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Wuhan Shengmao Corp

Important organic intermediates, used in resin curing agent and the raw material of organic synthesis. Appearance:Pale Yellow or colorless Transparent Liquid Application:Important organic intermediates, used in resin curing agent and the raw materi

3-Cyclohexen-1-Carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Cyclohexene-1-carboxaldehyde Manufacturer/High quality/Best price/In stock

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality tetrahydrobenzaldehyde supplier in China

Cas:100-50-5

Min.Order:200 Kilogram

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

EAST CHEMSOURCES LIMITED

3-Cyclohexene-1-Carboxaldehyde CAS No: 100-50-5 Properties: Third type inflammable colorless transparent liquid, with high Flash point liquid,Boiling point 163-165°C. Appearance: colorless transparent liquid Assay:≥98% Packing, Us

3-Cyclohexene-1-Carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $3.0 / 3.2

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Cyclohex-3-ene-1-carbaldehyde

Cas:100-50-5

Min.Order:1

Negotiable

Type:Other

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Our advantage: 1: High quality and Competitive price 2: Quality control, GC&HPLC&NMR or as your requested 3: Packing as your requested, and double check before shipment 4: Prompt shipment with professional documents 5: Excellent after-

3-Cyclohexene-1-Carboxaldehyde CAS NO.100-50-5

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

3-Cyclohexene-1-carboxaldehyde Basic information Product Name: 3-Cyclohexene-1-carboxaldehyde Synonyms: 4-FORMYL-1-CYCLOHEXENE;3-CYCLOHEXENYLMETHANAL;3-CYCLOHEXENE-1-CARBOXALDEHYDE;1,2,5

100-50-5

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product Name: 3-Cyclohexene-1-carboxaldehyde Synonyms: 4-FORMYL-1-CYCLOHEXENE;3-CYCLOHEXENYLMETHANAL;3-CYCLOHEXENE-1-CARBOXALDEHYDE;1,2,5,6-TETRAHYDROBENZALDEHYDE;1,2,3,6-TETRAHYDROBENZALDEHYDE;TETRAHYDROBE

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:100-50-5

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

3-Cyclohexen-1-Carboxaldehyde CAS:100-50-5 Specification mp 1-3°c bp 163-164 °c(lit.) density 0.94 g/ml at 25 °c(lit.) vapor density 3.8 (vs air) refractive index n20/d 1.474

Factory Supply 3-Cyclohexen-1-Carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and quality c

1,2,3,6-Tetrahydrobenzaldehyde

Cas:100-50-5

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

3-CYCLOHEXEN-1-CARBOXALDEHYDE

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery Appearance:slightly yellowish-green liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:Mainly used as fla

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 3-Cyclohexene-1-Carboxaldehyde CAS No.:100-50-5 Molecule Formula:C7H10O Molecule Weight:110.15 Purity: 98.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard

Best Quality 3-Cyclohexene-1-Carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical,

high purity 3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,2,3,6-Tetrahydrobenzaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1,2,3,6-Tetrahydrobenzaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

3-Cyclohexene-1-Carboxaldehyde

Cas:100-50-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

3-Cyclohexene-1-Carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 100-50-5 with competitive price

Cas:100-50-5

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2,3,6-Tetrahydrobenzaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

3-Cyclohexene-1-Carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Other

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 954kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

3-Cyclohexene-1-carboxaldehydeAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

3-Cyclohexene-1-carboxaldehyde, 98% 100-50-5

Cas:100-50-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

3-Cyclohexene-1-carboxaldehyde

Cas:100-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

buta-1,3-diene
106-99-0

buta-1,3-diene

acrolein
107-02-8

acrolein

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With erbium(III) triflate at 20℃; for 2h; Diels-Alder reaction; Ionic liquid; regioselective reaction;99%
In 1,4 dimethylcyclohexane at 150℃; under 30003 Torr; for 3h; Solvent; Temperature; Inert atmosphere; Autoclave;90%
K10-Fe(III) In dichloromethane at 20℃; for 6h;83%
2-(3-cyclohexenyl)-1,3-dithiane
53178-49-7

