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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,4-Dithiane

Cas:505-29-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Tengzhou Runlong Fragrance Co., Ltd.

1、Our factory passed ISO 9001, ISO 14001, ISO 22000 system certification; HALAL 、KOSHER、FCC AND FDA certificate are available. We can provide customers with better prices, and the supply is stable. 2、We founded in 2004,10% of the staff have more tha

FEMA 3831 1,4-dithiane CAS 505-29-3

Cas:505-29-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,4-Dithiane

Cas:505-29-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top quality CAS 505-29-3 with high-quality service

Cas:505-29-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,4-Dithiane 505-29-3

Cas:505-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 1,4-Dithiane CAS: 505-29-3 MF: C4H8S2 MW: 120.24 EINECS: 208-007-2 Mol File: 505-29-3.mol 1,4-Dithiane Structure 1,4-Dithiane Chemical Properties Melting point 107-113 °C (lit.) Boiling point 200 °C (

1,4-Dithiane

Cas:505-29-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Synthetic Flavour & Fragrance, 1,4-Dithiane CAS:505-29-3

Cas:505-29-3

Min.Order:1 Kilogram

FOB Price: $42.1 / 46.8

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

1,4-Dithiane CAS:505-29-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

1,4-Dithiane CAS:505-29-3

Cas:505-29-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,4-Dithiane

Cas:505-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,4-Dithiane

Cas:505-29-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,4-Dithiane

Cas:505-29-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,4-Dithiane

Cas:505-29-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1,4-Dithiane 505-29-3

Cas:505-29-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,4-dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1,4-Dithiane 5g

Cas:505-29-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

1,4-dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

1,4-DithianeAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

1,4-Dithiane CAS No.505-29-3

Cas:505-29-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

1,4-Dithiane cas 505-29-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,4-Dithiane cas 505-29-3

Cas:505-29-3

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

1.4-Dithiane manufacture

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:1g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

1,4-Dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,4-dithiane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,4-Dithiane 505-29-3

Cas:505-29-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1,4-Dithiacyclohexane

Cas:505-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

ethylene dibromide
106-93-4

ethylene dibromide

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With 1-pentyl-3-methylimidazolium bromide at 60℃; for 5.5h;92%
With sodium ethanolate In ethanol for 2.5h; Cyclization; Heating;64%
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With 25percent soude; tetrabutylammomium bromide In benzene at 80℃; for 4h; Product distribution; other concentration of catalyst and soude, time;87.5%
With 1-pentyl-3-methylimidazolium bromide at 60℃; for 0.133333h; Irradiation; microwave;81%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 150℃; for 0.333333h; microwave irradiation;81%
3,6-dithiaoctan-1,8-dithiol
25423-55-6

3,6-dithiaoctan-1,8-dithiol

1,2-bis(2-chloroethylthio)ethane
3563-36-8

1,2-bis(2-chloroethylthio)ethane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

1,4,7,10,13,16-hexathiacyclooctadecan
296-41-3

1,4,7,10,13,16-hexathiacyclooctadecan

C

1,4,7,10-tetrathiacyclododecane
25423-56-7

1,4,7,10-tetrathiacyclododecane

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 50℃;A n/a
B 70%
C 5%
2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane
16892-64-1

2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane

ethylene dibromide
106-93-4

ethylene dibromide

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

dimethyltin dibromide 1,4-dithiane 2:1 complex

dimethyltin dibromide 1,4-dithiane 2:1 complex

C

dimethyltin dibromide
2767-47-7

dimethyltin dibromide

Conditions
ConditionsYield
In further solvent(s) soln. of (Me2SnS)3 in BrCH2CH2Br was heated at 140°C for 35 h; excess C2H4Br2 was removed in vac. at room temp., products were sepd. by sublimation at 70°C; dithiane was identified by chromy., elem. anal. for 2Me2SnBr2*S(CH2CH2)2S;A n/a
B 58%
C 18%
{(C5H5)Ru(P(C6H5)3)2(SC2H4)}(1+)*CF3SO3(1-)*0.5CH2Cl2={(C5H5)Ru(P(C6H5)3)2(SC2H4)}(OSO2CF3)*0.5CH2Cl2
113322-95-5

