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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

High purity 1,1'-Bi-2-naphthol 98% TOP1 supplier in China

Cas:602-09-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality (±)-1,1'-Bi(2-Naphthol) supplier in China

Cas:602-09-5

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 602-09-5 1,1′-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,1'-binaphthyl-2,2'-diol

Cas:602-09-5

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,2'-Dihydroxy-1,1'-binaphthyl

Cas:602-09-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Product number 17482 English Name (±)-1,1-Bi(2-Naphthol) CAS Number 602-09-5 Purity 98% Molecular f

(±)-1,1-Bi(2-Naphthol) cas no. 602-09-5 98%

Cas:602-09-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

602-09-5 1,1'-Bi-2-naphthol Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate

602-09-5 1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 602-09-5 with competitive price

Cas:602-09-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS ?602-09-5 ,1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 1,1'-Bi-2-naphthol Synonyms: (+/-)-1,1'-BINAPHTHALENE-2,2'-DIOL;1,1'-BI-2,2'-NAPHTHOLS;(+/-)-1,1'-BI(2-NAPHTHOL);1,1'-BI-2-NAPHTHOL;[1,1']BINAPHTHALENYL-2,2&#39

1,1-Bi-2-naphthol CAS: 602-09-5

Cas:602-09-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

1,1'-Bi-2-naphtholCAS NO.:602-09-5

Cas:602-09-5

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1'-Bi-2-naphthol 602-09-5

Cas:602-09-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

1,1'-Bi-2-naphthol CAS:602-09-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

1,1'-Bi-2-naphthol CAS:602-09-5

Cas:602-09-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

1,1'-Bi-2-naphthol CAS: 602-09-5 Specification Name:1,1'-Bi-2-naphthol 602-09-5 Other name: (±)-1,1'-Bi(2-naphthol) Cas: 602-09-5 Color:white Purity:99%min Molecular formula:C20H14O2 Molecular weight:286.33 Melting point:

Factory supply 1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 1,1'-Bi-2-naphthol 98% 602-09-5;Please contact us by email freely. We are leading exporter in China. If you really need this car

1,1'-Bi-2-naphthol 98% 602-09-5 from Fandachem

Cas:602-09-5

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1,1'-Bi-2-Naphthol

Cas:602-09-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

ProName: High purity 1,1'-Bi-2-naphthol 98% TOP... CasNo: 602-09-5 Molecular Formula: C20H14O2 Appearance: white to beige powder Application: It is an important raw material and in... DeliveryTime: prompt PackAge: according to the clients

High purity 1,1'-Bi-2-naphthol 98% TOP1 supplier in China

Cas:602-09-5

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Offer N-Boc-D-proline C10H17NO4 CAS.37784-17-1 in China

Cas:602-09-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2,2'-Dihydroxy-1,1'-binaphthyl/High quality/Best price

Cas:602-09-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality (±)-1,1'-Bi(2-Naphthol)

Cas:602-09-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1,1'-Bi-2-naphthol

Cas:602-09-5

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

YUNBIO TECH CO.,LTD

Our Strength:-Flexible: We work in small teams with rapid communication channels. Respond quickly and efficiently to customer and market needs.-Innovative: We are focusing on the development of new products and keep close relationships with our custo

1,1'-Bi-2,2'-naphthol

Cas:602-09-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Regent 1,1'-Binaphthalene-2,2'-diol Powder CAS 602-09-5

Cas:602-09-5

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.8

Type:Trading Company

inquiry

Synthetic route

β-naphthol
135-19-3

β-naphthol

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With C24H13Cu2F9N4O7; oxygen In isopropyl alcohol at 90℃; under 760.051 Torr; for 24h;100%
With manganese (IV) dioxide In acetonitrile at 25℃; under 760.051 Torr;99.3%
With 2,6-dimethylpyridine; sodium perchlorate In acetonitrile electrolysis;98.6%
2,2'-dimethoxy-1,1'-binaphthyl
75685-01-7

2,2'-dimethoxy-1,1'-binaphthyl

A

2-hydroxy-2'-methoxy-1,1'-binaphthyl
35193-70-5

2-hydroxy-2'-methoxy-1,1'-binaphthyl

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With niobium pentachloride In toluene for 0.5h; Heating;A 99%
B 1%
β-naphthol
135-19-3

