Products

Refine

Country

Business Type

Certificate

Display

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 453-18-9 Methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

Methyl fluoroacetate CAS 453-18-9

Cas:453-18-9

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methyl Fluoroacetate

Cas:453-18-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Other

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

High Purity Methyl Fluoroacetate 453-18-9

Cas:453-18-9

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methyl Fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Methyl fluoroacetate cas 453-18-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methyl fluoroacetate cas 453-18-9

Cas:453-18-9

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

453-18-9

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Methyl fluoroacetate 453-18-9

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shenzhen Foris Technology Co. LTD

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Methyl fluoroacetate 453-18-9

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#453-18-9;CAT#A826773

Cas:453-18-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Anhui Sholon New Material Technology Co., Ltd.

1.Introduction of 453-18-9 Methyl fluoroacetate has the CAS registry number Appearance:Colorless, transparent liquid Storage:Store in a cool, dry place. Store in a tightly closed container Package:Can be packaged in acc

Methyl fluoroacetate

Cas:453-18-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Co.Ltd

1.Stable quality, high quality satisfy customer's high grade sourcing request. 2.Competitive price . 3.Correct delivery time promise. 4.Continuous improvement make sure the long-term cooperation. 5.Honest service for

Factory direct supply Methyl fluoroacetate CAS:453-18-9 with best price

Cas:453-18-9

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

Type:Trading Company

inquiry

Hangzhou KieRay Chem Co.,Ltd.

Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and inter

Methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Zouping Mingxing Chemical Co.,Ltd.

Methyl fluoroacetate CAS: 453-18-9 Molecular formula: C3H5FO2 Appearance: Colorless liquid Content: 99.5% Packing: 200kg Application:As intermediate for organic synthesis

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Chemlin Chemical Co., Ltd.

please contact us to confirm the required quantity and quote, we will provide you with COA,NMR,HPLC and other relevant information Storage:Store in a cool place. Keep container tightly closed in a dry and well-ventilated place Package:as your needs A

methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jinan Great Chemical Co.,Ltd.

Methyl fluoroacetate Molecular Formula C3H5FO2 Molecular Weight 92.07 CAS Registry Number 453-18-9 Methyl fluoroacetateSynon…

Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Pure Chemistry Scientific Inc.

Methyl fluoroacetate Application:2025667

Methyl fluoroacetate

Cas:453-18-9

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Wuhan Recedar Biotechnology Co., Ltd

24 hours after-sale service, good quality with competitive price.GMP standard factory to assure the quality and stable supply.Appearance:yellow to white solid Storage:keep sealed and keep from direct light Package:According client's requirements Appl

99% high quality factory price Methyl fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Ikg Chemical Co., Ltd.

IKGCHEM is a leading manufacturer and supplier of chemical in China.As a Professional chemical raw material supplier,our products are produced in accordance with ISO 9001:2015 Quality Management System and ISO14001:11393 Environmental Management Syst

Methyl Fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Methyl Fluoroacetate Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Methyl Fluoroacetate

Cas:453-18-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

3-ethoxyprop-1-ene
557-31-3

3-ethoxyprop-1-ene

Methyl fluoroiodoacetate
181224-33-9

Methyl fluoroiodoacetate

A

methyl fluoroacetate
453-18-9

methyl fluoroacetate

B

5-Ethoxy-2-fluoro-4-iodo-pentanoic acid methyl ester

5-Ethoxy-2-fluoro-4-iodo-pentanoic acid methyl ester

Conditions
ConditionsYield
With iron In tetrahydrofuran for 12h; Heating;A 9 % Spectr.
B 82%
Methyl fluoroiodoacetate
181224-33-9

Methyl fluoroiodoacetate

A

methyl fluoroacetate
453-18-9

methyl fluoroacetate

B

Propionic acid 1-fluoro-2-(4-iodomethyl-tetrahydro-furan-3-yl)-ethyl ester

Propionic acid 1-fluoro-2-(4-iodomethyl-tetrahydro-furan-3-yl)-ethyl ester

Conditions
ConditionsYield
With Allyl ether; iron In tetrahydrofuran for 13h; Heating;A 11 % Spectr.
B 81%
methyl chloroacetate
96-34-4

methyl chloroacetate

methyl fluoroacetate
453-18-9

methyl fluoroacetate

Conditions
ConditionsYield
With potassium fluoride; tetrabutylammomium bromide for 1.25h; Heating;79%
With acetamide; potassium fluoride at 100 - 110℃; for 3h; Substitution;30%
With acetamide; potassium fluoride at 100 - 110℃; for 3h; Substitution;30%
acrylonitrile
107-13-1

acrylonitrile

Methyl fluoroiodoacetate
181224-33-9

Methyl fluoroiodoacetate

A

methyl fluoroacetate
453-18-9

methyl fluoroacetate

B

4-Cyano-2-fluoro-butyric acid methyl ester

4-Cyano-2-fluoro-butyric acid methyl ester

Conditions
ConditionsYield
With [2,2]bipyridinyl; chromium chloride; iron In methanol at 70 - 80℃; for 10h;A 14 % Spectr.
B 74%
acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Methyl fluoroiodoacetate
181224-33-9

