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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 3-(Methylamino)toluene 99%min TOP1 supplier in China

Cas:696-44-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply N-methyl-m-toluidine

Cas:696-44-6

Min.Order:1

Negotiable

Type:Other

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:5 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

3-(Methylamino)toluene Basic information Product Name: 3-(Methylamino)toluene Synonyms: Aniline, N,m-dimethyl-;m,N-Dimethylaniline;m-Toluidine, N-methyl-;n,3-dimethyl-benzenamin;N,3-Dime

696-44-6

Cas:696-44-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3-(Methylamino)toluene 696-44-6

Cas:696-44-6

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 696-44-6 with best quality

Cas:696-44-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

N-Methyl-m-toluidine/methylaniline 696-44-6 factory wholesale/high quality/liquid

Cas:696-44-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Antimex Chemical Limied

ProName: High purity Dimethyl with good quality... CasNo: 67-68-5 Molecular Formula: C2H6OS Appearance: colorless clear liquid Application: Wide use in industry DeliveryTime: Prompt PackAge: 25kg/drum Port: Shanghai,

N-Methyl-M-toluidine

Cas:696-44-6

Min.Order:1 Metric Ton

FOB Price: $2.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-(Methylamino)toluene 696-44-6

Cas:696-44-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

3-(Methylamino)toluene CAS: 696-44-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

3-(Methylamino)toluene CAS: 696-44-6

Cas:696-44-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

N-Methyl-M-toluidine CAS NO.696-44-6

Cas:696-44-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

Molecular Formula C8H11N Molar Mass 121.18 Density 0.957g/mLat 25°C(lit.) Melting Point -10.08°C (estimate) Boling Point 204-206°C5mm Hg(lit.) Flash Point 194°F

manufacturer 3-(Methylamino)toluene Hot sale 696-44-6

Cas:696-44-6

Min.Order:1 Gram

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: N-Methyl-M-Toluidine CAS No.:696-44-6 Molecule Formula:C8H11N Molecule Weight:121.18 Purity: 99.0% Package: 200kg/drum Description:Colorless to light yellow liquid Manufacture Standards:Enterprise Standard

Best Quality N-Methyl-M-Toluidine

Cas:696-44-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 3-(Methylamino)toluene Synonyms: Aniline, N,m-dimethyl-;m,N-Dimethylaniline;m-Toluidine, N-methyl-;n,3-dimethyl-benzenamin;N,3-Dimethylbenzenamine;N-METHYL-M-TOLUIDINE;N-METHYL-3-TOLUIDINE;N,3-DIMETHYLANILINE CAS: 696-44-6 MF:

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

N-methyl-m-toluidine CAS 696-44-6

Cas:696-44-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

N-methyl-m-toluidine CAS 696-44-6

Cas:696-44-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Pale yellow oily liquid Storage:sealed and stored Package:200 kg / drum Application:As dye intermediates Transportation:by air or by sea or by Express Port:Shanghai, Ningbo, Tianjin,

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:1 Gram

Negotiable

Type:Trading Company

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

N-methyl-m-toluidine CAS 696-44-6

Cas:696-44-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

N-Methyl-m-methylaniline

Cas:696-44-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

99%

3-(Methylamino)toluene

Cas:696-44-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

N-Methyl-m-toluidine

Cas:696-44-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methanol
67-56-1

methanol

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With C31H30ClIrN3O(1+)*F6P(1-); potassium tert-butylate at 130℃; for 12h;98%
With C19H37IrN4(2+)*2I(1-); potassium carbonate at 120℃; for 17h; Inert atmosphere; Schlenk technique; Sealed tube;90%
With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃;
With hydrogen at 55℃; under 750.075 Torr; for 36h; Irradiation; Green chemistry;
With C19H24ClN2Ru; sodium hydroxide at 60℃; for 22h;99 %Chromat.
3-methyl-N-methylacetanilide
579-12-4

3-methyl-N-methylacetanilide

A

N-ethyl-N-methyl-3-methylaniline
15258-50-1

N-ethyl-N-methyl-3-methylaniline

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With triethyl borane; Triethoxysilane; sodium hydroxide In hexane at 80℃; for 6h; Reagent/catalyst; Solvent; Inert atmosphere; Sealed tube;A 2%
B 95%
Stage #1: 3-methyl-N-methylacetanilide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;
Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;
A 78%
B 11%
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 6h; Inert atmosphere; Schlenk technique; High pressure; Sealed tube;A n/a
B 72%
formaldehyd
50-00-0

