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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

T he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service Appearance:White

METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE

Cas:4707-47-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 4707-47-5 METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE Manufacturer

Cas:4707-47-5

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3,6-Dimethyl-β-resorcylic acid methyl ester

Cas:4707-47-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Leader Biochemical Group

About Product Details

China Northwest Largest Factory Manufacturer Supply METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE CAS 4707-47-5

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 4707-47-5 with best quality

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzoic acid,2,4-dihydroxy-3,6-dimethyl-, methyl ester

Cas:4707-47-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE CAS:4707-47-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high

METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE CAS:4707-47-5

Cas:4707-47-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid,2,4-dihydroxy-3,6-dimethyl-, methyl ester

Cas:4707-47-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid,2,4-dihydroxy-3,6-dimethyl-, methyl ester

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzoic acid,2,4-dihydroxy-3,6-dimethyl-, methyl ester

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $30.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Chemical Name: METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE CAS No.: 4707-47-5 Molecular Formula: C10H12O4 Molecular Weight: 196.2 Appearance:White to off-white powder Storage:Store in cool and dry place, away from sun light. Package:25KG Application

Methyl-2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Atraric acid ;METHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATE.99%

Cas:4707-47-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate CAS NO.4707-47-5

Cas:4707-47-5

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate CAS NO.4707-47-5

Cas:4707-47-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate CAS NO.4707-47-5

Cas:4707-47-5

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

ProductName:Methyl Atratate VERAMOSS Synonyms:Methyl atratate;Methyl 2,4-dihydroxy-3,6-dimethylbenzoate; CAS:4707-47-5 Molecular Formula:C10H12O4 Molecular Weight:196 EINECS No.:225-193-0 Appearance:Diamond-like crystal. Odour:Woody s

Methyl Atratate VERAMOSS

Cas:4707-47-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Methyl 2,4-dihydroxy-3,6-dimethylbenzoate CAS NO.4707-47-5

Cas:4707-47-5

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Methyl-2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl-2,4-dihydroxy-3,6-dimethylbenzoate

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Methyl 2,4-dihydroxy-3,6-diMethylbenzoate

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Tengzhou Runlong Fragrance Co., Ltd.

AN ISO 9001, ISO 14001, ISO 22024 CERTIFIED FACTORY,HALAL 、KOSHER、FCC AND FDA CERTIFICATE ARE AVAILABLE. Storage:1000KG Package:25kg per drum Application:Daily flavor, food additives Transportation:by air /by sea or by courier like DHL or Fedex Port:

Methyl-2,4-dihydroxy-3,6-dimethylbenzoate CAS 4707-47-5

Cas:4707-47-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Veramoss 100g

Cas:4707-47-5

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,4-dihydroxy-3,6-dimethylbenzoic acid
4707-46-4

2,4-dihydroxy-3,6-dimethylbenzoic acid

methyl iodide
74-88-4

methyl iodide

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: 2,4-dihydroxy-3,6-dimethylbenzoic acid With potassium hydrogencarbonate In N,N-dimethyl-formamide at 40℃; for 0.166667h; Inert atmosphere;
Stage #2: methyl iodide In N,N-dimethyl-formamide for 1.41667h; Inert atmosphere;
90.4%
methyl 4-hydroxy-3,6-dimethyl-2-oxycyclohex-3-enecarboxylate

methyl 4-hydroxy-3,6-dimethyl-2-oxycyclohex-3-enecarboxylate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With copper(II) choride dihydrate; sodium chloride In acetonitrile at 85℃; for 5h;88.7%
With copper(II) choride dihydrate; sodium chloride In acetonitrile at 85℃; for 5h;88.7%
With copper(II) choride dihydrate; sodium chloride In acetonitrile at 85℃; for 5h;88.7%
With copper(II) choride dihydrate; sodium chloride In acetonitrile at 85℃; for 5h;88.7%
With copper(II) choride dihydrate; sodium chloride In acetonitrile at 85℃; for 5h;88.7%
methanol
67-56-1

