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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Fenipentol

Cas:583-03-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Fenipentol

Cas:583-03-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

583-03-9 Fenipentol

Cas:583-03-9

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 583-03-9 with best price

Cas:583-03-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzenemethanol, a-butyl-

Cas:583-03-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

Fenipentol

Cas:583-03-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzenemethanol, a-butyl-

Cas:583-03-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

1-Phenyl-1-pentanol

Cas:583-03-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Fenipentol

Cas:583-03-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-Phenyl-1-pentanol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Phenyl-1-pentanol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:yellow to light brown crystals Storage:Room temperature with sealed well Package:according to the clients requirement Applicatio

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Fenipentol cas 583-03-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Fenipentol cas 583-03-9

Cas:583-03-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

583-03-9

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#583-03-9;CAT#A831823

Cas:583-03-9

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Fenipentol CAS NO.583-03-9

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

Fenipentol

Cas:583-03-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Toda Biotechnology Co., Limited.

Todachem specialize in exporting chemicals for 10 years, we manufacture and distribute high quality pharmaceutical APIs, intermediates, special chemicals, active molecule and other fine chemicals. We have our research laboratory and more than 100 n

Factory direct supply Fenipentol with best quality

Cas:583-03-9

Min.Order:1 Kilogram

FOB Price: $90.0 / 100.0

Type:Trading Company

inquiry

Shanghai Hanhong Scientific Co.,Ltd.

factory,reasonable price Appearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:pharmaceutical intermediates Transportation:by courier,air or sea Port:S

1-Phenylpentan-1-ol583-03-9

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou KieRay Chem Co.,Ltd.

Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and inter

Fenipentol

Cas:583-03-9

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1-Phenyl-1-pentanol

Cas:583-03-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

XinChem Corporation

We have our own research and development center, provide reliable quality products for you. Appearance:white powder Storage:Store in dry and cool place. Package:25KG/drum Application:Pharmaceutical Intermediates Transportation:by air or by sea Por

Fenipentol supplier/exporter China

Cas:583-03-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Wuhan HengHeDa Pharm Co., Ltd

CHEAP PRICE AND GOOD QUALITYAppearance:white powder Storage:At cool and dry place Package:5g;10g;100g;500g;1kg;25kg Application:INTERMEDIATES Transportation:BY AIR

Fenipentol

Cas:583-03-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai PotentPharm Science and Technology Co.,Ltd

1 good quality, better price and bettter service;2 Timely delivery;3 100% refunded if parcel is not delivered or poor quality.We will try to satisfy you upon receipt of your reply. I hope that we can become a long-term cooperative partner. Applicatio

1-Phenylpentan-1-ol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the Fenipentol, CAS:583-03-9 with the most competitive price and the best quality. We can

Fenipentol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Run-Biotech Co., Ltd.

1.We have rich experience in the development and production 2.Our factory is in Shanghai of China,We have convenient traffic conditions.3.We have advanced testing equipment and shipping line. Package:5g, 10g, 50g, 100g, 1kg Application:Pharmaceutical

1-phenylpentan-1-ol

Cas:583-03-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
In tetrahydrofuran; hexane at -78 - 20℃;100%
Stage #1: n-butyllithium With mischmetall tribromide In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78℃; for 3h; Imamoto reaction;
98%
In hexane at -78 - 20℃; for 1.16667h;95%
phenyl butyl ketone
1009-14-9

phenyl butyl ketone

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With C28H35ClCoN5(1+)*Cl(1-); potassium tert-butylate; hydrogen In tetrahydrofuran at 20℃; under 22502.3 Torr; for 16h; Autoclave;99%
With (4-NHCpr)Triaz(NHPiPr2)2Mn(CO)2Br; potassium tert-butylate; hydrogen In toluene at 80℃; under 15001.5 Torr; for 4h; Inert atmosphere; Autoclave;98%
With sodium tetrahydroborate In methanol at 20℃; for 2h;96%
1-bromo-butane
109-65-9

1-bromo-butane

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: 1-bromo-butane With magnesium; lithium chloride In tetrahydrofuran at 50℃; for 0.125h; Flow reactor;
Stage #2: benzaldehyde In tetrahydrofuran at 20℃; for 0.333333h; Flow reactor;
98%
Stage #1: 1-bromo-butane With magnesium; ethylene dibromide In 2-methyltetrahydrofuran at 20℃; Inert atmosphere;
Stage #2: benzaldehyde In 2-methyltetrahydrofuran at 0 - 20℃; for 1.25h; Grignard reaction; Inert atmosphere; chemoselective reaction;
86%
With magnesium 1) Et2O, 40 deg C, 1h, 2) 35 deg C, 1h; Multistep reaction;
triethyl-butyl plumbane
64346-32-3

triethyl-butyl plumbane

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-propanol
93-54-9

1-Phenyl-1-propanol

B

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at -78 - -30℃;A 98%
B 1.7%
1-Phenyl-3-buten-1-ol
80735-94-0