formaldehyd

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
Stage #1: formaldehyd; 1-amino-3-methylbenzene With sodium methylate In methanol at 65℃; for 1h;
Stage #2: With sodium tetrahydroborate at 65℃; for 1.5h;
93%
With sodium tetrahydroborate; sodium methylate In methanol 1) room temp., 5 h, 2) reflux;89%
With methanol; sodium tetrahydroborate; sodium at 60℃; for 2h;82%
methanol
67-56-1

methanol

1-methyl-3-nitrobenzene
99-08-1

1-methyl-3-nitrobenzene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With potassium tert-butylate at 130℃; for 24h; Sealed tube;93%
With [(N,N′-bis(diisopropylphosphino)-2,6-diaminopyridine)Mn(CO)3][Br]; potassium hydroxide at 110℃; for 16h; Molecular sieve; Sealed tube;80%
With [Ru(2-(6-methoxypyridin-2-yl)-1,10-phenanthroline)(MeCN)2Cl]Cl; sodium methylate at 110℃; for 12h; Green chemistry;87 %Chromat.
With platinum on carbon; potassium tert-butylate; hydrogen at 150℃; under 1500.15 Torr; for 24h; Autoclave;93 %Chromat.
mercaptoacetic acid
68-11-1

mercaptoacetic acid

N-methyl-N-nosyl-m-toluidine
211676-01-6

N-methyl-N-nosyl-m-toluidine

A

2-(4-nitrophenylthio)acetic acid
3406-75-5

2-(4-nitrophenylthio)acetic acid

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃;A n/a
B 92%
3-Iodotoluene
625-95-6

3-Iodotoluene

methylamine
74-89-5

methylamine

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 25℃; for 24h; Inert atmosphere;90%
methanol
67-56-1

methanol

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

A

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With copper(I) oxide; hydrogenchloride; titanium(IV) oxide In water for 6h; UV-irradiation;A 83%
B 15%
With aluminum oxide at 350 - 400℃;
tert-butyl-methyl-3-tolylcarbamate

tert-butyl-methyl-3-tolylcarbamate

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 25℃;83%
With trifluoroacetic acid In dichloromethane at 40℃; for 48h; Inert atmosphere; Schlenk technique;
With hydrogenchloride In water at 120℃;
1-methylamino-2-methyl-4,6-diphenylpyridinium tetrafluoroborate

1-methylamino-2-methyl-4,6-diphenylpyridinium tetrafluoroborate

A

2-methyl-4,6-diphenyl-pyridine
1912-16-9

2-methyl-4,6-diphenyl-pyridine

B

N-methyl-p-toluidine
623-08-5

N-methyl-p-toluidine

C

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

D

N,2-dimethylaniline
611-21-2

N,2-dimethylaniline

Conditions
ConditionsYield
In trifluoroacetic acid for 17h; Ambient temperature; Irradiation;A 81%
B n/a
C n/a
D n/a
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

A

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With 0.72KNaX-BS zeolite at 150℃; for 1h; Temperature;A 77%
B 22%
With NaY-BS zeolite at 150℃; for 1h;A 32%
B 43%
methanol
67-56-1

methanol

3-methylbenzoyl azide
71313-13-8

3-methylbenzoyl azide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
Stage #1: methanol; 3-methylbenzoyl azide at 70℃; for 3h; Inert atmosphere;
Stage #2: With C54H43ClN3P2Ru(1+)*F6P(1-); potassium carbonate at 140℃; Inert atmosphere;
77%
3-methyl-N-methylacetanilide
579-12-4

3-methyl-N-methylacetanilide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;72%
With hydrogenchloride In water; ethylene glycol at 20℃; for 3h; Inert atmosphere;
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With 0.94 HY-BS zeolite at 150℃; for 1h;67%
With binder-free FeHY-mmm zeolite In neat (no solvent) Sealed tube;
tert-butyl 1-allyl-2-methyl-2-(m-tolyl)hydrazinecarboxylate

tert-butyl 1-allyl-2-methyl-2-(m-tolyl)hydrazinecarboxylate

A

(E)-tert-butyl (3-(methyl(m-tolyl)amino)prop-1-en-1-yl)carbamate

(E)-tert-butyl (3-(methyl(m-tolyl)amino)prop-1-en-1-yl)carbamate

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 3h; [1,2]-Wittig Rearrangement;A 62%
B 9%
N-methyl-N-phenylpropanamide
5827-78-1

N-methyl-N-phenylpropanamide

A

N-methyl-N-n-propylaniline
13395-54-5

N-methyl-N-n-propylaniline

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
Stage #1: N-methyl-N-phenylpropanamide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;
Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;
A 61%
B 11%
methylamine
74-89-5

methylamine

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With copper In water at 100℃;52%
1-methoxy-2,6-dimethylpyridinium methyl sulfate
87117-15-5

