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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

2-Bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 59772-49-5 with competitive price

Cas:59772-49-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Benzenamine, 2-bromo-6-chloro- CAS59772-49-5

Cas:59772-49-5

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenamine, 2-bromo-6-chloro- 59772-49-5

Cas:59772-49-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

2-BROMO-6-CHLOROANILINE

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-BROMO-6-CHLOROANILINE CAS:59772-49-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

2-BROMO-6-CHLOROANILINE CAS:59772-49-5

Cas:59772-49-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Melting point 57-58 °C(Solv: water (7732-18-5); ethanol (64-17-5)) Boiling point 242.8±20.0 °C(Predicted) density 1.722±0.06 g/cm3(Predicte

2-Bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

2-BROMO-6-CHLOROANILINE

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

2-BROMO-6-CHLOROANILINE

Cas:59772-49-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 2-Bromo-6-Chlorobenzenamine CAS No.:59772-49-5 Molecule Formula:C6H5BrClN Molecule Weight:206.47 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

Best Quality 2-Bromo-6-Chlorobenzenamine with good supplier

Cas:59772-49-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:gray to off-white powder Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Bromo-6-chloroaniline cas no. 59772-49-5 98%

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

BenzenaMine, 2-broMo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Product name:2-BROMO-6-CHLOROANILINE Synonyms:2-Bromo-6-chlorobenzenamine;BenzenaMine, 2-broMo-6-chloro- CAS No:59772-49-5 Molecular formula:C6H5BrClN Molecular Weight:206.47 Boiling point 242.8±20.0 °C(Predicted) Density 1.722&plusm

2-BROMO-6-CHLOROANILINE china manufacture

Cas:59772-49-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

2-BROMO-6-CHLOROANILINEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-BROMO-6-CHLOROANILINE

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

59772-49-5

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

2-Bromo-6-Chloroaniline manufacturer

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Benzenamine, 2-bromo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Suzhou Sibian Chemical Technology Co., Ltd

Lower price, sample is available,large stock in warehouse.Best service, high quality and reasonable price.If you are looking for the material's manufacturer or supplier in China, Sibian chemical is your best choice. Application:Drug R&D

2-Bromo-6-chloroaniline

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-BROMO-6-CHLOROANILINE

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

2-Bromo-6-chloroaniline CAS NO.59772-49-5

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Hanhong Scientific Co.,Ltd.

factory,reasonable price Appearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:pharmaceutical intermediates Transportation:by courier,air or sea Port:S

2-Bromo-6-chloroaniline59772-49-5

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi

BenzenaMine, 2-broMo-6-chloro-

Cas:59772-49-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-bromo-6-chlorobenzoic acid
93224-85-2

2-bromo-6-chlorobenzoic acid

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
Stage #1: 2-bromo-6-chlorobenzoic acid With sulfuric acid at 60℃; for 1.5h;
Stage #2: With sodium azide at 20℃; for 42h; Schmidt rearrangement;
Stage #3: With ammonium hydroxide at 0℃;
92%
4-amino-3-bromo-5-chlorobenzenesulfonamide

4-amino-3-bromo-5-chlorobenzenesulfonamide

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
With sulfuric acid at 150℃; for 2h; Temperature;85%
2'-Chloro-6'-bromobenzanilide
90493-87-1

2'-Chloro-6'-bromobenzanilide

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
With sulfuric acid for 3h; Heating;66%
2-bromoaniline
615-36-1

2-bromoaniline

A

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

B

4-chloro-2-bromoaniline
873-38-1

4-chloro-2-bromoaniline

Conditions
ConditionsYield
With N-chloro-succinimide; 1-(3,5-bis(trifluoromethyl)phenyl)-3-((1S,2S)-2-(mesitylselanyl)-2,3-dihydro-1H-inden-1-yl)thiourea In chloroform-d1 at 0℃; for 18h; regioselective reaction;A 40%
B n/a
2-Chloroaniline
95-51-2

2-Chloroaniline

A

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

B

2-chloro-4-bromoaniline
38762-41-3

2-chloro-4-bromoaniline

Conditions
ConditionsYield
With dihydrogen peroxide; ammonium bromide; acetic acid at 20℃; for 2.5h;
Stage #1: o-chloroaniline With dihydrogen peroxide; acetic acid; potassium bromide In water at 20℃; for 3h;
Stage #2: With sodium hydrogencarbonate In diethyl ether; water regioselective reaction;
N-(2-bromophenyl)hydroxylamine
35758-75-9

