As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:585-07-9
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Cas:585-07-9
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:585-07-9
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inquirytert-Butyl methacrylate Basic information Product Name: tert-Butyl methacrylate Synonyms: TERTIARY-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE MONOMER;TBMA;T-BUTYL
Cas:585-07-9
Min.Order:1 Kilogram
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:585-07-9
Min.Order:1 Kilogram
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Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryAppearance:colorless liquid Storage:2-8°C Package:200kg/Drum Application:tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, b
Cas:585-07-9
Min.Order:1 Kilogram
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inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:585-07-9
Min.Order:1 Gram
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Cas:585-07-9
Min.Order:1 Kilogram
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Cas:585-07-9
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Product name: Tert-Butyl Methacrylate CAS No.:585-07-9 Molecule Formula:C8H14O2 Molecule Weight:142.19 Purity: 99% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING ITE
Cas:585-07-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
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Min.Order:1 Kilogram
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inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
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Min.Order:1 Metric Ton
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Type:Trading Company
inquirySuperior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used in organic syn
We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:585-07-9
Min.Order:1 Metric Ton
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inquiryProduct Name: tert-Butyl methacrylate CAS: 585-07-9 MF: C8H14O2 MW: 142.2 EINECS: 209-548-7 Mol File: 585-07-9.mol Appearance:Colorless clear liquid Storage:Preserve in wel
Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is
Cas:585-07-9
Min.Order:100 Kilogram
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Type:Other
inquiryJinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Cas:585-07-9
Min.Order:100 Gram
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inquiryAcmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:585-07-9
Min.Order:1 bottle
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Type:Lab/Research institutions
inquiryhigh quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Cas:585-07-9
Min.Order:0
Negotiable
Type:Manufacturers
inquiryOur clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Type:Lab/Research institutions
inquirySupply top quality products with a reasonable price Application:api
tert-Butyl methacrylate cas 585-07-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
tert-butyl bromoisobutyrate
methyl 5-chloro-2,4-dihydroxybenzoate
A
4-(1-tert-butoxycarbonyl-1-methylethoxy)-5-chloro-2-hydroxybenzoic acid methyl ester
B
tert-Butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: tert-butyl bromoisobutyrate; methyl 5-chloro-2,4-dihydroxybenzoate With tetrabutylammomium bromide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h; Stage #2: With hydrogenchloride In 1-methyl-pyrrolidin-2-one; water pH=~ 4; | A 72.2% B n/a |
Stage #1: tert-butyl bromoisobutyrate; methyl 5-chloro-2,4-dihydroxybenzoate With potassium carbonate; tetrabutylammomium bromide In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h; Stage #2: With hydrogenchloride In 1-methyl-pyrrolidin-2-one; water pH=~ 4; | A 72.2% B n/a |
With tetrabutylammomium bromide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 60 - 65℃; for 16h; | A 72.2% B n/a |
Conditions | Yield |
---|---|
With Petroleum ether; tert-butyl alcohol |
Conditions | Yield |
---|---|
With pyridine | |
With pyridine |
Conditions | Yield |
---|---|
With diethyl ether; hydroquinone |
1,2-propanediene
carbon monoxide
tert-butyl alcohol
tert-Butyl methacrylate
Conditions | Yield |
---|---|
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h; | 36 % Chromat. |
Conditions | Yield |
---|---|
With pentamethylbenzene, at 19.85℃; Kinetics; |
Conditions | Yield |
---|---|
Stage #1: 2-methylpropenal With tert-butylhypochlorite In tetrachloromethane at 20 - 50℃; for 5.5 - 6.5h; Stage #2: tert-butyl alcohol With triethylamine In tetrachloromethane at 0 - 20℃; for 19.5h; |
A
tert-Butyl methacrylate
B
Diethyl phosphonate
C
C18H38NO6P
D
