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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 2-fluoroacrylate Manufacturer/High quality/Best price/In stock

Cas:2343-89-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 2-Fluoroacrylate supplier in China

Cas:2343-89-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

Methyl 2-Fluoroacrylate [Chemical Name]: Methyl 2-Fluoroacrylate [CAS No.]: 2343-89-7 [Structure Formula]: [Molecular Formula]: C4H5F

Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply methyl 2-fluoroacrylate

Cas:2343-89-7

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 2-Propenoic acid,2-fluoro-, methyl ester 2343-89-7 ISO Manufacturer

Cas:2343-89-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Fluoroacrylic acid methyl ester

Cas:2343-89-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Methyl 2-Fluoroacrylate CAS:2343-89-7 MF: C4H5FO2 Appearance:White Powder Storage:Store in cool and dry place, away from sun light. Package:25KG Application:Syntheses Material Intermediates Transportation:By sea or by air Port:Qingdao Port

Methyl 2-Fluoroacrylate CAS:2343-89-7

Cas:2343-89-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Methyl 2-fluoroacrylate--

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 2343-89-7 with competitive price

Cas:2343-89-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Propenoic acid,2-fluoro-, methyl ester 2343-89-7

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

METHYL 2-FLUOROACRYLATE CAS: 2343-89-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

METHYL 2-FLUOROACRYLATE CAS: 2343-89-7

Cas:2343-89-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 2343-89-7 METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2343-89-7

Cas:2343-89-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Propenoic acid,2-fluoro-, methyl ester

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 2-fluoroacrylate

Cas:2343-89-7

Min.Order:0

Negotiable

Type:Manufacturers

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

high purity methyl 2-fluoroprop-2-enoate cas no.2343-89-7

Cas:2343-89-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

1. Well-equipped, stable and high-quality raw material supply chain, to provide customers with the best quality products. 2.Strict quality inspection process and professional certificate testing to ensure the quality level of the final product. 3.E

hot sale Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting Methyl 2-Fluoroacrylate, CAS NO: 2343-89-7 Please contact us by email freely. We are leading exporter in China. If you really need this cargo, pl

Methyl 2-Fluoroacrylate, CAS NO: 2343-89-7

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methyl 2-Fluoroacrylate

Cas:2343-89-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Methyl 2-Fluoroacrylate CAS No.:2343-89-7 Molecule Formula:C4H5FO2 Molecule Weight:104.08 Purity: 98.0% Package: 200kg/drum Description:Colorless or light yellow transparent liquid Manufacture Standards:Enterprise Standard

High Quality Methyl 2-Fluoroacrylate in stock

Cas:2343-89-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl 2-fluoroacrylate

Cas:2343-89-7

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:0

Negotiable

Type:Trading Company

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

METHYL2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

METHYL 2-FLUOROACRYLATE Basic information Product Name: METHYL 2-FLUOROACRYLATE Synonyms: METHYL 2-FLUOROACRYLATE;Methyl fluoroacrylate;2-Propenoic acid, 2-fluoro-, methyl ester;Methyl 2-fluoroprop-2-enoate;Methyl 2-fluoroacrylate, BHT stabliz

METHYL 2-FLUOROACRYLATE

Cas:2343-89-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Synthetic route

Methyl 2-Fluoro-3-(4-toluenesulfonyloxy)propanoate
85345-88-6

Methyl 2-Fluoro-3-(4-toluenesulfonyloxy)propanoate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With potassium phtalimide at -78 - 150℃; under 0.01 Torr;97%
Methyl 3-chloro-2-fluoropropanoate
55900-27-1

Methyl 3-chloro-2-fluoropropanoate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium phosphate In 1-methyl-pyrrolidin-2-one at 150℃; under 112.511 - 225.023 Torr;95%
With dimethyl amine In diethyl ether; benzene
methanol
67-56-1

methanol

2-fluoroacrylic acid
430-99-9

2-fluoroacrylic acid

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With thionyl chloride at 5 - 35℃; for 2h; Concentration; Reagent/catalyst;93%
dimethyl 2-fluoro-2-chloromethylmalonate

dimethyl 2-fluoro-2-chloromethylmalonate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium carbonate In 1-methyl-pyrrolidin-2-one at 150℃; under 225.023 Torr; for 4h;92%
methanol
67-56-1