2-(3-cyclohexenyl)-1,3-dithiane

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With silica gel; copper(II) nitrate In tetrachloromethane for 0.416667h; Ambient temperature;97%
With p-benzoquinone; sodium iodide In water; acetonitrile at 100℃; for 72h;74 %Chromat.
cyclohex-3-enylmethanol
72581-32-9, 1679-51-2

cyclohex-3-enylmethanol

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With titanium(IV) oxide; oxygen at 29.84℃; under 760.051 Torr; for 24h; Sealed tube; Irradiation;96%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; periodic acid In dichloromethane at 20℃; for 2h;78%
With tetrabutylammomium bromide; dihydrogen peroxide; [Ru3O(OAc)6(MeOH)3](1+)*AcO(1-) In dichloromethane at 20℃; for 24h;45%
In dichloromethane
2-Cyclohex-3-enyl-[1,3]dithiolane

2-Cyclohex-3-enyl-[1,3]dithiolane

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With silica gel; copper(II) nitrate In tetrachloromethane for 1h; Ambient temperature;96%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With LaNi5 hydride In tetrahydrofuran; methanol for 8h; Mechanism; Ambient temperature; other alkynes, alkenes, aldehydes, ketones; other rare earth alloys; var. reaction time and temp.;91%
4-(chloromethyl)cyclohex-1-ene
2555-08-0

4-(chloromethyl)cyclohex-1-ene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With 4Na(1+)*6H(1+)*NiMo6O24(10-)=Na4H6NiMo6O24; oxygen In water; acetonitrile at 20℃; under 760.051 Torr; for 12h; Irradiation;87%
2-Allyl-hex-5-enal
151259-43-7

2-Allyl-hex-5-enal

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
Cl2(PCy3)(N,N'-(Mes)2-imidazolidin-2-yl)Ru=CHC6H5 In benzene at 20℃; for 1h;82%
norborn-2-ene
498-66-8

norborn-2-ene

cis-7-iodobicyclo[2.2.1]heptan-exo-2-ol

cis-7-iodobicyclo[2.2.1]heptan-exo-2-ol

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With hypoiodous acid; acetone at -40 - 20℃;A 72%
B n/a
vinyl-2 dihydro-2,3 4H-pyranne
3236-44-0

vinyl-2 dihydro-2,3 4H-pyranne

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With diethylaluminium chloride; triphenylphosphine In dichloromethane at 25℃; for 1h;61%
With diethylaluminium chloride; triphenylphosphine In dichloromethane at 25℃; for 1h;61%
In hexane at 410℃;
norborn-2-ene
498-66-8

norborn-2-ene

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

C

exo-2,3-epoxynorbornane
278-74-0, 3146-39-2, 57378-36-6

exo-2,3-epoxynorbornane

D

exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

Conditions
ConditionsYield
With iodosylbenzene; TFTEP*FeCl In dichloromethane at 0℃; Yields of byproduct given;A 3.9%
B 0.3%
C n/a
D n/a
With iodosylbenzene; OEP*FeCl In dichloromethane at 0℃; Yield given. Yields of byproduct given;A 1.6%
B 0.2%
C n/a
D n/a
With iodosylbenzene; TFTEP*MnCl In dichloromethane at 0℃; Yield given. Yields of byproduct given;A 0.8%
B 0.2%
C n/a
D n/a
buta-1,3-diene
106-99-0

buta-1,3-diene

A

acrolein
107-02-8

acrolein

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With oxygen; bis(ethylene)rhodium acetylacetonate In toluene at 80℃; under 37503 Torr; for 1h;A 1%
B 0.3%
With oxygen; bis(ethylene)rhodium acetylacetonate In toluene at 80℃; under 37503 Torr; for 1h;A 1%
B 0.3%
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

cyclohex-3-enyl magnesium (1+); bromide

cyclohex-3-enyl magnesium (1+); bromide

toluene
108-88-3

toluene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
beim kurzen Kochen des Reaktionsprodukts mit verd. Schwefelsaeure;
Cyclohex-3-enylmethylnitrit
50552-13-1

Cyclohex-3-enylmethylnitrit

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
In benzene for 10h; Irradiation;
norborn-2-ene
498-66-8

norborn-2-ene

A

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

B

exo-2,3-epoxynorbornane
278-74-0, 3146-39-2, 57378-36-6

exo-2,3-epoxynorbornane

C

exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

Conditions
ConditionsYield
With iodosylbenzene; Mn(III)(SAP)NCS In acetonitrile Product distribution; other alkenes, var. additives (surfactants), var. pyridine concentrations;
With iodosylbenzene; Mn(T4PyP)OAc In acetonitrile at 30℃; var. olefins; other catalyst;
norborn-2-ene
498-66-8

norborn-2-ene

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

C

exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

Conditions
ConditionsYield
With pyrimido<5.4-g>pteridine 10-oxide In acetonitrile Product distribution; Mechanism; Ambient temperature; Irradiation;A 4 % Chromat.
B n/a
C 42 % Chromat.
Bicyclo<3.1.1>hept-2-en-exo-6-ol
111292-74-1

