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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Bromo-6-methoxynaphthalene Manufacturer/High quality/Best price/In stock

Cas:5111-65-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 6-Methoxy-2-Bromonaphthalene supplier in China

Cas:5111-65-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Factory supply 2-bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 6-Methoxy-2-Bromonaphthalene

Cas:5111-65-9

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

6-Bromo-2-methoxynaphthalene

Cas:5111-65-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Bromo-6-methoxynaphthalene CAS 5111-65-9

Cas:5111-65-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

2-Bromo-6-methoxynaphthalene 5111-65-9

Cas:5111-65-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 5111-65-9 with best quality

Cas:5111-65-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product Name: 2-Bromo-6-methoxynaphthalene Synonyms: BROMO(2-)-6-METHOXY NAPHTHALENE;BMN;2-BROMO-6-METHOXYNAPHTHALENE;2-BROMO-6-METHOXYNAPTHALENE;(6-BROM-2-NAPHTHYL)-METH

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Naphthalene,2-bromo-6-methoxy- 5111-65-9

Cas:5111-65-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 6-(Trifluoromethyl)nicotinic acid CAS: 231291-22-8 MF: C7H4F3NO2 MW: 191.11 EINECS: 624-411-5 Mol File: 231291-22-8.mol 6-(Trifluoromethyl)nicotinic acid Structure 6-(Trifluoromethyl)nicotinic acid Chemical Propertie

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Naphthalene,2-bromo-6-methoxy-

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Bromo-6-Methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-BROMO-6-METHOXYNAPHTHALENE

Cas:5111-65-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

2-Bromo-6-methoxynaphthaleneAppearance:White fine powder Storage:Kept in a cool,dry and ventilated place Package:according to customers' requirements Application:Meets the requirements Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by se

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystals Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediate

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 2-Bromo-6-Methoxynaphthalene CAS No.:5111-65-9 Molecule Formula:C11H9BrO Molecule Weight:237.09 Purity: 99.0% Package: 25kg/drum Description:Yellowish to off-white powder Manufacture Standards:Enterprise Standard

High Quality 2-Bromo-6-Methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Bromo-6-methoxynaphthalene cas no. 5111-65-9 98%

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-BroMo-6-Methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

2-Bromo-6-Methoxynaphthalene

Cas:5111-65-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

good quality and cheap price Package:25kg/200kg Application:as intermediates Transportation:by courier/sea/air

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

6-Methoxy-2-Bromonaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

2-Bromo-6-methoxynaphthalene

Cas:5111-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

methyl bromide
74-83-9

methyl bromide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 3h; Reflux;99%
With potassium tert-butylate In dimethyl sulfoxide for 0.25h;
2-Methoxynaphthalene
93-04-9

2-Methoxynaphthalene

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With hydrogen bromide; sodium bromide In chloroform; water at 0℃; Electrochemical reaction;98%
With bromine; acetic acid at 55 - 85℃; under 760.051 Torr; for 0.275h; Temperature;90.2%
With tin; bromine; acetic acid 2.) reflux; Multistep reaction;
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

methyl iodide
74-88-4

methyl iodide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 100℃;97%
With caesium carbonate In acetone at 0 - 26℃;97%
With potassium carbonate In N,N-dimethyl-formamide96%
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Stage #1: 6-bromo-naphthalen-2-ol With tetrabutyl-ammonium chloride; potassium carbonate at 135℃; Neat (no solvent);
Stage #2: carbonic acid dimethyl ester at 130 - 135℃; for 6h; Neat (no solvent);
95%
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

dimethyl sulfate
77-78-1

dimethyl sulfate

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate In acetone for 12h; Reflux;92%
With caesium carbonate In acetone at 20℃; for 0.5h;91%
With aluminum oxide; potassium hydroxide for 6h; microwave irradiation;88%
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With caesium carbonate In 1,2-dimethoxyethane at 145℃; for 1h; Microwave irradiation; Inert atmosphere; Sealed vessel;92%
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

methyl halide

methyl halide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 24h; Reflux;81%
With potassium carbonate In N,N-dimethyl-formamide at 80℃;
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