β-naphthol

1-diazo-2(1H)naphthalenone
773-90-0, 860253-14-1

1-diazo-2(1H)naphthalenone

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With palladium diacetate In dichloromethane at 20℃; for 36h; Inert atmosphere; Schlenk technique; enantioselective reaction;98%
With iron(III) trifluoromethanesulfonate In 1,2-dichloro-ethane for 10h; Reflux; Inert atmosphere; regioselective reaction;42%
β-naphthol
135-19-3

β-naphthol

A

1-chloro-2-naphthol
633-99-8

1-chloro-2-naphthol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With copper dichloride at 50 - 55℃; for 0.583333h; Neat (no solvent);A 5%
B 95%
With hydrogenchloride; iron(III) chloride
(+)-1,1'-binaphthyl-2,2'-diyl N-<(S)-α-methylbenzyl>thiophosphoroamidate

(+)-1,1'-binaphthyl-2,2'-diyl N-<(S)-α-methylbenzyl>thiophosphoroamidate

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 2h;95%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃;
rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene
173831-50-0

rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With 1-thiopropane; zinc dibromide In dichloromethane at 20℃; for 0.116667h; Inert atmosphere;95%
C38H20Cl2O4
121794-31-8

C38H20Cl2O4

1-(2-Carboxy-4,6-dichloro-phenyl)-naphthalene-2-carboxylic acid

1-(2-Carboxy-4,6-dichloro-phenyl)-naphthalene-2-carboxylic acid

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydroxide In ethanolA 93%
B n/a
<1,1'-Binaphthalene>-2,2'-diol dibutanoate
100465-50-7

<1,1'-Binaphthalene>-2,2'-diol dibutanoate

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 25℃; for 18h;92%
C38H21NO6
121794-33-0

C38H21NO6

1-(2-Carboxy-6-nitro-phenyl)-naphthalene-2-carboxylic acid

1-(2-Carboxy-6-nitro-phenyl)-naphthalene-2-carboxylic acid

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydroxide In ethanolA 91%
B n/a
C34H17Cl2NO6
121794-32-9

C34H17Cl2NO6

4,6-Dichloro-6'-nitro-biphenyl-2,2'-dicarboxylic acid

4,6-Dichloro-6'-nitro-biphenyl-2,2'-dicarboxylic acid

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydroxide In ethanolA 90%
B 88%
<1,1'-Binaphthalene>-2,2'-diol butanoate
124040-95-5, 124098-06-2, 124098-08-4

<1,1'-Binaphthalene>-2,2'-diol butanoate

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 25℃; for 24h;90%
3-hydroxy-2-naphthoic acid methyl ester
883-99-8

3-hydroxy-2-naphthoic acid methyl ester

β-naphthol
135-19-3

β-naphthol

A

dimethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate
47644-69-9, 69678-00-8, 18531-91-4

dimethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

B

(aS)-methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate
128702-23-8, 145415-62-9, 145415-63-0

(aS)-methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

C

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With tert-butylamine; copper dichloride In methanol at 50℃; for 0.75h; oxidative cross-coupling;A n/a
B 87%
C n/a
With tert-butylamine; copper dichloride In methanol at 50℃; for 0.5h; Yields of byproduct given;A n/a
B 86%
C n/a
With tert-butylamine In methanol for 3h; Ambient temperature;A 7 % Chromat.
B 81%
C 4 % Chromat.
2,2'-bis(benzyloxy)-1,1'-binaphthalene
99747-67-8

2,2'-bis(benzyloxy)-1,1'-binaphthalene

A

(rac)-2′-benzyloxy-1,1′-binaphtalene-2-ol
89867-54-9

(rac)-2′-benzyloxy-1,1′-binaphtalene-2-ol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With niobium pentachloride In toluene at -78℃; for 3h;A 87%
B 8%
naphthalen-2-ylamine
91-59-8

naphthalen-2-ylamine

β-naphthol
135-19-3

β-naphthol

A

7H-dibenzo[c,g]carbazole
194-59-2

7H-dibenzo[c,g]carbazole

B

1,1'-binaphthalene-2,2'-diamine
4488-22-6, 18531-95-8

1,1'-binaphthalene-2,2'-diamine

C

2-amino-2’-hydroxy-1,1’-binaphthyl
134532-03-9, 137848-28-3, 137848-29-4

2-amino-2’-hydroxy-1,1’-binaphthyl

D

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With rac-methylbenzylamine In methanol for 48h; Ambient temperature;A 1 % Chromat.
B 2 % Chromat.
C 85%
D 6 % Chromat.
((1S,2S,5R)-2-Isopropyl-5-methyl-cyclohexylsulfanyl)-acetic acid 2'-hydroxy-[1,1']binaphthalenyl-2-yl ester