methanol

ethyl 2,4-dihydroxy-3,6-dimethylbenzoate
31581-32-5

ethyl 2,4-dihydroxy-3,6-dimethylbenzoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With sodium methylate for 24h; transesterification; Heating;84%
methyl haematommate
34874-90-3

methyl haematommate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With hydrogenchloride; mercury; zinc In methanol Reduction;78%
With hydrogenchloride; amalgamated zinc
Multi-step reaction with 2 steps
1: sodium iodide; potassium carbonate; acetone
2: Hydrogenation
View Scheme
Multi-step reaction with 2 steps
1: sodium iodide; potassium carbonate; acetone
2: Hydrogenation
View Scheme
N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

methyl 3,5-dioxo-4-methylhexanoate
75950-51-5

methyl 3,5-dioxo-4-methylhexanoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide for 10h; Product distribution; Ambient temperature; other time, reagents ratio;36%
methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate
19104-04-2

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
In methanol; water18%
Cu2 O

Cu2 O

methyl 3,6-dimethyldihydro-β-resorcylate

methyl 3,6-dimethyldihydro-β-resorcylate

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate
19104-04-2

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With hydrogenchloride In methanol10%
2,4-dihydroxy-3,6-dimethylbenzoic acid
4707-46-4

2,4-dihydroxy-3,6-dimethylbenzoic acid

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With diethyl ether
In diethyl ether
methanol
67-56-1

methanol

chloroatranorin
479-16-3

chloroatranorin

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

methyl chlorohaemmatommate

methyl chlorohaemmatommate

Conditions
ConditionsYield
at 155℃;
ethanol
64-17-5

ethanol

atranorin
479-20-9

atranorin

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

ethyl hematommate
39503-14-5

ethyl hematommate

Conditions
ConditionsYield
With alkali at 150℃; im Rohr;
i-Amyl alcohol
123-51-3

i-Amyl alcohol

atranorin
479-20-9

atranorin

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

3-formyl-2,4-dihydroxy-6-methyl-benzoic acid isopentyl ester

3-formyl-2,4-dihydroxy-6-methyl-benzoic acid isopentyl ester

Conditions
ConditionsYield
With alkali at 150℃; im Rohr;
atranorin
479-20-9

atranorin

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With acetic acid
With water
With ethanol
atranorin
479-20-9

atranorin

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

methyl haematommate
34874-90-3

methyl haematommate

Conditions
ConditionsYield
With methanol at 150℃; im Rohr;
atranorin
479-20-9

atranorin

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid ethyl ester
62392-82-9

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid ethyl ester

Conditions
ConditionsYield
With ethanol; aniline
chloroatranorin
479-16-3

chloroatranorin

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With acetic acid at 150℃;
With methanol at 150℃;
2-benzyloxy-3-formyl-4-hydroxy-6-methyl-benzoic acid methyl ester
72935-20-7

2-benzyloxy-3-formyl-4-hydroxy-6-methyl-benzoic acid methyl ester

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
Hydrogenation;
methyl 4-benzyloxy-3-formyl-2-hydroxy-6-methylbenzoate
72935-21-8

methyl 4-benzyloxy-3-formyl-2-hydroxy-6-methylbenzoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
Hydrogenation;
2-hydroxy-4-methoxy-6-methyl-isophthalic acid-1-(3-hydroxy-4-methoxycarbonyl-2,5-dimethyl-phenyl ester)-3-methyl ester
15222-49-8

2-hydroxy-4-methoxy-6-methyl-isophthalic acid-1-(3-hydroxy-4-methoxycarbonyl-2,5-dimethyl-phenyl ester)-3-methyl ester