1-Phenyl-3-buten-1-ol

methyllithium
917-54-4

methyllithium

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With cerium(III) chloride; lithium hydride In tetrahydrofuran at -78℃; for 72h;94%
cyclopropyl bromide
4333-56-6

cyclopropyl bromide

benzaldehyde
100-52-7

benzaldehyde

tri-n-butyllithium magnesate complex

tri-n-butyllithium magnesate complex

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

1-phenyl-1-cyclopropylmethanol
1007-03-0

1-phenyl-1-cyclopropylmethanol

Conditions
ConditionsYield
Stage #1: cyclopropyl bromide; tri-n-butyllithium magnesate complex In tetrahydrofuran; hexane at 0℃; for 0.5h;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78 - -60℃;
A n/a
B 91%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-[(tert-butyl-dimethyl-silanyloxy)-phenyl-methyl]-1H-imidazole
410097-82-4

1-[(tert-butyl-dimethyl-silanyloxy)-phenyl-methyl]-1H-imidazole

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 0.166667h;90%
tributyl borane
122-56-5

tributyl borane

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(1,5-cyclooctadiene)nickel (0) In tetrahydrofuran; water at 20℃; for 20h; Product distribution; Further Variations:; Solvents; amount of water; with additive;90%
With bis(1,5-cyclooctadiene)nickel (0); tri-tert-butyl phosphine; caesium carbonate In tetrahydrofuran; hexane; toluene at 20℃; for 24h;86%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-(Benzyloxy)-5-(trimethylsilyl)pyrazole
166820-36-6

1-(Benzyloxy)-5-(trimethylsilyl)pyrazole

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

3(5)-trimethylsilylpyrazole

3(5)-trimethylsilylpyrazole

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at -78℃; for 0.166667h; Elimination; addition;A 88%
B 84%
2-phenyl-1,3-dioxolane
936-51-6

2-phenyl-1,3-dioxolane

lithium di-n-butylcuprate
24406-16-4

lithium di-n-butylcuprate

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: 2-phenyl-1,3-dioxolane With sodium dodecyl-sulfate; toluene-4-sulfonic acid In tetrahydrofuran; water at 25℃; for 3.5h;
Stage #2: lithium di-n-butylcuprate In diethyl ether; hexane at 25℃; for 12h; Further stages.;
87%
Stage #1: 2-phenyl-1,3-dioxolane With water; sodium dodecyl-sulfate; toluene-4-sulfonic acid In tetrahydrofuran at 25℃; for 3.5h; Inert atmosphere; polydimethylsiloxane (PDMS) thimble;
Stage #2: lithium di-n-butylcuprate In hexanes; diethyl ether for 12h;
Stage #3: With water In hexanes; diethyl ether
87%
2-pyridyl benzoate
5005-35-6

2-pyridyl benzoate

n-butylzinc chloride
42930-39-2

n-butylzinc chloride

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II) In N,N-dimethyl-formamide at 0 - 50℃; for 12h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;87%
phosphoric acid tributyl ester
126-73-8

phosphoric acid tributyl ester

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With lithium In tetrahydrofuran at -30℃; for 0.25h;86%
1-iodo-butane
542-69-8

1-iodo-butane

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: 1-iodo-butane With N-butylpyridinium tetrafluoroborate at 20℃; for 1h;
Stage #2: benzaldehyde With pyridine at 20℃; for 12h; Further stages.;
80%
With N,N,N,N,N,N-hexamethylphosphoric triamide; sec.-butyllithium; samarium(III) trifluoromethanesulfonate 1.) THF, cyclohexane, room temperature, 1 h, 2.) THF, cyclohexane, room temperature, 1 h; Yield given. Multistep reaction;
Yield given. Multistep reaction;
benzaldehyde
100-52-7

benzaldehyde

Tributyl-((2S,6S)-6-isopropyl-2-phenyl-tetrahydro-pyran-2-yloxymethyl)-stannane

Tributyl-((2S,6S)-6-isopropyl-2-phenyl-tetrahydro-pyran-2-yloxymethyl)-stannane

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

2-[(2R,6S)-6-isopropyl-2-phenyltetrahydro-2H-2-pyranyl]oxy-1-phenyl-1-ethanol

2-[(2R,6S)-6-isopropyl-2-phenyltetrahydro-2H-2-pyranyl]oxy-1-phenyl-1-ethanol

Conditions
ConditionsYield
Stage #1: Tributyl-((2S,6S)-6-isopropyl-2-phenyl-tetrahydro-pyran-2-yloxymethyl)-stannane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: benzaldehyde In tetrahydrofuran; hexane for 0.5h; Further stages.;
A 17%
B 80%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

