As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t
Cas:4771-80-6
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryItems Standard Result Appearance@25℃ Colorless transparent liquid Complies Assay ≥98%
Cas:4771-80-6
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
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inquiry3-Cyclohexenecarboxylic acid Cas No.:4771-80-6 Molecular Structure: 3-Cyclohexenecarboxylic acid 98% min. Synonyms: 3-Cyclohexene-1-carboxylic acid; 1-Cyclohexene-4-carboxylic acid;1,2,3,6-Tetrahydrobenzoic acid EINECS No.: 225-314-7 Mol
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryProduct description: Product name 3-Cyclohexenecarboxylic acid CAS number 4771-80-6 Assay ≥99% Appearance Colorless transparent liquid Capacity 200mt/year Application Pharmac
Cas:4771-80-6
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Cas:4771-80-6
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
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inquiryProduct Name 3-Cyclohexenecarboxylic acid Synonyms CYCLOHEX-3-ENE-1-CARBOXYLIC ACID;CYCLOHEX-3-ENECARBOXYLIC ACID;1,2,3,6-TETRAHYDROBENZOIC ACID;3-CYCLOHEXENECARBOXYLIC ACID;3-CYCLOHEXENE-1-CARBOXYL
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Cas:4771-80-6
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Cas:4771-80-6
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inquiryBeluga chemical professional supply High quality 3-Cyclohexenecarboxylic acid CAS 4771-80-6 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. M
Cas:4771-80-6
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Cas:4771-80-6
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inquiry3-Cyclohexene-1-carboxylic Acid CAS:4771-80-6 Specification Items Standard Result Appearance@25℃ Colorless transparent liquid Complies Assay &g
Cas:4771-80-6
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
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Cas:4771-80-6
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:4771-80-6
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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Cas:4771-80-6
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:4771-80-6
Min.Order:10 Gram
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Cas:4771-80-6
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Cas:4771-80-6
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inquiryConditions | Yield |
---|---|
4-tert-Butylcatechol In benzene at 120℃; for 2h; Diels-Alder Reaction; | 99% |
4-tert-Butylcatechol In hexane at 120℃; for 2h; Diels-Alder Reaction; | 99% |
With tetraacetyl diborate In neat (no solvent) at -78 - 20℃; Reagent/catalyst; | 99% |
Conditions | Yield |
---|---|
With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 8h; Green chemistry; | 99% |
With 4H3N*4H(1+)*CuMo6O18(OH)6(4-); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 12h; | 99% |
With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 20℃; | 96% |
Conditions | Yield |
---|---|
With hydroquinone at 240℃; under 3750.38 Torr; Temperature; Autoclave; Inert atmosphere; | 89.1% |
2-(prop-2-enyl)hex-5-enoic acid
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
Cl2(PCy3)(N,N'-(Mes)2-imidazolidin-2-yl)Ru=CHC6H5 In benzene at 20℃; for 1h; | 87% |
cyclohex-3-enylmethanol
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With chromium(VI) oxide; sulfuric acid In acetone at 0℃; Inert atmosphere; | 83% |
With Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium chloride; oxygen In 1,2-dichloro-ethane at 25℃; for 48h; | 81% |
With Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium chloride; oxygen In 1,2-dichloro-ethane at 20℃; for 48h; Schlenk technique; | 81% |
With manganese(II) bromide; silver carbonate; potassium hydroxide In 1,3,5-trimethyl-benzene at 50 - 165℃; for 20h; Schlenk technique; Inert atmosphere; | 78% |
With ruthenium trichloride; potassium hydroxide; potassium peroxomonosulphate for 6h; Ambient temperature; | 68% |
methyl cyclohex-3-ene-1-carboxylate
B
1,2,5,6-tetrahydrobenzoic acid
C
cyclohex-3-enylmethanol
D
cyclohexylmethyl alcohol