4-benzyl-4-methylmorpholinium chloride
55476-88-5

4-benzyl-4-methylmorpholinium chloride

A

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

B

6-benzyloxy-2-bromonaphthalene
2234-45-9

6-benzyloxy-2-bromonaphthalene

Conditions
ConditionsYield
With potassium carbonate at 150 - 160℃; for 2h;A n/a
B 72%
6-bromonaphthalen-2-yl 4-methylbenzenesulfonate

6-bromonaphthalen-2-yl 4-methylbenzenesulfonate

potassium methanolate
865-33-8

potassium methanolate

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
In acetonitrile at 45℃; Schlenk technique; Inert atmosphere;70%
In acetonitrile at 45℃; for 18.5h;70%
2-methoxy-6-(prop-1-en-2-yl)-naphthalene
34352-92-6

2-methoxy-6-(prop-1-en-2-yl)-naphthalene

A

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

B

2-(2-Bromo-1-fluoro-1-methyl-ethyl)-6-methoxy-naphthalene
182816-10-0

2-(2-Bromo-1-fluoro-1-methyl-ethyl)-6-methoxy-naphthalene

C

1-Bromo-6-(2-bromo-1-fluoro-1-methyl-ethyl)-2-methoxy-naphthalene

1-Bromo-6-(2-bromo-1-fluoro-1-methyl-ethyl)-2-methoxy-naphthalene

Conditions
ConditionsYield
With N-Bromosuccinimide; triethylamine tris(hydrogen fluoride) In dichloromethane for 14h; Ambient temperature;A 4%
B 29%
C 67%
potassium trifluoro(6-methoxynaphthalen-2-yl)borate
1163708-25-5, 1412414-27-7

potassium trifluoro(6-methoxynaphthalen-2-yl)borate

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With acetic acid; lithium bromide In dimethyl sulfoxide at 100℃; for 8h; Schlenk technique;56%
methanol
67-56-1

methanol

6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 100℃;
With sulfuric acid
at 100℃;
6-bromo-2-methoxy-1-naphthoic acid
610277-16-2

6-bromo-2-methoxy-1-naphthoic acid

A

6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

B

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With quinoline; copper
C15H19N3O

C15H19N3O

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With molecular sieve; Amberlyst XN-1010 resin; potassium iodide In N,N-dimethyl-formamide; acetonitrile at 70℃;
6-methoxy-2-naphthylamine
13101-88-7

6-methoxy-2-naphthylamine

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) aq. HCl, NaNO2, 2) K2CO3 / 1) H2O, 0 deg C, 1 h, 2) H2O
2: KI, Amberlyst XN-1010 resin, ground molecular sieve / acetonitrile; dimethylformamide / 70 °C
View Scheme
2-methoxy-1-naphthaldehyde
5392-12-1

2-methoxy-1-naphthaldehyde

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: potassium permanganate; potassium carbonate; aqueous acetone
2: diethyl ether
3: acetic acid; bromine / Irradiation.Sonnenlicht
4: ethanolic NaOH-solution
5: copper-powder; quinoline
View Scheme
1-bromo-2-naphthol
573-97-7

1-bromo-2-naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: tin; hydrochloric acid; alcohol
2: glacial acetic acid; bromine
3: tin (II)-chloride; concentrated hydrochloric acid; alcohol
4: KOH-solution
View Scheme
Multi-step reaction with 4 steps
1: tin; hydrochloric acid; alcohol
2: glacial acetic acid; bromine
3: sodium amalgam; alcohol
4: KOH-solution
View Scheme
Multi-step reaction with 5 steps
1: tin; hydrochloric acid; alcohol
2: glacial acetic acid; bromine
3: tin (II)-chloride; concentrated hydrochloric acid / weit. Reagens: Alkohol
4: sodium amalgam; alcohol
5: KOH-solution
View Scheme
Multi-step reaction with 4 steps
1: tin; hydrochloric acid; alcohol
2: glacial acetic acid; bromine
3: sodium amalgam; alcohol
4: KOH-solution
View Scheme
1,6-dibromo-2-naphthol
16239-18-2