1-methoxy-2,6-dimethylpyridinium methyl sulfate

A

2,6-dimethylpyridine
108-48-5

2,6-dimethylpyridine

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With Dimethylammonium sulphite In water at 150℃; for 24h;A 20%
B 42%
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

methyl iodide
74-88-4

methyl iodide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
man befreit das Produkt durch Ausfaellen seiner aether.Loesung mit Schwefelsaeure vom Toluidin, dampft die aether.Loesung ein, erhitzt den Rueckstand mit Eissigsaeureanhydrid und verseift das entstandene N-Methyl-;
Stage #1: 1-amino-3-methylbenzene With n-butyllithium In tetrahydrofuran; hexane at -40℃; for 0.25h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; hexane at -60 - 20℃; for 8h; Inert atmosphere;
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

methyl iodide
74-88-4

methyl iodide

A

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

trimethyl orthoformate
149-73-5

trimethyl orthoformate

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With sulfuric acid unter Entfernen des entstehenden Methanols auf 180grad und Erhitzen des danach isolierten Reaktionsprodukts mit wss.Salzsaeure;
N-methyl-N-(3-methylphenyl)carboxamide
39970-42-8

N-methyl-N-(3-methylphenyl)carboxamide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With water Heating; Yield given;
With hydrogenchloride In water at 100℃; for 2.5h;
N-methyl-N-(3-methylphenyl)carboxamide
39970-42-8

N-methyl-N-(3-methylphenyl)carboxamide

A

formate
71-47-6

formate

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With sodium hydroxide In water at 30℃; Rate constant; Mechanism; also aq. DMSO;
3-methyl-N-methylacetanilide
579-12-4

3-methyl-N-methylacetanilide

A

acetate
71-50-1

acetate

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With sodium hydroxide In water; dimethyl sulfoxide at 90℃; Rate constant; Mechanism;
(Dimethoxy-phenyl-methyl)-methyl-m-tolyl-amine
79431-18-8

(Dimethoxy-phenyl-methyl)-methyl-m-tolyl-amine

A

α,α-dimethoxybenzyl cation
38092-03-4, 102651-95-6

α,α-dimethoxybenzyl cation

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With water In 1,4-dioxane at 25℃; Rate constant;
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

Acetic formic anhydride
2258-42-6

Acetic formic anhydride

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With dimethylsulfide borane complex 1) THF, r.t., 2 h, 2) THF, reflux, 3 h; Multistep reaction;
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With dimethylsulfide borane complex 1.) THF, RT, 2h, 2.) THF, reflux, 3 h; Multistep reaction;
Multi-step reaction with 3 steps
1: benzene / Heating
2: anhydrous potassium carbonate, sodium hydroxide, tetrabutylammonium hydrogensulphate / benzene / 1 h / 5 - 10 °C / Heating
3: water / Heating
View Scheme
Multi-step reaction with 3 steps
1.1: tert-butyl alcohol / 24 h / 40 °C / Inert atmosphere; Schlenk technique
2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.33 h / 0 °C / Inert atmosphere; Schlenk technique
2.2: 20 °C / Inert atmosphere; Schlenk technique
3.1: trifluoroacetic acid / dichloromethane / 48 h / 40 °C / Inert atmosphere; Schlenk technique
View Scheme
3-Methylacetanilide
537-92-8

3-Methylacetanilide

dimethyl sulfate
77-78-1

dimethyl sulfate

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride 1.) benzene, water, 30 min, 2.) 2 h.; Multistep reaction;
methanol
67-56-1

methanol

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

aluminium oxide

aluminium oxide

A

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
at 350 - 400℃;
N-m-tolyl-glycine nitrile

N-m-tolyl-glycine nitrile

A

N-(2-aminoethyl)-3-methylaniline
14088-79-0

N-(2-aminoethyl)-3-methylaniline

B

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

3-methyl-N-nitroso-N-methylaniline
17485-25-5

3-methyl-N-nitroso-N-methylaniline

Conditions
ConditionsYield
With sodium azide In water; acetonitrile at 20℃;100%
With nitromethane; oxygen; copper(II) bis(trifluoromethanesulfonate); 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; for 20h; Sealed tube;63%
With hydrogenchloride; sodium nitrite at 0 - 5℃;2.5%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

4-bromo-N-methyl-N-(m-tolyl)benzamide

4-bromo-N-methyl-N-(m-tolyl)benzamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; Inert atmosphere;100%
With triethylamine In dichloromethane at 0 - 20℃;99%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

