CAS No.564-94-3,(-)-MYRTENAL Suppliers,MSDS download

Dayang Chem (Hangzhou) Co.,Ltd.

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Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl-

Cas:564-94-3

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Shanghai Upbio Tech Co.,Ltd

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Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl-

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:CLEAR COLOURLESS TO YELLOW LIQUID Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application

Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl-

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl-

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(1R)-(-)-Myrtenal

Cas:564-94-3

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Henan Tianfu Chemical Co., Ltd.

Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl- Application:Organic Chemicals

564-94-3

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Antimex Chemical Limied

CSR1608-1755 Application:surface active agent

CSR1608-1755

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Hangzhou Fandachem Co.,Ltd

Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl- cas 564-94-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde,6,6-dimethyl- cas 564-94-3

Cas:564-94-3

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CSR1608-1755 CAS NO.564-94-3

Cas:564-94-3

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Skyrun Industrial Co.,Ltd

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CSR1608-1755

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Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

Pin-2-ene-1-carbaldehyde

Cas:564-94-3

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Synthetic route

: 515-00-4
myrtenol

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With bromobenzene; sodium hydride; triphenylphosphine; palladium diacetate In tetrahydrofuran at 65℃; for 1h;	100%
With bromobenzene; sodium hydride; palladium diacetate; triphenylphosphine In tetrahydrofuran at 65℃; for 1h;	95%
With calcium hydride; oxygen; 2,2,6,6-tetramethyl-piperidine-N-oxyl; copper dichloride In acetonitrile at 25℃; for 3h;	93%

: 2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-[1,3]dioxolane

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With carbon tetrabromide In water; acetonitrile at 45℃; for 2h; sonication;	99%

: 80-56-8, 177698-18-9
Pinene

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With pentafluorobenzeneseleninic acid In benzene for 2h; Heating;	85%
With selenium(IV) oxide In 1,4-dioxane; ethanol at 60℃;	70%
With perfluorooctylselenic acid; iodosylbenzene In various solvent(s) Heating;	62%
With selenium(IV) oxide
With selenium(IV) oxide In 1,4-dioxane; ethanol at 65 - 95℃;

: 80-56-8, 177698-18-9
Pinene

A: 515-00-4
myrtenol

B: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 2-(N-oxido)pyridineseleninic anhydride In dichloromethane at 20℃; for 18h;	A 57% B 28%

: 515-00-4
myrtenol

: 108-95-2
phenol

A: 514-99-8
7,7-dimethyl-2-(hydroxymethyl)bicyclo<3.1.1>heptane

B: 4-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ylmethyl)phenol

C: 3-(2-((6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methoxy)benzyl)-6,6-dimethylbicyclo[3.1.1]hept-2-ene

D: 1344744-38-2
4-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ylmethyl)-9-isopropyl-8,9,10,10a-tetrahydro-6H-benzo[c]chromene

E: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
Stage #1: myrtenol; phenol With aluminum isopropoxide at 160℃; Stage #2: With hydrogenchloride In water	A n/a B 1.5% C 12% D n/a E 6%

...Expand

: 75-09-2
dichloromethane

: 81971-91-7
peroxyde de t-butyle et de myrtenyle

: 3-dichloromethyl-2,10-epoxypinane

B: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With sodium carbonate at 110℃; for 12h;	A 10% B 6%

...Expand

: 177698-19-0
Beta-pinene

A: 24903-95-5
nopinone

B: 16812-40-1
pinocarvone

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; titanium(IV) oxide In acetonitrile for 6h; Ambient temperature; Irradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 177698-19-0
Beta-pinene

A: 16812-40-1
pinocarvone

B: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; sodium acetate; sodium chloride; palladium dichloride 1.) AcOH, reflux; 2.) CH3CN, irradiation λ=366 nm; Yield given. Multistep reaction. Yields of byproduct given;