{(C5H5)Ru(P(C6H5)3)2(SC2H4)}(1+)*CF3SO3(1-)*0.5CH2Cl2={(C5H5)Ru(P(C6H5)3)2(SC2H4)}(OSO2CF3)*0.5CH2Cl2

tetraphenyl phosphonium chloride
2001-45-8

tetraphenyl phosphonium chloride

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)
32993-05-8

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: (C2H4S)n; PPh4Cl added to CD2Cl2-soln. of Ru-thiiran complex at 0°C; decompn. by warming to room temp.;A n/a
B 50%
formaldehyd
50-00-0

formaldehyd

ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

A

1,3-dithiolane
4829-04-3

1,3-dithiolane

B

1,4-Dithiane
505-29-3

1,4-Dithiane

C

3-methylideneamino-1,5,3-dithiazepane
1449678-80-1

3-methylideneamino-1,5,3-dithiazepane

D

1,3,6,8-tetrathiecane
154729-78-9

1,3,6,8-tetrathiecane

Conditions
ConditionsYield
With hydrogenchloride; hydrazine hydrate In water at 20℃; pH=0.45 - 0.5;A 30%
B 9%
C 49%
D 12%
trans-2,3-dichloro-1,4-dithiane
2040-67-7, 89124-15-2

trans-2,3-dichloro-1,4-dithiane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

2,2'-bi-1,3-dithiolanyl
6784-47-0

2,2'-bi-1,3-dithiolanyl

C

2,3-dihydro-1,4-dithiin
23230-01-5

2,3-dihydro-1,4-dithiin

D

2,3-dihydro-5,6-dichloro-1,4-dithiin
106691-43-4

2,3-dihydro-5,6-dichloro-1,4-dithiin

Conditions
ConditionsYield
With disodium 1,2-ethanedithiolate In ethanol for 12h;A 2%
B n/a
C 15%
D 6%
ethylene dibromide
106-93-4

ethylene dibromide

A

thirane
420-12-2

thirane

B

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With aluminum oxide; sulfide ion In toluene at 140℃; for 20h;A 1.5%
B 1.8%
thirane
420-12-2

thirane

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With aluminum oxide; hydrogen sulfide at 220℃;
2,2'-thiobis-ethanol
111-48-8

2,2'-thiobis-ethanol

A

1,4-Oxathiane
15980-15-1

1,4-Oxathiane

B

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With potassium pyrosulfate at 160 - 210℃;
With aluminium silicate at 240℃;
With cation exchanger at 180℃;
With toluene-4-sulfonic acid; acetaldehyde; benzene Unter Entfernen des entstehenden Wassers und Erhitzen des Reaktionsprodukts auf 200grad;
at 180℃; in Gegenwart eines sauren Kationen-Austauschers;
2,2'-thiobis-ethanol
111-48-8

2,2'-thiobis-ethanol

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With aluminum oxide at 225℃;
With hydrogen bromide; phenol
2-(2-benzothiazolylthio)ethanol
4665-63-8

2-(2-benzothiazolylthio)ethanol

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

2(3H)-Benzothiazolone
934-34-9

2(3H)-Benzothiazolone

Conditions
ConditionsYield
at 125 - 200℃;
1-(2-chloro-ethylsulfanyl)-2-propylsulfanyl-ethane
856365-85-0

1-(2-chloro-ethylsulfanyl)-2-propylsulfanyl-ethane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

1-Chloropropane
540-54-5

1-Chloropropane

Conditions
ConditionsYield
beim Erhitzen;
1-butylsulfanyl-2-(2-chloro-ethylsulfanyl)-ethane
159859-35-5

