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inquiryWelcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general
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inquiryChemical Name: Tert-Butyl Peroxy Benzoate CAS No.: 614-45-9 Molecular formula: C11H14O3 Molecular weight: 194.2 Structure: Brief Introduction: SF-C is low volatile, yellowish transparent liquid, is an ester of organic peroxides. Solub
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tert-Butyl peroxybenzoate CAS:614-45-9 Specification Item Specifications Results Appearance Light yellow transparent oily liquid Conforms Content %
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inquirySuperior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat
Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting tert-Butyl peroxybenzoate(TBPB;Trigonox C),CAS:614-45-9, Please contact us by email freely. We are leading exporter in China. If you really need this c
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
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Tert-Butyl perbenzoate 98%,cas:614-45-9 fandachem Application:Tert-Butyl perbenzoate 98%,cas:614-45-9 fandachem
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inquiryTert-Butyl peroxybenzoate CAS #: 614-45-9 Description: English name: Tert-Butyl peroxybenzoate Alias??: TBPB, CP-O2, initiator C, tert-butyl peroxide benzoate Structure: Formula: C11H14O3 Molecular Weight: 194.23 Product Pro
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inquiryConditions | Yield |
---|---|
Stage #1: tert-butyl alcohol With sodium hydroxide at 15 - 20℃; for 1h; Stage #2: benzoyl chloride at 10 - 15℃; for 1.5h; Temperature; | 98.3% |
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In water at 40℃; for 16h; Temperature; Solvent; Reagent/catalyst; | 98% |
With potassium iodide In water at 40℃; for 0.0166667h; Flow reactor; | 82% |
With oxygen; tetra-(n-butyl)ammonium iodide In decane; water at 20℃; for 16h; Inert atmosphere; | 81% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 11 - 12℃; | 95.3% |
With sodium hydroxide In water at 11 - 12℃; Product distribution / selectivity; Industry scale; | 95.3% |
With potassium hydroxide |
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In water at 40℃; for 24h; | 84% |
With potassium iodide In water at 40℃; for 0.0166667h; Flow reactor; | 84% |
With tris(2,2'-bipyridyl)ruthenium dichloride In decane; acetonitrile at 20℃; for 36h; Molecular sieve; Irradiation; Inert atmosphere; | 62% |
With tetrabutylammomium bromide In water at 40℃; Mechanism; | 10% |
tert.-butylhydroperoxide
di-tert-butyl peroxide
benzaldehyde
tert-Butyl peroxybenzoate
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In water for 2h; Reagent/catalyst; Wavelength; Irradiation; Green chemistry; | 83% |
Conditions | Yield |
---|---|
With potassium iodide In water at 40℃; for 0.0166667h; Catalytic behavior; Reagent/catalyst; Temperature; Time; Flow reactor; Green chemistry; | 81% |
Conditions | Yield |
---|---|
With copper diacetate In neat (no solvent) at 20℃; for 5h; Reagent/catalyst; Solvent; Green chemistry; | 80% |
tert.-butylhydroperoxide
benzyl alcohol
A
tert-Butyl peroxybenzoate
B
benzoic acid
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In water; benzonitrile at 40℃; for 24h; Schlenk technique; Sealed tube; | A 28% B 57% |
With C24H26ClN4Ru(1+)*CF3O3S(1-) In water at 20℃; for 3h; Reagent/catalyst; | A 35% B 53% |
With 6Cl(1-)*2C41H34N7O2(2+)*Ru(2+)*2C48H48N32O16 In hexane at 50℃; for 5h; | A 49 %Chromat. B 49 %Chromat. |
tert.-butylhydroperoxide
isobutyl acrylate
benzaldehyde
A
tert-Butyl peroxybenzoate
C
benzoic acid
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | A n/a B 42% C n/a |
tert.-butylhydroperoxide
di-tert-butyl peroxide
benzyl alcohol
tert-Butyl peroxybenzoate
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry; | 31% |
tert.-butylhydroperoxide
benzoic acid anhydride
A
tert-Butyl peroxybenzoate
B
benzoic acid
Conditions | Yield |
---|---|
In benzene at 50℃; Rate constant; |
Conditions | Yield |
---|---|
With di(tert.-butoxy)-tert.-butylperoxyaluminum In benzene for 72h; Product distribution; Mechanism; Ambient temperature; other conditions: other temperatures, other times; |
phenyl benzyl ketone
tert.-butylhydroperoxide
aluminum tri-tert-butoxide
A
tert-Butyl peroxybenzoate
B
benzoic acid tert-butyl ester
C
benzaldehyde
D
acetone
E
benzoic acid
F
tert-butyl alcohol