(S)-2,5-dihydropyrrole-1,2-dicarboxylic acid 1-tert-butyl ester
51154-06-4

(S)-2,5-dihydropyrrole-1,2-dicarboxylic acid 1-tert-butyl ester

tert-butyl (2S)-2-[methyl(m-tolyl)carbamoyl]-2,5-dihydropyrrole-1-carboxylate

tert-butyl (2S)-2-[methyl(m-tolyl)carbamoyl]-2,5-dihydropyrrole-1-carboxylate

Conditions
ConditionsYield
With pyridine; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 0 - 20℃; for 4h;100%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

Conditions
ConditionsYield
With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine In acetonitrile at -78℃; for 24h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation;100%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

N-methyl-N-(3-methylphenyl)carboxamide
39970-42-8

N-methyl-N-(3-methylphenyl)carboxamide

Conditions
ConditionsYield
With zinc(II) phthalocyanine; carbon dioxide; phenylsilane at 25℃; under 3750.38 Torr; for 6h; Autoclave; chemoselective reaction;99%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

N-(2-bromobenzyl)-N-methyl-m-tolylamine
436845-45-3

N-(2-bromobenzyl)-N-methyl-m-tolylamine

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 4h; Heating;98%
5-bromothiophene-2-carbonyl chloride
31555-60-9

5-bromothiophene-2-carbonyl chloride

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

5-bromo-N-methyl-N-(3-methylphenyl)thiophene-2-carboxamide
1252464-84-8

5-bromo-N-methyl-N-(3-methylphenyl)thiophene-2-carboxamide

Conditions
ConditionsYield
With triethylamine at 0℃; for 3h;97%
With triethylamine In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

4-amino-o-xylene
95-64-7

4-amino-o-xylene

Conditions
ConditionsYield
With aluminum oxide; aluminium trichloride for 0.0666667h; microwave irradiation;96%
carbon dioxide
124-38-9

carbon dioxide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N,N-dimethyl-m-toluidine
121-72-2

N,N-dimethyl-m-toluidine

Conditions
ConditionsYield
With diphenylsilane; caesium carbonate In acetonitrile at 80℃; under 750.075 Torr; for 72h; Schlenk technique; Inert atmosphere;95%
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry;93%
With dimanganese decacarbonyl; phenylsilane; C29H33N2P In acetonitrile at 100℃; under 750.075 Torr; for 15h;88%
3-(benzyloxy)-6-bromo-2,4,5-trimethylpyridine
1444336-77-9

3-(benzyloxy)-6-bromo-2,4,5-trimethylpyridine

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

5-(benzyloxy)-N,3,4,6-tetramethyl-N-m-tolylpyridin-2-amine

5-(benzyloxy)-N,3,4,6-tetramethyl-N-m-tolylpyridin-2-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene for 3h; Reflux;95%
carbon dioxide
124-38-9

carbon dioxide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N-methyl-N-(3-methylphenyl)carboxamide
39970-42-8

N-methyl-N-(3-methylphenyl)carboxamide

Conditions
ConditionsYield
With 1,10-Phenanthroline; phenylsilane; zinc diacetate In acetonitrile at 25℃; under 3750.38 Torr; for 4h; Autoclave;95%
With 2K(1+)*VOF4(2-)=K2{VOF4}; HSiPh3 In acetonitrile at 20℃; under 750.075 Torr; for 10h; Sealed tube; Autoclave;95%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 30℃; under 760.051 Torr; for 72h; Schlenk technique;93%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

trifluoroacetic acid
76-05-1

trifluoroacetic acid

N,3-dimethyl-N-(2,2,2-trifluoroethyl)aniline

N,3-dimethyl-N-(2,2,2-trifluoroethyl)aniline

Conditions
ConditionsYield
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique;95%
oct-1-ene
111-66-0

oct-1-ene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

3-methyl-N-(2-methyloctyl)aniline
1227053-80-6

3-methyl-N-(2-methyloctyl)aniline

Conditions
ConditionsYield
Stage #1: N-methyl-m-toluidine With N,N'-bis(2,6-dicyclopentyl-4-methoxyphenyl)formamidine; tetrabenzyl titanium at 20℃; for 0.333333h; Glovebox; Inert atmosphere;
Stage #2: oct-1-ene at 155℃; for 0.116667h; Sealed tube;
94%
With bis(indenyl)dimethyl-titanium In toluene at 105℃; for 24h; Inert atmosphere; regioselective reaction;84%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