Methyl fluoroiodoacetate

A

methyl fluoroacetate
453-18-9

methyl fluoroacetate

B

Dimethyl 2-fluoropentanedioate
7766-74-7

Dimethyl 2-fluoropentanedioate

Conditions
ConditionsYield
With [2,2]bipyridinyl; chromium chloride; iron In methanol at 70 - 80℃; for 11h;A 17 % Spectr.
B 71%
methanol
67-56-1

methanol

fluoroacetamide
640-19-7

fluoroacetamide

methyl fluoroacetate
453-18-9

methyl fluoroacetate

Conditions
ConditionsYield
With boron trifluoride
methyl 2-iodoacetate
5199-50-8

methyl 2-iodoacetate

methyl fluoroacetate
453-18-9

methyl fluoroacetate

Conditions
ConditionsYield
With silver fluoride at 170℃;
With mercury(II) fluoride at 170℃;
bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

methyl fluoroacetate
453-18-9

methyl fluoroacetate

Conditions
ConditionsYield
With thallium(I) fluoride; ethanol
With potassium fluoride; acetylacetone Irradiation.UV-Licht;
methanol
67-56-1

methanol

perfluoropropylene
116-15-4

perfluoropropylene

methyl fluoroacetate
453-18-9

methyl fluoroacetate

Conditions
ConditionsYield
With carbon dioxide; sodium In acetone
methanol
67-56-1

methanol

monofluoroacetyl chloride
359-06-8

monofluoroacetyl chloride

methyl fluoroacetate
453-18-9

methyl fluoroacetate

ethanol
64-17-5

ethanol

bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

Tlf

Tlf

methyl fluoroacetate
453-18-9

methyl fluoroacetate

dimethyl sulfate
77-78-1

dimethyl sulfate

sodium-fluoroacetate

sodium-fluoroacetate

methyl fluoroacetate
453-18-9

methyl fluoroacetate

methyl fluoroacetate
453-18-9

methyl fluoroacetate

allyl S-(5-amido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonicacid)-(2→6)-2-acetamido-2-deoxy-6-thio-α-Dgalactopyranoside

allyl S-(5-amido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonicacid)-(2→6)-2-acetamido-2-deoxy-6-thio-α-Dgalactopyranoside

allyl S-(5-fluoroacetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2→6)-2-acetamido-2-deoxy-6-thio-α-D-galactopyranoside

allyl S-(5-fluoroacetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2→6)-2-acetamido-2-deoxy-6-thio-α-D-galactopyranoside

Conditions
ConditionsYield
With triethylamine In methanol Inert atmosphere; Reflux;100%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

sodium fluoroacetate
62-74-8

sodium fluoroacetate

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran for 2h; Reflux;94%
(R)-N-benzylidene-2-methylpropane-2-sulfinamide
196929-85-8

(R)-N-benzylidene-2-methylpropane-2-sulfinamide

methyl fluoroacetate
453-18-9

methyl fluoroacetate

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-phenylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-phenylpropionic acid methyl ester

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at -80℃; for 0.5h; Inert atmosphere;88%
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;85%
tris(methylthio)methane
5418-86-0

tris(methylthio)methane

methyl fluoroacetate
453-18-9

methyl fluoroacetate

3-Fluoro-1,1,1-tris-methylsulfanyl-propan-2-one

3-Fluoro-1,1,1-tris-methylsulfanyl-propan-2-one

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane 1.) -95 deg C, 2 h, 2.) -95 deg C, 5 min;87%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

allyl 4-O-(5-amino-3,5-dideoxy-α-D-neuraminopyranosyl)-2-acetylamino-2-deoxy-α-D-galactopyranoside

allyl 4-O-(5-amino-3,5-dideoxy-α-D-neuraminopyranosyl)-2-acetylamino-2-deoxy-α-D-galactopyranoside

C22H35FN2O14
1263480-77-8

C22H35FN2O14

Conditions
ConditionsYield
With triethylamine In methanol at 20℃; Inert atmosphere; Cooling with ice;85%
With triethylamine In methanol at 20℃; Inert atmosphere; Cooling with ice;
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(R)-(-)-N-(4-chlorobenzylidene)-2-methylpropane-2-sulfinamide
507469-89-8