Bicyclo<3.1.1>hept-2-en-exo-6-ol

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With sodium hydroxide
carbon monoxide
201230-82-2

carbon monoxide

cyclohexa-1,4-diene
1165952-92-0

cyclohexa-1,4-diene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With rhodium (triphenylphosphine)acetylacetonatecarbonyl; hydrogen; triphenylphosphine at 80℃; under 7600 Torr; for 3h;71 % Spectr.
With hydrogen; rhodium 1.) from -196 deg C to RT, 2.) toluene, 50 deg C, 48 h, 70 atm; Yield given. Multistep reaction;
carbon monoxide
201230-82-2

carbon monoxide

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

A

1-cyclohexene-1-carboxaldehyde
1192-88-7

1-cyclohexene-1-carboxaldehyde

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With triphenyl phosphite; acetylacetonatobis(triphenylphosphite)rhodium; hydrogen at 80℃; under 7600 Torr; for 3h; Title compound not separated from byproducts;A 31 % Spectr.
B 42 % Spectr.
With rhodium (triphenylphosphine)acetylacetonatecarbonyl; hydrogen; triphenylphosphine at 80℃; under 7600 Torr; for 3h; Title compound not separated from byproducts;A 43 % Spectr.
B 30 % Spectr.
bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With acetic acid at 250℃;
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

magnesium compound of 4-bromo-cyclohexene-(1)

magnesium compound of 4-bromo-cyclohexene-(1)

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With toluene Behandeln des Reaktionsproduktes mit verd. Schwefelsaeure;
carbon monoxide
201230-82-2

carbon monoxide

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

A

1,4-cyclohexanedicarboxaldehyde
33424-83-8

1,4-cyclohexanedicarboxaldehyde

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

C

cis/trans-1,3-cyclohexanedicarboxaldehyde
55309-54-1

cis/trans-1,3-cyclohexanedicarboxaldehyde

D

cyclohex-2-enecarbaldehyde
42540-33-0

cyclohex-2-enecarbaldehyde

Conditions
ConditionsYield
With Rh4(CO)14; hydrogen In hexane at 19.85℃; Product distribution; Hydroformylation; reaction was studied by in-situ high-pressure IR spectroscopy;
Copper(I) trifluoromethanethiolate
3872-23-9

Copper(I) trifluoromethanethiolate

exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

3-(trifluoromethylthio)-2-norbornanol

3-(trifluoromethylthio)-2-norbornanol

Conditions
ConditionsYield
In toluene at 100 - 110℃; Title compound not separated from byproducts;
4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
Stage #1: 4-ethenylcyclohexene With cis-[Ru(2,9-Me2phen)2(OH2)2](PF6)2 In acetonitrile at 55℃; for 0.5h;
Stage #2: With dihydrogen peroxide In acetonitrile for 8h;
cyclohex-3-enylmethanol
72581-32-9, 1679-51-2

cyclohex-3-enylmethanol

A

1,2,5,6-tetrahydrobenzoic acid
4771-80-6

1,2,5,6-tetrahydrobenzoic acid

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With peracetic acid; dihydrogen peroxide; palladium on activated charcoal In dichloromethane; water at 59.84℃; for 1h;
With peracetic acid; dihydrogen peroxide; Mn(III)AlPO-5 In dichloromethane; water at 89.84℃; for 1h;
cyclohex-3-enylmethanol
72581-32-9, 1679-51-2

cyclohex-3-enylmethanol

A

3,4-epoxycyclohexane-1-carboxaldehyde

3,4-epoxycyclohexane-1-carboxaldehyde

B

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With peracetic acid; dihydrogen peroxide; palladium on activated charcoal In water; acetonitrile at 59.84℃; for 1h;
acrolein dimer
100-73-2

acrolein dimer

A

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

B

P2O5

P2O5

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) NaH, DMSO / 1) 25 deg C, 15 min., DMSO; 2) 25 deg C, 1 h
2: 61 percent / Et2AlCl, PPh3 / CH2Cl2 / 1 h / 25 °C
View Scheme
cyclohex-3-enylmethanol
72581-32-9, 1679-51-2

cyclohex-3-enylmethanol

A

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

B

RCu(CN)ZnI, (table I. entry 11)