methanol

1-chloro-1-fluoroethane
2317-91-1

1-chloro-1-fluoroethane

carbon monoxide
201230-82-2

carbon monoxide

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II); triethylamine at 100℃; under 5250.53 Torr; for 8h; Reagent/catalyst; Autoclave;91.8%
With bis(tri-t-butylphosphine)palladium(0) at 100℃; for 18h; Reagent/catalyst; Time; Autoclave;77.4%
methanol
67-56-1

methanol

1-bromo-1-fluoroethylene
420-25-7

1-bromo-1-fluoroethylene

carbon monoxide
201230-82-2

carbon monoxide

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; lithium carbonate; triethylamine at 90℃; for 6h; Reagent/catalyst; Temperature; Autoclave;90.7%
With dichloro[4,5-bis(diphenylphosphino)-9,9’-dimethylxanthene]palladium(II); triethylamine at 100℃; under 7500.75 Torr; for 8h; Reagent/catalyst; Autoclave;90.1%
With bis-triphenylphosphine-palladium(II) chloride; tributyl-amine; lithium carbonate at 90℃; under 7500.75 Torr; for 6h; Reagent/catalyst; Autoclave;71.8 g
1-chloro-1-fluoro-2,2-dimethoxycyclopropane

1-chloro-1-fluoro-2,2-dimethoxycyclopropane

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; methoxybenzene at 120 - 130℃; under 500 Torr; Reagent/catalyst; Temperature;89.5%
With 2,6-di-tert-butyl-4-methyl-phenol at 145℃; under 360 Torr;12.3 g
methyl 3-bromo-2-fluoro-2-chloropropanoate
2365-93-7

methyl 3-bromo-2-fluoro-2-chloropropanoate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine; sulfuric acid; zinc In water at 82 - 86℃; for 0.333333h;85%
With hydrogen sulfide; sodium N-nitroso-N-phenylhydroxylaminate; zinc In water at 100℃;82%
With zinc80%
With sulfuric acid; zinc
C13H13FO6

C13H13FO6

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine In sulfolane at 180℃; for 6h;83.9%
C14H15FO6

C14H15FO6

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 4-methoxy-phenol at 170℃; for 9h;81.2%
C14H25FO5

C14H25FO5

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine at 170℃; for 15h;81.2%
formaldehyd
50-00-0

formaldehyd

methyl fluoroacetate
453-18-9

methyl fluoroacetate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
Stage #1: methyl fluoroacetate With Dimethyl oxalate; sodium methylate In dimethyl sulfoxide at 15 - 25℃; for 1h; Inert atmosphere;
Stage #2: formaldehyd With 2,6-di-tert-butyl-4-methyl-phenol In dimethyl sulfoxide at 20 - 35℃; for 1h; Temperature; Reagent/catalyst; Inert atmosphere;
79.3%
Stage #1: methyl fluoroacetate With Dimethyl oxalate; sodium methylate In methanol; pentane at 20 - 25℃; for 24.25h; Claisen Condensation;
Stage #2: formaldehyd In pentane at 5 - 10℃; for 5h; Concentration; Reagent/catalyst; Temperature; Time;
58%
methyl 2R,3S-2,3-difluoro-2,3-dichloropropionate
67832-56-8, 76497-87-5, 76548-29-3

methyl 2R,3S-2,3-difluoro-2,3-dichloropropionate

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

B

methyl Z-α,β-difluoropropenoate
1660-56-6

methyl Z-α,β-difluoropropenoate

Conditions
ConditionsYield
With sulfuric acid; zinc at 100℃;A 10%
B 75%
methyl α,β-dibromo-α-fluoropropionate
380-26-7

methyl α,β-dibromo-α-fluoropropionate

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

B

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Conditions
ConditionsYield
With thiourea; zinc In diphenylether at 95℃; under 20 Torr;A 74%
B n/a
C13H15FO7S