(R)-(-)-N-(4-chlorobenzylidene)-2-methylpropane-2-sulfinamide

A

C14H19ClFNO3S

C14H19ClFNO3S

B

(RS,2R,3S)-3-(4-chlorophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

(RS,2R,3S)-3-(4-chlorophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A n/a
B 83%
With potassium tert-butylate In tetrahydrofuran at 30℃; for 0.5h; Inert atmosphere; Overall yield = 83 %;A n/a
B n/a
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
31469-15-5

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

methyl fluoroacetate
453-18-9

methyl fluoroacetate

methyl 3-cyano-4-fluoro-2,2-dimethyl-3-trimethylsilyloxybutanoate

methyl 3-cyano-4-fluoro-2,2-dimethyl-3-trimethylsilyloxybutanoate

Conditions
ConditionsYield
With gallium(III) iodide In dichloromethane at 20℃; for 5h;82%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

C17H17Cl2NOS
1547490-94-7

C17H17Cl2NOS

A

(RS,2R)-3,3-bis(4-chlorophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

(RS,2R)-3,3-bis(4-chlorophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

B

C20H22Cl2FNO3S

C20H22Cl2FNO3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 82%
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(S)-5-(aminomethyl)-3-(3-fluoro-4-(4-(pyridin-2-yl)-1H-pyrazol-1-yl)phenyl)oxazolidin-2-one

(S)-5-(aminomethyl)-3-(3-fluoro-4-(4-(pyridin-2-yl)-1H-pyrazol-1-yl)phenyl)oxazolidin-2-one

(S)-2-fluoro-N-((3-(3-fluoro-4-(4-(pyridin-2-yl)-1H-pyrazol-1-yl)phenyl)-2-oxooxazolidin-5-yl)methyl)acetamide

(S)-2-fluoro-N-((3-(3-fluoro-4-(4-(pyridin-2-yl)-1H-pyrazol-1-yl)phenyl)-2-oxooxazolidin-5-yl)methyl)acetamide

Conditions
ConditionsYield
In 2,2,2-trifluoroethanol at 80℃; for 15h;81%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

C12H17NOS
1015198-46-5

C12H17NOS

A

C15H22FNO3S

C15H22FNO3S

B

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-p-tolylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-p-tolylpropionic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A n/a
B 80%
With sodium hexamethyldisilazane In tetrahydrofuran; dichloromethane at -20℃; for 0.5h; Inert atmosphere; Overall yield = 80 %; Overall yield = 252 mg;A n/a
B n/a
formaldehyd
50-00-0

formaldehyd

methyl fluoroacetate
453-18-9

methyl fluoroacetate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
Stage #1: methyl fluoroacetate With Dimethyl oxalate; sodium methylate In dimethyl sulfoxide at 15 - 25℃; for 1h; Inert atmosphere;
Stage #2: formaldehyd With 2,6-di-tert-butyl-4-methyl-phenol In dimethyl sulfoxide at 20 - 35℃; for 1h; Temperature; Reagent/catalyst; Inert atmosphere;
79.3%
Stage #1: methyl fluoroacetate With Dimethyl oxalate; sodium methylate In methanol; pentane at 20 - 25℃; for 24.25h; Claisen Condensation;
Stage #2: formaldehyd In pentane at 5 - 10℃; for 5h; Concentration; Reagent/catalyst; Temperature; Time;
58%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(R)-2-methyl-N-(3-(trifluoromethyl)benzylidene)propane-2-sulfinamide

(R)-2-methyl-N-(3-(trifluoromethyl)benzylidene)propane-2-sulfinamide

A

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-(3-trifluoromethylphenyl)propionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-(3-trifluoromethylphenyl)propionic acid methyl ester

B

C15H19F4NO3S

C15H19F4NO3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 77%
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide
1208989-34-7

2-methylpropane-2-sulfinic acid [1-(2-methyl-1-ylphenyl)ethylidene]amide

A

C15H22FNO3S

C15H22FNO3S

B

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-o-tolylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-o-tolylpropionic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A n/a
B 76%
With potassium hexamethylsilazane In tetrahydrofuran; N,N-dimethyl-formamide at -40℃; for 0.5h; Inert atmosphere; Overall yield = 88 %; Overall yield = 277 mg;A n/a
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide

(R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide

A

(RS,2R,3S)-3-(4-bromophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid tert-butyl ester

(RS,2R,3S)-3-(4-bromophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid tert-butyl ester

B

C14H19BrFNO3S

C14H19BrFNO3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 76%
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

C24H41NO18

C24H41NO18

C26H42FNO19

C26H42FNO19

Conditions
ConditionsYield
With triethylamine In methanol at 0 - 50℃; Inert atmosphere;75%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

C12H17NOS

C12H17NOS

A

C15H22FNO3S

C15H22FNO3S

B

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-m-tolylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-m-tolylpropionic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A n/a
B 74%
With sodium t-butanolate In tetrahydrofuran at 10℃; for 0.5h; Inert atmosphere; Overall yield = 74 %; Overall yield = 233 mg;A n/a
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide
935263-24-4

