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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

tert-Butyl methacrylate Manufacturer/High quality/Best price/In stock

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply tert-butyl methacrylate

Cas:585-07-9

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic t-BUTYL METHACRYLATE 585-07-9 Manufacturer

Cas:585-07-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

tert-Butyl methacrylate Basic information Product Name: tert-Butyl methacrylate Synonyms: TERTIARY-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE MONOMER;TBMA;T-BUTYL

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

tertiary-Butyl Methacrylate

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 585-07-9 with best quality

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:colorless liquid Storage:2-8°C Package:200kg/Drum Application:tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, b

Tert-butyl methacrylate/TBMA with high quality

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2-Propenoic acid,2-methyl-, 1,1-dimethylethyl ester

Cas:585-07-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Propenoic acid,2-methyl-, 1,1-dimethylethyl ester

Cas:585-07-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Propenoic acid,2-methyl-, 1,1-dimethylethyl ester

Cas:585-07-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Tert-Butyl Methacrylate CAS No.:585-07-9 Molecule Formula:C8H14O2 Molecule Weight:142.19 Purity: 99% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING ITE

High Quality Tert-Butyl Methacrylate in stock

Cas:585-07-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

585-07-9 CAS NO.585-07-9

Cas:585-07-9

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used in organic syn

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

TERT-BUTYL METHACRYLATE

Cas:585-07-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product Name: tert-Butyl methacrylate CAS: 585-07-9 MF: C8H14O2 MW: 142.2 EINECS: 209-548-7 Mol File: 585-07-9.mol Appearance:Colorless clear liquid Storage:Preserve in wel

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

tertiary-Butyl Methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Other

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

High Purity Tert-Butyl Methacrylate 585-07-9

Cas:585-07-9

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Tert-Butyl Methacrylate

Cas:585-07-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec tert-Butyl methacrylate 25ml

Cas:585-07-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

tert-Butyl Methacrylate MonoMer (stabilized with MEHQ)

Cas:585-07-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Tert-Butyl Methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

tertiary-Butyl Methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhejiang Haizhou Pharmaceutical Co., Ltd.

tert-Butyl methacrylate

Cas:585-07-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Propenoic acid,2-methyl-, 1,1-dimethylethyl ester

Cas:585-07-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

585-07-9

Cas:585-07-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

tert-Butyl methacrylate cas 585-07-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

tert-Butyl methacrylate cas 585-07-9

Cas:585-07-9

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

tert-butyl bromoisobutyrate
23877-12-5

tert-butyl bromoisobutyrate

methyl 5-chloro-2,4-dihydroxybenzoate
67828-69-7

methyl 5-chloro-2,4-dihydroxybenzoate

A

4-(1-tert-butoxycarbonyl-1-methylethoxy)-5-chloro-2-hydroxybenzoic acid methyl ester
1003567-14-3

4-(1-tert-butoxycarbonyl-1-methylethoxy)-5-chloro-2-hydroxybenzoic acid methyl ester

B

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
Stage #1: tert-butyl bromoisobutyrate; methyl 5-chloro-2,4-dihydroxybenzoate With tetrabutylammomium bromide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h;
Stage #2: With hydrogenchloride In 1-methyl-pyrrolidin-2-one; water pH=~ 4;
A 72.2%
B n/a
Stage #1: tert-butyl bromoisobutyrate; methyl 5-chloro-2,4-dihydroxybenzoate With potassium carbonate; tetrabutylammomium bromide In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h;
Stage #2: With hydrogenchloride In 1-methyl-pyrrolidin-2-one; water pH=~ 4;
A 72.2%
B n/a
With tetrabutylammomium bromide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h;A 72.2%
B n/a
sodium t-butanolate
865-48-5

sodium t-butanolate

Methacryloyl chloride
920-46-7

Methacryloyl chloride

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
With Petroleum ether; tert-butyl alcohol
Methacryloyl chloride
920-46-7

Methacryloyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
With pyridine
With pyridine
Methacryloyl chloride
920-46-7

Methacryloyl chloride

magnesium bromide-tert-butylate

magnesium bromide-tert-butylate

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
With diethyl ether; hydroquinone
1,2-propanediene
463-49-0