Conditions | Yield |
---|---|
With hydrogen; sodium methylate; C44H48Cl2N2P2Ru In tetrahydrofuran at 100℃; under 37503.8 Torr; for 2.5h; Product distribution / selectivity; Autoclave; | A n/a B n/a C 77% D n/a |
With hydrogen; sodium methylate; RuCl2(L-1) In tetrahydrofuran at 80 - 100℃; under 37503.8 Torr; for 2.5 - 5h; Product distribution / selectivity; | A n/a B n/a C 67% D n/a |
2-exo-aminonorbornan-3-one hydrochloride
A
1,2,5,6-tetrahydrobenzoic acid
B
2-hydroxycyclopentylacetic acid
2-exo-hydroxynorbornan-7-one
D
tricyclo<2.2.1.02.6>heptanone
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite In water for 0.666667h; | A 6% B n/a C 15% D 3.1% |
2-exo-aminonorbornan-3-one hydrochloride
A
1,2,5,6-tetrahydrobenzoic acid
2-exo-hydroxynorbornan-7-one
C
tricyclo<2.2.1.02.6>heptanone
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite In water | A 6% B 15% C 3.1% |
2-diazonorbornan-3-one
A
1,2,5,6-tetrahydrobenzoic acid
B
tricyclo<2.2.1.02.6>heptanone
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite In water | A 36 mg B 3.6% |
2-diazonorbornan-3-one
A
1,2,5,6-tetrahydrobenzoic acid
2-endo-hydroxynorbornan-3-one
2-hydroxybicyclo<3.1.1>heptan-6-one
D
tricyclo<2.2.1.02.6>heptanone
Conditions | Yield |
---|---|
With sulfuric acid In water | A n/a B n/a C n/a D 1% |
Conditions | Yield |
---|---|
With potassium carbonate |
Conditions | Yield |
---|---|
With sodium carbonate |
trans-3-Methoxycyclohexanecarboxylic acid
A
1,2,5,6-tetrahydrobenzoic acid
B
3-cyclohexenecarboxylic anhydride
Conditions | Yield |
---|---|
With sulfuric acid; acetic anhydride |
(+/-)-trans-3-bromo-cyclohexanecarboxylic acid
N,N-diethylaniline
1,2,5,6-tetrahydrobenzoic acid
3-Cyclohexene-1-carboxaldehyde
A
1,2,5,6-tetrahydrobenzoic acid
B
3-hydroxymethylcyclohexene
Conditions | Yield |
---|---|
With potassium hydroxide at 70℃; | |
With potassium hydroxide; sodium hydroxide at 250℃; |
ethyl-3-cyclohexene-1-carboxylate
A
1,2,5,6-tetrahydrobenzoic acid
B
ethene
Conditions | Yield |
---|---|
Product distribution; Thermodynamic data; Irradiation; Arrhenius parameters, different threshold energies; |
4-methoxyphenylthiomethyl 3-cyclohexenecarboxylate
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In water; acetonitrile electrolyse (electrodes of platinum, constant current of 0.1 A); Yield given; |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran Yield given; |
2-endo-aminonorbornane-3-one hydrochloride
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite In water for 0.25h; |
Conditions | Yield |
---|---|
Hydrolysis; | |
Stage #1: methyl cyclohex-3-ene-1-carboxylate With water; sodium hydroxide In methanol at 20℃; for 16h; Stage #2: With hydrogenchloride In methanol; water Product distribution / selectivity; |
Conditions | Yield |
---|---|
at 200℃; |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With N,N-diethylaniline |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With sodium hydroxide | |
With potassium hydroxide |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With sodium hydroxide |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With potassium hydroxide; silver nitrate |
methylammonium carbonate
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With ethanol |
A
1,2,5,6-tetrahydrobenzoic acid
B
cyclohex-3-enylmethanol
Conditions | Yield |
---|---|
With potassium hydroxide at 65 - 75℃; |
A
1,2,5,6-tetrahydrobenzoic acid
B
trans-4-methoxycyclohexane-1-carboxylic acid
Conditions | Yield |
---|---|
With sodium hydroxide |
1,2,5,6-tetrahydrobenzoic acid
cyclohex-3-enylmethanol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In diethyl ether a) 22 deg C, 12 h, b) reflux, 4 h; | 100% |
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere; | 100% |
With C25H42N6Rh(1+)*CF3O3S(1-); phenylsilane In tetrahydrofuran at 30℃; for 20h; Inert atmosphere; | 71% |
With lithium aluminium tetrahydride In diethyl ether for 5h; Heating; |
1,2,5,6-tetrahydrobenzoic acid
methyl iodide
methyl cyclohex-3-ene-1-carboxylate
Conditions | Yield |
---|---|
With calcium sulfate; silver(l) oxide for 24h; | 100% |
