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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality N-(P-Toluenesulfonyl)-L-Glutamic Acid supplier in China

Cas:4816-80-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply N-(p-tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:1

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

N-(p-Tolylsulphonyl)-L-glutamic acid Manufacturer/High quality/Best price/In stock

Cas:4816-80-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

N-(4-Toluenesulfonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

N-(p-Tolylsulphonyl)-L-glutamic acid 4816-80-2

Cas:4816-80-2

Min.Order:1 Metric Ton

FOB Price: $500.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 4816-80-2 with competitive price

Cas:4816-80-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

L-Glutamic acid,N-[(4-methylphenyl)sulfonyl]-

Cas:4816-80-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Leader Biochemical Group

About Product Details Items Specifications Test Results Appearance White to white crystalline powde

China Biggest Factory Manufacturer Supply N-(p-Tolylsulphonyl)-L-glutamic acid CAS 4816-80-2

Cas:4816-80-2

Min.Order:100 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

L-Glutamic acid,N-[(4-methylphenyl)sulfonyl]-

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

N-(P-Toluenesulfonyl)-L-Glutamic Acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

N-Tosyl-(+)-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Tos-Glu-OH

Cas:4816-80-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:white crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Protect

L-Glutamic acid,N-[(4-methylphenyl)sulfonyl]-

Cas:4816-80-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: N-(p-Tolylsulphonyl)-L-glutamic acid Synonyms: N-P-TOSYL-L-GLUTAMIC ACID;N-(P-TOLUENESULFONYL)-L-GLUTAMIC ACID;N-TOSYL-L-GLU;(S)-2-(4-MethylphenylsulfonaMido)pentanedioic acid;(2S)-2-(4-methylbenzenesulfonamido)pentanedioic acid;(

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Wuhu Nuowei Chemistry Technologies Co., Ltd.

Wuhu Nuovo Chemical Technology Co., Ltd. was established in August 2014, mainly engaged in the development, production and sales of ionic liquids, ribose, nucleosides, nucleotides and related chemicals; Products are mainly used in new energy, new ma

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

N-(p-Toluenesulfonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

N-(P-Toluenesulfonyl)-L-Glutamic Acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

N-tosyl-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

N-p-Tosyl-L-glutaMic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

Tosyl-L-Glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

N-(p-Tolylsulphonyl)-L-glutamic acid cas 4816-80-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

N-(p-Tolylsulphonyl)-L-glutamic acid cas 4816-80-2

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:white crystalline powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

N-tosyl-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

4816-80-2 Application:intermediate

L-Glutamic acid, N-[(4-methylphenyl)sulfonyl]-

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

N-(p-Tolylsulphonyl)-L-glutamic acid

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

N-(p-Tolylsulphonyl)-L-Glutamic Acid manufacturer

Cas:4816-80-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

C20H31NO6S
55666-46-1

C20H31NO6S

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 20℃;100%
L-glutamic acid
56-86-0

L-glutamic acid

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 70℃;93%
L-glutamic acid
56-86-0

L-glutamic acid

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Conditions
ConditionsYield
Stage #1: L-glutamic acid; p-toluenesulfonyl chloride With sodium hydroxide In water at 70℃; for 1.5h;
Stage #2: With hydrogenchloride In water at 0℃; pH=3;
92%
Stage #1: L-glutamic acid; p-toluenesulfonyl chloride With sodium hydroxide at 70℃;
Stage #2: With hydrogenchloride at 0℃; pH=~ 3;
92%
Stage #1: L-glutamic acid With sodium hydroxide at 25 - 30℃;
Stage #2: p-toluenesulfonyl chloride at 70 - 75℃; pH=< 9;
76%
L-glutamic acid di-tert-butyl ester hydrochloride
32677-01-3

L-glutamic acid di-tert-butyl ester hydrochloride

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triethylamine / dichloromethane / 1 h
2: trifluoroacetic acid / dichloromethane / 20 °C
View Scheme
dexmethylphenidate N-tosyl-l-glutamate Salt

dexmethylphenidate N-tosyl-l-glutamate Salt

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Conditions
ConditionsYield
Stage #1: dexmethylphenidate N-tosyl-l-glutamate Salt With sodium hydrogencarbonate In ethyl acetate at 40℃; for 0.5h;
Stage #2: With hydrogenchloride In water; iso-butanol at 10 - 40℃; for 0.5h;
ethanol
64-17-5