1,2-propanediene

carbon monoxide
201230-82-2

carbon monoxide

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h;36 % Chromat.
C15H21O4S
529495-12-3

C15H21O4S

A

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

B

toluene-4-sulfinyloxyl
19646-38-9

toluene-4-sulfinyloxyl

Conditions
ConditionsYield
With pentamethylbenzene, at 19.85℃; Kinetics;
isobutene
115-11-7

isobutene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

isobutene
115-11-7

isobutene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-methylpropenal
78-85-3

2-methylpropenal

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
Stage #1: 2-methylpropenal With tert-butylhypochlorite In tetrachloromethane at 20 - 50℃; for 5.5 - 6.5h;
Stage #2: tert-butyl alcohol With triethylamine In tetrachloromethane at 0 - 20℃; for 19.5h;
2-{N-tert-butyl-N-[1-(diethyl-phosphoryl)-2,2-dimethyl-propyl]-aminooxy}-2-methyl-propionic acid tert-butyl ester

2-{N-tert-butyl-N-[1-(diethyl-phosphoryl)-2,2-dimethyl-propyl]-aminooxy}-2-methyl-propionic acid tert-butyl ester

A

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

B

Diethyl phosphonate
762-04-9, 123-22-8

Diethyl phosphonate

C

C18H38NO6P
1431319-34-4

C18H38NO6P

D

N-(2-methyl-2-propyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)aminoxyl
188526-94-5

N-(2-methyl-2-propyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)aminoxyl

Conditions
ConditionsYield
under 7.50075E-06 Torr; Kinetics;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃;
methacryloyl anhydride
760-93-0

methacryloyl anhydride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
With tempol; 2,4-dimethyl-6-tert-butylphenol; 4-methoxy-phenol; magnesium bromide at 90℃; for 6h; Reagent/catalyst;
t-butyl pyruvate
76849-54-2

t-butyl pyruvate

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 2h;
Stage #2: t-butyl pyruvate In tetrahydrofuran; mineral oil at 0 - 20℃;
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate
495417-67-9

2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate

block-copoly{2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, anionic polymerization, Mn = 18E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate

block-copoly{2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, anionic polymerization, Mn = 18E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate

Conditions
ConditionsYield
Stage #1: 2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate With diethylzinc; (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 2h;
Stage #2: tert-Butyl methacrylate In tetrahydrofuran at -78℃; for 1h;
100%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate
495417-68-0

2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate

block-copoly{2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, Mn = 9.0E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate

block-copoly{2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, Mn = 9.0E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate

Conditions
ConditionsYield
Stage #1: 2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate With diethylzinc; (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 3h;
Stage #2: tert-Butyl methacrylate In tetrahydrofuran at -78℃; for 1h;
100%
poly(methyl methacrylate), 1,1-bis[3-(bromomethyl)phenyl]ethyl-terminated, Mn 1.23E4 Da by SEC, Mn 1.35E4 Da by osmometry, Mw/Mn 1.04; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene

poly(methyl methacrylate), 1,1-bis[3-(bromomethyl)phenyl]ethyl-terminated, Mn 1.23E4 Da by SEC, Mn 1.35E4 Da by osmometry, Mw/Mn 1.04; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 3-arm, Mw 3.33E4 Da, Mw/Mn 1.02; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate

poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 3-arm, Mw 3.33E4 Da, Mw/Mn 1.02; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate

Conditions
ConditionsYield
Stage #1: tert-Butyl methacrylate With (diphenylmethyl)potassium In tetrahydrofuran
Stage #2: poly(methyl methacrylate), 1,1-bis[3-(bromomethyl)phenyl]ethyl-terminated, Mn 1.23E4 Da by SEC, Mn 1.35E4 Da by osmometry, Mw/Mn 1.04; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene In tetrahydrofuran at -78℃; for 1h;
100%
poly(methyl methacrylate), with 3,97 3-(bromomethyl)phenyl end groups, Mn 1.24E4 Da by SEC, Mn 1.32E4 by osmometry, Mn 1.36E4 Da by NMR, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene

poly(methyl methacrylate), with 3,97 3-(bromomethyl)phenyl end groups, Mn 1.24E4 Da by SEC, Mn 1.32E4 by osmometry, Mn 1.36E4 Da by NMR, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 5-arm, Mw 6.27E4 Da, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate

poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 5-arm, Mw 6.27E4 Da, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate

