoluene
106-38-7

para-bromotoluene

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
Stage #1: para-bromotoluene With iodine; magnesium In tetrahydrofuran at 35℃; for 2h;
Stage #2: 2-bromo-pyridine; tetrakis(triphenylphosphine) palladium(0); zinc(II) chloride In tetrahydrofuran; toluene at 50℃; for 2.5h; Conversion of starting material;
91.7%
Stage #1: para-bromotoluene With ethylene dibromide; trifluoroacetic acid; cobalt(II) bromide; zinc In acetonitrile at 20℃; for 1h; Inert atmosphere; Sealed tube;
Stage #2: 2-bromo-pyridine With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide; acetonitrile at 50℃; for 1h; Inert atmosphere; Sealed tube;
78%
Stage #1: para-bromotoluene With iodine; magnesium In tetrahydrofuran at 35℃; for 2h;
Stage #2: 2-bromo-pyridine; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 50℃; for 2.5h; Conversion of starting material;
9%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-tolyl iodide
624-31-7

4-tolyl iodide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With PEG 4000; palladium diacetate; potassium carbonate at 120℃; for 15h;91%
2-fluoropyridine
372-48-5

2-fluoropyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With C35H31BrN4NiP In tetrahydrofuran at 25℃; for 12h; Schlenk technique; Inert atmosphere;91%
With C26H24ClN2NiP*0.1C7H8 In diethyl ether at 25℃; for 24h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;89%
para-bromotoluene
106-38-7

para-bromotoluene

C11H20AlNO

C11H20AlNO

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With palladium diacetate; tris-(o-tolyl)phosphine In toluene at 20℃; for 5h; Inert atmosphere;91%
Trimethylenediamine
109-76-2

Trimethylenediamine

para-methylacetophenone
122-00-9

para-methylacetophenone

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With oxygen; palladium diacetate; toluene-4-sulfonic acid In tetrahydrofuran for 9h; Reflux;91%
With hydrogenchloride; iodine; oxygen In dimethyl sulfoxide at 80℃; for 4h;85%
With oxygen In ethanol at 100℃; under 760.051 Torr; for 26h;71%
With oxygen; copper(II) bis(trifluoromethanesulfonate); toluene-4-sulfonic acid In hexan-1-ol at 110℃; for 24h; Sealed tube; Schlenk technique;67%
With tris(2,2'-bipyridyl)ruthenium dichloride; oxygen; toluene-4-sulfonic acid In acetonitrile at 82℃; for 48h; Irradiation;50%
para-chlorotoluene
106-43-4

para-chlorotoluene

pyridin-2-ylzinc(II) bromide

pyridin-2-ylzinc(II) bromide

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); XPhos In tetrahydrofuran at 65℃; for 24h; Negishi cross-coupling; Inert atmosphere;89%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

potassium (4-methylphenyl)trifluoroborate

potassium (4-methylphenyl)trifluoroborate

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In ethanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;89%
2-hydroxypyridin
142-08-5

2-hydroxypyridin

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
Stage #1: 2-hydroxypyridin With potassium carbonate; bromo-tris(1-pyrrolidinyl)phosphonium hexafluorophosphate In 1,4-dioxane at 100℃; for 3h; Inert atmosphere;
Stage #2: 4-methylphenylboronic acid With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane; water at 100℃; Suzuki-Miyaura coupling; Inert atmosphere;
88%
2-pyridyl dimethylsulfamate
1282034-09-6

2-pyridyl dimethylsulfamate

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Conditions
ConditionsYield
With 1-Methylpyrrolidine; C20H20ClN3Ni In tetrahydrofuran at 50℃; for 12h; Schlenk technique; Inert atmosphere;88%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