ethanol

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

N-[(4-methylphenyl)sulfonyl]-β-alanine ethyl ester
76616-47-2

N-[(4-methylphenyl)sulfonyl]-β-alanine ethyl ester

Conditions
ConditionsYield
With sulfuric acid Reflux;95%
methyl 2-[2-[4-[(4-chlorophenyl)phenylmethyl]-1-piperazinyl]ethoxy]-acetate
83881-46-3, 163837-44-3, 163837-46-5

methyl 2-[2-[4-[(4-chlorophenyl)phenylmethyl]-1-piperazinyl]ethoxy]-acetate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

dextrorotatory methyl-2-[2-[4-[(4-chlorophenyl)phenylmethyl]-1-piperazinyl]ethoxy]acetate N-[(4-methylphenyl)sulfonyl]-L-glutamate

dextrorotatory methyl-2-[2-[4-[(4-chlorophenyl)phenylmethyl]-1-piperazinyl]ethoxy]acetate N-[(4-methylphenyl)sulfonyl]-L-glutamate

Conditions
ConditionsYield
In water; isopropyl alcohol at 20 - 60℃; for 1h; Product distribution / selectivity;90.7%
In water; isopropyl alcohol at 20 - 60℃; for 1h; Product distribution / selectivity;63.9%
4,4'-bipyridine
553-26-4

4,4'-bipyridine

cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

[Co((+)-N-p-tolylsulfonylglutamate)(4,4'-bipyridine)](n)*H2O

[Co((+)-N-p-tolylsulfonylglutamate)(4,4'-bipyridine)](n)*H2O

Conditions
ConditionsYield
In water High Pressure; mixing of Co(NO3)2*6H2O, N-p-tolylsulfonyl-L-glutamic acid and 4,4'-bipyin H2O in Teflon reactor, heating to 120°C for 3 d; slow cooling to room temp., crystn., elem. anal.;89%
zinc(II) nitrate hexahydrate

zinc(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

trans-1,2-bis(4-pyridyl)ethylene
1135-32-6

trans-1,2-bis(4-pyridyl)ethylene

[Zn(1,2-bis(4-pyridyl)ethylene)(N-carbamyl-L-glutamate)2H2O]

[Zn(1,2-bis(4-pyridyl)ethylene)(N-carbamyl-L-glutamate)2H2O]

Conditions
ConditionsYield
Stage #1: zinc(II) nitrate hexahydrate; trans-1,2-bis(4-pyridyl)ethylene In ethanol; water; N,N-dimethyl-formamide for 0.166667h;
Stage #2: N-tosyl-L-glutamic acid With sodium hydroxide In ethanol; water; N,N-dimethyl-formamide for 730.5h;
83%
N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

Cu(N-p-tolylsulfonyl-L-glutamate dianion)*H2O

Cu(N-p-tolylsulfonyl-L-glutamate dianion)*H2O

Conditions
ConditionsYield
In ethanol; water addn. of hot aq. soln. of Cu-salt to EtOH soln. of ligand; crystn. on cooling to room temp.; elem. anal.;80%
N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

2-(4'-methylbenzenesulfonyl)-L-glutamic acid dichloride
108590-52-9

2-(4'-methylbenzenesulfonyl)-L-glutamic acid dichloride

Conditions
ConditionsYield
With thionyl chloride for 0.5h; Heating;79.7%
With diethyl ether; phosphorus pentachloride
N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

1-(4'-methylbenzenesulfonyl)-5-oxopyrrolidine-2-carboxylic acid
21957-65-3

1-(4'-methylbenzenesulfonyl)-5-oxopyrrolidine-2-carboxylic acid

Conditions
ConditionsYield
With acetyl chloride for 2h; Heating;74.46%
With dicyclohexyl-carbodiimide In dichloromethane Ambient temperature;63%
With chloroform; phosphorus trichloride
4-(2-pyridyl)pyridine
581-47-5

4-(2-pyridyl)pyridine

cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

[Co((+)-N-p-tolylsulfonylglutamate)(2,4'-bipyridine)2(H2O)2](n)*5nH2O

[Co((+)-N-p-tolylsulfonylglutamate)(2,4'-bipyridine)2(H2O)2](n)*5nH2O

Conditions
ConditionsYield
In water High Pressure; mixing of Co(NO3)2*6H2O, N-p-tolylsulfonyl-L-glutamic acid and 2,4'-bipyin H2O in Teflon reactor, heating to 120°C for 3 d; slow cooling to room temp., crystn., elem. anal.;70.3%
cadmium(II) acetate hydrate

cadmium(II) acetate hydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Cd2(N-p-tolylsulfonyl-L-glutamate dianion)2(H2O)6

