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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Bicyclo[2.2.1]heptan-2-one Manufacturer/High quality/Best price/In stock

Cas:497-38-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Norcamphor supplier in China

Cas:497-38-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Norcamphor

Cas:497-38-1

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Natural Extract 98% NORCAMPHOR 497-38-1 HACCP Manufacturer

Cas:497-38-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Norcamphor

Cas:497-38-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

tianfu-chem_2-Norbornanone,497-38-1

Cas:497-38-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 497-38-1 with competitive price

Cas:497-38-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

NORCAMPHOR CAS:497-38-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates,

NORCAMPHOR CAS:497-38-1

Cas:497-38-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:1 Gram

FOB Price: $89.0

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance: colorless to white adhering crystals Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermed

Norcamphor

Cas:497-38-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

NORCAMPHOR

Cas:497-38-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Norcamphor

Cas:497-38-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Bicyclo[2.2.1]heptan-2-one cas no. 497-38-1 98%

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Norcamphor B57021 1g

Cas:497-38-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

NorcaMphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

NORCAMPHOR

Cas:497-38-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Bicyclo[2.2.1]heptan-2-one

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

Norcamphor

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Bicyclo[2.2.1]heptan-2-one cas 497-38-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Bicyclo[2.2.1]heptan-2-one cas 497-38-1

Cas:497-38-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

NORCAMPHOR

Cas:497-38-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With tert.-butylnitrite; oxygen; acetic acid In toluene at 50℃; for 9h;99%
With oxygen; Nafion polymer anchored ruthenium oxide pyrochlore composite In acetone at 20℃; under 760.051 Torr; for 12h;98%
With γ-picolinium chlorochromate; silica gel In dichloromethane at 20℃; for 13h;97%
exo-2-norbornanol
497-37-0

exo-2-norbornanol

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); sodium bromide In acetic acid for 10h; Ambient temperature;95%
With perfluoro-cis-2-n-butyl-3-n-propyloxaziridine In various solvent(s) Ambient temperature;94%
With nitrosonium tetrafluoroborate In various solvent(s) for 96h; Ambient temperature;55%
(+/-)-endo-2-norborneol
497-36-9

(+/-)-endo-2-norborneol

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); sodium bromide In acetic acid for 10h; Ambient temperature;95%
With perfluoro-cis-2-n-butyl-3-n-propyloxaziridine In various solvent(s) Ambient temperature;90%
With potassium chlorochromate on SiO2 In dichloromethane for 80h; Ambient temperature;80%
norborn-2-ene
498-66-8

norborn-2-ene

A

2,3-epoxynorbornane
278-74-0

2,3-epoxynorbornane

B

Norbornan-2-on
497-38-1

Norbornan-2-on

C

Norborneol
497-36-9, 497-37-0

Norborneol

Conditions
ConditionsYield
With (PF6)2; oxygen In acetonitrile at 65℃; under 2068.6 Torr; Mechanism; Product distribution; also in the presence of H2O2; other alkene; also hydroxylation of cyclohexane;A 94%
B n/a
C n/a
With oxygen; isobutyraldehyde In acetonitrile at 60℃; for 1h;A 91%
B n/a
C n/a
With oxygen In acetone at -72℃; under 2 - 2.5 Torr; for 0.75h; Product distribution; Mechanism;
With dihydrogen peroxide; C18H22O7V In water; acetonitrile at 80℃; for 6h; Catalytic behavior;
With dihydrogen peroxide; C23H29N6O7V2(1-)*H2O*H(1+) In methanol at 70℃; for 6h; Catalytic behavior; Reagent/catalyst;
potassium Sodium

potassium Sodium

5-ethylidene-2-norbornanol

5-ethylidene-2-norbornanol

5-ethylidene-3-norbornanol

5-ethylidene-3-norbornanol

aluminum isopropoxide
555-31-7

aluminum isopropoxide

p-benzoquinone
106-51-4

p-benzoquinone

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
In toluene85%
(bicyclo[2.2.1]hept-2-yloxy)-trimethyl-silane