Conditions
ConditionsYield
Stage #1: tert-Butyl methacrylate With (diphenylmethyl)potassium In tetrahydrofuran
Stage #2: poly(methyl methacrylate), with 3,97 3-(bromomethyl)phenyl end groups, Mn 1.24E4 Da by SEC, Mn 1.32E4 by osmometry, Mn 1.36E4 Da by NMR, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene In tetrahydrofuran at -78℃; for 1h;
100%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

3-bromo-2-methyl-acrylic acid tert-butyl ester
912809-59-7

3-bromo-2-methyl-acrylic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: tert-Butyl methacrylate With bromine In tetrachloromethane at 25℃; for 2h;
Stage #2: With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrachloromethane at 25℃; for 5h;
100%
Multi-step reaction with 2 steps
1: bromine / tetrachloromethane / 0 - 20 °C / Inert atmosphere
2: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 0 - 20 °C / Inert atmosphere
View Scheme
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

polymer, Mn 6.30E4, PDI 1.95 by GPC; monomer(s): tert-butyl methacrylate

polymer, Mn 6.30E4, PDI 1.95 by GPC; monomer(s): tert-butyl methacrylate

Conditions
ConditionsYield
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0 - 20℃; for 2h;100%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

4-bromo-2-methylbenzonitrile
67832-11-5

4-bromo-2-methylbenzonitrile

3-(4-cyano-3-methyl-phenyl)-2-methyl-acrylic acid tert-butyl ester
929202-11-9

3-(4-cyano-3-methyl-phenyl)-2-methyl-acrylic acid tert-butyl ester

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); N-Methyldicyclohexylamine; johnphos In 1,4-dioxane at 80℃; Heck coupling;100%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

tert-butyl 2,3-dibromo-2-methylpropanoate
854416-76-5

tert-butyl 2,3-dibromo-2-methylpropanoate

Conditions
ConditionsYield
With bromine In tetrachloromethane at 0 - 20℃; Inert atmosphere;100%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

pentan-3-one
96-22-0

pentan-3-one

methyl iodide
74-88-4

methyl iodide

2,2,4,6-Tetramethyl-cyclohexane-1,3-dione

2,2,4,6-Tetramethyl-cyclohexane-1,3-dione

Conditions
ConditionsYield
Stage #1: tert-Butyl methacrylate; pentan-3-one With potassium tert-butylate In tetrahydrofuran at 25℃; for 0.5h; Michael addition-Claisen condensation;
Stage #2: methyl iodide In tetrahydrofuran at 50℃; for 3h; Further stages.;
98%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-benzyloxycarbonyl-1-butene
219506-75-9

2-benzyloxycarbonyl-1-butene

poly(t-butyl methacrylate)-block-poly(benzyl-2-ethylacrylate)

poly(t-butyl methacrylate)-block-poly(benzyl-2-ethylacrylate)

Conditions
ConditionsYield
With 1,1-Diphenylpropyllithium In tetrahydrofuran at -78℃; for 15h;98%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-chloro-2-methyl-4-phenylbutane
4830-95-9

2-chloro-2-methyl-4-phenylbutane

tert-butyl 2,4,4-trimethyl-6-phenylhexanoate

tert-butyl 2,4,4-trimethyl-6-phenylhexanoate

Conditions
ConditionsYield
With Cp*TiCl3; triethylamine hydrochloride; zinc In ethyl acetate at 22℃; for 12h; Inert atmosphere; Glovebox;98%
3-methyl-butan-2-one
563-80-4

3-methyl-butan-2-one

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

4,4,6-trimethylcyclohexane-1,3-dione
104355-62-6

4,4,6-trimethylcyclohexane-1,3-dione

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 25℃; for 0.5h; Michael addition-Claisen condensation;97%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

diethyl (((diphenylmethylene)amino)methyl)phosphonate
122570-91-6

diethyl (((diphenylmethylene)amino)methyl)phosphonate

C26H36NO5P

C26H36NO5P

Conditions
ConditionsYield
Stage #1: diethyl N-(diphenylmethylene) aminomethyl phosphonate With C36H45NO9; sodium t-butanolate In toluene at -78℃; for 0.166667h; Michael Addition; Inert atmosphere;
Stage #2: tert-Butyl methacrylate In toluene at -78℃; for 1h; Michael Addition; Inert atmosphere; stereoselective reaction;
93%
2-ethyl-1-butene
760-21-4