1-butylsulfanyl-2-(2-chloro-ethylsulfanyl)-ethane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

n-Butyl chloride
109-69-3

n-Butyl chloride

Conditions
ConditionsYield
beim Erhitzen;
3,6,9-trithia-1,11-undecanediol
14440-77-8

3,6,9-trithia-1,11-undecanediol

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With hydrogen bromide; phenol
ethanol
64-17-5

ethanol

bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

3-mercaptopropionitrile
1001-58-7

3-mercaptopropionitrile

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

3,3'-thiobis-propanenitrile
111-97-7

3,3'-thiobis-propanenitrile

Conditions
ConditionsYield
Reagiert des Natriumsalzes;
bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With sulfur dichloride at 0℃;
With sodium sulfide
With phenol at 180℃; im Rohr;
With sulfur at 200℃;
bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

Conditions
ConditionsYield
at 180℃;
at 180℃; Gleichgewicht;
bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

ethene
74-85-1

ethene

C

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

Conditions
ConditionsYield
at 220℃; Prod.5:HCl;
at 180℃; Prod.5:HCl;
2-(2-mercapto-ethylsulfanyl)-ethanol
98026-19-8

2-(2-mercapto-ethylsulfanyl)-ethanol

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With hydrogenchloride Erhitzen des Reaktionsprodukts in Phenol bis auf 180grad;
1-Chloro-2-<2-(methylthio)ethylthio>ethane
125787-98-6

1-Chloro-2-<2-(methylthio)ethylthio>ethane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

methylene chloride
74-87-3

methylene chloride

Conditions
ConditionsYield
beim Erhitzen;
bis(2-hydroxyethyl) disulfide
1892-29-1

bis(2-hydroxyethyl) disulfide

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With potassium pyrosulfate under 20 Torr;
With potassium pyrosulfate; phosphoric acid; zinc(II) chloride at 200℃;
2,5,8-trithianonane
37460-04-1

2,5,8-trithianonane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

methylthiol
74-93-1

methylthiol

C

2-methylsulfanyl-ethanethiol
22322-43-6

2-methylsulfanyl-ethanethiol

D

methyl vinyl sulfide
1822-74-8

methyl vinyl sulfide

Conditions
ConditionsYield
bei der trockener Destillation;Produkt5:1.2-Bis-<2-methylmercapto-aethylmercapto>-aethan;
1-chloro-3,6-dithiaoctane
92569-22-7

1-chloro-3,6-dithiaoctane

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

chloroethane
75-00-3

chloroethane

Conditions
ConditionsYield
Destillation;
beim Erhitzen;
2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol
5244-34-8

2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With hydrogen bromide; phenol
2-ethoxy-1,3,2-dithiaphospholane
70164-20-4

2-ethoxy-1,3,2-dithiaphospholane

ethyl iodide
75-03-6

ethyl iodide

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
at 90℃;
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With aluminum oxide at 300℃;
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

1,4-Dithiane
505-29-3

1,4-Dithiane

Conditions
ConditionsYield
With sodium sulfide; ethanol
Dibutyl sulfide
544-40-1

Dibutyl sulfide

ethylene dibromide
106-93-4

ethylene dibromide

A

1,4-Dithiane
505-29-3

1,4-Dithiane

B

1-bromo-butane
109-65-9

1-bromo-butane

5,8-dithiadodecane
13362-39-5

5,8-dithiadodecane

ethylene dibromide
106-93-4

ethylene dibromide

1,4-Dithiane
505-29-3

1,4-Dithiane

1,4-Dithiane
505-29-3

1,4-Dithiane

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

{C5H5Fe(CO)2(1,4-dithiane)}BF4

{C5H5Fe(CO)2(1,4-dithiane)}BF4

Conditions
ConditionsYield
In dichloromethane byproducts: THF; (Ar), organic compound added to soln. of Fe-complex, stirred for 3h (room temp.); filtered, concd. (vacuum), filtered into ether/petroleum ether (2/1), ppt. washed with ether and petroleum ether, dried (vacuum), elem. anal.;99%
1,4-Dithiane
505-29-3