RCu(CN)ZnI, (table I. entry 11)

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaNO2, H2SO4 / H2O / -10 °C
2: benzene / 10 h / Irradiation
View Scheme
ethyl-3-cyclohexene-1-carboxylate
15111-56-5

ethyl-3-cyclohexene-1-carboxylate

A

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

B

RCu(CN)ZnI, (table I. entry 11)

RCu(CN)ZnI, (table I. entry 11)

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: LiAlH4 / diethyl ether / Heating
2: NaNO2, H2SO4 / H2O / -10 °C
3: benzene / 10 h / Irradiation
View Scheme
benzylamine
100-46-9

benzylamine

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Benzyl-cyclohex-3-en-(E)-ylidenemethyl-amine

Benzyl-cyclohex-3-en-(E)-ylidenemethyl-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

1,2,5,6-tetrahydrobenzoic acid
4771-80-6

1,2,5,6-tetrahydrobenzoic acid

Conditions
ConditionsYield
With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 8h; Green chemistry;99%
With 4H3N*4H(1+)*CuMo6O18(OH)6(4-); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 12h;99%
With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 20℃;96%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

cyclohex-3-enylmethanol
72581-32-9, 1679-51-2

cyclohex-3-enylmethanol

Conditions
ConditionsYield
Stage #1: 3-Cyclohexene-1-carboxaldehyde With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 3h; Inert atmosphere;
Stage #2: With sodium hydroxide In water at 0℃; for 12h; Inert atmosphere;
99%
With 1-Methylpyrrolidine; C13H12MnN3O5; hydrogen In tetrahydrofuran at 100℃; under 37503.8 Torr; for 24h; Autoclave; Glovebox;98%
With dmap; formic acid; hexarhodium hexadecacarbonyl; carbon monoxide In tetrahydrofuran at 30℃; under 3800 Torr; for 5h;93%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

3-cyclohexene-1-carboxylic acid 3-cyclohexen-1-ylmethyl ester
2611-00-9

3-cyclohexene-1-carboxylic acid 3-cyclohexen-1-ylmethyl ester

Conditions
ConditionsYield
With trimethylaluminum; isopropyl alcohol; 2,7-dimethyl-1,8-biphenylenediol In hexane; toluene at 21℃; for 0.25h; Tishchenko reaction;99%
With (2,7-dimethyl-1,8-biphenylenedioxy)-bis(diisopropoxyaluminum) In toluene at 21℃; for 0.25h; Dimerization; Tishchenko reaction;98%
i-PrOAl 1,1'-biphenyl-2-oxy-2'-perfluorooctanesulfonamide In toluene at 20℃; for 0.5h; Tishchenko reaction;95%
N-allyl-N-phenylamine
589-09-3

N-allyl-N-phenylamine

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

N-<(1-allyl-3-cyclohexenyl)methylene>aniline
100747-84-0

N-<(1-allyl-3-cyclohexenyl)methylene>aniline

Conditions
ConditionsYield
With Pd(PPh3); trifluoroacetic acid In benzene at 80℃; for 20h;99%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

C13H23BO3

C13H23BO3

Conditions
ConditionsYield
With FeBr2*2THF; C30H46N4Si2(2+) In acetonitrile at 20℃; for 12h; Glovebox; Inert atmosphere; Sealed tube;99%
With C14H24N4Si(1+)*I(1-) In benzene-d6 at 24℃; for 0.166667h; Catalytic behavior; Inert atmosphere; Schlenk technique; regioselective reaction;86%
With [((2,6-(i-Pr)2C6H3)NC(=CH2)CH=C(Me)N(2,6-(i-Pr)2C6H3))Ge] In benzene-d6 at 60℃; for 24h; Inert atmosphere; Glovebox; Sealed tube; chemoselective reaction;98 %Spectr.
With C18H21La In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere;
With tris(η5-methylcyclopentadienyl)lanthanum(III) In tetrahydrofuran at 20℃; for 0.166667h; Catalytic behavior; Schlenk technique; Glovebox; Inert atmosphere; chemoselective reaction;99 %Spectr.
phenyl selenocyanate
2179-79-5