(bicyclo[2.2.1]hept-2-yloxy)-trimethyl-silane

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.416667h;84%
bicyclo[2.2.1]heptan-2-one oxime
4576-48-1, 49805-50-7, 49805-51-8, 141782-05-0

bicyclo[2.2.1]heptan-2-one oxime

A

Norbornan-2-on
497-38-1

Norbornan-2-on

2-bromo-2-nitronorbornane

2-bromo-2-nitronorbornane

Conditions
ConditionsYield
With chloroperoxidase from fungus Caldaromyces fumago; dihydrogen peroxide; potassium bromide In water for 4h;A 17%
B 82%
(+-)-methyl-[2exo]norbornyl ether
10395-53-6

(+-)-methyl-[2exo]norbornyl ether

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With HOF* CH3CN; sodium fluoride In chloroform; water; acetonitrile 0 deg C -> room temperature;80%
endo-2-methoxybicyclo<2.2.1>heptane
10395-53-6, 10395-55-8, 60263-60-7

endo-2-methoxybicyclo<2.2.1>heptane

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With HOF* CH3CN; sodium fluoride In chloroform; water; acetonitrile 0 deg C -> room temperature;80%
2-(bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

2-(bicyclo[2.2.1]hept-2-yloxy)-tetrahydro-pyran

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.333333h;80%
N'-Bicyclo[2.2.1]hept-(2Z)-ylidene-N,N-dimethyl-hydrazine
61852-67-3

N'-Bicyclo[2.2.1]hept-(2Z)-ylidene-N,N-dimethyl-hydrazine

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With ferric nitrate In dichloromethane 30 min., r.t., then reflux;79%
exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With [iron(III)(5,10,15,20-tetraphenyl-21H,23H-porphine)] perchlorate In 1,4-dioxane at 80℃; for 3h;77%
norbornene
279-23-2

norbornene

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With ruthenium trichloride; sodium periodate In tetrachloromethane; water; acetonitrile Heating;75%
With nitronium tetrafluoborate In various solvent(s) for 168h; Ambient temperature;70%
With sodium periodate; ruthenium tetroxide In acetonitrile at 40℃; for 96h;92 % Turnov.
2,3-epoxynorbornane
278-74-0

2,3-epoxynorbornane

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With lithium perchlorate In diethyl ether for 1h; Ambient temperature;70%
thionorcamphor
51849-44-6

thionorcamphor

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With oxygen In tetrachloromethane Irradiation;67%
With oxygen In methanol Product distribution; Mechanism; Irradiation; var. solvents, times, and yields, rate of (1)O2 quenching, efficiency of (1)O2 generation, stability;63%
norborn-2-ene
498-66-8

norborn-2-ene

diisobutylaluminium hydride
1191-15-7

diisobutylaluminium hydride

A

Norbornan-2-on
497-38-1

Norbornan-2-on

exo-2-norbornanol
497-37-0

exo-2-norbornanol

(+/-)-endo-2-norborneol
497-36-9

(+/-)-endo-2-norborneol

D

3-isobutylbicyclo<2.2.1>heptan-2-one
108350-17-0

3-isobutylbicyclo<2.2.1>heptan-2-one

E

2,2'-exo-binorbornane
726187-24-2

2,2'-exo-binorbornane

Conditions
ConditionsYield
With oxygen; zirconium(IV) chloride In toluene at 20℃; Product distribution; further reagents;A 1%
B 62%
C 16%
D 8%
E 4%
(E)-exo-2-bromo-3'-phenylbicyclo<2.2.1>heptan-endo-3-spiro-2'-oxirane
144264-87-9, 144301-97-3

(E)-exo-2-bromo-3'-phenylbicyclo<2.2.1>heptan-endo-3-spiro-2'-oxirane

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In toluene Heating;A 35%
B 60%
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In toluene Mechanism; Heating; diff. bicyclo<2.2.1>heptan-3-spiro-2'-oxiranes;A 35%
B 60%
3-Tosyl-3-aza-tricyclo(3.2.1.02.4-exo)octan
4948-76-9