1,4-Dithiane

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate

{(C5H5Fe(CO)2)2(μ-1,4-dithiane)}(BF4)2

{(C5H5Fe(CO)2)2(μ-1,4-dithiane)}(BF4)2

Conditions
ConditionsYield
In dichloromethane byproducts: THF; (Ar), organic compound added to soln. of Fe-complex (molar ratio: 1/2), stirred for 12h (room temp.); pptd., filtered, washed with ether and petroleum ether, dried (vacuum), elem. anal.;98%
1,4-Dithiane
505-29-3

1,4-Dithiane

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium
12092-47-6

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

[Rh(cyclo-octa-1,5-diene)(dithian)]PF6
68264-13-1

[Rh(cyclo-octa-1,5-diene)(dithian)]PF6

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; addn. of AgPF6 to suspn. of Rh-complex contg. excess of dithian, stirring for 10 min; filtration, evapn. of filtrate (vac.), crystn. (Me2CO/Et2O); elem. anal.;98%
1,4-Dithiane
505-29-3

1,4-Dithiane

tris(acetonitrile)pentamethylcyclopentadienylrhodium hexafluorophosphate

tris(acetonitrile)pentamethylcyclopentadienylrhodium hexafluorophosphate

[Rh(η5-pentamethylcyclopentadienyl)(acetonitrile)(dithian)](PF6)2

[Rh(η5-pentamethylcyclopentadienyl)(acetonitrile)(dithian)](PF6)2

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring for 15 min; evapn. (reduced pressure), crystn. (Me2CO/Et2O); elem. anal.;95%
1,4-Dithiane
505-29-3

1,4-Dithiane

bromoacetic acid
79-08-3

bromoacetic acid

1,4-Dithianium-essigsaeure-betain-hydrobromid
30843-64-2

1,4-Dithianium-essigsaeure-betain-hydrobromid

Conditions
ConditionsYield
In nitromethane at 40℃;93%
1,4-Dithiane
505-29-3

1,4-Dithiane

1,4-dithiane 1-oxide
19087-70-8

1,4-dithiane 1-oxide

Conditions
ConditionsYield
With nitric acid; Bu4(1+)*AuCl4(1-) In nitromethane; water for 2h; Ambient temperature;93%
With N-(tert-butyl)-N-chloro-cyanamide In water; acetonitrile at 25℃;90%
With sodium periodate In water; acetone at 20℃; for 24h;38.3%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

[Pd(η3-1-phenylallyl)(dithian)]PF6
68246-34-4

[Pd(η3-1-phenylallyl)(dithian)]PF6

Conditions
ConditionsYield
In acetone N2-atmosphere; addn. of AgPF6 to suspn. of Pd-complex contg. excess of dithian, stirring for 10 min; filtration, evapn. of filtrate (vac.), crystn. (Me2CO/Et2O); elem. anal.;92%
1,4-Dithiane
505-29-3

1,4-Dithiane

dimethyltin dichloride
753-73-1

dimethyltin dichloride

dimethyltin dichloride 1,4-dithiane 2:1 complex

dimethyltin dichloride 1,4-dithiane 2:1 complex

Conditions
ConditionsYield
In neat (no solvent) Me2SnCl2 and 1,4-dithiane were heated at 140°C in a sealed tube under vac. for 12 h; sublimation at 70°C/0.5 mm Hg; elem. anal.;90%
1,4-Dithiane
505-29-3

