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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
4,6-di-tert-Butyl-2-methylphenolAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:An important raw material and intermediate used in Organic Synthesis, Pharmaceuticals Transportatio
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inquiryPhenol,2,4-bis(1,1-dimethylethyl)-6-methyl-Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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inquiry4,6-DI-TERT-BUTYL-2-METHYLPHENOL Basic information Product Name: 4,6-DI-TERT-BUTYL-2-METHYLPHENOL Synonyms: 2,4-bis(1
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product name:4,6-di-tert-butyl-o-cresol;2,4-bis(1,1-dimethylethyl)-6-methyl-pheno;2,4-bis~(1,1-dimethylethyl)-6-methyl-phenol;2,4-bis(1,1-dimethylethy… Package:in 180kg/galvanized dum
high purity Application:Drug intermediates Materials intermediates and active molecules
2,4-di-tert-butyl-6-hydroxymethylphenol
A
2,4-di-tert-butyl-6-methylphenol
B
6,6'-(ethane-1,2-diyl)bis(2,4-di-tert-butylphenol)
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran; chlorobenzene for 4h; Heating; | A 68% B 16% |
With lithium aluminium tetrahydride In tetrahydrofuran; chlorobenzene for 4h; Heating; | A 10% B 66% |
ortho-cresol
tert-butyl alcohol
A
2-Methyl-4-t-butylphenol
B
2-tert-Butyl-6-methylphenol
C
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With carbon tetrabromide at 175℃; for 6h; Sealed tube; | A 68% B 3% C 27% |
With carbon tetrabromide at 175℃; for 6h; Sealed tube; | A 39% B 8% C 51% |
2,4-di-tert-butyl-6-methylaniline hydrochloride
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite |
Conditions | Yield |
---|---|
With aluminium trichloride at 105℃; |
Conditions | Yield |
---|---|
With sulfuric acid | |
With sulfuric acid In benzene |
Conditions | Yield |
---|---|
With sulfuric acid |
t-butyl bromide
6-acetoxy-2-tert-butyl-6-methyl-cyclohexa-2,4-dienone
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
In diethyl ether |
ortho-cresol
isobutene
A
2-Methyl-4-t-butylphenol
B
2-tert-Butyl-6-methylphenol
C
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With aluminium(III) phenoxide at 100℃; for 2h; |
2-Methyl-4-t-butylphenol
2-tert-Butyl-6-methylphenol
A
2,4-di-tert-butyl-6-methylphenol
B
ortho-cresol
Conditions | Yield |
---|---|
In neat (no solvent) at 79.9 - 179.9℃; Equilibrium constant; effect of temperature; |
2,6-di-tert-butyl-4-methyl-phenol
ortho-cresol
A
p-cresol
B
2-tert-Butyl-4-methylphenol
C
2-tert-Butyl-6-methylphenol
D
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
sulfuric acid at 80℃; for 8h; Yield given. Further byproducts given. Yields of byproduct given; |
2,6-di-tert-butyl-4-methyl-phenol
ortho-cresol
A
2-Methyl-4-t-butylphenol
B
2-tert-Butyl-4-methylphenol
C
2-tert-Butyl-6-methylphenol
D
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
sulfuric acid at 80℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given; | |
sulfuric acid at 80℃; for 2h; Yield given. Further byproducts given. Yields of byproduct given; |
aluminium trichloride
tertiary butyl chloride
ortho-cresol
A
2-Methyl-4-t-butylphenol
B
2-tert-Butyl-6-methylphenol
C
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
at 105℃; |
sulfuric acid
ortho-cresol
isobutene
A
2-Methyl-4-t-butylphenol
B
2-tert-Butyl-6-methylphenol
C
2,4-di-tert-butyl-6-methylphenol
2,2-dimethyl-3-butyne
A
(3E)-5,5-dimethylhex-3-en-2-one
B
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
In hexane at 70 - 80℃; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: CHCl3 2: diethyl ether View Scheme |
2,4-di-tert-butyl-6-methylphenol
2-bromo-1,5-di-tert-butyl-3-methyl-benzene
Conditions | Yield |
---|---|
With trimethyl phosphite; bromine at 60 - 65℃; for 11h; | 95% |
Conditions | Yield |
---|---|
