As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t
Cas:696-44-6
Min.Order:100 Gram
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:696-44-6
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inquiry3-(Methylamino)toluene Basic information Product Name: 3-(Methylamino)toluene Synonyms: Aniline, N,m-dimethyl-;m,N-Dimethylaniline;m-Toluidine, N-methyl-;n,3-dimethyl-benzenamin;N,3-Dime
Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:696-44-6
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:696-44-6
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:696-44-6
Min.Order:10 Kilogram
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inquiryProName: High purity Dimethyl with good quality... CasNo: 67-68-5 Molecular Formula: C2H6OS Appearance: colorless clear liquid Application: Wide use in industry DeliveryTime: Prompt PackAge: 25kg/drum Port: Shanghai,
Cas:696-44-6
Min.Order:1 Metric Ton
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:696-44-6
Min.Order:1 Kilogram
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inquiry3-(Methylamino)toluene CAS: 696-44-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int
Cas:696-44-6
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:696-44-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryProduct Detail Minimum Order Qty. 10 Gram
Cas:696-44-6
Min.Order:10 Gram
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Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:696-44-6
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inquiryMolecular Formula C8H11N Molar Mass 121.18 Density 0.957g/mLat 25°C(lit.) Melting Point -10.08°C (estimate) Boling Point 204-206°C5mm Hg(lit.) Flash Point 194°F
Cas:696-44-6
Min.Order:1 Gram
Negotiable
Type:Other
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:696-44-6
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:696-44-6
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquiryProduct name: N-Methyl-M-Toluidine CAS No.:696-44-6 Molecule Formula:C8H11N Molecule Weight:121.18 Purity: 99.0% Package: 200kg/drum Description:Colorless to light yellow liquid Manufacture Standards:Enterprise Standard
Cas:696-44-6
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:696-44-6
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryProduct Name: 3-(Methylamino)toluene Synonyms: Aniline, N,m-dimethyl-;m,N-Dimethylaniline;m-Toluidine, N-methyl-;n,3-dimethyl-benzenamin;N,3-Dimethylbenzenamine;N-METHYL-M-TOLUIDINE;N-METHYL-3-TOLUIDINE;N,3-DIMETHYLANILINE CAS: 696-44-6 MF:
Cas:696-44-6
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:696-44-6
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:696-44-6
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:696-44-6
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquirySuperior quality, moderate price & quick delivery. Appearance:Pale yellow oily liquid Storage:sealed and stored Package:200 kg / drum Application:As dye intermediates Transportation:by air or by sea or by Express Port:Shanghai, Ningbo, Tianjin,
We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:696-44-6
Min.Order:1 Metric Ton
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Type:Trading Company
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
99%
Cas:696-44-6
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryhigh purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier
Conditions | Yield |
---|---|
With C31H30ClIrN3O(1+)*F6P(1-); potassium tert-butylate at 130℃; for 12h; | 98% |
With C19H37IrN4(2+)*2I(1-); potassium carbonate at 120℃; for 17h; Inert atmosphere; Schlenk technique; Sealed tube; | 90% |
With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; | |
With hydrogen at 55℃; under 750.075 Torr; for 36h; Irradiation; Green chemistry; | |
With C19H24ClN2Ru; sodium hydroxide at 60℃; for 22h; | 99 %Chromat. |
3-methyl-N-methylacetanilide
A
N-ethyl-N-methyl-3-methylaniline
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With triethyl borane; Triethoxysilane; sodium hydroxide In hexane at 80℃; for 6h; Reagent/catalyst; Solvent; Inert atmosphere; Sealed tube; | A 2% B 95% |
Stage #1: 3-methyl-N-methylacetanilide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube; | A 78% B 11% |
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 6h; Inert atmosphere; Schlenk technique; High pressure; Sealed tube; | A n/a B 72% |
Conditions | Yield |
---|---|
Stage #1: formaldehyd; 1-amino-3-methylbenzene With sodium methylate In methanol at 65℃; for 1h; Stage #2: With sodium tetrahydroborate at 65℃; for 1.5h; | 93% |
With sodium tetrahydroborate; sodium methylate In methanol 1) room temp., 5 h, 2) reflux; | 89% |
With methanol; sodium tetrahydroborate; sodium at 60℃; for 2h; | 82% |
Conditions | Yield |
---|---|
With potassium tert-butylate at 130℃; for 24h; Sealed tube; | 93% |