1,6-dibromo-2-naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tin (II)-chloride; concentrated hydrochloric acid; alcohol
2: KOH-solution
View Scheme
Multi-step reaction with 2 steps
1: tin; concentrated hydrochloric acid; alcohol
2: KOH-solution
View Scheme
Multi-step reaction with 2 steps
1: acetic acid; tin / 3 h / 100 - 120 °C
2: potassium carbonate / acetone; water / 4 h / 10 - 50 °C / Cooling
View Scheme
2-methoxy-1-naphthoic acid
947-62-6

2-methoxy-1-naphthoic acid

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: diethyl ether
2: acetic acid; bromine / Irradiation.Sonnenlicht
3: ethanolic NaOH-solution
4: copper-powder; quinoline
View Scheme
methyl ester of 2-methoxy-1-naphthalenecarboxylic acid
13343-92-5

methyl ester of 2-methoxy-1-naphthalenecarboxylic acid

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: acetic acid; bromine / Irradiation.Sonnenlicht
2: ethanolic NaOH-solution
3: copper-powder; quinoline
View Scheme
4,6-dibromo-β-naphthol
102153-54-8

4,6-dibromo-β-naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium amalgam; alcohol
2: KOH-solution
View Scheme
1,4,6-tribromo-[2]naphthol
116632-10-1

1,4,6-tribromo-[2]naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium amalgam; alcohol
2: KOH-solution
View Scheme
Multi-step reaction with 3 steps
1: tin (II)-chloride; concentrated hydrochloric acid / weit. Reagens: Alkohol
2: sodium amalgam; alcohol
3: KOH-solution
View Scheme
1,3,4,6-tetrabromo-[2]naphthol
98994-65-1

1,3,4,6-tetrabromo-[2]naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium amalgam; alcohol
2: KOH-solution
View Scheme
methyl 6-bromo-2-methoxy-1-naphthoate
854817-26-8

methyl 6-bromo-2-methoxy-1-naphthoate

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ethanolic NaOH-solution
2: copper-powder; quinoline
View Scheme
β-naphthol
135-19-3

β-naphthol

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: glacial acetic acid; bromine
2: tin (II)-chloride; concentrated hydrochloric acid; alcohol
3: KOH-solution
View Scheme
Multi-step reaction with 3 steps
1: glacial acetic acid; bromine
2: sodium amalgam; alcohol
3: KOH-solution
View Scheme
Multi-step reaction with 4 steps
1: glacial acetic acid; bromine
2: tin (II)-chloride; concentrated hydrochloric acid / weit. Reagens: Alkohol
3: sodium amalgam; alcohol
4: KOH-solution
View Scheme
2-(6-methoxynaphthyl)magnesium bromide

2-(6-methoxynaphthyl)magnesium bromide

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

B

naproxen
23981-80-8

naproxen

Conditions
ConditionsYield
In tetrahydrofuran
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

kieselguhr

kieselguhr

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

Conditions
ConditionsYield
With sodium hydroxide; dimethyl sulfate In water
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

2-methyl-4-(6-methoxynaphthalen-2-yl)but-3-yn-2-ol
129112-99-8

2-methyl-4-(6-methoxynaphthalen-2-yl)but-3-yn-2-ol

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine for 17h; Heating;100%
With copper(l) iodide; ethanolamine; triphenylphosphine; palladium on activated charcoal In water; acetonitrile at 80℃; for 15h; Sonogashira cross-coupling;80%
With bis-triphenylphosphine-palladium(II) chloride; copper(I) In triethylamine at 90℃; for 20h;79%
With tetrakis(triphenylphosphine) palladium(0); triphenylphosphine; lithium bromide; copper(ll) bromide In tetrahydrofuran at 90℃; for 2h; Substitution; Title compound not separated from byproducts;
With copper(l) iodide; palladium diacetate; N-ethyl-N,N-diisopropylamine; triphenylphosphine In N,N-dimethyl-formamide at 70℃; for 12h; Inert atmosphere; Glovebox;
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

phenylboronic acid
98-80-6

phenylboronic acid

2-methoxy-6-phenylnaphthalene
59115-43-4

2-methoxy-6-phenylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; (η5-C5H5)Re(NO)(P(C6H5)3)P(C6H5)2; palladium diacetate In toluene at 100℃; for 0.25h; Suzuki cross-couplings reaction;100%
With palladium diacetate; tetrabutylammomium bromide; potassium carbonate In water at 70℃; for 1h;99%
With potassium fluoride; o-(dicyclohexylphosphino)diisopropylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In N,N-dimethyl-formamide at 80℃; for 40h; Suzuki cross-coupling;98%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

copper(I) cyanide
544-92-3

copper(I) cyanide

2-cyano-6-methoxynaphthalene
67886-70-8

2-cyano-6-methoxynaphthalene

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 4h; Heating;100%
Substitution;
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