2,2-difluoro-1-phenyl-3-buten-1-ol
85864-61-5

2,2-difluoro-1-phenyl-3-buten-1-ol

Conditions
ConditionsYield
With 3-bromo-3,3-difluropropene In tetrahydrofuran; diethyl ether; hexane; pentane at -95℃;A 78%
B n/a
tributyl borane
122-56-5

tributyl borane

1-benzyl-tetrahydro-thiophenium tetrafluoroborate

1-benzyl-tetrahydro-thiophenium tetrafluoroborate

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

1,2-diphenylhexan-1-ol
38610-98-9

1,2-diphenylhexan-1-ol

Conditions
ConditionsYield
Stage #1: tributyl borane; 1-benzyl-tetrahydro-thiophenium tetrafluoroborate With lithium hexamethyldisilazane In tetrahydrofuran; 1,4-dioxane at 5℃; for 5h;
Stage #2: With sodium hydroxide; dihydrogen peroxide
A 78%
B 11%
n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With tributyl(2-methoxyethyl)phosphonium bis(CF3SO2)imide In tetrahydrofuran at 0℃; Grignard reaction;76%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

methyl 2-bromoacrylate
4519-46-4

methyl 2-bromoacrylate

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

4-hydroxy-4-phenyl-but-2-ynoic acid methyl ester
33553-90-1

4-hydroxy-4-phenyl-but-2-ynoic acid methyl ester

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 3h; Inert atmosphere;A 76%
B 6%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

2-trimethylsilylbenzaldehyde
17887-55-7

2-trimethylsilylbenzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: n-butyllithium; 2-trimethylsilylbenzaldehyde With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere;
Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;
74%
chlorotitanium triisopropoxide
78350-68-2

chlorotitanium triisopropoxide

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
In diethyl ether for 6h; -20 deg C to 22 deg C;72%
With N,N,N,N,-tetramethylethylenediamine In hexane for 16h; -70 deg C to room temperature; Yield given;
1-iodo-butane
542-69-8

1-iodo-butane

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
Stage #1: 1-iodo-butane With 1-butylpyridinium bromide; N-butylpyridinium tetrafluoroborate; zinc at 50℃; for 1h;
Stage #2: benzaldehyde at 20℃; for 12h;
A 70%
B n/a
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

benzaldehyde
100-52-7

benzaldehyde

A

phenyl butyl ketone
1009-14-9

phenyl butyl ketone

B

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: n-butyllithium; benzaldehyde In tetrahydrofuran at -78℃; for 0.333333h;
Stage #2: With N-(tert-butyl)benzenesulfinimidoyl chloride In tetrahydrofuran at -78℃; for 5h;
A 12%
B 68%
With vanadium(III) chloride In dichloromethane for 16h; Product distribution; Heating; var. solvent, temp., time;
di-n-butylzinc
1119-90-0

di-n-butylzinc

diethylzinc
557-20-0

diethylzinc

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

(S)-1-phenyl-1-propanol
613-87-6

(S)-1-phenyl-1-propanol

Conditions
ConditionsYield
With catalyst: (-)-3-exo-(dimethylamino)isoborneol In toluene toluene-soln. of catalyst added Bu2Zn at 30°C; after 15 min added Et2Zn; mixt. stirred for 10 min and cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;A 14%
B 68%
With catalyst: (-)-3-exo-(dimethylamino)isoborneol In toluene toluene-soln. of catalyst added Et2Zn at 30°C; after 15 min added Bu2Zn; cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;A 35%
B 44%
(ZnC3H6CH3N(CH3)2CHCH(C(CH3)2C2H4)C(CH3)CHO)2