((1S,2S,5R)-2-Isopropyl-5-methyl-cyclohexylsulfanyl)-acetic acid 2'-hydroxy-[1,1']binaphthalenyl-2-yl ester

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at -20℃; for 0.5h;85%
β-naphthol
135-19-3

β-naphthol

Dimethyl-p-toluidine
99-97-8

Dimethyl-p-toluidine

A

1-(2-(dimethylamino)-5-methylphenyl)naphthalene-2-ol
1346854-94-1

1-(2-(dimethylamino)-5-methylphenyl)naphthalene-2-ol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With methanesulfonic acid; 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluorophthalocyaninato-iron(II) In dichloromethane at 0℃; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Green chemistry;A 84%
B 18%
C25H25O3PSeSi

C25H25O3PSeSi

A

bis[2-(trimethylsilyl)ethyl]-diselenide
439675-12-4

bis[2-(trimethylsilyl)ethyl]-diselenide

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 20℃; for 0.666667h;A 83%
B n/a
2-methyl-1,2-epoxypropane
558-30-5

2-methyl-1,2-epoxypropane

(S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol
79082-80-7

(S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol

A

6,6'-bis(2-hydroxy-2-methylpropyl)-1,1'-binaphthyl-2,2'-diol
1274926-89-4

6,6'-bis(2-hydroxy-2-methylpropyl)-1,1'-binaphthyl-2,2'-diol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
Stage #1: (S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol With n-butyllithium In tetrahydrofuran; hexane at -78 - -70℃; for 5h; Inert atmosphere;
Stage #2: 2-methyl-1,2-epoxypropane With boron trifluoride diethyl etherate In tetrahydrofuran; hexane at -78 - -40℃; for 2h; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water at 20℃; pH=< 1; Cooling with ice;
A 82%
B 5%
4-methoxy-N,N-dimethylanilne
701-56-4

4-methoxy-N,N-dimethylanilne

β-naphthol
135-19-3

β-naphthol

A

1-(2-(dimethylamino)-5-methoxyphenyl)naphthalene-2-ol
1346855-14-8

1-(2-(dimethylamino)-5-methoxyphenyl)naphthalene-2-ol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With methanesulfonic acid; 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluorophthalocyaninato-iron(II) In dichloromethane at 0℃; for 24h; Green chemistry;A 82%
B 20%
7,22-dihydro-8,21-dioxa-tetranaphtho<2,1-b:1',2'-d:2'',1''-h:1''',2'''-j>cyclododecene
172748-15-1, 172824-34-9, 176199-86-3

7,22-dihydro-8,21-dioxa-tetranaphtho<2,1-b:1',2'-d:2'',1''-h:1''',2'''-j>cyclododecene

A

2,2'-di(bromomethyl)-1,1'-binaphthalene
54130-90-4, 86631-56-3, 37803-02-4

2,2'-di(bromomethyl)-1,1'-binaphthalene

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With boron tribromide In dichloromethane for 1h; 0 deg C - room temperature;A 66.6%
B 81.1%
With boron tribromide In dichloromethane for 1h; 0 deg C - room temperature;A 54.5%
B 72.7%
1-bromo-2-naphthol
573-97-7

1-bromo-2-naphthol

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With carbon dioxide; zinc; palladium on activated charcoal In water at 20℃; under 7500.6 Torr; for 48h; Ullmann coupling;81%
With copper at 230℃;
With copper
Multi-step reaction with 5 steps
1: sodium hydride / N,N-dimethyl-formamide
2: sulfuryl dichloride / dichloromethane
3: potassium carbonate / N,N-dimethyl-formamide
4: 1,10-Phenanthroline; potassium tert-butylate / pyridine / 4 h / 120 °C / Microwave irradiation; Inert atmosphere
5: hydrogenchloride / ethanol; water / 3 h / 50 °C
View Scheme
3-hydroxy-2-naphthoic acid methyl ester
883-99-8