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid
chloroatranorin
479-16-3

chloroatranorin

acetic acid
64-19-7

acetic acid

A

3-chloro-2,6-dihydroxy-4-methylbenzaldehyde
57074-21-2

3-chloro-2,6-dihydroxy-4-methylbenzaldehyde

B

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
at 150℃;
ethanol
64-17-5

ethanol

atranorin
479-20-9

atranorin

aniline
62-53-3

aniline

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid ethyl ester
62392-82-9

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid ethyl ester

atranorin
479-20-9

atranorin

aniline
62-53-3

aniline

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid methyl ester

2,4-dihydroxy-6-methyl-3-(phenylimino-methyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With methanol
N-(acetyl)pyrrolidine
4030-18-6

N-(acetyl)pyrrolidine

methyl 3,5-dioxo-4-methylhexanoate
75950-51-5

methyl 3,5-dioxo-4-methylhexanoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide 1.) 4 h, room temperature, 2.) pH 9.2 buffer, overnight; Yield given. Multistep reaction;
N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

methyl 3,5-dioxo-4-methylhexanoate
75950-51-5

methyl 3,5-dioxo-4-methylhexanoate

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

n-butyl 2,4-dihydroxy-3,6-dimethylbenzoate
75950-52-6

n-butyl 2,4-dihydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With lithium diisopropyl amide for 12h; Ambient temperature;
atranorin
479-20-9

atranorin

A

orcinol
504-15-4

orcinol

B

atranol
526-37-4

atranol

C

2,5-dimethyl-1,3-benzenediol
488-87-9

2,5-dimethyl-1,3-benzenediol

D

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

E

methyl haematommate
34874-90-3

methyl haematommate

F

3-hydroxy-2,5-dimethylphenyl 2,4-dihydroxy-3,6-dimethylbenzoate

3-hydroxy-2,5-dimethylphenyl 2,4-dihydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
at 230 - 250℃; for 0.75h; Product distribution; pyrolysis;
1,1,4-trimethyl, 4-acetyl-ethylenediamine
20929-21-9

1,1,4-trimethyl, 4-acetyl-ethylenediamine

methyl 3,5-dioxo-4-methylhexanoate
75950-51-5

methyl 3,5-dioxo-4-methylhexanoate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide 1.) 4 h, room temperature, 2.) pH 9.2 buffer, overnight; Yield given. Multistep reaction;
N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

3-Methyl-2,4-pentanedione
815-57-6

3-Methyl-2,4-pentanedione

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
Multistep reaction;
chloroatranorin
479-16-3

chloroatranorin

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

B

tert-butyl 5-chlorohaematommate

tert-butyl 5-chlorohaematommate

Conditions
ConditionsYield
for 40h; Heating;
2.5-dimethyl-cyclohexanedione-(4.6)-carboxylic acid-(1)-methyl ester

2.5-dimethyl-cyclohexanedione-(4.6)-carboxylic acid-(1)-methyl ester

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With palladium asbestos at 150℃;
barbatic acid methyl ester

barbatic acid methyl ester

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

3-Acetoxymethyl-4,6-dimethoxy-2,5-dimethyl-benzoic acid methyl ester
148014-54-4

3-Acetoxymethyl-4,6-dimethoxy-2,5-dimethyl-benzoic acid methyl ester

(3-carbomethoxy-4,6-dihydroxy-2,5-dimethylphenyl)-(3-carbomethoxy-4,6-dimethoxy-2,5-dimethylphenyl)methane
148014-55-5

(3-carbomethoxy-4,6-dihydroxy-2,5-dimethylphenyl)-(3-carbomethoxy-4,6-dimethoxy-2,5-dimethylphenyl)methane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In toluene for 0.25h; Ambient temperature;100%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

methyl iodide
74-88-4

methyl iodide

methyl 2,4-dimethoxy-3,6-dimethylbenzoate
58061-99-7

methyl 2,4-dimethoxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20 - 50℃; Inert atmosphere;98%
With potassium carbonate In acetone Reflux;50%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

methyl 3-chloro-4,6-dihydroxy-2,5-dimethylbenzoate
947-52-4

methyl 3-chloro-4,6-dihydroxy-2,5-dimethylbenzoate

Conditions
ConditionsYield
With N-chloro-succinimide In acetonitrile at 50℃; for 5h;98%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