1,4-Dithiane

2CH3(1-)*2Co(3+)*4(HONC(CH3)C(CH3)NO)(1-)=(CH3Co(HONC(CH3)C(CH3)NO)2)2

2CH3(1-)*2Co(3+)*4(HONC(CH3)C(CH3)NO)(1-)=(CH3Co(HONC(CH3)C(CH3)NO)2)2

CH3Co(HONC(CH3)C(CH3)NO)2(C4H8S2)Co(HONC(CH3)C(CH3)NO)2CH3
100203-27-8

CH3Co(HONC(CH3)C(CH3)NO)2(C4H8S2)Co(HONC(CH3)C(CH3)NO)2CH3

Conditions
ConditionsYield
In dichloromethane (CH3Co(dmgH)2)2 and dithiane are stirred under N2 in CH2Cl2 at room temp. until all dissolved; ether added, ppt. collected by filtration, washed with ether and dried in vacuo at room temp.; elem. anal.;90%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

2Ag(1+)*3(CH2)4S2*2CF3SO3(1-)=[Ag2((CH2)4S2)3][CF3SO3]2

2Ag(1+)*3(CH2)4S2*2CF3SO3(1-)=[Ag2((CH2)4S2)3][CF3SO3]2

Conditions
ConditionsYield
In methanol; dichloromethane addn. of a soln. of 3 equivs. of 1,4-dithiane in CH2Cl2 to a soln. of 2 equivs. of silver salt in methanol, stirring at room temp. for 1 h; filtration, washing with CH2Cl2, drying in vac.; elem. anal.;90%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

[(norbornadiene)rhodium(I)chloride]2
12257-42-0

[(norbornadiene)rhodium(I)chloride]2

[Rh(norbornadiene)(dithian)]PF6
68264-15-3

[Rh(norbornadiene)(dithian)]PF6

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; addn. of AgPF6 to suspn. of Rh-complex contg. excess of dithian, stirring for 10 min; filtration, evapn. of filtrate (vac.), crystn. (Me2CO/Et2O); elem. anal.;90%
1,4-Dithiane
505-29-3

1,4-Dithiane

tert-butyl 4-bromobenzoperoxoate
2123-95-7

tert-butyl 4-bromobenzoperoxoate

1,4-dithian-2-yl 4-bromobenzoate

1,4-dithian-2-yl 4-bromobenzoate

Conditions
ConditionsYield
With copper-iron mixed oxide In dichloromethane; acetonitrile at 140℃; for 24h; Sealed tube;90%
1,4-Dithiane
505-29-3

1,4-Dithiane

tert-butyl 4-methylbenzoperoxoate
22313-60-6

tert-butyl 4-methylbenzoperoxoate

1,4-dithian-2-yl 4-methylbenzoate

1,4-dithian-2-yl 4-methylbenzoate

Conditions
ConditionsYield
With copper-iron mixed oxide In dichloromethane; acetonitrile at 140℃; for 24h; Sealed tube;89%
1,4-Dithiane
505-29-3

1,4-Dithiane

pentacarbonyl(tetrafluoroborato)rhenium
78670-75-4

pentacarbonyl(tetrafluoroborato)rhenium

{((CO)5Re)(C4H8S2)}(1+)*BF4(1-)={((CO)5Re)(C4H8S2)}BF4
118504-51-1

{((CO)5Re)(C4H8S2)}(1+)*BF4(1-)={((CO)5Re)(C4H8S2)}BF4

Conditions
ConditionsYield
In dichloromethane (Ar); addn. of 1,4-dithiane to a suspn. of one equiv. of (CO)5ReFBF3 and stirring at room temp. for 24 h;; sepn. of the residue; washing with CH2Cl2; vacuum drying; elem. anal.;87%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver(I) nitrite
7783-99-5

silver(I) nitrite

Ag(1+)*(CH2)4S2*NO2(1-)=[Ag((CH2)4S2)]NO2

Ag(1+)*(CH2)4S2*NO2(1-)=[Ag((CH2)4S2)]NO2

Conditions
ConditionsYield
In water; acetone addn. of a soln. of 1,4-dithiane in acetone to a soln. of silver salt inwater; elem. anal.;87%
1,4-Dithiane
505-29-3