3-hydroxy-2-naphthoic acid methyl ester

β-naphthol
135-19-3

β-naphthol

A

(aS)-methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate
128702-23-8, 145415-62-9, 145415-63-0

(aS)-methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With ytterbium(III) triflate; CuCl(OH)-TMEDA In tetrahydrofuran at 20℃; for 24h; Product distribution; Further Variations:; Reagents; Solvents; Catalysts; time;A 81%
B n/a
CuCl(OH)-TMEDA In tetrahydrofuran at 20℃; for 48h;
2,2′-bis(tert-butyldimethylsiloxy)-1,1′-binaphthalene
1618090-36-0

2,2′-bis(tert-butyldimethylsiloxy)-1,1′-binaphthalene

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With potassium hydrogen difluoride In methanol at 20℃; for 48h;79%
C35H26O2

C35H26O2

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -78℃; for 1h;78.7%
1-bromo-2-naphthol
573-97-7

1-bromo-2-naphthol

β-naphthol
135-19-3

β-naphthol

A

1-bromo-2'-hydroxy-2,1'-dinaphthyl ether
156835-40-4

1-bromo-2'-hydroxy-2,1'-dinaphthyl ether

B

(Naphthyl-(2))-(2-hydroxy-naphthyl-(1))-aether
172297-36-8

(Naphthyl-(2))-(2-hydroxy-naphthyl-(1))-aether

C

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With sodium hydroxide at 100℃; for 4h;A n/a
B n/a
C 77%
With sodium hydroxide In toluene at 100℃; for 4h; Product distribution; Mechanism; var. base stoichiometry, var. solvents, var. base cation; other 2-naphthols;
With sodium hydroxide at 100℃; for 4h; Title compound not separated from byproducts;
phenyl 2-hydroxy-3-naphthoate
7260-11-9

phenyl 2-hydroxy-3-naphthoate

β-naphthol
135-19-3

β-naphthol

A

phenyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

phenyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

B

diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate
170889-47-1

diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate

C

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With oxygen; (S,S)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); copper(l) chloride In tetrahydrofuran at 20℃; for 3h;A 72%
B n/a
C n/a
butyl 3-hydroxynaphthalene-2-carboxylate
7260-07-3

butyl 3-hydroxynaphthalene-2-carboxylate

β-naphthol
135-19-3

β-naphthol

A

Butyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate
145372-03-8

Butyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

B

2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylic acid dibutyl ester
145372-04-9

2,2'-Dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylic acid dibutyl ester

C

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With tert-butylamine; copper dichloride In isopropyl alcohol at 50℃; for 2h; Yields of byproduct given;A 71%
B n/a
C n/a
β-naphthol
135-19-3

β-naphthol

A

C20H12O2
1203550-09-7

C20H12O2

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With iron(III) chloride hexahydrate In toluene at 60℃; for 5h;A 15%
B 71%
4-(4-methylphenyl)morpholine
3077-16-5

4-(4-methylphenyl)morpholine

β-naphthol
135-19-3

β-naphthol

A

1-(5-methyl-2-morpholinophenyl)naphthalen-2-ol
1415461-03-8

1-(5-methyl-2-morpholinophenyl)naphthalen-2-ol

B

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Conditions
ConditionsYield
With methanesulfonic acid; 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluorophthalocyaninato-iron(II) In dichloromethane at 0℃; for 24h; Green chemistry;A 71%
B 34%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

dinaphtho[2,1-b;1',2'-d]furan
194-63-8

dinaphtho[2,1-b;1',2'-d]furan

Conditions
ConditionsYield
zeolite HSZ-360 In various solvent(s) for 5h; Heating;100%
With HY zeolite In 1,2-dichloro-benzene at 180℃; for 4h;94%
In toluene Reflux; Acidic conditions;94%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol
79082-80-7