methyl 5-bromo-2,4-dihydroxy-3,6-dimethylbenzoate
72922-67-9

methyl 5-bromo-2,4-dihydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With bromine In tetrachloromethane; acetic acid for 1h; Ambient temperature;96%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

physodalic acid
90689-60-4

physodalic acid

4-formyl-3,8-dihydroxy-9-(2,4-dihydroxy-5-methoxycarbonyl-3,6-dimethylbenzyl)-1,6-dimethyl-11-oxo-11H-dibenzo<1,4>dioxepin-7-carboxylic acid

4-formyl-3,8-dihydroxy-9-(2,4-dihydroxy-5-methoxycarbonyl-3,6-dimethylbenzyl)-1,6-dimethyl-11-oxo-11H-dibenzo<1,4>dioxepin-7-carboxylic acid

Conditions
ConditionsYield
With toluene-4-sulfonic acid In 1,4-dioxane for 7h; Heating;96%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate
19104-04-2

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
In diethyl ether; acetone for 18h; Ambient temperature;95%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

4-O-(t-butoxycarbonyl)-2-hydroxy-3,6-dimethyl methylbenzoate
908292-00-2

4-O-(t-butoxycarbonyl)-2-hydroxy-3,6-dimethyl methylbenzoate

Conditions
ConditionsYield
With dmap; N-ethyl-N,N-diisopropylamine In dichloromethane for 4h;93%
hexamethylenetetramine
100-97-0

hexamethylenetetramine

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

formyl-3-dihydroxy-4,6-dimethyl-2,5-benzoate de methyle
34874-76-5

formyl-3-dihydroxy-4,6-dimethyl-2,5-benzoate de methyle

Conditions
ConditionsYield
With trifluoroacetic acid Formylation; Duff formylation;90%
Stage #1: hexamethylenetetramine; 2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester With trifluoroacetic acid at 0℃; for 2.5h; Inert atmosphere; Reflux;
Stage #2: With water for 2.5h; Inert atmosphere; Reflux;
76%
With water; trifluoroacetic acid 1.) reflux, 14 h; 2.) 65 deg C, 8 h; Yield given. Multistep reaction;
With water; trifluoroacetic acid 1.) reflux, 12 h; 2.) 60 deg C, 6 h; Yield given. Multistep reaction;
With trifluoroacetic acid for 20h; Inert atmosphere; Reflux;
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

methyl 2,4-bis(methoxymethoxy)-3,6-dimethylbenzoate

methyl 2,4-bis(methoxymethoxy)-3,6-dimethylbenzoate

Conditions
ConditionsYield
Stage #1: 2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester With sodium hydride In tetrahydrofuran at 0℃; Inert atmosphere; Schlenk technique;
Stage #2: chloromethyl methyl ether In tetrahydrofuran at 0 - 20℃; for 5h; Inert atmosphere; Schlenk technique;
90%
Stage #1: 2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester With sodium hydride In tetrahydrofuran at 0℃; for 0.333333h; Inert atmosphere;
Stage #2: chloromethyl methyl ether In tetrahydrofuran; toluene at 25℃; for 3h; Inert atmosphere;
87%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

propargyl bromide
106-96-7

propargyl bromide

methyl 2-hydroxy-3,6-dimethyl-4-(prop-2-yn-1-yloxy) benzoate

methyl 2-hydroxy-3,6-dimethyl-4-(prop-2-yn-1-yloxy) benzoate

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃; for 12h;90%
With potassium carbonate In acetone Reflux;75%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

t-butyldimethylsiyl triflate
69739-34-0

t-butyldimethylsiyl triflate

C22H40O4Si2

C22H40O4Si2

Conditions
ConditionsYield
With 2,6-dimethylpyridine In dichloromethane at 0 - 20℃; Inert atmosphere;90%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2-hydroxy-4-benzyloxy-3,6-dimethylbenzoic acid
56410-32-3