Cd2(N-p-tolylsulfonyl-L-glutamate dianion)2(H2O)6

Conditions
ConditionsYield
In ethanol; water addn. of aq. soln. of Cd-salt to EtOH soln. of ligand; crystn. on concn.; elem. anal.;70%
zinc(II) acetate hydrate

zinc(II) acetate hydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

[Zn(N-p-tolylsulfonyl-L-glutamate dianion)(H2O)2]*H2O

[Zn(N-p-tolylsulfonyl-L-glutamate dianion)(H2O)2]*H2O

Conditions
ConditionsYield
In ethanol; water addn. of aq. soln. of Zn-salt to EtOH soln. of ligand; crystn. on concn.; elem. anal.;70%
methanol
67-56-1

methanol

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

dimethyl (2S)-2-{[(4-methylphenyl)sulfonyl]amino}pentane-1,5-dioate
95305-51-4

dimethyl (2S)-2-{[(4-methylphenyl)sulfonyl]amino}pentane-1,5-dioate

Conditions
ConditionsYield
With sulfuric acid Reflux;69%
With chloro-trimethyl-silane cooling;
4-(2-pyridyl)pyridine
581-47-5

4-(2-pyridyl)pyridine

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

[zinc(2,4'-bipyridine)(H2O)((+)-N-tosyl-L-glutamate)]
1431535-97-5

[zinc(2,4'-bipyridine)(H2O)((+)-N-tosyl-L-glutamate)]

Conditions
ConditionsYield
With sodium hydroxide In methanol; water for 0.166667h; pH=6;68%
Methadone
76-99-3

Methadone

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

(6R)-6-(dimethylamino)-4,4-diphenyl-3-heptanone-(+)-N-tosyl glutamate salt

(6R)-6-(dimethylamino)-4,4-diphenyl-3-heptanone-(+)-N-tosyl glutamate salt

Conditions
ConditionsYield
In acetone at 25 - 55℃; Solvent;66%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

water
7732-18-5

water

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

Zn2(N-tosyl-L-glutamic acid(-2H))2(1,10-phenanthroline)2(H2O)2

Zn2(N-tosyl-L-glutamic acid(-2H))2(1,10-phenanthroline)2(H2O)2

Conditions
ConditionsYield
With sodium fluoride at 120℃; for 120h;65%
methanol
67-56-1

methanol

1,3-di(4-pyridyl)propane
17252-51-6

1,3-di(4-pyridyl)propane

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

[Zn(C12H13NO6S-Me)2(1,3-bis(4-pyridyl)propane)2]

[Zn(C12H13NO6S-Me)2(1,3-bis(4-pyridyl)propane)2]

Conditions
ConditionsYield
With NaOH In methanol; water High Pressure; Zn compd., N-tosyl-L-glutamic acid, bpp, and NaOH (1:1:1:2 molar ratio) in H2O/MeOH (1/1) stirerd for 5 min; filtered, crystd. on storage at room temp. for 3 d, septd., elem. anal.;62%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

Zn2(N-tosyl-L-glutamic acid(-2H))2(1,10-phenanthroline)2

Zn2(N-tosyl-L-glutamic acid(-2H))2(1,10-phenanthroline)2

Conditions
ConditionsYield
With sodium fluoride In water at 120℃; for 120h;61%
4,4'-bipyridine
553-26-4

4,4'-bipyridine

nickel(II) nitrate hexahydrate

nickel(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

[Ni((+)-N-p-tolylsulfonyl-L-glutamate)(4,4'-bipyridine)2(H2O)0.5](n)*0.5nH2O

[Ni((+)-N-p-tolylsulfonyl-L-glutamate)(4,4'-bipyridine)2(H2O)0.5](n)*0.5nH2O

Conditions
ConditionsYield
In water High Pressure; mixing of Ni(NO3)2*6H2O, N-p-tolylsulfonyl-L-glutamic acid and 4,4'-bipyin H2O in Teflon reactor, heating to 120°C for 3 d; slow cooling to room temp., crystn., elem. anal.;56%
1H-imidazole
288-32-4

1H-imidazole

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

[zinc(imidazole)(H2O)((+)-N-tosyl-L-glutamate)]
1431535-96-4

[zinc(imidazole)(H2O)((+)-N-tosyl-L-glutamate)]

Conditions
ConditionsYield
With sodium hydroxide In methanol; water for 0.166667h; pH=6;56%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