3-Tosyl-3-aza-tricyclo(3.2.1.02.4-exo)octan

A

Norbornan-2-on
497-38-1

Norbornan-2-on

N-tosyl nortricyclamine

N-tosyl nortricyclamine

Conditions
ConditionsYield
With lithium diisopropyl amide In diethyl ether; hexane at -78℃; for 2h;A 15%
B 60%
bicyclo[2.2.1]heptan-2-one oxime
4576-48-1, 49805-50-7, 49805-51-8, 141782-05-0

bicyclo[2.2.1]heptan-2-one oxime

A

Norbornan-2-on
497-38-1

Norbornan-2-on

2-chloro-2-nitronorbornane

2-chloro-2-nitronorbornane

Conditions
ConditionsYield
With chloroperoxidase from fungus Caldaromyces fumago; potassium chloride; dihydrogen peroxide In water for 4h;A 39%
B 59%
endo-2-norbornyl methyl ether
10395-55-8

endo-2-norbornyl methyl ether

acetonitrile
75-05-8

acetonitrile

A

Norbornan-2-on
497-38-1

Norbornan-2-on

exo-2-norbornylacetamide
28607-02-5

exo-2-norbornylacetamide

Conditions
ConditionsYield
With nitrosonium tetrafluoroborate at 0℃; for 6h;A 58%
B 10%
With nitrosonium tetrafluoroborate at 0℃; for 15h;A 58%
B 10%
exo-2-bicyclo[2.2.1]heptanol

exo-2-bicyclo[2.2.1]heptanol

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
In para-xylene for 24h; Inert atmosphere; Reflux;58%
With sodium bromate; Rexyn 101 H resin at 20℃; for 8h;
With tert.-butylhydroperoxide; [Fe(N-(2-pyridylmethyl)iminodiethanolate)(NO3)]2(NO3)2*2CH3OH In methanol; dodecane at 50℃; for 24h; Catalytic behavior; Reagent/catalyst;
5-norbornene-2-ol
694-97-3

5-norbornene-2-ol

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

Norborneol
497-36-9, 497-37-0

Norborneol

Conditions
ConditionsYield
nickel at 135 - 140℃; for 48h; Heating;A 53%
B 7%
nickel at 135 - 140℃; for 36h; Heating;A 42%
B 7%
sodium bismuthate

sodium bismuthate

phospholic acid

phospholic acid

2-hydroxy-2-norbornanecarboxylic acid
41248-20-8

2-hydroxy-2-norbornanecarboxylic acid

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
In water53%
In water50%
exo-2-norbornyl chloride
67844-27-3

exo-2-norbornyl chloride

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With silver(I) nitrite; antimony pentafluoride 1.) Freon-113, -30 deg C, 30 min, 2.) -25 deg C, 2 h then 0 deg C, 3 h;52%

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

2-nitronorbornane
35520-82-2

2-nitronorbornane

C

Norborneol
497-36-9, 497-37-0

Norborneol

D

Bis(2-bicyclo<2.2.1>heptanyl)ether

Bis(2-bicyclo<2.2.1>heptanyl)ether

Conditions
ConditionsYield
With silver(I) nitrite In diethyl ether for 2h; 1.) 0 deg C, 2 h then room temp., 40 h;A 50%
B 38%
C n/a
D n/a
exo-2-norbornyl methyl ether
10395-53-6

exo-2-norbornyl methyl ether

acetonitrile
75-05-8

acetonitrile

A

Norbornan-2-on
497-38-1

Norbornan-2-on

exo-2-norbornylacetamide
28607-02-5

exo-2-norbornylacetamide

Conditions
ConditionsYield
With nitrosonium tetrafluoroborate at 0℃; for 6h;A 33%
B 16%
endo-5-norbornen-2-ol
694-97-3

endo-5-norbornen-2-ol

A

Norbornan-2-on
497-38-1

Norbornan-2-on

B

Norborneol
497-36-9, 497-37-0

Norborneol

Conditions
ConditionsYield
nickel at 135 - 140℃; for 24h; Heating;A 32%
B 4%
Conditions
ConditionsYield
nickel at 135 - 140℃; for 24h; Heating;A 30%
B 5%
norbornane
279-23-2

norbornane

Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With chromium(VI) oxide; acetic anhydride; acetic acid In dichloromethane29%
Norbornan-2-on
497-38-1

Norbornan-2-on

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2-trifluoromethanesulfonyloxybicyclo[2.2.1]hept-2-ene
82361-91-9