(S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol

Conditions
ConditionsYield
With bromine In acetonitrile at 0℃; for 3h;100%
With bromine In acetonitrile at 0℃; for 2.5h;99%
With bromine at -78℃;99.9%
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene
173831-50-0

rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene

Conditions
ConditionsYield
Stage #1: 1,1'-bi-2-naphthol With sodium hydride In tetrahydrofuran at 0 - 20℃;
Stage #2: chloromethyl methyl ether In tetrahydrofuran at 20℃; for 4.5h;
100%
With sodium hydride In tetrahydrofuran at 20℃; for 4h;98%
Stage #1: 1,1'-bi-2-naphthol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 1h; Inert atmosphere;
Stage #2: chloromethyl methyl ether In N,N-dimethyl-formamide at 0 - 20℃; for 5h; Inert atmosphere;
95%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl
141807-44-5, 126613-06-7, 128544-05-8, 128575-34-8

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl

Conditions
ConditionsYield
With pyridine In dichloromethane at 0℃; for 6h;100%
With 2,6-dimethylpyridine; dmap In dichloromethane99%
With pyridine In dichloromethane at 20℃; for 6h;99%
acetic anhydride
108-24-7

acetic anhydride

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2,2'-diacetoxy-1,1'-binaphthyl
100569-82-2, 101758-48-9, 69677-98-1

2,2'-diacetoxy-1,1'-binaphthyl

Conditions
ConditionsYield
zeolite HSZ-360 In neat (no solvent) at 60℃; for 12h;100%
With sodium hydroxide at 0 - 5℃; for 0.5h;98.6%
With N,N'-diiodo-N,N'-1,2-ethanediylbis(p-toluenesulphonamide) at 80℃; for 0.25h; neat (no solvent);97%
allyl methyl carbonate
35466-83-2

allyl methyl carbonate

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2,2'-bis(2-propenyloxy)-1,1'-binaphthyl
59031-18-4

2,2'-bis(2-propenyloxy)-1,1'-binaphthyl

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran at 25℃; for 24h; Condensation;100%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(Ra)-5,6,7,8,5',6',7',8'-octahydro-[1,1']binaphthalenyl-2,2'-diol
39648-74-3, 65355-00-2, 65355-14-8

(Ra)-5,6,7,8,5',6',7',8'-octahydro-[1,1']binaphthalenyl-2,2'-diol

Conditions
ConditionsYield
With hydrogen; Ru on alumina support In ethanol at 100℃; under 37503.8 - 45004.5 Torr; for 3h; Product distribution / selectivity;100%
With hydrogen; 5%-palladium/activated carbon In ethanol at 50 - 100℃; under 37503.8 - 60006 Torr; for 0.5 - 5.5h; Product distribution / selectivity;98%
With hydrogen; 5%-palladium/activated carbon In ethanol at 70℃; under 37503.8 - 45004.5 Torr; Conversion of starting material;98%
With hydrogen; Ru/C In ethanol at 50 - 70℃; under 37503.8 - 45004.5 Torr; for 0.5 - 1.5h; Product distribution / selectivity;98%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl
141807-44-5, 126613-06-7, 128544-05-8, 128575-34-8

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl

Conditions
ConditionsYield
100%
2,6-dimethylpyridine
108-48-5

2,6-dimethylpyridine

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl
141807-44-5, 126613-06-7, 128544-05-8, 128575-34-8

(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl

Conditions
ConditionsYield
With dmap; trifluoromethanesulfonic acid anhydride In dichloromethane100%
With dmap; trifluoromethanesulfonic acid anhydride In dichloromethane100%
benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2-hydroxy-2'-phenylsulfonyloxy-1,1-binaphthyl
1414774-25-6, 904313-68-4, 938192-82-6

2-hydroxy-2'-phenylsulfonyloxy-1,1-binaphthyl

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃;100%
2-formylbenzene boronic acid
40138-16-7

2-formylbenzene boronic acid

(R)-1-Phenylethylhydroxylamine
2912-98-3

(R)-1-Phenylethylhydroxylamine

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

C35H26BNO3

C35H26BNO3

Conditions
ConditionsYield
With magnesium sulfate; caesium carbonate In chloroform-d1 for 0.25h;100%
dichloro(thiophene-2-yl)phosphine
1726-72-3

dichloro(thiophene-2-yl)phosphine

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(1,1′-bi-2-naphthol(-2H))P(C4H3S)
1470071-95-4