((2,6-iPr2C6H3)NCH2CH2N(2,6-iPr2C6H3))Y(CH2SiMe3)(THF)2
708268-52-4

((2,6-iPr2C6H3)NCH2CH2N(2,6-iPr2C6H3))Y(CH2SiMe3)(THF)2

C84H110N6O2Y2

C84H110N6O2Y2

Conditions
ConditionsYield
In benzene at 20℃; for 48h;100%
triethylsilane
617-86-7

triethylsilane

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

2-(4-methyl-2-(triethylsilyl)phenyl)pyridine
1450751-49-1

2-(4-methyl-2-(triethylsilyl)phenyl)pyridine

Conditions
ConditionsYield
Stage #1: 2-(4-methylphenyl)pyridine With norborn-2-ene; C30H33IrN2O2 In toluene at 115℃; for 3h; Inert atmosphere;
Stage #2: triethylsilane In toluene at 115℃; for 24h; Inert atmosphere;
99%
Stage #1: 2-(4-methylphenyl)pyridine With C30H34ClIrN2 In o-xylene at 100℃; for 6h;
Stage #2: triethylsilane With tert-butylethylene for 18h;
87%
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); norbornene; potassium acetate In toluene at 120℃; for 20h; Inert atmosphere;84%
With norborn-2-ene; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); potassium acetate In toluene at 120℃; for 16h; Schlenk technique; Inert atmosphere;84%
With norbornene; [Ir(hydride)2(1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(pyridine)3][BF4] In tetrahydrofuran at 110℃; for 24h; Sealed tube; Inert atmosphere; Schlenk technique;71%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

3-(methoxycarbonyl)-υ-triazolo<3,4-a>pyridine
150176-08-2

3-(methoxycarbonyl)-υ-triazolo<3,4-a>pyridine

9-methyl-7-(pyridin-2-yl)-6H-pyrido[2,1-a]isoquinolin-6-one

9-methyl-7-(pyridin-2-yl)-6H-pyrido[2,1-a]isoquinolin-6-one

Conditions
ConditionsYield
With [Cp*Rh(CH3CN)3](SbF6)2 In 2,2,2-trifluoroethanol at 140℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;99%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

formaldehyd
50-00-0

formaldehyd

1-(5-methyl-2-(pyridin-2-yl)phenyl)ethan-1-one

1-(5-methyl-2-(pyridin-2-yl)phenyl)ethan-1-one

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; acetic acid; silver(I) triflimide In 2,2,2-trifluoroethanol at 120℃; for 24h; Sealed tube; Green chemistry; regioselective reaction;99%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(4-methyl-2,6-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)pyridine

2-(4-methyl-2,6-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)pyridine

Conditions
ConditionsYield
With C25H40O2P2Ru In tetrahydrofuran at 120℃; for 20h; Inert atmosphere; Sealed tube;99%
With C25H36O2P2Ru In tetrahydrofuran at 120℃; for 20h; Sealed tube; Glovebox; Schlenk technique; Inert atmosphere; regioselective reaction;99%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

2-(4-methylphenyl)pyridine N-oxide
33421-24-8

2-(4-methylphenyl)pyridine N-oxide

Conditions
ConditionsYield
With dihydrogen peroxide; acetic acid In water at 73℃;97%
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane; water at 40℃; for 12h; Inert atmosphere;81%
With 3-chloro-benzenecarboperoxoic acid In tetrahydrofuran at 20℃; Inert atmosphere; Cooling with ice;34%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

2,2,2-trifluoroacetamide
354-38-1

2,2,2-trifluoroacetamide

2,2,2-trifluoro-N-(5-methyl-2-pyridin-2-yl)acetamide

2,2,2-trifluoro-N-(5-methyl-2-pyridin-2-yl)acetamide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; magnesium oxide; palladium diacetate In 1,2-dichloro-ethane at 80℃;97%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

cyclohexenone
930-68-7

cyclohexenone

C18H19NO
1342303-17-6

C18H19NO

Conditions
ConditionsYield
With tris(acetonitrile)(η5-pentamethylcyclopentadienyl)rhodium(III) hexafluoroantimonate In dichloromethane at 40℃; for 48h; Inert atmosphere;97%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