1,4-Dithiane

pentacarbonyl(tetrafluoroborato)rhenium
78670-75-4

pentacarbonyl(tetrafluoroborato)rhenium

{((CO)5Re)2(C4H8S2)}(2+)*2BF4(1-)={((CO)5Re)2(C4H8S2)}(BF4)2

{((CO)5Re)2(C4H8S2)}(2+)*2BF4(1-)={((CO)5Re)2(C4H8S2)}(BF4)2

Conditions
ConditionsYield
In dichloromethane (Ar); addn. of 1,4-dithiane to a suspn. of two equiv. of (CO)5ReFBF3 and stirring at room temp. for 24 h;; sepn. of the residue; washing with CH2Cl2; vacuum drying; elem. anal.;85%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver nitrate

silver nitrate

AgNO3*{1,4}dithiane
23739-38-0

AgNO3*{1,4}dithiane

Conditions
ConditionsYield
In methanol; dichloromethane addn. of a soln. of 1,4-dithiane in CH2Cl2 to a soln. of silver salt in methanol; elem. anal.;85%
In ethanol
In ethanol
1,4-Dithiane
505-29-3

1,4-Dithiane

mer-[(1,4-bis(diphenylphosphino)butane)aquatrichlororuthenium(III)]
243643-58-5

mer-[(1,4-bis(diphenylphosphino)butane)aquatrichlororuthenium(III)]

mer-[RuCl3(1,4-bis(diphenylphosphino)butane)(1,4-dithiane)]
890526-28-0

mer-[RuCl3(1,4-bis(diphenylphosphino)butane)(1,4-dithiane)]

Conditions
ConditionsYield
In dichloromethane all manipulations under Ar atm.; Ru and S compds. dissolved in CH2Cl2 with stirring at room temp. for 12 h; concd.; pptd. with Et2O,filtered, washed with Et2O, dried in vac.; elem.anal.;85%
1,4-Dithiane
505-29-3

1,4-Dithiane

tert-butyl p-chloroperoxybenzoate
2203-13-6

tert-butyl p-chloroperoxybenzoate

1,4-dithian-2-yl 4-chlorobenzoate

1,4-dithian-2-yl 4-chlorobenzoate

Conditions
ConditionsYield
With copper-iron mixed oxide In dichloromethane; acetonitrile at 140℃; for 24h; Sealed tube;85%
1,4-Dithiane
505-29-3

1,4-Dithiane

[N-(trifluoromethylsulfonyl)imino][4-(trifluoromethyl)phenyl]-λ3-bromane
957188-75-9

[N-(trifluoromethylsulfonyl)imino][4-(trifluoromethyl)phenyl]-λ3-bromane

C5H8F3NO2S3
1251955-12-0

C5H8F3NO2S3

Conditions
ConditionsYield
In dichloromethane at -78 - 0℃; for 2h; Inert atmosphere;84%
1,4-Dithiane
505-29-3

1,4-Dithiane

tert-butyl perester of 4-methoxybenzoic acid
43084-97-5

tert-butyl perester of 4-methoxybenzoic acid

1,4-dithian-2-yl 4-methoxybenzoate

1,4-dithian-2-yl 4-methoxybenzoate

Conditions
ConditionsYield
With copper-iron mixed oxide In dichloromethane; acetonitrile at 140℃; for 24h; Sealed tube;83%
1,4-Dithiane
505-29-3