Conditions | Yield |
---|---|
With sulfuric acid Product distribution; multistep reaction; various temperature and reaction time; |
tert.-butylhydroperoxide
3-methyl-1-phenylbutan-2-one
aluminum tri-tert-butoxide
A
phenylacetic acid
B
tert-Butyl peroxybenzoate
C
benzaldehyde
D
acetic acid
E
benzoic acid
F
tert-butyl alcohol
Conditions | Yield |
---|---|
With sulfuric acid Product distribution; multistep reaction; various temperature and reaction time; |
tert.-butylhydroperoxide
aluminum tri-tert-butoxide
1-phenyl-acetone
A
tert-Butyl peroxybenzoate
B
tert-butyl peroxyacetate
C
benzaldehyde
D
acetic acid
E
benzoic acid
F
tert-butyl alcohol
Conditions | Yield |
---|---|
With sulfuric acid Product distribution; multistep reaction; various temperature and reaction time; |
tert.-butylhydroperoxide
aluminum tri-tert-butoxide
1,3-Diphenylpropanone
A
tert-Butyl peroxybenzoate
B
t-butyl phenylacetate
C
benzoic acid tert-butyl ester
D
t-butyl phenylperacetate
E
benzaldehyde
F
tert-butyl alcohol
Conditions | Yield |
---|---|
With sulfuric acid Product distribution; multistep reaction; various temperature and reaction time; |
tert.-butylhydroperoxide
methyl 2-oxo-2-phenylacetate
aluminum tri-tert-butoxide
A
methanol
B
tert-Butyl peroxybenzoate
C
carbon dioxide
D
benzoic acid
E
tert-butyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 120h; Product distribution; Mechanism; other temperature, reaction time; |
tert.-butylhydroperoxide
Benzyl acetate
aluminum tri-tert-butoxide
A
tert-Butyl peroxybenzoate
B
acetic acid tert-butyl ester
C
tert-butyl peroxyacetate
D
acetic acid
E
benzoic acid
F
benzyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 3h; Product distribution; Mechanism; |
tert.-butylhydroperoxide
(RS)-methyl mandelate
aluminum tri-tert-butoxide
A
methanol
B
methyl 2-oxo-2-phenylacetate
C
tert-Butyl peroxybenzoate
D
carbon dioxide
E
benzoic acid
F
tert-butyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 72h; Product distribution; Mechanism; |
tert.-butylhydroperoxide
aluminum tri-tert-butoxide
benzoic acid anhydride
A
tert-Butyl peroxybenzoate
B
acetic acid tert-butyl ester
C
tert-butyl peroxyacetate
D
benzoic acid tert-butyl ester
Conditions | Yield |
---|---|
In benzene at 20℃; for 5h; Product distribution; Mechanism; other reagent; |
tert.-butylhydroperoxide
aluminum tri-tert-butoxide
benzeneacetic acid methyl ester
A
methanol
B
methyl 2-oxo-2-phenylacetate
C
tert-Butyl peroxybenzoate
D
carbon dioxide
E
benzoic acid
F
tert-butyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 120h; Product distribution; Mechanism; other temperature, reaction time; |
tert.-butylhydroperoxide
benzyl methyl ether
A
benzoic acid methyl ester
B
tert-Butyl peroxybenzoate
C
benzoic acid tert-butyl ester
Conditions | Yield |
---|---|
With aluminum tri-tert-butoxide In benzene at 20℃; for 72h; Oxidation; | A 0.07 mol B 0.11 mol C 0.02 mol |
tert.-butylhydroperoxide
ethyl diphenylmethyl ether
A
benzophenone
B
tert-Butyl peroxybenzoate
C
benzoic acid ethyl ester
D
phenol
Conditions | Yield |
---|---|
With aluminum tri-tert-butoxide In benzene at 20℃; for 72h; Oxidation; | A 0.53 mol B 0.10 mol C 0.11 mol D 0.06 mol |
tert.-butylhydroperoxide
benzyl diphenylmethyl ether
A
tert-Butyl peroxybenzoate
B
benzoic acid benzyl ester
C
benzaldehyde
D
benzoic acid
Conditions | Yield |
---|---|
With aluminum tri-tert-butoxide In benzene at 20℃; for 72h; Oxidation; | A 0.02 mol B 0.06 mol C 0.06 mol D 0.46 mol |
tert.-butylhydroperoxide
dibenzyl ether
A
tert-Butyl peroxybenzoate
B
benzoic acid tert-butyl ester
C
benzoic acid benzyl ester
D
benzyl alcohol
Conditions | Yield |
---|---|
With aluminum tri-tert-butoxide In benzene at 20℃; for 96h; Oxidation; Further byproducts given; | A 0.16 mol B 0.02 mol C 0.20 mol D 0.12 mol |
benzyl methyl ether
phenyl 3-methylbutanoate
aluminum tri-tert-butoxide
A
methanol
B
formic acid
C
tert-Butyl peroxybenzoate
D
benzoic acid
Conditions | Yield |
---|---|
In benzene at 20℃; for 96h; Product distribution; Oxidation; | A 0.16 mol B 0.23 mol C 0.11 mol D 0.25 mol |
ethyl diphenylmethyl ether
phenyl 3-methylbutanoate
aluminum tri-tert-butoxide
A
tert-Butyl peroxybenzoate
B
ethanol
C
benzoic acid ethyl ester
D
acetic acid
Conditions | Yield |
---|---|
In benzene at 20℃; for 96h; Product distribution; Oxidation; | A 0.10 mol B 0.30 mol C 0.17 mol D 0.12 mol |
benzyl diphenylmethyl ether
phenyl 3-methylbutanoate
aluminum tri-tert-butoxide
A
tert-Butyl peroxybenzoate