(1,1′-bi-2-naphthol(-2H))P(C4H3S)

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 1h;100%
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(±)-1,1′-binaphthyl-2-2′-diyl dimetacrylate
159701-51-6, 96499-45-5

(±)-1,1′-binaphthyl-2-2′-diyl dimetacrylate

Conditions
ConditionsYield
With phosphoric acid; trifluoroacetic anhydride In water at 20℃; for 0.25h;100%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(R)-6,6'-dibromo-1,1'-binaphth-2-ol
65283-60-5

(R)-6,6'-dibromo-1,1'-binaphth-2-ol

Conditions
ConditionsYield
With bromine In dichloromethane at -78℃;100%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxathiepine 4,4-dioxide

dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxathiepine 4,4-dioxide

Conditions
ConditionsYield
With fluorosulfonyl fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; Sealed tube;100%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

C20H8(2)H6O2

C20H8(2)H6O2

Conditions
ConditionsYield
With perchloric acid; chloroform-d1; d(4)-methanol at 95℃; for 96h; Inert atmosphere;100%
bromoacetic acid
79-08-3

bromoacetic acid

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

Binaphtho-2,2'-diessigsaeure
112463-20-4, 51751-91-8, 119292-01-2

Binaphtho-2,2'-diessigsaeure

Conditions
ConditionsYield
With potassium carbonate In methanol for 6h; Heating;99.6%
With potassium carbonate In methanol
2,2'-di(bromomethyl)-1,1'-binaphthalene
54130-90-4, 86631-56-3, 37803-02-4

2,2'-di(bromomethyl)-1,1'-binaphthalene

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

A

7,22-dihydro-8,21-dioxa-tetranaphtho<2,1-b:1',2'-d:2'',1''-h:1''',2'''-j>cyclododecene
172748-15-1, 172824-34-9, 176199-86-3

7,22-dihydro-8,21-dioxa-tetranaphtho<2,1-b:1',2'-d:2'',1''-h:1''',2'''-j>cyclododecene

C42H28O2

C42H28O2

Conditions
ConditionsYield
With caesium carbonate In acetone for 24h; Heating;A 99.3%
B 98.9%
allyl bromide
106-95-6

allyl bromide

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2,2'-bis(2-propenyloxy)-1,1'-binaphthyl
59031-18-4

2,2'-bis(2-propenyloxy)-1,1'-binaphthyl

Conditions
ConditionsYield
With potassium carbonate In acetone for 24h; Reflux;99%
With potassium carbonate for 0.0666667h; Microwave irradiation;95%
With potassium carbonate In acetone
tris(bis(trimethylsilyl)amido)ytterbium(III)

tris(bis(trimethylsilyl)amido)ytterbium(III)

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(Li(THF)2)3Yb(1,1'-(C10H6-2-O)2)3

(Li(THF)2)3Yb(1,1'-(C10H6-2-O)2)3

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran; diethyl ether; hexane byproducts: HN(SiMe3)2; under anaerobic cond., 1 equiv. of n-BuLi in n-hexane was added to THF-soln. of naphthole-compd. at 0 °C, 1/3 equiv. of rare-earth compd.was added in Et2O to this soln., stirring at 0 °C for ca. 10 min; solvent was removed in vac., solid was recrystd. from THF-petroleum ether at -20 °C, elem. anal.;99%
bis(trimethylsilyl)amide yttrium(III)

bis(trimethylsilyl)amide yttrium(III)

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(Li(THF)2)3Y(1,1'-(C10H6-2-O)2)3

(Li(THF)2)3Y(1,1'-(C10H6-2-O)2)3

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran; diethyl ether; hexane byproducts: HN(SiMe3)2; under anaerobic cond., 1 equiv. of n-BuLi in n-hexane was added to THF-soln. of naphthole-compd. at 0 °C, 1/3 equiv. of rare-earth compd.was added in Et2O to this soln., stirring at 0 °C for ca. 10 min; solvent was removed in vac., solid was recrystd. from THF-petroleum ether at -20 °C;99%
With n-BuLi In tetrahydrofuran; diethyl ether; hexane byproducts: HN(SiMe3)2; under anaerobic cond., 1 equiv. of n-BuLi in n-hexane was added to THF-soln. of naphthole-compd. at 0 °C, 1/3 equiv. of rare-earth compd.was added in Et2O to this soln., stirring at 0 °C for ca. 10 min; solvent was removed in vac., solid was recrystd. from THF-petroleum ether at -20 °C, elem. anal.;99%
tris(bis(trimethylsilyl)amido)europium(III)

tris(bis(trimethylsilyl)amido)europium(III)