(6-methoxy-2-naphthalene)boronic acid
156641-98-4

(6-methoxy-2-naphthalene)boronic acid

Conditions
ConditionsYield
Stage #1: 2-Bromo-6-methoxynaphthalene With sec.-butyllithium In tetrahydrofuran; hexane at -78℃;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane for 0.166667h;
100%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran at -78℃;
Stage #2: With Trimethyl borate In tetrahydrofuran
89%
Stage #1: 2-Bromo-6-methoxynaphthalene With magnesium In tetrahydrofuran
Stage #2: With Trimethyl borate In tetrahydrofuran at 0 - 5℃; for 0.25h;
Stage #3: With water In tetrahydrofuran for 0.25h;
80%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -60℃; for 1.16667h;
Stage #2: With boric acid tributyl ester In tetrahydrofuran; hexane at -60 - 5℃; for 2.5h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water at 5℃;
59%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane at -78 - 0℃; for 1.16667h;
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

Conditions
ConditionsYield
With boron tribromide In dichloromethane at 0 - 20℃; for 6h; Inert atmosphere;100%
With hydrogen bromide; 1-butyl-3-methylimidazolium Tetrafluoroborate at 115℃; for 10h;95%
With boron tribromide In dichloromethane at 0 - 20℃; for 1h;75%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

1,6-dibromo-2-methoxynaphthalene
66996-59-6

1,6-dibromo-2-methoxynaphthalene

Conditions
ConditionsYield
With N-bromosuccimimide In tetrahydrofuran for 2h; Heating;100%
With N-Bromosuccinimide In tetrahydrofuran for 2h; Reflux;100%
With N-Bromosuccinimide In tetrahydrofuran for 2h; Reflux;97%
carbon monoxide
201230-82-2

carbon monoxide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-methoxy-6-naphthoic acid
2471-70-7

2-methoxy-6-naphthoic acid

Conditions
ConditionsYield
With dicobalt octacarbonyl; potassium carbonate; methyloxirane In methanol at 60℃; under 760 Torr; for 10.5h;100%
Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

6-bromo-2-methoxynaphthalene-1-carbaldehyde
247174-18-1

6-bromo-2-methoxynaphthalene-1-carbaldehyde

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at 40℃; for 2h;100%
With titanium tetrachloride In dichloromethane at 0 - 20℃;100%
With titanium tetrachloride In dichloromethane at 0 - 20℃;100%
styrene
100-42-5

styrene

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

(E)-2-methoxy-6-styrylnaphthalene
123871-53-4

(E)-2-methoxy-6-styrylnaphthalene

Conditions
ConditionsYield
With tetrabutylammomium bromide; caesium carbonate; palladium(II) acetylacetonate In N,N-dimethyl acetamide at 100℃; for 3h; Heck reaction;99%
With C38H38Cl2N4P2Pd; sodium carbonate In N,N-dimethyl-formamide at 140℃; for 3h; Reagent/catalyst; Heck Reaction; Inert atmosphere;87%
With C11H20N3(1+)*C2F6NO4S2(1-); palladium diacetate at 70℃; for 6h; Heck Reaction; Ionic liquid; Inert atmosphere;75%
With sodium acetate; palladium In N,N-dimethyl acetamide at 130 - 140℃;60%
methyl 2-methylbutanoate
868-57-5

methyl 2-methylbutanoate

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

methyl α-(6-methoxy-naphthalen-2-yl)-α-methyl-butyrate

methyl α-(6-methoxy-naphthalen-2-yl)-α-methyl-butyrate

Conditions
ConditionsYield
With tri-tert-butyl phosphine; lithium dicyclohexylamide; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; for 10h;99%
4,4-dimethylcyclohexenone
1073-13-8