2-trifluoromethanesulfonyloxybicyclo[2.2.1]hept-2-ene

Conditions
ConditionsYield
Stage #1: Norbornan-2-on With lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; for 3h; Inert atmosphere;
100%
With n-butyllithium; diisopropylamine In tetrahydrofuran59%
Norbornan-2-on
497-38-1

Norbornan-2-on

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

2-(4-fluorophenyl)bicyclo[2.2.1]heptan-2-ol
1000052-55-0

2-(4-fluorophenyl)bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
Stage #1: 1-Bromo-4-fluorobenzene With iodine; magnesium In tetrahydrofuran at 0℃; for 4h;
Stage #2: Norbornan-2-on In tetrahydrofuran at 0 - 20℃;
Stage #3: With water In tetrahydrofuran
99%
With magnesium
Stage #1: 1-Bromo-4-fluorobenzene With iodine; magnesium In tetrahydrofuran Cooling with ice; Inert atmosphere;
Stage #2: Norbornan-2-on In tetrahydrofuran at 20℃; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water pH=7;
Norbornan-2-on
497-38-1

Norbornan-2-on

chloromethyl phenyl sulfone
7205-98-3

chloromethyl phenyl sulfone

C14H16O3S
89211-06-3

C14H16O3S

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran; tert-butyl alcohol at 10 - 15℃;97%
Norbornan-2-on
497-38-1

Norbornan-2-on

2-norbornanone oxime
4576-48-1

2-norbornanone oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In methanol97%
With hydroxylamine hydrochloride; sodium acetate In methanol Heating;85%
With hydroxylamine hydrochloride; sodium acetate In methanol; water at 60℃;76%
Norbornan-2-on
497-38-1

Norbornan-2-on

(+/-)-endo-2-norborneol
497-36-9

(+/-)-endo-2-norborneol

Conditions
ConditionsYield
With lithium diisobutyl-tert-butylaluminium hydride In tetrahydrofuran; hexane at -78℃; for 3h;97%
With potassium dihydrobis(1-pyrazolyl)borate In ethanol at 20℃; for 24h; Reduction;91%
Multi-step reaction with 2 steps
1: p-toluenesulfonic acid / methanol
2: NaBH4 / propan-2-ol; H2O / 16 h / Ambient temperature
View Scheme
Stage #1: Norbornan-2-on With Al-methanesulfonyldiisobutylalane In diethyl ether at 25℃; for 1h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In diethyl ether for 2h; Inert atmosphere; stereoselective reaction;
51 %Chromat.
With trans-[(2-(diphenylphosphanyl)-N-(pyridine-2-ylmethyl)ethaneamine)RuCl2(PPh3)]*dichloromethane; potassium tert-butylate; hydrogen In isopropyl alcohol at 60℃; under 7500.75 Torr; for 1h; Catalytic behavior; Inert atmosphere; Autoclave;96.6 %Chromat.
2-Aminobenzyl alcohol
5344-90-1

2-Aminobenzyl alcohol

Norbornan-2-on
497-38-1

Norbornan-2-on

3-azatetracyclo[10.2.1.0(2,11).0(4,9)]pentadeca-2(11),3,5,7,9-pentaene

3-azatetracyclo[10.2.1.0(2,11).0(4,9)]pentadeca-2(11),3,5,7,9-pentaene

Conditions
ConditionsYield
With benzophenone; potassium tert-butylate In 1,4-dioxane at 90℃; for 0.5h; Friedlaender synthesis; Inert atmosphere;97%
With potassium hydroxide; benzophenone; dichlorotetrakis(dimethyl sulfoxide)ruthenium(II) In 1,4-dioxane at 80℃; for 24h;75%
With benzophenone; potassium tert-butylate In 1,4-dioxane at 90℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;
Norbornan-2-on
497-38-1

Norbornan-2-on

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Conditions
ConditionsYield
In diethyl ether for 0.5h;96%
Norbornan-2-on
497-38-1