C8H8(2)H3N

C8H8(2)H3N

Conditions
ConditionsYield
With water-d2; silver trifluoromethanesulfonate In chloroform-d1 at 90℃; for 18h; regioselective reaction;94%
styrene
292638-84-7

styrene

carbon monoxide
201230-82-2

carbon monoxide

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

(S)-N-methyl-2-phenyl-N-(m-tolyl)propanamide

(S)-N-methyl-2-phenyl-N-(m-tolyl)propanamide

Conditions
ConditionsYield
With C52H52NO5P; palladium(II) iodide In tetrahydrofuran at 20℃; under 38002.6 Torr; for 72h; Autoclave; enantioselective reaction;94%
cyanoacetic acid
372-09-8

cyanoacetic acid

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

2-cyano-N-methyl-N-(m-tolyl)acetamide

2-cyano-N-methyl-N-(m-tolyl)acetamide

Conditions
ConditionsYield
Stage #1: cyanoacetic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h;
Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane at 0 - 20℃;
93%
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃; for 1h; Inert atmosphere; Schlenk technique;81%
Stage #1: cyanoacetic acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 3h;
Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane; N,N-dimethyl-formamide at 0℃;
styrene
292638-84-7

styrene

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

3-methyl-N-(2-phenylpropyl)aniline
1041517-59-2

3-methyl-N-(2-phenylpropyl)aniline

Conditions
ConditionsYield
With pentakis(dimethylamido)tantalum In hexane at 140℃; for 96h; Inert atmosphere; Sealed tube; regioselective reaction;93%
formaldehyd
50-00-0

formaldehyd

C12H12N2O

C12H12N2O

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

C21H23N3O

C21H23N3O

Conditions
ConditionsYield
With C38H38N4O2Rh(1+)*F6P(1-) In acetonitrile at 20℃; for 7h; Mannich Aminomethylation; enantioselective reaction;93%
9-hydroxycalabaxanthone
35349-68-9

9-hydroxycalabaxanthone

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

C33H33NO7

C33H33NO7

Conditions
ConditionsYield
Stage #1: bis(trichloromethyl) carbonate; N-methyl-m-toluidine With triethylamine In dichloromethane at 20℃; for 4h; Cooling with ice;
Stage #2: 9-hydroxycalabaxanthone With dmap In dichloromethane at 20℃; Cooling with ice;
92%
N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

(+/-)-methyl 4-phenylbut-3-yn-2-yl carbonate

(+/-)-methyl 4-phenylbut-3-yn-2-yl carbonate

(R)-N,3-dimethyl-N-(4-phenylbut-3-yn-2-yl)aniline

(R)-N,3-dimethyl-N-(4-phenylbut-3-yn-2-yl)aniline

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); (R)-segphos In tert-Amyl alcohol at 60℃; for 48h; Glovebox; enantioselective reaction;91%
4-trifluoromethylbenzoic acid
455-24-3

4-trifluoromethylbenzoic acid

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N,3-dimethyl-N-(4-(trifluoromethyl)benzyl)aniline

N,3-dimethyl-N-(4-(trifluoromethyl)benzyl)aniline

Conditions
ConditionsYield
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique;90%
1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole
884866-01-7

1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N-methyl-2-phenyl-N-(m-tolyl)-N'-tosylacetimidamide

N-methyl-2-phenyl-N-(m-tolyl)-N'-tosylacetimidamide

Conditions
ConditionsYield
In toluene at 120℃; for 12h; Inert atmosphere;89%
Ethyl bromodifluoroacetate
667-27-6

Ethyl bromodifluoroacetate

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N-methyl-N-(3-methylphenyl)carboxamide
39970-42-8

N-methyl-N-(3-methylphenyl)carboxamide

Conditions
ConditionsYield
With water In N,N-dimethyl-formamide at 110℃; for 6h; Schlenk technique;89%
With copper (I) acetate; caesium carbonate; XPhos In N,N-dimethyl-formamide at 110℃; for 12h;79%
With copper (I) acetate; caesium carbonate; XPhos In water; N,N-dimethyl-formamide at 110℃; for 12h; Schlenk technique;79%
5-phenyl-3H-furan-2-one
1955-39-1

5-phenyl-3H-furan-2-one

N-methyl-m-toluidine
696-44-6

N-methyl-m-toluidine

N-methyl-N-(3-methylphenyl)-4-oxo-4-phenylbutanamide
1056199-48-4

N-methyl-N-(3-methylphenyl)-4-oxo-4-phenylbutanamide

Conditions
ConditionsYield
for 3h; Heating;87%

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