2-ethyl-1-butene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-((((benzyloxy)carbonyl)amino)oxy)-2-methylpropanoic acid

2-((((benzyloxy)carbonyl)amino)oxy)-2-methylpropanoic acid

tert-butyl 4-((((benzyloxy)carbonyl)amino)methyl)-4-ethyl-2-methylhexanoate

tert-butyl 4-((((benzyloxy)carbonyl)amino)methyl)-4-ethyl-2-methylhexanoate

Conditions
ConditionsYield
Stage #1: 2-((((benzyloxy)carbonyl)amino)oxy)-2-methylpropanoic acid With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; caesium carbonate In dichloromethane at 25℃; for 0.166667h; Schlenk technique; Inert atmosphere;
Stage #2: 2-ethyl-1-butene; tert-Butyl methacrylate With water In dichloromethane at 25℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation; chemoselective reaction;
93%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-Methylcyclohexanone
583-60-8

2-Methylcyclohexanone

tert-butyl 3-(1-methyl-2-oxocyclohexyl)-2-methylpropanoate

tert-butyl 3-(1-methyl-2-oxocyclohexyl)-2-methylpropanoate

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 20℃; for 1.5h; Michael addition;92%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

para-iodoanisole
696-62-8

para-iodoanisole

(E)-tert-butyl 3-(4-methoxyphenyl)-2-methylacrylate
1415412-15-5

(E)-tert-butyl 3-(4-methoxyphenyl)-2-methylacrylate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 6h; Heck Reaction; Inert atmosphere;92%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

(2,2-dimethylcyclopropyl)(phenyl)methanone
5685-43-8

(2,2-dimethylcyclopropyl)(phenyl)methanone

tert-butyl (1R,2R)-2-benzoyl-1,4,4-trimethylcyclopentane-1-carboxylate

tert-butyl (1R,2R)-2-benzoyl-1,4,4-trimethylcyclopentane-1-carboxylate

Conditions
ConditionsYield
With manganese; C52H52Cl2F6N2O2Ti; triethylamine hydrochloride In ethyl acetate at 22℃; for 12h; Inert atmosphere; Sealed tube; stereoselective reaction;91%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
126688-97-9

2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(2E,4E)-2-methylnona-2,4-dienenoic acid tert-butyl ester

(2E,4E)-2-methylnona-2,4-dienenoic acid tert-butyl ester

Conditions
ConditionsYield
With oxygen; palladium diacetate In N,N-dimethyl acetamide at 50℃; for 6h;90%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

tert-Butyl 2-(Phenylsulfonyl)acetate
138336-33-1

tert-Butyl 2-(Phenylsulfonyl)acetate

di-tertbutyl 2-methyl-4-(phenylsulfonyl)pentanedioate

di-tertbutyl 2-methyl-4-(phenylsulfonyl)pentanedioate

Conditions
ConditionsYield
With caesium carbonate In acetonitrile Michael Addition; Inert atmosphere; Reflux;90%
ethylenebis(triphenylphosphine)platinum(0)
12120-15-9

ethylenebis(triphenylphosphine)platinum(0)

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

Pt(P(C6H5)3)2(CH2C(CH3)COOC(CH3)3)
186495-03-4

Pt(P(C6H5)3)2(CH2C(CH3)COOC(CH3)3)

Conditions
ConditionsYield
In toluene byproducts: C2H4; N2-atmosphere; stirring equimolar amts. for 2 h; cooling to 0°C, pptn. on addn. of petroleum ether, collection (filtration), washing (petroleum ether), drying (vac.); elem. anal.;89%
iodobenzene
591-50-4

iodobenzene

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

(2E)-tert-butyl 2-methyl-3-phenylprop-2-enoate
98831-01-7

(2E)-tert-butyl 2-methyl-3-phenylprop-2-enoate

Conditions
ConditionsYield
With potassium carbonate at 80℃; Heck Reaction; Micellar solution;89%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

poly(tert-butyl methacrylate), atom transfer radical polymerization product, Mn: 47000, PDI: 1.14; monomer(s): tert-butyl methacrylate

poly(tert-butyl methacrylate), atom transfer radical polymerization product, Mn: 47000, PDI: 1.14; monomer(s): tert-butyl methacrylate