C13H15FO7S

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol In sulfolane at 140℃; for 17h;73.8%
methyl α-bromo-α-fluoropropionate

methyl α-bromo-α-fluoropropionate

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

B

methyl 2,2-difluoropropanoate
38650-84-9

methyl 2,2-difluoropropanoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; hydrogen fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 50℃; for 48h; Solvent; Temperature; Reagent/catalyst; Cooling with ice;A 23%
B 73%
methanol
67-56-1

methanol

1-bromo-1-fluoroethylene
420-25-7

1-bromo-1-fluoroethylene

carbon monoxide
201230-82-2

carbon monoxide

A

2-fluoroacrylic acid
430-99-9

2-fluoroacrylic acid

B

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(ll); triethylamine at 100℃; under 7500.75 Torr; for 13h; Autoclave;A 14.1%
B 70.9%
methyl α-bromo-α-fluoropropionate

methyl α-bromo-α-fluoropropionate

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

B

2,2-difluoropropanoic acid
373-96-6

2,2-difluoropropanoic acid

C

methyl 2,2-difluoropropanoate
38650-84-9

methyl 2,2-difluoropropanoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; hydrogen fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 50℃; for 72h; Reagent/catalyst; Solvent; Temperature; Cooling with ice;A 18%
B 5%
C 70%
dimethyl 2-fluoro-2-(hydroxymethyl)malonate
107843-23-2

dimethyl 2-fluoro-2-(hydroxymethyl)malonate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With sulfolane; potassium fluoride; 2,6-di-tert-butyl-4-methyl-phenol at 90 - 105℃; under 760.051 Torr; for 1.25h;70%
With 2,6-di-tert-butyl-4-methyl-phenol; sodium carbonate In 1-methyl-pyrrolidin-2-one at 150℃; under 225.023 Torr;24 g
methyl (2R,3R)-2,3-difluoro-2,3-dichloropropionate
76548-29-3

methyl (2R,3R)-2,3-difluoro-2,3-dichloropropionate

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

B

methyl Z-α,β-difluoropropenoate
1660-56-6

methyl Z-α,β-difluoropropenoate

C

methyl α,β-difluoroacrylate
76474-26-5

methyl α,β-difluoroacrylate

Conditions
ConditionsYield
With sulfuric acid; zinc at 100℃;A 10%
B 64%
C 10%
2,3-Dichlor-2-fluor-propansaeuremethylester
53510-07-9

2,3-Dichlor-2-fluor-propansaeuremethylester

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With sulfuric acid; water; zinc at 100 - 110℃;52%
2,3-difluoropropionic acid methyl ester
4447-55-6

2,3-difluoropropionic acid methyl ester

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With sodium fluoride at 30℃; for 3h;46.9%
methanol
67-56-1

methanol

Vinylidene fluoride
75-38-7

Vinylidene fluoride

carbon monoxide
201230-82-2

carbon monoxide

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
Stage #1: methanol With bis-triphenylphosphine-palladium(II) chloride; triethylamine; triphenylphosphine; lithium iodide In 1,4-dioxane at -78 - 30℃; for 1.5h; Autoclave; Sealed tube; Inert atmosphere;
Stage #2: Vinylidene fluoride; carbon monoxide In 1,4-dioxane at 90℃; under 3000.3 Torr; for 24h; Concentration; Solvent; Temperature; Autoclave; Sealed tube;
5%
methyl 3-bromo-2-fluoropropionate
399-86-0

methyl 3-bromo-2-fluoropropionate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With dimethyl amine In diethyl ether; benzene
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

A

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

(1S,2R,4S)-2-Fluoro-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

(1S,2R,4S)-2-Fluoro-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

(1R,2R,4R)-2-Fluoro-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

(1R,2R,4R)-2-Fluoro-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With thiourea; zinc 1.) diphenyl ether, 95 deg C, 20 Torr, 2.) room temperature; Yield given. Multistep reaction. Yields of byproduct given;
methyl α-bromo-α-fluoropropionate

methyl α-bromo-α-fluoropropionate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 10H-phenothiazine; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 70℃; for 5h; Product distribution / selectivity;
formaldehyd
50-00-0

formaldehyd

C6H6FO5(1-)*Na(1+)

C6H6FO5(1-)*Na(1+)

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
Stage #1: C6H6FO5(1-)*Na(1+) In dimethyl sulfoxide for 0.333333h; Molecular sieve;
Stage #2: formaldehyd In dimethyl sulfoxide at 40℃; for 1.5h; Molecular sieve;
19 g
1,1-dimethoxyethylene
922-69-0