B
benzoic acid
C
benzyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 96h; Product distribution; Oxidation; | A 0.02 mol B 0.46 mol C 0.13 mol |
dibenzyl ether
phenyl 3-methylbutanoate
aluminum tri-tert-butoxide
A
tert-Butyl peroxybenzoate
B
benzoic acid
C
benzyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 96h; Product distribution; Oxidation; | A 0.16 mol B 0.51 mol C 0.12 mol |
benzhydryl methyl ether
phenyl 3-methylbutanoate
aluminum tri-tert-butoxide
A
benzoic acid methyl ester
B
benzophenone
C
tert-Butyl peroxybenzoate
D
phenol
Conditions | Yield |
---|---|
In benzene at 20℃; for 96h; Product distribution; Oxidation; | A 0.19 mol B 0.54 mol C 0.11 mol D 0.05 mol |
tert-Butyl peroxybenzoate
Dichlorophenylphosphine
acrylic acid
butan-1-ol
butyl 3-[butoxy(phenyl)phosphinyl]propionate
Conditions | Yield |
---|---|
97% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 2h; chemoselective reaction; | 97% |
tert-Butyl peroxybenzoate
4-(1,1-dimethylethyl)-benzenemethanamine
N-(4-(tert-butyl)benzyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 97% |
tert-Butyl peroxybenzoate
2,2-dimethylpropylamine
N-2,2-dimethylpropylbenzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 6h; chemoselective reaction; | 96% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 3h; chemoselective reaction; | 96% |
tert-Butyl peroxybenzoate
4-methoxy-benzylamine
N-(4-methoxybenzyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 96% |
Conditions | Yield |
---|---|
Stage #1: prasterone acetate With copper(I) bromide In dichloromethane for 0.25h; Heating; Stage #2: tert-Butyl peroxybenzoate In dichloromethane Heating; | 95% |
tert-Butyl peroxybenzoate
methanephosphonous acid mono-n-butyl ester
methallyl carbamate
Conditions | Yield |
---|---|
95% |
Conditions | Yield |
---|---|
With ammonium hydroxide In neat (no solvent) at 20℃; for 6h; chemoselective reaction; | 95% |
4-(aminomethyl)pyridine
tert-Butyl peroxybenzoate
N-benzoyl-4-(aminomethyl)pyridine
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 10h; chemoselective reaction; | 95% |
tert-Butyl peroxybenzoate
cyclohexylmethylamine
Ν-(cyclohexylmethyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 3h; chemoselective reaction; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 3h; chemoselective reaction; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 6h; chemoselective reaction; | 95% |
tert-Butyl peroxybenzoate
diphenyl acetylene
3,4-diphenyl-isochromen-1-one
Conditions | Yield |
---|---|
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; cesium pivalate; Trimethylacetic acid at 80℃; for 18h; Inert atmosphere; Schlenk technique; | 95% |
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; cesium pivalate; Trimethylacetic acid In 2,2,2-trifluoroethanol at 80℃; for 18h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 94% |
tert-Butyl peroxybenzoate
furan-2-ylmethanamine
N-(2-furylmethyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 10h; chemoselective reaction; | 94% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 6h; chemoselective reaction; | 94% |
tert-Butyl peroxybenzoate
benzyl-methyl-amine
N-methyl-N-benzylbenzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 10h; chemoselective reaction; | 94% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 94% |
tert-Butyl peroxybenzoate
(4-aminomethyl)aniline
N-(4'-Aminobenzyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 14h; chemoselective reaction; | 94% |
tert-Butyl peroxybenzoate
para-fluorobenzylamine
Ν-(4-fluorobenzyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 10h; chemoselective reaction; | 94% |
tert-Butyl peroxybenzoate
4-aminobenzyl cyanide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 94% |
Conditions | Yield |
---|---|
With iodine; sodium carbonate In acetonitrile at 70℃; for 24h; | 94% |
With iodine; sodium carbonate In 1,4-dioxane at 80℃; for 24h; | 93% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 93% |
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 12h; chemoselective reaction; | 93% |
tert-Butyl peroxybenzoate
m-aminobenzylamine
N-(3-aminobenzyl)benzamide
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 14h; chemoselective reaction; | 93% |
tert-Butyl peroxybenzoate
4-aminomethylphenol
N-benzoyl-4-hydroxybenzylamine
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 14h; chemoselective reaction; | 93% |
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