(R)-(-)-N-(4-cyanobenzylidene)-2-methylpropane-2-sulfinamide

A

(RS,2R,3S)-3-(4-cyanophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

(RS,2R,3S)-3-(4-cyanophenyl)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)propionic acid methyl ester

B

C15H19FN2O3S

C15H19FN2O3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 71%
B n/a
N-tert-butylsulfinyl ketoimine
891782-22-2

N-tert-butylsulfinyl ketoimine

methyl fluoroacetate
453-18-9

methyl fluoroacetate

A

C20H24FNO3S

C20H24FNO3S

B

C20H24FNO3S

C20H24FNO3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 71%
B n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

(RS)-N-[(2-naphthyl)methylidene]-2-methyl-2-propanesulfinamide
507469-91-2

(RS)-N-[(2-naphthyl)methylidene]-2-methyl-2-propanesulfinamide

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-naphthalen-2-ylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-naphthalen-2-ylpropionic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;70%
With potassium hexamethylsilazane In tetrahydrofuran; N,N-dimethyl-formamide at -40℃; for 0.5h; Inert atmosphere;n/a
methyl fluoroacetate
453-18-9

methyl fluoroacetate

N-t-butylsulfinyl-2-pyridinyl carboxaenamine
1015198-59-0

N-t-butylsulfinyl-2-pyridinyl carboxaenamine

A

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-pyridin-2-ylpropionic acid methyl ester

(RS,2R,3S)-2-fluoro-3-(2-methylpropane-2-sulfinylamino)-3-pyridin-2-ylpropionic acid methyl ester

B

C13H19FN2O3S

C13H19FN2O3S

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.5h; Inert atmosphere; diastereoselective reaction;A 70%
B n/a
1-indoline
496-15-1

1-indoline

methyl fluoroacetate
453-18-9

methyl fluoroacetate

2-fluoro-1-(indolin-1-yl)ethanone

2-fluoro-1-(indolin-1-yl)ethanone

Conditions
ConditionsYield
at 80℃; for 12h;70%
Dimethyl oxalate
553-90-2

Dimethyl oxalate

methyl fluoroacetate
453-18-9

methyl fluoroacetate

O-methylisourea hemisulfate
52328-05-9

O-methylisourea hemisulfate

C7H7FN2O4

C7H7FN2O4

Conditions
ConditionsYield
Stage #1: Dimethyl oxalate; methyl fluoroacetate With sodium methylate In toluene at 25℃; for 2h;
Stage #2: O-methylisourea hemisulfate With sodium methylate In toluene at 35℃; for 8h;
70%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

allyl 6-O-(5-amino-3,5-dideoxy-α-D-neuraminopyranosyl)-2-amino-2-deoxy-α-D-galactopyranoside

allyl 6-O-(5-amino-3,5-dideoxy-α-D-neuraminopyranosyl)-2-amino-2-deoxy-α-D-galactopyranoside

C22H34F2N2O14
1263481-00-0

C22H34F2N2O14

Conditions
ConditionsYield
With triethylamine In methanol at 20℃; Inert atmosphere; Cooling with ice;67%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)ethyl]cyclohexylamine hydrochloride

trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)ethyl]cyclohexylamine hydrochloride

trans-N-{4-[2-(4-benzo[1,3]dioxol-4-ylpiperidin-1-yl)ethyl]cyclohexyl}-2-fluoroacetamide

trans-N-{4-[2-(4-benzo[1,3]dioxol-4-ylpiperidin-1-yl)ethyl]cyclohexyl}-2-fluoroacetamide

Conditions
ConditionsYield
Stage #1: methyl fluoroacetate With potassium trimethylsilonate In 1,4-dioxane at 20℃;
Stage #2: trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)ethyl]cyclohexylamine hydrochloride With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In 1,4-dioxane at 20℃; for 4h;
66.7%
methyl fluoroacetate
453-18-9

methyl fluoroacetate

trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)-ethyl]-cyclohexylamine hydrochloride

trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)-ethyl]-cyclohexylamine hydrochloride

N-trans-{4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)-ethyl]-cyclohexyl}-2-fluoro-acetamide
1395922-18-5

N-trans-{4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)-ethyl]-cyclohexyl}-2-fluoro-acetamide

Conditions
ConditionsYield
Stage #1: methyl fluoroacetate With potassium trimethylsilonate In 1,4-dioxane at 20℃;
Stage #2: trans-4-[2-(4-benzo[1,3]dioxol-4-yl-piperidin-1-yl)-ethyl]-cyclohexylamine hydrochloride With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In 1,4-dioxane at 20℃; for 4h;
66.7%

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View