1,1-dimethoxyethylene

Dichlorofluoromethane
75-43-4

Dichlorofluoromethane

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
Stage #1: 1,1-dimethoxyethylene; Dichlorofluoromethane With tetrabutylammomium bromide; potassium hydroxide In hexane; water at 5 - 10℃;
Stage #2: With 2,6-di-tert-butyl-4-methyl-phenol at 0 - 145℃; under 360 Torr;
dimethyl 2-fluoro-2-chlorosulfinyloxymethylmalonate

dimethyl 2-fluoro-2-chlorosulfinyloxymethylmalonate

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium carbonate In 1-methyl-pyrrolidin-2-one at 130℃; under 225.023 Torr; for 4h;
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

3-methoxy-1-iodobenzene
766-85-8

3-methoxy-1-iodobenzene

(Z)-methyl 2-fluoro-3-(3-methoxyphenyl)acrylate

(Z)-methyl 2-fluoro-3-(3-methoxyphenyl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

(Z)-methyl 2-fluoro-3-(2-methylphenyl)acrylate

(Z)-methyl 2-fluoro-3-(2-methylphenyl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

(Z)-methyl 2-(2-fluoro-3-methoxy-3-oxoprop-1-en-1-yl)benzoate

(Z)-methyl 2-(2-fluoro-3-methoxy-3-oxoprop-1-en-1-yl)benzoate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

2-iodonaphthalene
612-55-5

2-iodonaphthalene

(Z)-methyl 2-fluoro-3-(naphth-2-yl)acrylate
1075204-23-7

(Z)-methyl 2-fluoro-3-(naphth-2-yl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
iodobenzene
591-50-4

iodobenzene

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

methyl (Z)-2-fluoro-3-phenylpropenoate
370-07-0, 56695-79-5, 56695-78-4

methyl (Z)-2-fluoro-3-phenylpropenoate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Reagent/catalyst; Temperature; Heck Reaction; stereospecific reaction;99%
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Sealed tube; Inert atmosphere;
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

(Z)-methyl 3-(4-fluorophenyl)-2-fluoroacrylate

(Z)-methyl 3-(4-fluorophenyl)-2-fluoroacrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

4-Iodobenzotrifluoride
455-13-0

4-Iodobenzotrifluoride

methyl Z-2-fluoro-3-(4-trifluoromethylphenyl)prop-2-enoate
126976-31-6

methyl Z-2-fluoro-3-(4-trifluoromethylphenyl)prop-2-enoate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;99%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

2-6-dimethoxybenzoic acid
1466-76-8

2-6-dimethoxybenzoic acid

(Z)-methyl 2-fluoro-3-(2,6-dimethoxyphenyl)acrylate

(Z)-methyl 2-fluoro-3-(2,6-dimethoxyphenyl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane; dimethyl sulfoxide at 120℃; for 12h; Sealed tube; diastereoselective reaction;98%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

octadec-1-ene
112-88-9

octadec-1-ene

methyl (Z)-2-fluorononadec-2-enoate

methyl (Z)-2-fluorononadec-2-enoate

Conditions
ConditionsYield
With [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II) In dichloromethane at 80℃; for 15h; Cross Metathesis; Inert atmosphere; Sealed tube; diastereoselective reaction;98%
propylamine
107-10-8

propylamine

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

N-(n-propyl)-α-fluoroacrylamide
1378386-19-6

N-(n-propyl)-α-fluoroacrylamide

Conditions
ConditionsYield
In methanol at 20℃; for 24h;96.14%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine
93102-05-7

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

methyl 1-benzyl 3-fluoropyrrolidine-3-carboxylate
1279669-60-1

methyl 1-benzyl 3-fluoropyrrolidine-3-carboxylate

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 4h;95%
With trifluoroacetic acid In dichloromethane at 20℃; for 4h; Inert atmosphere;80%
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

1-(1,1-dimethylethyl)-1H-indole-1,2-dicarboxylic acid 2-methyl ester
163229-48-9

1-(1,1-dimethylethyl)-1H-indole-1,2-dicarboxylic acid 2-methyl ester

C19H22FNO6

C19H22FNO6

Conditions
ConditionsYield
With [Ir(dF(Me)ppy)2dtbbpy]PF6 In tetrahydrofuran at 28℃; Inert atmosphere; Glovebox; Irradiation;93%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

(R)-N-(1-phenylethyl)-N-(methoxymethyl)-N-(trimethylsilylmethyl)amine
133407-38-2