-butyl vinyl ether
111-34-2

-butyl vinyl ether

C18H23NO

C18H23NO

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In toluene at 60℃; for 12h; Schlenk technique; Inert atmosphere;97%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

N-benzoylbenzenesulfenamide
23847-33-8

N-benzoylbenzenesulfenamide

2-(4-methyl-2,6-bis(phenylthio)phenyl)pyridine
1584673-41-5

2-(4-methyl-2,6-bis(phenylthio)phenyl)pyridine

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II) In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere;97%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

3-methoxy-1-phenylpropene
16277-67-1

3-methoxy-1-phenylpropene

C22H23NO

C22H23NO

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; (R)-2,2'-bis[bis(3,5-dimethyl-4-methoxyphenyl)phosphino]-1,1'-binaphthyl In toluene at 60℃; for 48h; Schlenk technique; Inert atmosphere; enantioselective reaction;97%
styrene
292638-84-7

styrene

2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

2-(2,6-divinylphenyl-4-methyl)-phenylpyridine
1127213-37-9

2-(2,6-divinylphenyl-4-methyl)-phenylpyridine

Conditions
ConditionsYield
With 1-pentyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)amide; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper (I) acetate; silver sulfate at 25℃; for 15h; Reagent/catalyst; Sealed tube; Inert atmosphere;97%
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate; silver(I) triflimide at 20℃; for 24h; Sealed tube; Inert atmosphere; Green chemistry;94%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Benzohydroxamic acid
495-18-1

Benzohydroxamic acid

Poly(bisphenol A carbonate)

Poly(bisphenol A carbonate)

A

BPA
80-05-7

BPA

B

N-(5-methyl-2-(pyridin-2-yl)phenyl)benzamide
1581756-73-1

N-(5-methyl-2-(pyridin-2-yl)phenyl)benzamide

Conditions
ConditionsYield
Stage #1: Benzohydroxamic acid; Poly(bisphenol A carbonate) With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In 2-methyltetrahydrofuran at 30℃; for 4h;
Stage #2: 2-(4-methylphenyl)pyridine With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) triflimide at 60℃; for 15h;
A 97%
B 78%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

bromobenzene
108-86-1

bromobenzene

2-(5'-methyl[1,1':3',1'’-terphenyl]-2'-yl)pyridine
1039045-19-6

2-(5'-methyl[1,1':3',1'’-terphenyl]-2'-yl)pyridine

Conditions
ConditionsYield
With rhodium(II) acetate dimer; 1,3-bis(mesityl)imidazolium chloride; sodium t-butanolate; tricyclohexylphosphine In toluene at 80℃;96%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; 1-Adamantanecarboxylic acid; potassium carbonate In toluene at 120℃; for 18h; Inert atmosphere;
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

Tetraethyl methylenediphosphonate
1660-94-2

Tetraethyl methylenediphosphonate

C21H31NO6P2

C21H31NO6P2

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver sulfate In 1,2-dichloro-ethane at 80℃; for 12h; Sealed tube;96%
2-(4-methylphenyl)pyridine
4467-06-5

2-(4-methylphenyl)pyridine

2-(4-methyl-3-nitrophenyl)pyridine
4373-56-2

2-(4-methyl-3-nitrophenyl)pyridine

Conditions
ConditionsYield
Stage #1: 2-(4-methylphenyl)pyridine With tert-butyl methyl ether; nitric acid In tetrahydrofuran at 0℃;
Stage #2: With sulfuric acid In dichloromethane at 0℃; for 1h; Further stages.;
95%
With dodecacarbonyl-triangulo-triruthenium; copper(II) nitrate trihydrate; oxone||potassium monopersulfate triple salt; tetrabutylammonium acetate; silver trifluoroacetate In 1,2-dichloro-ethane at 95℃; for 36h; Sealed tube; regioselective reaction;76%
With sulfuric acid; potassium nitrate

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