phenyl selenocyanate

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

(1R,4R,5R)-4-Phenylselanyl-6-oxa-bicyclo[3.2.1]octane-7-carbonitrile

(1R,4R,5R)-4-Phenylselanyl-6-oxa-bicyclo[3.2.1]octane-7-carbonitrile

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane for 0.166667h; Ambient temperature;98%
benzylamine
100-46-9

benzylamine

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

(E)-N-(cyclohex-3-en-1-ylmethylene)-1-phenylmethanamine

(E)-N-(cyclohex-3-en-1-ylmethylene)-1-phenylmethanamine

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane for 0.5h; Ambient temperature;98%
In toluene at 110 - 115℃; Dean-Stark;
methyldiphenylsilane
776-76-1

methyldiphenylsilane

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

(cyclohex-3-enylmethoxy)-methyl-diphenyl-silane

(cyclohex-3-enylmethoxy)-methyl-diphenyl-silane

Conditions
ConditionsYield
With (triphenylphosphine)copper(I) hydride hexamer In toluene at 20℃; for 2h;98%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

3-cyclohexene-1-carbonitrile
100-45-8

3-cyclohexene-1-carbonitrile

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate; acetylhydroxamic acid In acetonitrile for 16h; Reflux;97%
With ammonium acetate; acetic acid; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate at 70℃; for 12h; Inert atmosphere;94%
Stage #1: 3-Cyclohexene-1-carboxaldehyde With hydroxylamine hydrochloride; triethylamine In acetonitrile at 80℃;
Stage #2: With phthalic anhydride In acetonitrile at 25 - 80℃; for 18h;
64%
Multi-step reaction with 2 steps
1: 94 percent / hydroxylamine hydrochloride, sodium acetate / H2O / 2 h / 45 °C
2: 77 percent / acetic acid anhydride / 1 h / Ambient temperature
View Scheme
Multi-step reaction with 2 steps
1: acetylhydroxamic acid; boron trifluoride diethyl etherate / methanol / Reflux
2: bismuth(lll) trifluoromethanesulfonate / acetonitrile / 8 h / Reflux
View Scheme
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

A

toluene
108-88-3

toluene

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With palladium/alumina; hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 3.6%
B 96.4%
With hydrogen In hexane at 325℃; Flow reactor; Green chemistry;A 83.4%
B 16.4%
In octane at 300℃; for 1h; Reagent/catalyst; Temperature;A 82%
B 10%
In octane at 200℃; for 1h;A 25%
B 44%
ethylene glycol
107-21-1

ethylene glycol

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

2-(3-cyclohexenyl)-1,3-dioxolane
28193-08-0

2-(3-cyclohexenyl)-1,3-dioxolane

Conditions
ConditionsYield
With Envirocat EPZ10 supported reagent for 0.0333333h; microwave irradiation;96%
With KU-2 cation exchanger H(1+) In toluene at 130℃;87%
With ammonium chloride; benzene
With ammonium chloride; benzene
allyl bromide
106-95-6

allyl bromide

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

α-(2-propenyl)-3-cyclohexen-1-methanol
91055-81-1

α-(2-propenyl)-3-cyclohexen-1-methanol

Conditions
ConditionsYield
With tin; hydrogen bromide In diethyl ether; water Ambient temperature;96%
With manganese; cyclopentadienyl titanium(IV) trichloride; trimethylsilyl bromide; triethylamine hydrobromide In tetrahydrofuran Inert atmosphere;90%
(i) Mg, (ii) /BRN= 774001/; Multistep reaction;
With magnesium In diethyl ether
Malonic acid monomethyl ester
16695-14-0

Malonic acid monomethyl ester

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

(propene-2 oate de methyle) yl-4 cyclohexene trans
124939-60-2

(propene-2 oate de methyle) yl-4 cyclohexene trans

Conditions
ConditionsYield
With piperidine In pyridine RT, overnight, reflux, 2 h;96%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

1,2-di(cyclohex-3-en-1-yl)ethane-1,2-diol

1,2-di(cyclohex-3-en-1-yl)ethane-1,2-diol

Conditions
ConditionsYield
With chloro-trimethyl-silane; zinc; bis(cyclopentadienyl)vanadium dichloride In tetrahydrofuran at 20℃; for 13h; Reduction;96%
With samarium; trimethylsilyl bromide In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;64%
tert-butyldiphenylsilane
33729-92-9

tert-butyldiphenylsilane

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

4-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexene

4-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexene

Conditions
ConditionsYield
With (triphenylphosphine)copper(I) hydride hexamer In toluene at 40℃; for 6h;96%
2-bromoprop-1-ene
557-93-7