1,4-Dithiane

palladium(II) hexafluoroacetylacetonate

palladium(II) hexafluoroacetylacetonate

(C4H8S2)2Pd(2+)*2CF3COCHCOCF3(1-)=(C4H8S2)2Pd(CF3COCHCOCF3)2

(C4H8S2)2Pd(2+)*2CF3COCHCOCF3(1-)=(C4H8S2)2Pd(CF3COCHCOCF3)2

Conditions
ConditionsYield
In pentane a pentane solution of Pd(F6acac)2 was added to a solution of 1,4-C4H8S2 in pentane with stirring; filtrated and vac. dried;82%
1,4-Dithiane
505-29-3

1,4-Dithiane

silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

(2-methylallyl)palladium-chloride dimer

(2-methylallyl)palladium-chloride dimer

[Pd(η3-2-methylallyl)(dithian)]PF6
68246-32-2

[Pd(η3-2-methylallyl)(dithian)]PF6

Conditions
ConditionsYield
In acetone N2-atmosphere; addn. of AgPF6 to suspn. of Pd-complex contg. excess of dithian, stirring for 10 min; filtration, evapn. of filtrate (vac.), crystn. (Me2CO/Et2O); elem. anal.;82%
1,4-Dithiane
505-29-3

1,4-Dithiane

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)
88496-72-4

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)

trans-[RuCl2(1,4-bis(diphenylphosphino)butane)(1,4-dithiane)]
890526-27-9

trans-[RuCl2(1,4-bis(diphenylphosphino)butane)(1,4-dithiane)]

Conditions
ConditionsYield
In dichloromethane all manipulations under Ar atm.; mixt. of Ru and S compds. stirred in CH2Cl2 at room temp. for 30 min; concd.; pptd. with Et2O,filtered, washed with Et2O, dried in vac.; elem.anal.;80%
1,4-Dithiane
505-29-3

1,4-Dithiane

bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

[PdCl2(dithian)(0.1Me2CO)]n

[PdCl2(dithian)(0.1Me2CO)]n

Conditions
ConditionsYield
With acetone In acetone N2-atmosphere; stirring for 16 h (pptn.); filtration, washing (Me2CO, Et2O), drying (vac., 56°C); elem. anal.;80%
1,4-Dithiane
505-29-3

1,4-Dithiane

potassium hexacyanoruthenate(II) trihydrate

potassium hexacyanoruthenate(II) trihydrate

K3[Ru(CN)5(1,4-dithiane)]*3H2O

K3[Ru(CN)5(1,4-dithiane)]*3H2O

Conditions
ConditionsYield
With bromine In ethanol; water to soln. Ru complex in aq. EtOH Br2 was added and stirred for 20 min, 3-fold excess ligand was added dropwise under Ar and allowed to stand for 1 day; react. mixt. was cooled in ice bath and acetone was added, ppt. was filtered, washed with acetone and Et2O, and dried; elem. anal.;80%
1,4-Dithiane
505-29-3

1,4-Dithiane

tert-Butyl peroxybenzoate
614-45-9

tert-Butyl peroxybenzoate

2-(benzoyloxy)-1,4-dithiane
81146-36-3

2-(benzoyloxy)-1,4-dithiane

Conditions
ConditionsYield
With copper-iron mixed oxide In dichloromethane; acetonitrile at 140℃; for 24h; Sealed tube;80%
1,4-Dithiane
505-29-3

1,4-Dithiane

tetracarbonyldi-μ-chlorodirhodium(I)

tetracarbonyldi-μ-chlorodirhodium(I)

silver perchlorate

silver perchlorate

Rh(1+)*2CO*C4H8S2*[ClO4](1-)=[Rh(CO)2(C4H8S2)][ClO4]

Rh(1+)*2CO*C4H8S2*[ClO4](1-)=[Rh(CO)2(C4H8S2)][ClO4]

Conditions
ConditionsYield
In acetone byproducts: silver chloride; (N2); stoich. amt. of AgClO4 added to complex soln., stirred in dark for 5 min, slight excess of ligand added; filtered (Kieselguhr), collected over Et2O under N2, ppt. filtered off,washed with Et2O, dried in vac.; elem. anal.;79%

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