With titanium(IV) isopropylate at 80℃; for 6h; | 84.4% |
furan
2,4-di-tert-butyl-6-methylphenol
2,4-di-tert-butyl-6-(2-furyl)-6-methylcyclohexa-2,4-dien-1-one
Conditions | Yield |
---|---|
With [bis(acetoxy)iodo]benzene In 1,1,1,3',3',3'-hexafluoro-propanol at 0℃; for 0.0388889h; oxidative Friedel Crafts reaction; regioselective reaction; | 72% |
2,4-di-tert-butyl-6-methylphenol
methoxybenzene
4,6-di-tert-butyl-4'-methoxy-2-methylbiphenyl-3-ol
Conditions | Yield |
---|---|
With bis-[(trifluoroacetoxy)iodo]benzene In 1,1,1,3',3',3'-hexafluoro-propanol at 0℃; for 0.0388889h; oxidative Friedel Crafts reaction; | 67% |
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With Oxone; sodium hydrogencarbonate In water; acetone at 20℃; for 1h; | 67% |
2,4-di-tert-butyl-6-methylphenol
5,7-di-t-butyl-1-oxaspiro<2.5>octa-5,7-dien-4-one
Conditions | Yield |
---|---|
With sodium hypochlorite pentahydrate; tetra-(n-butyl)ammonium iodide In ethyl acetate at 25℃; for 0.5h; Green chemistry; chemoselective reaction; | 63% |
2,4-di-tert-butyl-6-methylphenol
A
3,5-di-tert-butyl-2-hydroxybenzaldehyde
B
3,5-di-tert-butyl-2-hydroxybenzyl bromide
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dimethyl sulfoxide at 120℃; Oxidation; | A 54% B n/a |
Conditions | Yield |
---|---|
With 2,2,2-trifluoroethanol; [bis(acetoxy)iodo]benzene at 20℃; for 0.25h; Hosomi-Sakurai reaction; | 42% |
2,4-di-tert-butyl-6-methylphenol
2,4-di-t-butyl-6-methyl-4-nitrocyclohexa-2,5-dienone
Conditions | Yield |
---|---|
With nitric acid In acetic acid at 5℃; | 40% |
With nitric acid In acetic acid | 577 mg |
tert.-butylhydroperoxide
2,4-di-tert-butyl-6-methylphenol
A
2,4-di-tert-butyl-6-tert-butylperoxy-6-methyl-cyclohexa-2,4-dienone
Conditions | Yield |
---|---|
With cobalt naphthenate; benzene |
2,4-di-tert-butyl-6-methylphenol
2,4-di-tert-butyl-6-methyl-cyclohexanone
Conditions | Yield |
---|---|
With nickel at 160 - 180℃; under 110326 Torr; Hydrogenation; | |
(i) H2, Raney-Ni, (ii) Na2Cr2O7; Multistep reaction; |
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With nickel at 185 - 220℃; under 110326 - 117681 Torr; Hydrogenation; |
2,4-di-tert-butyl-6-methylphenol
2,4-di-tert-butyl-6-methylphenol
6,8,3',5'-tetra-tert-butyl-spiro[chroman-2,1'-cyclohexa-3',5'-dien]-2'-one
Conditions | Yield |
---|---|
With silver(l) oxide; benzene |
2,4-di-tert-butyl-6-methylphenol
phenyl isocyanate
phenyl-carbamic acid-(2,4-di-tert-butyl-6-methyl-phenyl ester)
Conditions | Yield |
---|---|
With Petroleum ether |
Conditions | Yield |
---|---|
With ethanol; sodium methylate |
Conditions | Yield |
---|---|
With sodium hydroxide at 80 - 85℃; |
2,4-di-tert-butyl-6-methylphenol
Conditions | Yield |
---|---|
With potassium tert-butylate; oxygen |
2,4-di-tert-butyl-6-methylphenol
(15N)-2,4-di-t-butyl-6-methyl-4-nitrocyclohexa-2,5-dienone
Conditions | Yield |
---|---|
With [15N]-nitric acid In acetic acid at 5℃; Yield given; |
2,4-di-tert-butyl-6-methylphenol
2,4-di-t-butyl-c-6-hydroxy-6-methyl-r-2,c-5-dinitrocyclohex-3-enone
2,4-di-t-butyl-r-2-hydroxy-6-methyl-t-5,c-6-dinitrocyclohex-3-enone
2,4-di-t-butyl-6-methyl-r-2,c-5,t-6-trinitrocyclohex-3-enone
2,4-di-t-butyl-6-methyl-r-2,t-5,c-6-trinitrocyclohex-3-enone
Conditions | Yield |
---|---|
With Nitrogen dioxide In benzene at 20℃; for 5h; Yield given. Further byproducts given. Yields of byproduct given; |
2,4-di-tert-butyl-6-methylphenol
2,4-di-t-butyl-r-2-hydroxy-6-methyl-t-5,c-6-dinitrocyclohex-3-enone
2,4-di-t-butyl-r-2-hydroxy-6-methyl-t-5,t-6-dinitrocyclohex-3-enone
2,4-di-t-butyl-6-methyl-r-2,c-5,t-6-trinitrocyclohex-3-enone
2,4-di-t-butyl-6-methyl-r-2,t-5,c-6-trinitrocyclohex-3-enone
Conditions | Yield |
---|---|
With Nitrogen dioxide In benzene at 20℃; for 5h; Yield given. Further byproducts given. Yields of byproduct given; |
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