1,2,5,6-tetrahydrobenzoic acid
(1RS,4SR,5RS)-4-bromo-6-oxabicyclo<3.2.1>octan-7-one
Conditions | Yield |
---|---|
With bromine; potassium bromide at 150℃; for 3h; | 99.4% |
With trimethylsilyl bromide; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine In chloroform for 12h; Heating; | 55% |
With trimethylsilyl bromide; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine In chloroform for 12h; Heating; | 55% |
With trimethylsilyl bromide; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine In chloroform for 12h; Product distribution; Heating; other unsaturated carboxylic acid; various amines, solvents and reaction times; | 55% |
Multi-step reaction with 2 steps 1: 89 percent / Br2 / CHCl3 / 0.25 h / 20 °C 2: 75 percent / aq. NaOH; phenolphthalein / 0.5 h / 60 °C View Scheme |
Conditions | Yield |
---|---|
With hydrogen; 3% Pd/C In benzene at 100℃; under 6205.94 Torr; | 99% |
With hydrogen; 3% Pd/C In hexane at 100℃; under 6205.94 Torr; | 99% |
With hydrogen; Rhodium chloride tri(triphenylphosphine-meta-trisulfonate) In water for 18h; Ambient temperature; | 95% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene Dean-Stark; Large scale; | 99% |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With dmap; copper diacetate In acetonitrile at 80℃; for 3h; Schlenk technique; Sealed tube; | 99% |
1,2,5,6-tetrahydrobenzoic acid
(+/-)-4-iodo-6-oxabicyclo[3.2.1]octan-7-one
Conditions | Yield |
---|---|
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With sodium hydrogencarbonate Stage #2: With iodine; potassium iodide at 20℃; for 16h; | 97% |
With iodine; sodium hydrogencarbonate; potassium iodide In water at 20℃; for 24h; | 96% |
With iodine; sodium hydrogencarbonate; potassium iodide In water at 20℃; for 16h; | 96% |
1,2,5,6-tetrahydrobenzoic acid
phenylselenium trichloride
(4-carboxy-2-chlorocyclohexyl)phenylselenium dichloride
Conditions | Yield |
---|---|
In diethyl ether at 0℃; | 97% |
1,2,5,6-tetrahydrobenzoic acid
methyl iodide
1-methyl-3-cyclohexenecarboxylic acid
Conditions | Yield |
---|---|
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With n-butyllithium; bis(dimethylamino)(i-propyl)phosphine oxide; diisopropylamine In tetrahydrofuran; hexane at -20 - 20℃; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran; hexane at -25 - 20℃; | 97% |
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With n-butyllithium; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; hexane at -78 - 60℃; for 2.5h; Stage #2: methyl iodide In tetrahydrofuran; hexane at 20℃; | |
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With n-butyllithium; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; hexane at -78 - 60℃; for 2h; Stage #2: methyl iodide In tetrahydrofuran; hexane | 27 g |
Conditions | Yield |
---|---|
With palladium (II) trifluoroacetate; sodium anthraquinone-2-sulfonate; oxygen; magnesium sulfate In chlorobenzene at 110℃; under 760.051 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Concentration; Sealed tube; | 97% |
1,2,5,6-tetrahydrobenzoic acid
2,3-Dichloro-1-propanol
Cyclohex-3-enecarboxylic acid 2,3-dichloro-propyl ester
Conditions | Yield |
---|---|
With sulfuric acid In toluene at 130℃; | 96% |
With sulfuric acid In toluene at 90℃; Rate constant; |
1,2,5,6-tetrahydrobenzoic acid
3-thiabis(4-chlorocyclohexanecarboxylic) acid
Conditions | Yield |
---|---|
With sulfur dichloride In dichloromethane at -40 - 20℃; for 3h; | 96% |
Conditions | Yield |
---|---|
With iodine; sodium hydrogencarbonate; potassium iodide In water at 20℃; | 96% |
Multi-step reaction with 2 steps 1: 94 percent / NaHCO3, I2/KI / H2O / 21 h / 21 °C 2: 89 percent / DBU / tetrahydrofuran / 16 h / Heating View Scheme | |
Multi-step reaction with 2 steps 1: sodium hydrogencarbonate; potassium iodide; iodine / water / 12 h / 20 °C 2: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 6 h / 70 °C / Inert atmosphere View Scheme |
1,2,5,6-tetrahydrobenzoic acid
benzyl alcohol
(±)-benzyl cyclohex-3-ene-1-carboxylate
Conditions | Yield |
---|---|
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In chloroform | 96% |
meta-fluoroaniline