2-bromoprop-1-ene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

4-(1'-hydroxy-2'-methylprop-2-enyl)cyclohexene
139021-69-5

4-(1'-hydroxy-2'-methylprop-2-enyl)cyclohexene

Conditions
ConditionsYield
Stage #1: 2-bromoprop-1-ene With lithium In diethyl ether at -30 - 20℃; for 1.75h; Inert atmosphere;
Stage #2: 3-Cyclohexene-1-carboxaldehyde In diethyl ether at -30 - 20℃; for 1.75h; Inert atmosphere;
Stage #3: With water; ammonium chloride In diethyl ether Cooling with ice;
96%
1-methylindole
603-76-9

1-methylindole

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

3-(3-cyclohexen-1-ylmethyl)-1-methyl-1H-indole

3-(3-cyclohexen-1-ylmethyl)-1-methyl-1H-indole

Conditions
ConditionsYield
With indium(III) tris[bis(trifluoromethanesulfonyl)amide]; methyldiphenylsilane In 1,4-dioxane at 50℃; for 24h; Inert atmosphere; Schlenk technique;96%
cyclopentanone
120-92-3

cyclopentanone

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

2,5-bis(1,2,5,6-tetra-hydro-benzylidene)-cyclopentanone

2,5-bis(1,2,5,6-tetra-hydro-benzylidene)-cyclopentanone

Conditions
ConditionsYield
With sodium hydroxide In ethanol at 25℃; for 3h;96%
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

1,2,5,6-tetrahydrobenzaldehyde diethyl acetal
6314-88-1

1,2,5,6-tetrahydrobenzaldehyde diethyl acetal

Conditions
ConditionsYield
With toluene-4-sulfonic acid In ethanol Heating;95%
With Amberlyst 15 at 4℃; for 1h;93%
With ethanol; ammonium chloride
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

cyclohex-3-enyl(trimethylsilyloxy)acetonitrile
85906-00-9

cyclohex-3-enyl(trimethylsilyloxy)acetonitrile

Conditions
ConditionsYield
niobium pentafluoride at 20℃; for 0.166667h;95%
With N-methyl-2-indolinone In dichloromethane at 20℃; for 0.166667h;90%
With zinc(II) iodide
methyl cyanoformate
17640-15-2

methyl cyanoformate

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

1-cyano-1-(4'-cyclohexenyl)-1-(methoxycarbonyloxy)methane

1-cyano-1-(4'-cyclohexenyl)-1-(methoxycarbonyloxy)methane

Conditions
ConditionsYield
With diisopropylamine In tetrahydrofuran Addition;95%
Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

(cyclohex-3-enylmethoxy)-dimethyl-phenyl-silane

(cyclohex-3-enylmethoxy)-dimethyl-phenyl-silane

Conditions
ConditionsYield
With (triphenylphosphine)copper(I) hydride hexamer In toluene at 20℃; for 2h;95%
malononitrile
109-77-3

malononitrile

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

recorcinol
108-46-3

recorcinol

2-amino-4-(cyclohex-3-enyl)-7-hydroxy-4H-chromene-3-carbonitrile

2-amino-4-(cyclohex-3-enyl)-7-hydroxy-4H-chromene-3-carbonitrile

Conditions
ConditionsYield
Stage #1: malononitrile; 3-Cyclohexene-1-carboxaldehyde With morpholine In ethanol for 0.25h;
Stage #2: recorcinol In ethanol at 20℃; for 72h;
95%
4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester
1539-32-8

4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester

buta-1,3-diene
106-99-0

buta-1,3-diene

3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

C14H24O

C14H24O

Conditions
ConditionsYield
With chromium dichloride; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile In tetrahydrofuran at 20℃; for 24h; Irradiation; diastereoselective reaction;95%
3-Cyclohexene-1-carboxaldehyde
100-50-5

3-Cyclohexene-1-carboxaldehyde

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In water at 45℃; for 2h;94%
With hydroxylamine hydrochloride; sodium acetate In methanol Ambient temperature;92%
With hydroxylamine hydrochloride; sodium carbonate In ethanol; water for 3h; Ambient temperature;90%

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