C12H13NO6S(2-)*Cd(2+)*C12H8N2

C12H13NO6S(2-)*Cd(2+)*C12H8N2

Conditions
ConditionsYield
With sodium hydroxide In water at 140℃; for 168h; pH=5;53.2%
N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

potassium hydroxide

potassium hydroxide

A

Cu(N-p-tolylsulfonyl-L-glutamate dianion)*H2O

Cu(N-p-tolylsulfonyl-L-glutamate dianion)*H2O

B

K[Cu(N-p-tolylsulfonyl-L-glutamate trianion)]*3H2O

K[Cu(N-p-tolylsulfonyl-L-glutamate trianion)]*3H2O

Conditions
ConditionsYield
In ethanol; water addn. of hot aq. soln. of Cu-salt to EtOH soln. of ligand, crystn. on cooling to room temp., collection of first product, addn. of KOH to filtrate to pH 9; pptn. on addn. of dioxane; elem. anal.;A n/a
B 50%
1H-imidazole
288-32-4

1H-imidazole

cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

C12H13NO6S(2-)*Cd(2+)*H2O*C3H4N2

C12H13NO6S(2-)*Cd(2+)*H2O*C3H4N2

Conditions
ConditionsYield
With sodium hydroxide In water at 140℃; for 168h; pH=5;47%
pyridin-3-ylamine
462-08-8

pyridin-3-ylamine

cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

2C12H13NO6S(2-)*2Cd(2+)*5C5H6N2*2.5H2O

2C12H13NO6S(2-)*2Cd(2+)*5C5H6N2*2.5H2O

Conditions
ConditionsYield
With sodium hydroxide In water at 140℃; for 168h; pH=5;45.1%
methanol
67-56-1

methanol

1,3-di(4-pyridyl)propane
17252-51-6

1,3-di(4-pyridyl)propane

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

[Zn(C12H13NO6S-Me)2(1,3-bis(4-pyridyl)propane)]

[Zn(C12H13NO6S-Me)2(1,3-bis(4-pyridyl)propane)]

Conditions
ConditionsYield
With NaOH In methanol; water High Pressure; Zn compd., N-tosyl-L-glutamic acid, bpp, and NaOH (1:1:1:2 molar ratio) in H2O/MeOH (1/3) stirerd for 5 min; filtered, crystd. on storage at room temp. for 3 d, septd., elem. anal.;45%
pyridin-3-ylamine
462-08-8

pyridin-3-ylamine

zinc(II) nitrate hexahydrate

zinc(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

C12H13NO6S(2-)*Zn(2+)*C5H6N2*3H2O

C12H13NO6S(2-)*Zn(2+)*C5H6N2*3H2O

Conditions
ConditionsYield
With sodium hydroxide In water at 140℃; for 168h; pH=5;45%
4-(2-pyridyl)pyridine
581-47-5

4-(2-pyridyl)pyridine

nickel(II) nitrate hexahydrate

nickel(II) nitrate hexahydrate

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

Ni((+)-N-p-tolylsulfonylglutamate)(2,4'-bipyridine)2(H2O)2](n)*5nH2O

Ni((+)-N-p-tolylsulfonylglutamate)(2,4'-bipyridine)2(H2O)2](n)*5nH2O

Conditions
ConditionsYield
In water High Pressure; mixing of Ni(NO3)2*6H2O, N-p-tolylsulfonyl-L-glutamic acid and 2,4'-bipyin H2O in Teflon reactor, heating to 120°C for 3 d; slow cooling to room temp., crystn., elem. anal.;44.9%
1,3,5-Trioxan
110-88-3

1,3,5-Trioxan

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

3-[(4S)-5-oxo-3-(toluene-4-sulfonyl)-oxazolidin-4-yl]-propionic acid
91958-79-1

3-[(4S)-5-oxo-3-(toluene-4-sulfonyl)-oxazolidin-4-yl]-propionic acid

Conditions
ConditionsYield
With dichloromethane; toluene-4-sulfonic acid; benzene
With thionyl chloride; acetic anhydride; acetic acid
formaldehyd
50-00-0

formaldehyd

N-tosyl-L-glutamic acid
4816-80-2

N-tosyl-L-glutamic acid

3-[(4S)-5-oxo-3-(toluene-4-sulfonyl)-oxazolidin-4-yl]-propionic acid
91958-79-1

3-[(4S)-5-oxo-3-(toluene-4-sulfonyl)-oxazolidin-4-yl]-propionic acid

Conditions
ConditionsYield
With thionyl chloride; acetic anhydride; acetic acid
With toluene-4-sulfonic acid at 135℃;

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