N-(2-bromophenyl)hydroxylamine

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: NaHCO3 / diethyl ether; H2O / 1 h / T < 5 deg C; or in benzene
2: 71 percent / SOCl2 / diethyl ether / 1 h / T < 5 deg C
3: 66 percent / 70percent H2SO4 / 3 h / Heating
View Scheme
N-(2-Bromo-phenyl)-N-hydroxy-benzamide
90493-81-5

N-(2-Bromo-phenyl)-N-hydroxy-benzamide

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 71 percent / SOCl2 / diethyl ether / 1 h / T < 5 deg C
2: 66 percent / 70percent H2SO4 / 3 h / Heating
View Scheme
2-Chloroaniline
95-51-2

2-Chloroaniline

A

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

B

2-chloro-4,6-dibromoaniline
874-18-0

2-chloro-4,6-dibromoaniline

C

2-chloro-4-bromoaniline
38762-41-3

2-chloro-4-bromoaniline

Conditions
ConditionsYield
With bromine at 20 - 25℃; for 0.0333333h; pH=8.5 - 9; aq. buffer;
sulfanilamide
63-74-1

sulfanilamide

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: N-chloro-succinimide / tetrahydrofuran / 25 h / 40 °C
2: N-Bromosuccinimide / acetonitrile / 3 h / 20 °C
3: sulfuric acid / 2 h / 150 °C
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

1-bromo-3-chloro-2-nitrobenzene
59772-48-4

1-bromo-3-chloro-2-nitrobenzene

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In 1,2-dichloro-ethane at 70℃; for 2h;94%
With trifluoroacetyl peroxide In dichloromethane at -5 - 5℃; for 2h;75%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

benzo[b]thiophen-3-yl-3-boronic acid
113893-08-6

benzo[b]thiophen-3-yl-3-boronic acid

C14H10ClNS

C14H10ClNS

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In ethanol; toluene for 4h; Reflux;91%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

benzofurane-3-ylboronic acid

benzofurane-3-ylboronic acid

C14H10ClNO

C14H10ClNO

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In ethanol; toluene for 4h; Reflux;91%
3-chloro-4-(4',4',5',5'-tetramethyl-1',3',2'-dioxaborolan-2'-yl)-N-(TIPS)pyrrole
1126425-82-8

3-chloro-4-(4',4',5',5'-tetramethyl-1',3',2'-dioxaborolan-2'-yl)-N-(TIPS)pyrrole

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

2-chloro-6-(4-chloro-1-(triisopropylsilyl)-1H-pyrrol-3-yl)aniline
1126425-92-0

2-chloro-6-(4-chloro-1-(triisopropylsilyl)-1H-pyrrol-3-yl)aniline

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In water; butan-1-ol at 35℃; for 12h; Suzuki-Miyaura coupling; Inert atmosphere;82%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)pyrrole
365564-11-0

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(triisopropylsilyl)pyrrole

2-chloro-6-(1-(triisopropylsilyl)-1H-pyrrol-3-yl)aniline
1126425-86-2

2-chloro-6-(1-(triisopropylsilyl)-1H-pyrrol-3-yl)aniline

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In water; butan-1-ol at 35℃; for 12h; Suzuki-Miyaura coupling; Inert atmosphere;82%
methyl (S)-2-((tert-butoxycarbonyl)amino)-5-(triethylsilyl)pent-4-ynoate
1152312-10-1

methyl (S)-2-((tert-butoxycarbonyl)amino)-5-(triethylsilyl)pent-4-ynoate

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C23H35ClN2O4Si

C23H35ClN2O4Si

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); N-Methyldicyclohexylamine In 1,4-dioxane at 60℃; for 36h; Inert atmosphere; Sealed tube;82%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

phenylboronic acid
98-80-6

phenylboronic acid

3-chloro-[1,1'-biphenyl]-2-amine
76838-82-9

3-chloro-[1,1'-biphenyl]-2-amine

Conditions
ConditionsYield
Stage #1: 2-bromo-6-chloroaniline; phenylboronic acid With potassium carbonate In 1,4-dioxane; water for 0.166667h;
Stage #2: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane; water for 1h;
81.1%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