1,2,5,6-tetrahydrobenzoic acid
cyclohex-3-enecarboxylic acid (3-fluoro-phenyl)-amide
Conditions | Yield |
---|---|
With dmap; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In dichloromethane | 95% |
With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide Acylation; |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
With iodine; sodium hydrogencarbonate; potassium iodide In dichloromethane; water at 5 - 20℃; for 3h; | 95% |
Conditions | Yield |
---|---|
With pentamethoxy tantalum; 1-(Trimethylsilyl)imidazole In neat (no solvent) at 50℃; for 48h; Inert atmosphere; Sealed tube; | 95% |
With benzotriazol-1-ol; 1,2-dichloro-ethane; triethylamine In N,N-dimethyl-formamide at 23℃; for 16h; Inert atmosphere; |
1,2,5,6-tetrahydrobenzoic acid
Conditions | Yield |
---|---|
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With sodium hydrogencarbonate In water at 20℃; Stage #2: With iodine; potassium iodide In water at 20℃; Darkness; | 95% |
1,2,5,6-tetrahydrobenzoic acid
benzyloxycarbonyl azide
benzyl N-(cyclohex-3-en-1-yl)carbamate
Conditions | Yield |
---|---|
With dmap; copper diacetate In acetonitrile at 80℃; for 3h; Schlenk technique; Sealed tube; | 95% |
1,2,5,6-tetrahydrobenzoic acid
(1RS,4RS,5RS)-4-bromo-6-oxabicyclo<3.2.1>octan-7-one
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane at 20℃; for 7h; Darkness; Molecular sieve; | 94% |
With lead(IV) acetate; zinc dibromide | 70% |
With lead(IV) acetate; zinc dibromide In 1,2-dimethoxyethane | 70% |
1,2,5,6-tetrahydrobenzoic acid
(1RS,4SR,5RS)-4-bromo-6-oxabicyclo<3.2.1>octan-7-one
Conditions | Yield |
---|---|
With bromine; potassium bromide at 120℃; for 3h; | A 4% B 94% |
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; | 94% |
With dmap; diisopropyl-carbodiimide In dichloromethane at 20℃; | 73% |
With dmap; diisopropyl-carbodiimide In dichloromethane Inert atmosphere; Schlenk technique; | 68% |
1,2,5,6-tetrahydrobenzoic acid
N-methoxylamine hydrochloride
O-methyl (+/-)-cyclohex-3-enecarbohydroxamate
Conditions | Yield |
---|---|
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With triethylamine In dichloromethane for 0.0833333h; Inert atmosphere; Stage #2: N-methoxylamine hydrochloride With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane for 10h; Inert atmosphere; | 93% |
1,2,5,6-tetrahydrobenzoic acid
endo-4-iodo-6-oxabicyclo<3,2,1>octan-7-one
Conditions | Yield |
---|---|
With sodium hypochlorite solution; acetic acid; sodium iodide In water; acetonitrile at 20℃; for 3h; Reagent/catalyst; Solvent; Temperature; | 92% |
With iodine; sodium hydrogencarbonate; sodium iodide In water at 20℃; | 89% |
With iodine; sodium hydrogencarbonate; potassium iodide In water at 20℃; for 18h; | 84% |
1,2,5,6-tetrahydrobenzoic acid
tert-butyl methyl ether
methyl cyclohex-3-ene-1-carboxylate
Conditions | Yield |
---|---|
With iron(III) trifluoromethanesulfonate at 90℃; Schlenk technique; | 92% |
1,2,5,6-tetrahydrobenzoic acid
3,4-Dihydroxycyclohexanecarboxylic acid-γ-lactone
Conditions | Yield |
---|---|
With 5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride; iodosylbenzene In dichloromethane for 20h; Ambient temperature; | 91% |
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With 3-chloro-benzenecarboperoxoic acid In tetrachloromethane for 4h; Stage #2: With triethylamine In tetrachloromethane at 65℃; for 4h; | 50% |
Multi-step reaction with 2 steps 1: m-CPBA / CH2Cl2 / 0 °C 2: chlorobenzene / 130 °C View Scheme | |
Multi-step reaction with 2 steps 1: aqueous peroxyformic acid 2: 0.06 Torr View Scheme | |
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With 3-chloro-benzenecarboperoxoic acid Stage #2: With triethylamine |
Conditions | Yield |
---|---|
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane for 0.25h; Inert atmosphere; Stage #2: aniline In dichloromethane at 20℃; Inert atmosphere; | 91% |
Stage #1: 1,2,5,6-tetrahydrobenzoic acid With 1,1'-carbonyldiimidazole In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Stage #2: aniline In tetrahydrofuran at 20℃; Inert atmosphere; |
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