2-hydroxy-4-benzyloxy-3,6-dimethylbenzoic acid

methyl 4-(4-benzyloxy-2-hydroxy-3,6-dimethylbenzoyloxy)-2-hydroxy-3,6-dimethylbenzoate
111258-35-6

methyl 4-(4-benzyloxy-2-hydroxy-3,6-dimethylbenzoyloxy)-2-hydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene Ambient temperature;84%
With trifluoroacetic anhydride In toluene at 20℃; Esterification;63%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2-methoxy-4-(4-methoxybenzyloxy)-3,6-dimethylbenzoic acid
261174-54-3

2-methoxy-4-(4-methoxybenzyloxy)-3,6-dimethylbenzoic acid

C28H30O8

C28H30O8

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene at 20℃; Esterification;82%
Allyl acetate
591-87-7

Allyl acetate

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

C13H16O4

C13H16O4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In toluene at 110℃; for 3h;80%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2-hydroxy-4-methoxy-3,6-dimethylbenzoic acid
479-26-5

2-hydroxy-4-methoxy-3,6-dimethylbenzoic acid

methyl barbatate
5014-22-2

methyl barbatate

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene at 20℃; Esterification;77%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2-methoxy-4-benzyloxy-3,6-dimethylbenzoic acid
125304-84-9

2-methoxy-4-benzyloxy-3,6-dimethylbenzoic acid

C27H28O7
261174-77-0

C27H28O7

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene at 20℃; Esterification;74%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2,4-dihydroxy-3,6-dimethylbenzoic acid
4707-46-4

2,4-dihydroxy-3,6-dimethylbenzoic acid

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -70 - 20℃; for 12h;74%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

ethylene dibromide
106-93-4

ethylene dibromide

methyl 4-(2-bromoethoxy)-2-hydroxy-3,6-dimethylbenzoate

methyl 4-(2-bromoethoxy)-2-hydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;73%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2,4-O-dimethyl-β-orcinolcarboxylic acid
56410-34-5

2,4-O-dimethyl-β-orcinolcarboxylic acid

4-(2,4-dimethoxy-3,6-dimethyl-benzoyloxy)-2-hydroxy-3,6-dimethyl-benzoic acid methyl ester
81050-84-2

4-(2,4-dimethoxy-3,6-dimethyl-benzoyloxy)-2-hydroxy-3,6-dimethyl-benzoic acid methyl ester

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene at 20℃; Esterification;69%
With sodium hydroxide; thionyl chloride; acetone
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

2-hydroxy-4-(4-methoxybenzyloxy)-3,6-dimethylbenzoic acid
261174-53-2

2-hydroxy-4-(4-methoxybenzyloxy)-3,6-dimethylbenzoic acid

C27H28O8

C27H28O8

Conditions
ConditionsYield
With trifluoroacetic anhydride In toluene at 20℃; Esterification;69%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

acetic anhydride
108-24-7

acetic anhydride

4-(methoxycarbonyl)-2,5-dimethyl-1,3-phenylene diacetate
57369-96-7

4-(methoxycarbonyl)-2,5-dimethyl-1,3-phenylene diacetate

Conditions
ConditionsYield
With pyridine at 20℃; for 12h;68%
With pyridine
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

allyl bromide
106-95-6

allyl bromide

methyl 4-(allyloxy)-2-hydroxy-3,6-dimethylbenzoate

methyl 4-(allyloxy)-2-hydroxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;53%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

methyl iodide
74-88-4

methyl iodide

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate
19104-04-2

methyl 2-hydroxy-4-methoxy-3,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;50%
2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester
4707-47-5

2,4-dihydroxy-3,6-dimethyl-benzoic acid methyl ester

allyl bromide
106-95-6

allyl bromide

methyl 2,4-bis(allyloxy)-3,6-dimethylbenzoate

methyl 2,4-bis(allyloxy)-3,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;47%

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