Norbornan-2-on

2-oxabicyclo[3.2.1]octan-3-one
5724-61-8

2-oxabicyclo[3.2.1]octan-3-one

Conditions
ConditionsYield
With acyltransferase from Mycobacterium smegmatis; dihydrogen peroxide; ethyl acetate In water at 35℃; for 7h; Baeyer-Villiger Ketone Oxidation; Enzymatic reaction;96%
With oxone; silica gel In dichloromethane at 20℃; for 8h; Baeyer-Villiger oxidation;95%
With Oxone at 40℃; for 7h; Baeyer-Villiger oxidation; Ionic liquid;95%
Norbornan-2-on
497-38-1

Norbornan-2-on

benzylamine
100-46-9

benzylamine

endo-N-benzyl-2-aminonorbornane
35718-03-7, 131511-14-3

endo-N-benzyl-2-aminonorbornane

Conditions
ConditionsYield
With sodium tris(acetoxy)borohydride In 1,2-dichloro-ethane for 6h; Ambient temperature;95%
With sodium tris(acetoxy)borohydride In tetrahydrofuran for 6h; Ambient temperature;
Norbornan-2-on
497-38-1

Norbornan-2-on

nitromethane
75-52-5

nitromethane

phenylmethanethiol
100-53-8

phenylmethanethiol

2-benzylthio-2-nitromethyl-bicyclo[2.2.1]heptane

2-benzylthio-2-nitromethyl-bicyclo[2.2.1]heptane

Conditions
ConditionsYield
With ethylenediamine for 14h; Heating;95%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Norbornan-2-on
497-38-1

Norbornan-2-on

benzyl azide
622-79-7

benzyl azide

(1R,2S,6S,7S)-5-Benzyl-6-trimethylsilanyloxy-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-3-ene

(1R,2S,6S,7S)-5-Benzyl-6-trimethylsilanyloxy-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-3-ene

Conditions
ConditionsYield
Stage #1: Norbornan-2-on; benzyl azide With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 2.5h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at 0℃; for 1h;
95%
Norbornan-2-on
497-38-1

Norbornan-2-on

ethyl acetate
141-78-6

ethyl acetate

exo-ethyl (2-hydroxy-bicyclo[2.2.1]hept-2-yl)acetate
72055-12-0, 144657-45-4, 145575-95-7, 145576-12-1

exo-ethyl (2-hydroxy-bicyclo[2.2.1]hept-2-yl)acetate

Conditions
ConditionsYield
Stage #1: ethyl acetate With lithium hexamethyldisilazane In tetrahydrofuran at -70℃; for 0.166667h;
Stage #2: Norbornan-2-on In tetrahydrofuran Reformatsky reaction; cooling;
95%
Norbornan-2-on
497-38-1

Norbornan-2-on

ethyl iodoacetae
623-48-3

ethyl iodoacetae

exo-ethyl (2-hydroxy-bicyclo[2.2.1]hept-2-yl)acetate
72055-12-0, 144657-45-4, 145575-95-7, 145576-12-1

exo-ethyl (2-hydroxy-bicyclo[2.2.1]hept-2-yl)acetate

Conditions
ConditionsYield
With manganese; copper(l) iodide; trifluoroacetic acid In acetonitrile at 20℃; for 12h; Reformatsky Reaction; Schlenk technique; Inert atmosphere;95%
With nickel(II) iodide; manganese; trifluoroacetic acid In acetonitrile at 20℃; for 12h; Inert atmosphere;93%
Norbornan-2-on
497-38-1

Norbornan-2-on

aniline
62-53-3

aniline

N-phenylbicyclo[2.2.1]heptan-2-amine

N-phenylbicyclo[2.2.1]heptan-2-amine

Conditions
ConditionsYield
With formic acid; C18H24Cl2IrN3 In water at 20℃; for 12h; Schlenk technique; Green chemistry;94%
With sodium tris(acetoxy)borohydride; acetic acid In tetrahydrofuran for 48h; Ambient temperature;
Norbornan-2-on
497-38-1

Norbornan-2-on

1-azido-3-iodopropane
58503-62-1

1-azido-3-iodopropane

C10H15N3O

C10H15N3O

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 2.5h;94%
Norbornan-2-on
497-38-1