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(Li(THF)2)3Eu(1,1'-(C10H6-2-O)2)3

(Li(THF)2)3Eu(1,1'-(C10H6-2-O)2)3

Conditions
ConditionsYield
With t-BuLi In tetrahydrofuran; diethyl ether; hexane byproducts: HN(SiMe3)2; under anaerobic cond., 1 equiv. of t-BuLi in hexane was added to THF-soln. of naphthole-compd. at 0 °C, 1/3 equiv. rare-earth compd. was added in Et2O to this soln., stirring at 0 °C for ca. 10 min; solvent was removed in vac., solid was recrystd. from THF-petroleum ether at -20 °C;99%
tris(bis(trimethylsilyl)amido)praseodymium(III)

tris(bis(trimethylsilyl)amido)praseodymium(III)

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(Li(THF)2)3Pr(1,1'-(C10H6-2-O)2)3

(Li(THF)2)3Pr(1,1'-(C10H6-2-O)2)3

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran; diethyl ether; hexane byproducts: HN(SiMe3)2; under anaerobic cond., 1 equiv. of n-BuLi in n-hexane was added to THF-soln. of naphthole-compd. at 0 °C, 1/3 equiv. of rare-earth compd.was added in Et2O to this soln., stirring at 0 °C for ca. 10 min; solvent was removed in vac., solid was recrystd. from THF-petroleum ether at -20 °C, elem. anal.;99%
Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2,2'-diphenoxy-1,1'-binaphthalene

2,2'-diphenoxy-1,1'-binaphthalene

Conditions
ConditionsYield
Stage #1: 1,1'-bi-2-naphthol With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.25h;
Stage #2: Diphenyliodonium triflate In tetrahydrofuran at 40℃; for 0.75h;
99%
Stage #1: 1,1'-bi-2-naphthol With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.25h;
Stage #2: Diphenyliodonium triflate In tetrahydrofuran at 40℃; for 0.75h;
99%
With sodium hydroxide In water at 20 - 50℃; for 17.5h;98%
1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

1,1'-binaphthyl-2,2'-diyl sulfite
1326309-92-5, 1334180-26-5, 236401-85-7

1,1'-binaphthyl-2,2'-diyl sulfite

Conditions
ConditionsYield
With thionyl chloride; triethylamine In diethyl ether at 0℃;99%
With pyridine; thionyl chloride In diethyl ether at 0℃; for 3h; Inert atmosphere;99%
benzoic acid
65-85-0

benzoic acid

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

(±)-1,1′-binaphthyl-2-2′-diyl dibenzoate
53545-44-1

(±)-1,1′-binaphthyl-2-2′-diyl dibenzoate

Conditions
ConditionsYield
With phosphoric acid; trifluoroacetic anhydride In water at 20℃; for 0.25h;99%
Diphenyliodonium fluoride

Diphenyliodonium fluoride

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

2,2'-diphenoxy-1,1'-binaphthalene

2,2'-diphenoxy-1,1'-binaphthalene

Conditions
ConditionsYield
With sodium hydrogencarbonate In dichloromethane at 40℃;99%
1-iodo-butane
542-69-8

1-iodo-butane

carbon monoxide
201230-82-2

carbon monoxide

1,1'-bi-2-naphthol
602-09-5

1,1'-bi-2-naphthol

<1,1'-Binaphthalene>-2,2'-diol dipentanoate
100465-51-8, 110902-38-0

<1,1'-Binaphthalene>-2,2'-diol dipentanoate

Conditions
ConditionsYield
With rhodium(III) chloride; 1,3-bis-(diphenylphosphino)propane; sodium carbonate; sodium bromide In 1,4-dioxane at 120℃; under 750.075 Torr; for 24h; Inert atmosphere; chemoselective reaction;99%

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