(ZnC3H6CH3N(CH3)2CHCH(C(CH3)2C2H4)C(CH3)CHO)2

diethylzinc
557-20-0

diethylzinc

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

(S)-1-phenyl-1-propanol
613-87-6

(S)-1-phenyl-1-propanol

Conditions
ConditionsYield
In toluene toluene-soln. of Zn-complex added benzaldehyde; cooled to 0°C; added Et2Zn; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;A 14%
B 67%
In toluene toluene-soln. of Zn-complex added Bu2Zn; mixt. stirred at -78°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;A 13%
B 66%
benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

butyl magnesium bromide
693-04-9

butyl magnesium bromide

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
Stage #1: benzoic acid ethyl ester With lithium diisobutyl-tert-butoxyaluminum hydride In tetrahydrofuran; hexane at 0℃; for 3h;
Stage #2: butyl magnesium bromide In tetrahydrofuran; diethyl ether; hexane at 20℃; for 0.5h;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; diethyl ether; hexane
66%
With lithium borohydride In tetrahydrofuran at 0℃; for 24h;61%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

benzaldehyde
100-52-7

benzaldehyde

A

phenylethane 1,2-diol
93-56-1

phenylethane 1,2-diol

B

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

C

benzoic acid
65-85-0

benzoic acid

D

benzyl alcohol
100-51-6

benzyl alcohol

E

Tetrabutylzinn, (Tributylstannylmethyl)-benzoat

Tetrabutylzinn, (Tributylstannylmethyl)-benzoat

Conditions
ConditionsYield
Yield given. Multistep reaction;A 65%
B n/a
C n/a
D 8%
E n/a
propan-1-ol
71-23-8

propan-1-ol

1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With C17H15Cl3N5Ru; potassium hydroxide at 110℃; under 750.075 Torr; for 12h; Inert atmosphere; Sealed tube; Green chemistry;65%
With [(4-(4-CF3)-Ph)Tr(NP(iPr)2)(NHP(iPr)2)Ir(cod)]; potassium tert-butylate In 1,4-dioxane at 125℃; for 4h; Inert atmosphere; Sealed tube;
benzylidene dichloride
98-87-3

benzylidene dichloride

tributyl borane
122-56-5

tributyl borane

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With sodium perborate; tert.-butyl lithium In tetrahydrofuran 1.) -78 deg C, 30 min; 2.) r.t., 2 h;64%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

2-bromo-3,3,3-trifluoropropene
1514-82-5

2-bromo-3,3,3-trifluoropropene

benzaldehyde
100-52-7

benzaldehyde

A

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

B

1-phenyl-2-(trifluoromethyl)-2-propen-1-ol
14633-65-9

1-phenyl-2-(trifluoromethyl)-2-propen-1-ol

Conditions
ConditionsYield
Stage #1: n-butyllithium; 2-bromo-3,3,3-trifluoropropene In diethyl ether at -100℃; for 0.25h;
Stage #2: benzaldehyde In diethyl ether at -100℃; for 0.25h;
A 64%
B 25%
pentanal
110-62-3

pentanal

phenylboronic acid
98-80-6

phenylboronic acid

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

Conditions
ConditionsYield
With chlorobis(cyclooctene)rhodium(I) dimer; α-Oxo-phenylmethan-diphenylphosphin; sodium carbonate In water; toluene at 60℃; Schlenk technique; Inert atmosphere;64%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

phenyl butyl ketone
1009-14-9

phenyl butyl ketone

Conditions
ConditionsYield
With nickel(II) triflate; cyclohexanone; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 110℃; for 12h; Schlenk technique;99%
With Oxone; 3,3'-diiodo-2,2',6,6'-tetramethoxy-4,4'-biphenyldicarboxylic acid In nitromethane; water at 30 - 35℃; for 11.5h;98%
With menthol; Dess-Martin periodane In dichloromethane for 0.333333h; Dess-Martin oxidation;95%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

1-bromo-1-phenylpentane
127356-65-4

1-bromo-1-phenylpentane

Conditions
ConditionsYield
With sulfurous dibromide In toluene for 6h;99%
With pyridine; phosphorus tribromide In diethyl ether for 2.5h; Ambient temperature;77%
With phosphorus tribromide In diethyl ether at 0 - 20℃;22%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

trimethyl-(1-phenylpentoxy)silane

trimethyl-(1-phenylpentoxy)silane

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 24h; Inert atmosphere;96%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,2,2-trichloro-N-(1-phenylpentyl)acetimidate

2,2,2-trichloro-N-(1-phenylpentyl)acetimidate

Conditions
ConditionsYield
Stage #1: 1-Phenyl-1-pentanol With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 0.25h; Inert atmosphere;
Stage #2: trichloroacetonitrile In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;
96%
bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