: 177698-19-0
Beta-pinene

A: 58434-29-0
myrtenyl hydroperoxide

: 105815-51-8
7,7-Dimethyl-3-oxatricyclo<4.1.1.02,4>octane-2-methanol

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; 5,15,10,20-tetraphenylporphyrin; Ti(O-t-Bu) In chloroform-d1 at 0℃; for 28h; Product distribution; Irradiation; other catalysts;	A 43 % Spectr. B 23 % Spectr. C 16 % Spectr. D 18 % Spectr.
With oxygen; 5,15,10,20-tetraphenylporphyrin; Ti(O-t-Bu) In chloroform-d1 at 0℃; for 28h; Irradiation;	A 43 % Spectr. B 23 % Spectr. C 16 % Spectr. D 18 % Spectr.

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 16812-40-1
pinocarvone

: 33081-46-8
6,6-Dimethylspirobicyclo<3.1.1>heptan-3-ol-2,2'-oxirane

C: 28664-04-2
3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; 5,15,10,20-tetraphenylporphyrin; titanium(IV) isopropylate In dichloromethane at 0℃; for 20h; Irradiation;	A 5 % Spectr. B 81 % Spectr. C 9 % Spectr. D 3 % Spectr.

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 16812-40-1
pinocarvone

: 33081-46-8
6,6-Dimethylspirobicyclo<3.1.1>heptan-3-ol-2,2'-oxirane

C: 28664-04-2
3-hydroxy-6,6-dimethylbicyclo[3.1.1]heptan-2-one

: 32162-27-9
(1α,2β,4β,6α)-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane

E: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; thiamine diphosphate; bis(acetylacetonate)oxovanadium In dichloromethane at 0℃; Product distribution; Irradiation; other catalysts;	A 8 % Spectr. B 46 % Spectr. C 28 % Spectr. D 10 % Spectr. E 8 % Spectr.

...Expand

: 58434-29-0
myrtenyl hydroperoxide

A: 16812-40-1
pinocarvone

B: 547-61-5, 1674-08-4, 2158-49-8, 3917-59-7, 5947-36-4, 6712-79-4, 19889-99-7, 19894-98-5
pinocarveol

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
In hexane at 40℃; for 3528h; Product distribution; isomerization reaction;

...Expand

: 22321-84-2, 51131-99-8, 51547-39-8, 75992-91-5, 129263-38-3
trans-pinocarveyl hydroperoxide

A: 16812-40-1
pinocarvone

B: 547-61-5, 1674-08-4, 2158-49-8, 3917-59-7, 5947-36-4, 6712-79-4, 19889-99-7, 19894-98-5
pinocarveol

C: 58434-29-0
myrtenyl hydroperoxide

D: 515-00-4
myrtenol

E: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With copper acetylacetonate Product distribution; Ambient temperature; other metal compounds; other hydroperoxide;

...Expand

: 515-00-4
myrtenol

A: 19250-17-0
myrtenic acid

B: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With chlorine dioxide In tetrachloromethane at 50℃; for 0.75h;	A 4 % Chromat. B 41 % Chromat.

dextrorotatory myrtenol: dextrorotatory myrtenol

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
d-myrtenal;

: 64-19-7
acetic acid

: 515-00-4
myrtenol

chromic acid: chromic acid

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 4501-58-0, 23727-15-3, 91200-86-1, 91819-58-8
campholenyc aldehyde

B: 1686-14-2
α-pinene epoxide

C: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 9,10-Dicyanoanthracene; oxygen In various solvent(s) Product distribution; Further Variations:; Reagents; Solvents; Oxidation; Irradiation;

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 4501-58-0, 23727-15-3, 91200-86-1, 91819-58-8
campholenyc aldehyde

B: 547-61-5, 1674-08-4, 2158-49-8, 3917-59-7, 5947-36-4, 6712-79-4, 19889-99-7, 19894-98-5
pinocarveol