(R)-N-(1-phenylethyl)-N-(methoxymethyl)-N-(trimethylsilylmethyl)amine

methyl 3-fluoro-1-[(1R)-1-phenylethyl]pyrrolidine-3-carboxylate
1461698-11-2

methyl 3-fluoro-1-[(1R)-1-phenylethyl]pyrrolidine-3-carboxylate

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 5h; Inert atmosphere;92%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

methyl (2Z)-2-fluoro-3-(2-methoxyphenyl)acrylate

methyl (2Z)-2-fluoro-3-(2-methoxyphenyl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane; dimethyl sulfoxide at 120℃; for 12h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; diastereoselective reaction;92%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

N-methylaniline
100-61-8

N-methylaniline

3-fluoro-1-phenylpyrrolidin-2-one

3-fluoro-1-phenylpyrrolidin-2-one

Conditions
ConditionsYield
With Quinuclidine; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate In acetonitrile for 16h; Sealed tube; Inert atmosphere; Irradiation;92%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

3,5-difluoro-N-hydroxybenzenecarboximidoyl chloride
677728-84-6

3,5-difluoro-N-hydroxybenzenecarboximidoyl chloride

methyl 3-(3,5-difluorophenyl)-5-fluoro-4,5-dihydro-1,2-oxazole-5-carboxylate

methyl 3-(3,5-difluorophenyl)-5-fluoro-4,5-dihydro-1,2-oxazole-5-carboxylate

Conditions
ConditionsYield
With sodium hydrogencarbonate In isopropyl alcohol at 40℃; for 1h;91%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

4-iodobenzonitrile
3058-39-7

4-iodobenzonitrile

methyl Z-3-(4-cyanophenyl)-2-fluoroprop-2-enoate
126976-32-7

methyl Z-3-(4-cyanophenyl)-2-fluoroprop-2-enoate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; stereospecific reaction;90%
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Sealed tube; Inert atmosphere;
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

(Z)-methyl 3-(4-bromophenyl)-2-fluoroacrylate

(Z)-methyl 3-(4-bromophenyl)-2-fluoroacrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane at 90℃; for 4h; Heck Reaction; chemoselective reaction;89%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

mesitylenecarboxylic acid
480-63-7

mesitylenecarboxylic acid

(Z)-methyl 2-fluoro-3-(2,4,6-trimethylphenyl)acrylate

(Z)-methyl 2-fluoro-3-(2,4,6-trimethylphenyl)acrylate

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; silver carbonate In 1,4-dioxane; dimethyl sulfoxide at 120℃; for 12h; Sealed tube; diastereoselective reaction;89%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

2-fluoroacrylic acid
430-99-9

2-fluoroacrylic acid

Conditions
ConditionsYield
Stage #1: methyl 2-fluoroprop-2-enoate With sodium hydroxide In ethanol; water for 0.5h; pH=11; Inert atmosphere;
Stage #2: With hydrogenchloride In diethyl ether; water Inert atmosphere;
87%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

A

(Z)-methyl 2-fluoro-4-phenyl-2-butenoate
113924-47-3

(Z)-methyl 2-fluoro-4-phenyl-2-butenoate

B

methyl (Z)-2-fluoro-5-phenylpent-2-enoate

methyl (Z)-2-fluoro-5-phenylpent-2-enoate

Conditions
ConditionsYield
With [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II) In chloroform at 80℃; for 15h; Reagent/catalyst; Solvent; Cross Metathesis; Inert atmosphere; Sealed tube; diastereoselective reaction;A n/a
B 87%
methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

1-(but-3-en-1-yl)-2-methoxybenzene
63667-83-4

1-(but-3-en-1-yl)-2-methoxybenzene

methyl (Z)-2-fluoro-5-(2-methoxyphenyl)pent-2-enoate

methyl (Z)-2-fluoro-5-(2-methoxyphenyl)pent-2-enoate

Conditions
ConditionsYield
With [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II) In dichloromethane at 80℃; for 15h; Cross Metathesis; Inert atmosphere; Sealed tube; diastereoselective reaction;87%
1-Decene
872-05-9

1-Decene

methyl 2-fluoroprop-2-enoate
2343-89-7

methyl 2-fluoroprop-2-enoate

methyl (Z)-2-fluoroundeca-2-enoate

methyl (Z)-2-fluoroundeca-2-enoate

Conditions
ConditionsYield
With [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II) In dichloromethane at 80℃; for 15h; Cross Metathesis; Inert atmosphere; Sealed tube; diastereoselective reaction;87%
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