1-phenylpentyl chloroformate

1-phenylpentyl chloroformate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;96%
carbon disulfide
75-15-0

carbon disulfide

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

methyl iodide
74-88-4

methyl iodide

S-methyl O-1-phenyl-1-pentyl dithiocarbonate

S-methyl O-1-phenyl-1-pentyl dithiocarbonate

Conditions
ConditionsYield
Stage #1: carbon disulfide; 1-Phenyl-1-pentanol With sodium hydride In tetrahydrofuran at 20℃; for 10h; Addition;
Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 1h; Methylation;
95%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

4-sulfanylphenol
637-89-8

4-sulfanylphenol

1-hydroxy-4-<(1-phenylpentyl)thio>benzene
84851-63-8

1-hydroxy-4-<(1-phenylpentyl)thio>benzene

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 4h; Ambient temperature;94%
butanoic acid anhydride
106-31-0

butanoic acid anhydride

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

1-phenylpentyl butyrate
58687-94-8

1-phenylpentyl butyrate

Conditions
ConditionsYield
With dmap In dichloromethane at 20℃;94%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

pentylbenzene
538-68-1

pentylbenzene

Conditions
ConditionsYield
With sulfuric acid; nickel In water at 10℃; for 2h;92%
With chloro-trimethyl-silane; acetonitrile; sodium iodide In hexane for 24h; Ambient temperature;74%
With chloro-trimethyl-silane; acetonitrile; sodium iodide In hexane for 24h; Ambient temperature;74%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

acetic anhydride
108-24-7

acetic anhydride

1-phenyl-1-(acetyloxy)pentane
38488-01-6

1-phenyl-1-(acetyloxy)pentane

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 20℃;92%
With pyridine; triethylamine In dichloromethane at 20℃;80%
With triethylamine In dichloromethane
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

benzoic acid
65-85-0

benzoic acid

1-oxo-1-phenylpentan-2-yl benzoate
1312799-25-9

1-oxo-1-phenylpentan-2-yl benzoate

Conditions
ConditionsYield
Stage #1: 1-Phenyl-1-pentanol; benzoic acid With N-Bromosuccinimide In 1,4-dioxane at 60℃; for 1h; Sealed tube;
Stage #2: With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 60℃; for 4h;
92%
Stage #1: 1-Phenyl-1-pentanol; benzoic acid With N-Bromosuccinimide In 1,4-dioxane at 60℃; for 1h;
Stage #2: With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane for 4h;
92%
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water; ethyl acetate at 100℃; for 12h; Schlenk technique;70%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

<1-(phenylthio)pentyl>benzene
68602-14-2

<1-(phenylthio)pentyl>benzene

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 0.666667h; Ambient temperature;91%
1-butanethiol
109-79-5

1-butanethiol

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

<(1-phenylpentyl)thio>butane
84851-58-1

<(1-phenylpentyl)thio>butane

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 8h; Ambient temperature;90%
β-mercaptopropionamide
763-35-9

β-mercaptopropionamide

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

3-<(phenylpentyl)thio>propanamide
84851-60-5

3-<(phenylpentyl)thio>propanamide

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 8h; Ambient temperature;90%
methanol
67-56-1

methanol

1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

Conditions
ConditionsYield
With oxygen; potassium carbonate at 150℃; under 4500.45 Torr; for 48h; Autoclave;90%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

(1-(trifluoromethoxy)pentyl)benzene

(1-(trifluoromethoxy)pentyl)benzene

Conditions
ConditionsYield
With potassium fluoride; 2-fluoropyridine; silver trifluoromethanesulfonate; Selectfluor In ethyl acetate at 20℃; for 12h; Glovebox; Inert atmosphere;87%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

methyl 4-mercaptobenzoate
6302-65-4

methyl 4-mercaptobenzoate

methyl 4-<(1-phenylpentyl)thio>benzoate
84851-61-6

methyl 4-<(1-phenylpentyl)thio>benzoate

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 3h; Ambient temperature;86%
1-Phenyl-1-pentanol
583-03-9

1-Phenyl-1-pentanol

para-bromobenzenethiol
106-53-6

para-bromobenzenethiol

1-bromo-4-<(1-phenylpentyl)thio>benzene
84851-62-7

1-bromo-4-<(1-phenylpentyl)thio>benzene

Conditions
ConditionsYield
With zinc(II) iodide In 1,2-dichloro-ethane for 0.333333h; Ambient temperature;86%

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