2-Biphenylboronic acid
4688-76-0

2-Biphenylboronic acid

C18H14ClN

C18H14ClN

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In ethanol; water; toluene at 100℃; for 15h;80%
iodobenzene
591-50-4

iodobenzene

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C18H13BrClN

C18H13BrClN

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 4h; Inert atmosphere; Reflux;70%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

potassium vinyltrifluoroborate

potassium vinyltrifluoroborate

2-chloro-6-vinylaniline

2-chloro-6-vinylaniline

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In tetrahydrofuran; water at 80℃; for 9h;56%
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

chloroacetyl chloride
79-04-9

chloroacetyl chloride

chloro-acetic acid-(2-bromo-6-chloro-anilide)

chloro-acetic acid-(2-bromo-6-chloro-anilide)

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

N,N-diethyl-glycine-(2-bromo-6-chloro-anilide)
100140-98-5

N,N-diethyl-glycine-(2-bromo-6-chloro-anilide)

2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

methyl 2-vinyl-6-chloroaniline-N-carboxylate

methyl 2-vinyl-6-chloroaniline-N-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate / tetrahydrofuran; water / 9 h / 80 °C
2: pyridine / dichloromethane / 0 - 25 °C
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

methyl 7-chloro-indole-1-carboxylate

methyl 7-chloro-indole-1-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate / tetrahydrofuran; water / 9 h / 80 °C
2: pyridine / dichloromethane / 0 - 25 °C
3: bis(benzonitrile)palladium(II) dichloride; tert.-butylnitrite; oxygen / tert-butyl alcohol / 15 h / 70 °C / 760.05 Torr / Schlenk technique
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

7-chloro-1H-indole
53924-05-3

7-chloro-1H-indole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate / tetrahydrofuran; water / 9 h / 80 °C
2: pyridine / dichloromethane / 0 - 25 °C
3: bis(benzonitrile)palladium(II) dichloride; tert.-butylnitrite; oxygen / tert-butyl alcohol / 15 h / 70 °C / 760.05 Torr / Schlenk technique
4: potassium hydroxide / methanol / 1 h / Reflux
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

7-(o-tolyl)-1H-indole
1073494-35-5

7-(o-tolyl)-1H-indole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate / tetrahydrofuran; water / 9 h / 80 °C
2: pyridine / dichloromethane / 0 - 25 °C
3: bis(benzonitrile)palladium(II) dichloride; tert.-butylnitrite; oxygen / tert-butyl alcohol / 15 h / 70 °C / 760.05 Torr / Schlenk technique
4: potassium hydroxide / methanol / 1 h / Reflux
5: palladium diacetate; potassium phosphate; ruphos / tetrahydrofuran; toluene / 22 h / 100 °C / Schlenk technique; Inert atmosphere
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C21H12ClNO

C21H12ClNO

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate / toluene; ethanol / 4 h / Reflux
2: triethylamine / 0 °C
3: trichlorophosphate / nitrobenzene / 12 h / 150 °C
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C27H24BNO3

C27H24BNO3

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate / toluene; ethanol / 4 h / Reflux
2: triethylamine / 0 °C
3: trichlorophosphate / nitrobenzene / 12 h / 150 °C
4: potassium acetate; tris-(dibenzylideneacetone)dipalladium(0); XPhos / 1,4-dioxane / 12 h / Reflux
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C54H33N5S

C54H33N5S

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate / toluene; ethanol / 4 h / Reflux
2: triethylamine / 0 °C
3: trichlorophosphate / nitrobenzene / 12 h / 150 °C
4: potassium acetate; tris-(dibenzylideneacetone)dipalladium(0); XPhos / 1,4-dioxane / 12 h / Reflux
5: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol; water / 12 h / Reflux
View Scheme
2-Chloro-6-bromoaniline
59772-49-5

2-Chloro-6-bromoaniline

C54H32N4S

C54H32N4S

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate / toluene; ethanol / 4 h / Reflux
2: triethylamine / 0 °C
3: trichlorophosphate / nitrobenzene / 12 h / 150 °C
4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 12 h / Reflux
5: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol; water / 5 h / Reflux
6: tris-(dibenzylideneacetone)dipalladium(0); XPhos; potassium phosphate / 1,4-dioxane / 12 h / Reflux
View Scheme

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