Norbornan-2-on

2,2-dihydroperoxybicyclo[2.2.1]heptane
1360613-31-5

2,2-dihydroperoxybicyclo[2.2.1]heptane

Conditions
ConditionsYield
With dihydrogen peroxide In water; acetonitrile at 20℃; for 1.33333h;94%
Norbornan-2-on
497-38-1

Norbornan-2-on

Conditions
ConditionsYield
With magnesium; mercury dichloride In ethanol at 20℃; for 12h;93%
With isopropyl alcohol; Ni(0) nanoparticles In tetrahydrofuran at 76℃; for 1h;58%
With sodium tetrahydroborate at 60℃; for 48h;30%
Norbornan-2-on
497-38-1

Norbornan-2-on

1-azidohexane
6926-45-0

1-azidohexane

(1S,2S,6S,7R)-3-Hexyl-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-4-en-2-ol

(1S,2S,6S,7R)-3-Hexyl-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-4-en-2-ol

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 2.5h;93%
Norbornan-2-on
497-38-1

Norbornan-2-on

lithium acetylide ethylenediamine complex

lithium acetylide ethylenediamine complex

2-exo-ethynylbicyclo<2.2.1>heptan-2-ol
18084-03-2, 55373-77-8

2-exo-ethynylbicyclo<2.2.1>heptan-2-ol

Conditions
ConditionsYield
In tetrahydrofuran Ambient temperature;92%
Norbornan-2-on
497-38-1

Norbornan-2-on

lithium enolate of ethyl fluoroacetate
83192-17-0

lithium enolate of ethyl fluoroacetate

Fluoro-(2-hydroxy-bicyclo[2.2.1]hept-2-yl)-acetic acid ethyl ester
92397-93-8

Fluoro-(2-hydroxy-bicyclo[2.2.1]hept-2-yl)-acetic acid ethyl ester

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether at -85℃;91%
Norbornan-2-on
497-38-1

Norbornan-2-on

1-azido-4-chloro-butane
671821-46-8

1-azido-4-chloro-butane

(1S,2S,6S,7R)-3-(4-Chloro-butyl)-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-4-en-2-ol

(1S,2S,6S,7R)-3-(4-Chloro-butyl)-3,4,5-triaza-tricyclo[5.2.1.02,6]dec-4-en-2-ol

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 2.5h;91%
pyrrolidine
123-75-1

pyrrolidine

Norbornan-2-on
497-38-1

Norbornan-2-on

1-(bicyclo[2.2.1]hept-2-ylidene)pyrrolidinium hexafluorophosphate
1174393-33-9

1-(bicyclo[2.2.1]hept-2-ylidene)pyrrolidinium hexafluorophosphate

Conditions
ConditionsYield
With ammonium hexafluorophosphate In toluene for 2h; Reflux;91%
Norbornan-2-on
497-38-1

Norbornan-2-on

benzylamine
100-46-9

benzylamine

N-exo-benzylbicyclo[2.2.1]heptan-2-amine

N-exo-benzylbicyclo[2.2.1]heptan-2-amine

Conditions
ConditionsYield
Stage #1: Norbornan-2-on; benzylamine With titanium(IV) isopropylate In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;
Stage #2: With ammonia borane In tetrahydrofuran at 20℃; for 8h; Inert atmosphere;
91%
Norbornan-2-on
497-38-1

Norbornan-2-on

(2-aminophenyl)(phenyl)methanone
2835-77-0

(2-aminophenyl)(phenyl)methanone

9-phenyl-1,2,3,4-tetrahydro-1,4-methanoacridine
40166-51-6

9-phenyl-1,2,3,4-tetrahydro-1,4-methanoacridine

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate at 60℃; for 0.5h; Friedlaender synthesis; Ionic liquid;91%
Norbornan-2-on
497-38-1

Norbornan-2-on

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl 2-hydroxy(3-oxobicyclo[2.2.1]hept-2-ylidene)ethanoate
1350294-96-0

ethyl 2-hydroxy(3-oxobicyclo[2.2.1]hept-2-ylidene)ethanoate

Conditions
ConditionsYield
Stage #1: Norbornan-2-on; oxalic acid diethyl ester With sodium hydride In tetrahydrofuran at 60℃;
Stage #2: With hydrogenchloride; water In tetrahydrofuran
91%

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