N-(2-methyl-2-propyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)aminoxyl
Conditions | Yield |
---|---|
under 7.50075E-06 Torr; Kinetics; |
Conditions | Yield |
---|---|
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; |
Conditions | Yield |
---|---|
With tempol; 2,4-dimethyl-6-tert-butylphenol; 4-methoxy-phenol; magnesium bromide at 90℃; for 6h; Reagent/catalyst; |
t-butyl pyruvate
Methyltriphenylphosphonium bromide
tert-Butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: Methyltriphenylphosphonium bromide With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 2h; Stage #2: t-butyl pyruvate In tetrahydrofuran; mineral oil at 0 - 20℃; |
tert-Butyl methacrylate
2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate
block-copoly{2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, anionic polymerization, Mn = 18E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: 2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethyl methacrylate With diethylzinc; (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 2h; Stage #2: tert-Butyl methacrylate In tetrahydrofuran at -78℃; for 1h; | 100% |
tert-Butyl methacrylate
2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate
block-copoly{2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate/tert-butyl methacrylate}, Mn = 9.0E3, Mw/Mn = 1.03; Monomer(s): 2-[2-[2-[(t-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate; tert-butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: 2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate With diethylzinc; (diphenylmethyl)potassium In tetrahydrofuran at -78℃; for 3h; Stage #2: tert-Butyl methacrylate In tetrahydrofuran at -78℃; for 1h; | 100% |
poly(methyl methacrylate), 1,1-bis[3-(bromomethyl)phenyl]ethyl-terminated, Mn 1.23E4 Da by SEC, Mn 1.35E4 Da by osmometry, Mw/Mn 1.04; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene
tert-Butyl methacrylate
poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 3-arm, Mw 3.33E4 Da, Mw/Mn 1.02; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: tert-Butyl methacrylate With (diphenylmethyl)potassium In tetrahydrofuran Stage #2: poly(methyl methacrylate), 1,1-bis[3-(bromomethyl)phenyl]ethyl-terminated, Mn 1.23E4 Da by SEC, Mn 1.35E4 Da by osmometry, Mw/Mn 1.04; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene In tetrahydrofuran at -78℃; for 1h; | 100% |
poly(methyl methacrylate), with 3,97 3-(bromomethyl)phenyl end groups, Mn 1.24E4 Da by SEC, Mn 1.32E4 by osmometry, Mn 1.36E4 Da by NMR, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene
tert-Butyl methacrylate
poly[(methyl methacrylate)-b-(tert-butyl methacrylate)], asymmetric star-branched, 5-arm, Mw 6.27E4 Da, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene; tert-butyl methacrylate
Conditions | Yield |
---|---|
Stage #1: tert-Butyl methacrylate With (diphenylmethyl)potassium In tetrahydrofuran Stage #2: poly(methyl methacrylate), with 3,97 3-(bromomethyl)phenyl end groups, Mn 1.24E4 Da by SEC, Mn 1.32E4 by osmometry, Mn 1.36E4 Da by NMR, Mw/Mn 1.03; monomer(s): methyl methacrylate; 1,1-bis[3-(tert-butyldimethylsilyloxymethyl)phenyl]ethylene In tetrahydrofuran at -78℃; for 1h; | 100% |
tert-Butyl methacrylate
3-bromo-2-methyl-acrylic acid tert-butyl ester
Conditions | Yield |
---|---|
Stage #1: tert-Butyl methacrylate With bromine In tetrachloromethane at 25℃; for 2h; Stage #2: With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrachloromethane at 25℃; for 5h; | 100% |
Multi-step reaction with 2 steps 1: bromine / tetrachloromethane / 0 - 20 °C / Inert atmosphere 2: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 0 - 20 °C / Inert atmosphere View Scheme |
tert-Butyl methacrylate
Conditions | Yield |
---|---|
With potassium tert-butylate; triisobutylaluminum In hexane; toluene at 0 - 20℃; for 2h; | 100% |
tert-Butyl methacrylate
4-bromo-2-methylbenzonitrile
3-(4-cyano-3-methyl-phenyl)-2-methyl-acrylic acid tert-butyl ester
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium (0); N-Methyldicyclohexylamine; johnphos In 1,4-dioxane at 80℃; Heck coupling; | 100% |
tert-Butyl methacrylate
tert-butyl 2,3-dibromo-2-methylpropanoate
Conditions | Yield |
---|---|
With bromine In tetrachloromethane at 0 - 20℃; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
Stage #1: tert-Butyl methacrylate; pentan-3-one With potassium tert-butylate In tetrahydrofuran at 25℃; for 0.5h; Michael addition-Claisen condensation; Stage #2: methyl iodide In tetrahydrofuran at 50℃; for 3h; Further stages.; | 98% |
tert-Butyl methacrylate
2-benzyloxycarbonyl-1-butene
Conditions | Yield |
---|---|