Conditions
ConditionsYield
With ethyl 2-bromoisobutyrate; [(1,3,5-iPr3C6H3)Ru(μ-Cl)3RuCl(C2H4)(PCy3)] In toluene at 35℃;88%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

poly(tert-butyl methacrylate), Mn = 12871, Mw/Mn = 1.28; Monomer(s): tert-butyl methacrylate

poly(tert-butyl methacrylate), Mn = 12871, Mw/Mn = 1.28; Monomer(s): tert-butyl methacrylate

Conditions
ConditionsYield
With Methyl 2-bromopropionate; N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide; copper(ll) bromide In acetone at 60℃; for 1.33333h;86%
rac-3-sulfanylpropane-1,2-diol
96-27-5

rac-3-sulfanylpropane-1,2-diol

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

6,7-dihydroxy-2-methyl-4-thiaheptanoic acid t-butyl ester
167768-11-8

6,7-dihydroxy-2-methyl-4-thiaheptanoic acid t-butyl ester

Conditions
ConditionsYield
With triethylamine for 0.5h; Ambient temperature;84%
With sodium bicarbonate; triethylamine; citric acid In water84%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

triethoxyphenylsilane
780-69-8

triethoxyphenylsilane

methyl-3-phenyl-propionic acid tert-butyl ester
70836-95-2, 107772-28-1, 126639-62-1

methyl-3-phenyl-propionic acid tert-butyl ester

Conditions
ConditionsYield
With sodium hydroxide; cyclo-octa-1,5-diene; [Rh(OH)(cod)]2 In 1,4-dioxane at 90℃; for 16h;84%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

carbon dioxide
124-38-9

carbon dioxide

para-thiocresol
106-45-6

para-thiocresol

4-(tert-butoxy)-3-methyl-4-oxo-3-(p-tolylthio)butanoic acid

4-(tert-butoxy)-3-methyl-4-oxo-3-(p-tolylthio)butanoic acid

Conditions
ConditionsYield
With iron(III) chloride; potassium tert-butylate In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 12h; Glovebox; Schlenk technique; Irradiation; Sealed tube; regioselective reaction;84%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

tert-butyl ((1R,4R)-bornylideneamino)acetate
110269-68-6

tert-butyl ((1R,4R)-bornylideneamino)acetate

di-tert-butyl (2R)-2-<(1R,4R)-bornylideneamino>-4-methylglutamate
133445-88-2, 133521-71-8

di-tert-butyl (2R)-2-<(1R,4R)-bornylideneamino>-4-methylglutamate

Conditions
ConditionsYield
With n-butyllithium; tert-butyl alcohol In tetrahydrofuran; hexane at -78℃; for 18h;83%
(5,10,15,20-tetraphenylporphyrin)aluminum methyl

(5,10,15,20-tetraphenylporphyrin)aluminum methyl

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

C20N4H8(C6H5)4AlOCOCCH3C2H5CO2C4H9
136750-17-9

C20N4H8(C6H5)4AlOCOCCH3C2H5CO2C4H9

Conditions
ConditionsYield
With carbon dioxide In benzene under irradiation with visible light at 30°C for 3 h;; observed by NMR spectroscopy;;83%
tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

C12H20O3S3

C12H20O3S3

C30H56O6S3

C30H56O6S3

Conditions
ConditionsYield
With sodium methylate In methanol at 20℃; for 48h;82%
triethylsilane
617-86-7

triethylsilane

tert-Butyl methacrylate
585-07-9

tert-Butyl methacrylate

1-tert-butoxy-2-methyl-1-triethylsiloxypropene

1-tert-butoxy-2-methyl-1-triethylsiloxypropene

Conditions
ConditionsYield
Stage #1: triethylsilane With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate at 20℃; for 0.5h; Neat (no solvent);
Stage #2: tert-Butyl methacrylate at 3.5 - 6℃; for 5.5h; Neat (no solvent); Cooling with ice water;
81.5%

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