4,4-dimethylcyclohexenone

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-(4,4-dimethylcyclohexa-1,5-dienyl)-6-methoxynaphthalene

2-(4,4-dimethylcyclohexa-1,5-dienyl)-6-methoxynaphthalene

Conditions
ConditionsYield
Stage #1: 4,4-dimethylcyclohexenone With tris-(dibenzylideneacetone)dipalladium(0); toluene-4-sulfonic acid hydrazide; lithium tert-butoxide; XPhos In 1,4-dioxane for 0.0166667h; Inert atmosphere;
Stage #2: 2-Bromo-6-methoxynaphthalene In 1,4-dioxane at 110℃; Inert atmosphere;
99%
ethyl bromide
74-96-4

ethyl bromide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-methoxy-6-ethylnaphthalene
21388-17-0

2-methoxy-6-ethylnaphthalene

Conditions
ConditionsYield
Stage #1: ethyl bromide With magnesium In tetrahydrofuran for 0.666667h; Inert atmosphere;
Stage #2: 2-Bromo-6-methoxynaphthalene With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 60℃; for 3h; Inert atmosphere;
99%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

lithium methyltriolborate

lithium methyltriolborate

2-methyl-6-methoxynaphthalene
26386-94-7

2-methyl-6-methoxynaphthalene

Conditions
ConditionsYield
With palladium diacetate; ruphos In methanol; water at 80℃; for 12h; Inert atmosphere;99%
1-decyne
764-93-2

1-decyne

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

C27H30O

C27H30O

Conditions
ConditionsYield
With water; potassium carbonate In 1-methyl-pyrrolidin-2-one at 135℃; for 24h; Catalytic behavior; Sonogashira Cross-Coupling;99%
n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-butyl-6-methoxynaphthalene
701270-26-0

2-butyl-6-methoxynaphthalene

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In tetrahydrofuran at 0℃; for 4h; Reflux; Inert atmosphere;99%
9-fluorenone
486-25-9

9-fluorenone

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

9-(6-methoxynaphthalene-2-yl)-9H-fluorene-9-ol

9-(6-methoxynaphthalene-2-yl)-9H-fluorene-9-ol

Conditions
ConditionsYield
Stage #1: 2-Bromo-6-methoxynaphthalene With iodine; magnesium In tetrahydrofuran Inert atmosphere;
Stage #2: 9-fluorenone In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;
99%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

(1-morpholino-1-oxopropan-2-yl)zinc pivalate

(1-morpholino-1-oxopropan-2-yl)zinc pivalate

2-(6-methoxynaphthalen-2-yl)-1-morpholinopropan-1-one

2-(6-methoxynaphthalen-2-yl)-1-morpholinopropan-1-one

Conditions
ConditionsYield
With bis(dibenzylideneacetone)-palladium(0); DavePhos In tetrahydrofuran at 40℃; for 4h; Negishi Coupling; Inert atmosphere;99%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

allyltributylstanane
24850-33-7

allyltributylstanane

2-methoxy-6-(2'-propenyl)naphthalene
139633-65-1

2-methoxy-6-(2'-propenyl)naphthalene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); lithium chloride In N,N-dimethyl-formamide at 100℃; for 5h; Inert atmosphere;99%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

C11H8(2)HBrO

C11H8(2)HBrO

Conditions
ConditionsYield
With tetrakis(tetrabutylammonium)decatungstate(VI); 2,4,6-Triisopropylthiophenol; water-d2 In acetonitrile for 48h; Irradiation;99%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

((6-methoxynaphthalen-2-yl)ethynyl)trimethylsilane
454431-03-9

((6-methoxynaphthalen-2-yl)ethynyl)trimethylsilane

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With ethylmagnesium bromide In tetrahydrofuran Heating;
Stage #2: 2-Bromo-6-methoxynaphthalene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; benzene Heating;
98%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine; triphenylphosphine In tetrahydrofuran at 78℃; for 20h; Inert atmosphere;98.4%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine; triphenylphosphine In tetrahydrofuran at 20℃; for 15h;92%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

(±)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthalene
74866-27-6, 117745-41-2, 117745-45-6