C: 1686-14-2
α-pinene epoxide

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 9,10-Dicyanoanthracene; oxygen In acetonitrile Product distribution; Further Variations:; Solvents; Oxidation; Irradiation;

...Expand

: 177698-19-0
Beta-pinene

A: 16812-40-1
pinocarvone

: 1674-08-4
3-hydroxy-β-pinene

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; Co-Fe3O4 at 60℃; under 760.051 Torr; for 7h; Product distribution; Further Variations:; Catalysts;

...Expand

: 177698-19-0
Beta-pinene

A: 547-61-5, 1674-08-4, 2158-49-8, 3917-59-7, 5947-36-4, 6712-79-4, 19889-99-7, 19894-98-5
pinocarveol

B: 515-00-4
myrtenol

C: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 2,6-dimethylpyridine; oxygen; rose bengal; acetic anhydride In methanol at 20℃; for 4h; UV-irradiation;

...Expand

: 177698-19-0
Beta-pinene

A: 515-00-4
myrtenol

B: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; rose bengal In N,N-dimethyl-formamide at 20℃; for 4h; UV-irradiation;

: 177698-19-0
Beta-pinene

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; rose bengal; acetic anhydride In methanol at 20℃; for 4h; UV-irradiation;

: 80-56-8, 177698-18-9
Pinene

A: 80-57-9
verbenone

B: 1820-09-3, 1845-30-3, 5416-53-5, 13040-03-4, 18881-04-4, 19890-02-9, 22339-08-8, 80795-83-1, 473-67-6
Verbenol

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen; rose bengal In N,N-dimethyl-formamide at 20℃; for 4h; UV-irradiation;
With dihydrogen peroxide In acetonitrile at 60℃; for 24h; Temperature;	A 41 %Chromat. B 13 %Chromat. C 17 %Chromat. D 11 %Chromat.

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 80-57-9
verbenone

B: 1820-09-3, 1845-30-3, 5416-53-5, 13040-03-4, 18881-04-4, 19890-02-9, 22339-08-8, 80795-83-1, 473-67-6
Verbenol

C: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 2,6-dimethylpyridine; oxygen; rose bengal; acetic anhydride In methanol at 20℃; for 4h; UV-irradiation;

...Expand

: 177698-19-0
Beta-pinene

A: 16812-40-1
pinocarvone

: trans-pinocarveol

C: 515-00-4
myrtenol

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen at 60℃; under 760.051 Torr; for 6h; Neat (no solvent);

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 80-57-9
verbenone

B: 1820-09-3, 1845-30-3, 5416-53-5, 13040-03-4, 18881-04-4, 19890-02-9, 22339-08-8, 80795-83-1, 473-67-6
Verbenol

C: 16812-40-1
pinocarvone

: trans-pinocarveol

E: 1686-14-2
α-pinene epoxide

F: 515-00-4
myrtenol

G: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen at 60℃; under 760.051 Torr; for 6h; Neat (no solvent);

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 80-57-9
verbenone

B: 1820-09-3, 1845-30-3, 5416-53-5, 13040-03-4, 18881-04-4, 19890-02-9, 22339-08-8, 80795-83-1, 473-67-6
Verbenol

C: 16812-40-1
pinocarvone

: trans-pinocarveol

E: 515-00-4
myrtenol

F: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With oxygen at 60℃; under 3800.26 Torr; for 3.5h; Neat (no solvent); Autoclave;

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 16812-40-1
pinocarvone

B: 547-61-5, 1674-08-4, 2158-49-8, 3917-59-7, 5947-36-4, 6712-79-4, 19889-99-7, 19894-98-5
pinocarveol

C: 22321-84-2
pinocarveyl hydroperoxide

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With 6,7-bis[3-(Nε-tert-butyloxycarbonyllysine methyl ester)]-1,3,5,8-tetramethyl-2,4-divinylporphyrin immobilized in silica gel In chloroform at 20℃; for 30h; Quantum yield; Time; Irradiation;