With 1,1-Diphenylpropyllithium In tetrahydrofuran at -78℃; for 15h; | 98% |
Conditions | Yield |
---|---|
With Cp*TiCl3; triethylamine hydrochloride; zinc In ethyl acetate at 22℃; for 12h; Inert atmosphere; Glovebox; | 98% |
3-methyl-butan-2-one
tert-Butyl methacrylate
4,4,6-trimethylcyclohexane-1,3-dione
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran at 25℃; for 0.5h; Michael addition-Claisen condensation; | 97% |
tert-Butyl methacrylate
diethyl (((diphenylmethylene)amino)methyl)phosphonate
Conditions | Yield |
---|---|
Stage #1: diethyl N-(diphenylmethylene) aminomethyl phosphonate With C36H45NO9; sodium t-butanolate In toluene at -78℃; for 0.166667h; Michael Addition; Inert atmosphere; Stage #2: tert-Butyl methacrylate In toluene at -78℃; for 1h; Michael Addition; Inert atmosphere; stereoselective reaction; | 93% |
Conditions | Yield |
---|---|
Stage #1: 2-((((benzyloxy)carbonyl)amino)oxy)-2-methylpropanoic acid With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; caesium carbonate In dichloromethane at 25℃; for 0.166667h; Schlenk technique; Inert atmosphere; Stage #2: 2-ethyl-1-butene; tert-Butyl methacrylate With water In dichloromethane at 25℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation; chemoselective reaction; | 93% |
Conditions | Yield |
---|---|
With potassium tert-butylate In tetrahydrofuran at 20℃; for 1.5h; Michael addition; | 92% |
tert-Butyl methacrylate
para-iodoanisole
(E)-tert-butyl 3-(4-methoxyphenyl)-2-methylacrylate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 6h; Heck Reaction; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
With manganese; C52H52Cl2F6N2O2Ti; triethylamine hydrochloride In ethyl acetate at 22℃; for 12h; Inert atmosphere; Sealed tube; stereoselective reaction; | 91% |
tert-Butyl methacrylate
2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Conditions | Yield |
---|---|
With oxygen; palladium diacetate In N,N-dimethyl acetamide at 50℃; for 6h; | 90% |
tert-Butyl methacrylate
tert-Butyl 2-(Phenylsulfonyl)acetate
Conditions | Yield |
---|---|
With caesium carbonate In acetonitrile Michael Addition; Inert atmosphere; Reflux; | 90% |
ethylenebis(triphenylphosphine)platinum(0)
tert-Butyl methacrylate
Pt(P(C6H5)3)2(CH2C(CH3)COOC(CH3)3)
Conditions | Yield |
---|---|
In toluene byproducts: C2H4; N2-atmosphere; stirring equimolar amts. for 2 h; cooling to 0°C, pptn. on addn. of petroleum ether, collection (filtration), washing (petroleum ether), drying (vac.); elem. anal.; | 89% |
iodobenzene
tert-Butyl methacrylate
(2E)-tert-butyl 2-methyl-3-phenylprop-2-enoate
Conditions | Yield |
---|---|
With potassium carbonate at 80℃; Heck Reaction; Micellar solution; | 89% |
tert-Butyl methacrylate
Conditions | Yield |
---|---|
With ethyl 2-bromoisobutyrate; [(1,3,5-iPr3C6H3)Ru(μ-Cl)3RuCl(C2H4)(PCy3)] In toluene at 35℃; | 88% |
tert-Butyl methacrylate
Conditions | Yield |
---|---|
With Methyl 2-bromopropionate; N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide; copper(ll) bromide In acetone at 60℃; for 1.33333h; | 86% |
rac-3-sulfanylpropane-1,2-diol
tert-Butyl methacrylate
6,7-dihydroxy-2-methyl-4-thiaheptanoic acid t-butyl ester
Conditions | Yield |
---|---|
With triethylamine for 0.5h; Ambient temperature; | 84% |
With sodium bicarbonate; triethylamine; citric acid In water | 84% |
tert-Butyl methacrylate
triethoxyphenylsilane
methyl-3-phenyl-propionic acid tert-butyl ester
Conditions | Yield |
---|---|
With sodium hydroxide; cyclo-octa-1,5-diene; [Rh(OH)(cod)]2 In 1,4-dioxane at 90℃; for 16h; | 84% |
Conditions | Yield |
---|---|
With iron(III) chloride; potassium tert-butylate In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 12h; Glovebox; Schlenk technique; Irradiation; Sealed tube; regioselective reaction; | 84% |
tert-Butyl methacrylate
tert-butyl ((1R,4R)-bornylideneamino)acetate
di-tert-butyl (2R)-2-<(1R,4R)-bornylideneamino>-4-methylglutamate
Conditions | Yield |
---|---|
With n-butyllithium; tert-butyl alcohol In tetrahydrofuran; hexane at -78℃; for 18h; | 83% |
tert-Butyl methacrylate
C20N4H8(C6H5)4AlOCOCCH3C2H5CO2C4H9
Conditions | Yield |
---|---|
With carbon dioxide In benzene under irradiation with visible light at 30°C for 3 h;; observed by NMR spectroscopy;; | 83% |
Conditions | Yield |
---|---|
With sodium methylate In methanol at 20℃; for 48h; | 82% |
Conditions | Yield |
---|---|
Stage #1: triethylsilane With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate at 20℃; for 0.5h; Neat (no solvent); Stage #2: tert-Butyl methacrylate at 3.5 - 6℃; for 5.5h; Neat (no solvent); Cooling with ice water; | 81.5% |
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