(±)-6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthalene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; bis-[(trifluoroacetoxy)iodo]benzene In dichloromethane at -40℃; for 1.5h;98%
With boron trifluoride diethyl etherate; thallium(III) trifluoroacetate In acetonitrile Ambient temperature;76%
Benzophenone imine
1013-88-3

Benzophenone imine

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

N-(diphenyl methylene)-6-methoxy-2-naphthylamine

N-(diphenyl methylene)-6-methoxy-2-naphthylamine

Conditions
ConditionsYield
With potassium tert-butylate; bis(dibenzylideneacetone)-palladium(0); 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 100℃; for 5h;98%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

K4[Fe(CN)6]

K4[Fe(CN)6]

2-cyano-6-methoxynaphthalene
67886-70-8

2-cyano-6-methoxynaphthalene

Conditions
ConditionsYield
With sodium carbonate; palladium diacetate at 140℃; for 16h;98%
With sodium carbonate; potassium iodide; N,N`-dimethylethylenediamine; copper(II) bis(tetrafluoroborate) In N,N-dimethyl acetamide at 140℃; for 16h;96%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl 2-(6-methoxynaphthalen-2-yl)-2-oxoacetate
56547-13-8

ethyl 2-(6-methoxynaphthalen-2-yl)-2-oxoacetate

Conditions
ConditionsYield
Stage #1: 2-Bromo-6-methoxynaphthalene With magnesium In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: oxalic acid diethyl ester In tetrahydrofuran at -78 - 0℃; for 5h;
98%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran at -80℃; for 3h;
Stage #2: oxalic acid diethyl ester In tetrahydrofuran at -80℃; for 5h;
81%
Stage #1: 2-Bromo-6-methoxynaphthalene With iodine; magnesium In tetrahydrofuran Inert atmosphere;
Stage #2: oxalic acid diethyl ester In tetrahydrofuran at -78 - 20℃; for 14h; Inert atmosphere;
Stage #1: 2-Bromo-6-methoxynaphthalene With iodine; magnesium In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;
Stage #2: oxalic acid diethyl ester In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
2-trimethylsilylpropionitrile
18151-58-1

2-trimethylsilylpropionitrile

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-(6-methoxynaphthalen-2-yl)propionitrile
86603-94-3

2-(6-methoxynaphthalen-2-yl)propionitrile

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); zinc(II) fluoride; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 90℃; for 18h;98%
2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-Methoxynaphthalene
93-04-9

2-Methoxynaphthalene

Conditions
ConditionsYield
With 4-methyl-morpholine; tetrahydroxydiboron; 5%-palladium/activated carbon In 1,2-dichloro-ethane at 50℃; for 3h;98%
With hydrogen; triethylamine In methanol; water at 120℃; under 22502.3 Torr; for 96h; Autoclave;95%
With sodium hydride; lithium iodide In tetrahydrofuran; mineral oil at 50℃; for 7h; Reagent/catalyst; Solvent; Temperature; Sealed tube;81%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

(6-methoxynaphthalen-2-yl)(methyl)sulfane
210823-16-8

(6-methoxynaphthalen-2-yl)(methyl)sulfane

Conditions
ConditionsYield
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere;
98%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;
Stage #3: With ammonium hydroxide In tetrahydrofuran; hexane at 20℃; Inert atmosphere;
98%
Stage #1: 2-Bromo-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: Dimethyldisulphide In tetrahydrofuran at 20℃; for 1h;
90.2%
With sodium hydroxide; n-butyllithium In tetrahydrofuran58%
1-ethynyl-2-methoxybenzene
767-91-9

1-ethynyl-2-methoxybenzene

2-Bromo-6-methoxynaphthalene
5111-65-9

2-Bromo-6-methoxynaphthalene

2-methoxy-6-((2-methoxyphenyl)ethynyl)naphthalene
1048030-55-2

2-methoxy-6-((2-methoxyphenyl)ethynyl)naphthalene

Conditions
ConditionsYield
With copper(l) iodide; potassium tetrachloropalladate(II); N,N,N,N,-tetramethylethylenediamine; di‐tert‐butyl‐(1‐phenylindol‐2‐yl)phosphane at 80℃; for 20h; Sonogashira coupling; Inert atmosphere;98%

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