...Expand

: 80-56-8, 177698-18-9
Pinene

A: 16812-40-1
pinocarvone

: trans-pinocarveol

C: 22321-84-2
pinocarveyl hydroperoxide

D: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

Conditions

Conditions	Yield
With chlorophyll extract of fresh spinach leaves immobilized in silica gel In chloroform at 20℃; Reagent/catalyst; Irradiation;

...Expand

: 130827-43-9
(1S,2S)-1-phenyl-N2-methyl-1,2-propandiamine

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 130827-39-3, 130857-87-3, 130857-92-0
(1R,2R,3R,4S,5S)-2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-1,5-dimethyl-4-phenyl-imidazolidine

Conditions

Conditions	Yield
In chloroform for 24h; Ambient temperature;	100%

: 130857-96-4
1R,2S-N,N-dimethyl-2-phenyl-3-methyl-1,3-diaminoethane

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 130827-41-7, 130857-89-5, 130857-95-3
(1S,2S,3R,4S,5R)-2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-1,3,4-trimethyl-5-phenyl-imidazolidine

Conditions

Conditions	Yield
In chloroform for 24h; Ambient temperature;	100%

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 4764-14-1
6,6-dimethylbicyclo<3.3.1>heptane-2-carboxaldehyde

Conditions

Conditions	Yield
With hydrogen; SC-1 Ni2B In methanol at 25℃; under 760 Torr; for 24h;	96%
With hydrido(triphenylphosphine)copper(I) hexamer; phenylsilane In toluene for 5h; Ambient temperature;	80%

: 67-64-1
acetone

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 56933-99-4
4-(6,6-dimethylbicyclo[3,1,1]hept-2-en-2-yl)-2-butanone

Conditions

Conditions	Yield
With Pd-MgO; hydrogen at 75℃; under 3750.38 Torr; for 3h;	95%

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 149-73-5
trimethyl orthoformate

: 1263208-49-6
2,2-dimethoxymethyl-6,6-dimethyl-bicyclo[3.1.1]hept-2-ene

Conditions

Conditions	Yield
With 1-ethyl-3-methylimidazolium hydrogensulfate In methanol at 5 - 20℃; for 2h;	93%

: 504-02-9
1,3-cylohexanedione

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: C16H22O2

Conditions

Conditions	Yield
With ethylenediamine diacetic acid In neat (no solvent) at 20℃; for 0.5h; Knoevenagel Condensation; Green chemistry;	93%

: 676-58-4
methylmagnesium chloride

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 33829-99-1
1-(6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-ethanol

Conditions

Conditions	Yield
In tetrahydrofuran for 12h; Ambient temperature;	92%

: 542-92-7
cyclopenta-1,3-diene

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: (1R)-(-)-myrtenal

Conditions

Conditions	Yield
With pyrrolidine In methanol for 5h; Inert atmosphere; Schlenk technique;	90%

: 52509-14-5
(1,3-dioxolan-2-yl-methyl)triphenylphosphonium bromide

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 124931-24-4
(E)-3-(6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)prop-2-enal

Conditions

Conditions	Yield
Stage #1: (1,3-dioxolan-2-yl-methyl)triphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.5h; Sealed tube; Inert atmosphere; Stage #2: 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde In tetrahydrofuran at 20℃; for 6h; Sealed tube; Inert atmosphere;	90%

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 515-00-4
myrtenol

Conditions

Conditions	Yield
With lithium pyrrolidinoborohydride at 25℃;	89%
With LiPyrrBH3 In tetrahydrofuran at 25℃; for 3h;	89%
With sodium triphenyl boronhydride In tetrahydrofuran at 0℃; for 1h;	100 % Chromat.
With formic acid; iron(II) tetrafluoroborate hexahydrate; tris(2-diphenylphosphinoethyl)phosphine In tetrahydrofuran at 60℃; for 2h; Schlenk technique; Inert atmosphere;	99 %Chromat.

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 22339-11-3
α-pinenyl bromide

Conditions

Conditions	Yield
Stage #1: 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde With sodium tetrahydroborate In tetrahydrofuran at 20℃; for 8h; Stage #2: With carbon tetrabromide; triphenylphosphine In tetrahydrofuran; dichloromethane at 0℃; for 0.5h;	84%

: 1123-49-5
3,5-dimethyl-4-nitroisoxazole

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 5-[2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)vinyl]-3-methyl-4-nitroisoxazole

Conditions

Conditions	Yield
With piperidine In ethanol at 65℃; for 2h;	81%

: (Z)-2-cyano-3-mercapto-3-(phenylamino)acrylamide

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 884536-72-5
(RR,RS)-5-cyano-2-(6',6'-dimethylbicyclo[3.1.1]hept-2'-en-2'-yl)-6-phenylamino-2,3-dihydro-1,3-thiazin-4(1H)-one

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In ethanol for 2h; Heating;	80%

: 6610-29-3
4-methylthiosemicarbazide

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: C12H19N3S

Conditions

Conditions	Yield
With hydrogenchloride In ethanol at 85℃;	80%

: 461-72-3
2,4-imidazolidinedione

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 5-[1-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-meth-(Z)-ylidene]-imidazolidine-2,4-dione

Conditions

Conditions	Yield
With sodium acetate on alumina for 0.0333333h; microwave irradiation;	76%

: 75-05-8
acetonitrile

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 324538-16-1
C12H17NO

Conditions

Conditions	Yield
With [2,6-(iPr2PO)2C6H3]NiCH2CN at 20℃; for 24h; Inert atmosphere;	73%

: 130827-42-8
(1R,2S)-1-phenyl-N2-methyl-1,2-propandiamine

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

A: 130827-39-3, 130857-87-3, 130857-92-0
(1R,2R,3S,4R,5S)-2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-1,5-dimethyl-4-phenyl-imidazolidine

B: 130827-39-3, 130857-87-3, 130857-92-0
(1S,2S,3S,4R,5S)-2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-1,5-dimethyl-4-phenyl-imidazolidine

Conditions

Conditions	Yield
In chloroform for 24h; Ambient temperature;	A 71% B 12%

...Expand

: 1875-48-5
N-aminophthalamide

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

A: 1445-69-8
2,3-dihydrophthalazine-1,4-dione

B: 121597-24-8
myrtenal phthaloylhydrazone

Conditions

Conditions	Yield
In ethanol for 2.5h; Heating;	A n/a B 67%

...Expand

: 64-18-6
formic acid

: 931-53-3
Cyclohexyl isocyanide

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 2-(cyclohexylamino)-1-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-oxoethyl formate

Conditions

Conditions	Yield
In dichloromethane at 0 - 20℃; for 48h; Passerini Condensation; Inert atmosphere;	66%

...Expand

: 64-18-6
formic acid

: 119072-55-8, 7188-38-7
tert-butylisonitrile

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 2-(tert-butylamino)-1-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-oxoethyl formate

Conditions

Conditions	Yield
In dichloromethane at 0 - 20℃; for 48h; Passerini Condensation; Inert atmosphere;	64%

...Expand

: N-Boc-(tri-n-butylstannyl)dimethylamine

: 564-94-3
6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

: 1,1-dimethylethyl N-methyl-N-[(bicyclo[3.3.1](4,4-dimethyl-6-formyl)heptyl)methyl] carbamate

Conditions

Conditions	Yield
Stage #1: N-Boc-(tri-n-butylstannyl)dimethylamine With n-butyllithium In tetrahydrofuran at -78℃; for 0.283333h; Metallation; Stage #2: In tetrahydrofuran at -78 - -53℃; for 0.416667h; Transmetallation; Stage #3: 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde With chloro-trimethyl-silane In tetrahydrofuran at -78 - 20℃; Substitution;	62%