With [(N,N′-bis(diisopropylphosphino)-2,6-diaminopyridine)Mn(CO)3][Br]; potassium hydroxide at 110℃; for 16h; Molecular sieve; Sealed tube; | 80% |
With [Ru(2-(6-methoxypyridin-2-yl)-1,10-phenanthroline)(MeCN)2Cl]Cl; sodium methylate at 110℃; for 12h; Green chemistry; | 87 %Chromat. |
With platinum on carbon; potassium tert-butylate; hydrogen at 150℃; under 1500.15 Torr; for 24h; Autoclave; | 93 %Chromat. |
mercaptoacetic acid
N-methyl-N-nosyl-m-toluidine
A
2-(4-nitrophenylthio)acetic acid
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; | A n/a B 92% |
Conditions | Yield |
---|---|
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 25℃; for 24h; Inert atmosphere; | 90% |
methanol
1-amino-3-methylbenzene
A
N,N-dimethyl-m-toluidine
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With copper(I) oxide; hydrogenchloride; titanium(IV) oxide In water for 6h; UV-irradiation; | A 83% B 15% |
With aluminum oxide at 350 - 400℃; |
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 25℃; | 83% |
With trifluoroacetic acid In dichloromethane at 40℃; for 48h; Inert atmosphere; Schlenk technique; | |
With hydrogenchloride In water at 120℃; |
A
2-methyl-4,6-diphenyl-pyridine
B
N-methyl-p-toluidine
C
N-methyl-m-toluidine
D
N,2-dimethylaniline
Conditions | Yield |
---|---|
In trifluoroacetic acid for 17h; Ambient temperature; Irradiation; | A 81% B n/a C n/a D n/a |
carbonic acid dimethyl ester
1-amino-3-methylbenzene
A
N,N-dimethyl-m-toluidine
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With 0.72KNaX-BS zeolite at 150℃; for 1h; Temperature; | A 77% B 22% |
With NaY-BS zeolite at 150℃; for 1h; | A 32% B 43% |
Conditions | Yield |
---|---|
Stage #1: methanol; 3-methylbenzoyl azide at 70℃; for 3h; Inert atmosphere; Stage #2: With C54H43ClN3P2Ru(1+)*F6P(1-); potassium carbonate at 140℃; Inert atmosphere; | 77% |
Conditions | Yield |
---|---|
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube; | 72% |
With hydrogenchloride In water; ethylene glycol at 20℃; for 3h; Inert atmosphere; |
carbonic acid dimethyl ester
1-amino-3-methylbenzene
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With 0.94 HY-BS zeolite at 150℃; for 1h; | 67% |
With binder-free FeHY-mmm zeolite In neat (no solvent) Sealed tube; |
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 3h; [1,2]-Wittig Rearrangement; | A 62% B 9% |
N-methyl-N-phenylpropanamide
A
N-methyl-N-n-propylaniline
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
Stage #1: N-methyl-N-phenylpropanamide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube; | A 61% B 11% |
Conditions | Yield |
---|---|
With copper In water at 100℃; | 52% |
1-methoxy-2,6-dimethylpyridinium methyl sulfate
A
2,6-dimethylpyridine
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With Dimethylammonium sulphite In water at 150℃; for 24h; | A 20% B 42% |
Conditions | Yield |
---|---|
man befreit das Produkt durch Ausfaellen seiner aether.Loesung mit Schwefelsaeure vom Toluidin, dampft die aether.Loesung ein, erhitzt den Rueckstand mit Eissigsaeureanhydrid und verseift das entstandene N-Methyl-; | |
Stage #1: 1-amino-3-methylbenzene With n-butyllithium In tetrahydrofuran; hexane at -40℃; for 0.25h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran; hexane at -60 - 20℃; for 8h; Inert atmosphere; |
1-amino-3-methylbenzene
methyl iodide
A
N,N-dimethyl-m-toluidine
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With sulfuric acid unter Entfernen des entstehenden Methanols auf 180grad und Erhitzen des danach isolierten Reaktionsprodukts mit wss.Salzsaeure; |
N-methyl-N-(3-methylphenyl)carboxamide
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With water Heating; Yield given; | |
With hydrogenchloride In water at 100℃; for 2.5h; |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 30℃; Rate constant; Mechanism; also aq. DMSO; |
Conditions | Yield |
---|---|
With sodium hydroxide In water; dimethyl sulfoxide at 90℃; Rate constant; Mechanism; |
(Dimethoxy-phenyl-methyl)-methyl-m-tolyl-amine
A
α,α-dimethoxybenzyl cation
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With water In 1,4-dioxane at 25℃; Rate constant; |
Conditions | Yield |
---|---|
With dimethylsulfide borane complex 1) THF, r.t., 2 h, 2) THF, reflux, 3 h; Multistep reaction; |
Conditions | Yield |
---|---|
With dimethylsulfide borane complex 1.) THF, RT, 2h, 2.) THF, reflux, 3 h; Multistep reaction; | |
Multi-step reaction with 3 steps 1: benzene / Heating 2: anhydrous potassium carbonate, sodium hydroxide, tetrabutylammonium hydrogensulphate / benzene / 1 h / 5 - 10 °C / Heating 3: water / Heating View Scheme | |
Multi-step reaction with 3 steps 1.1: tert-butyl alcohol / 24 h / 40 °C / Inert atmosphere; Schlenk technique 2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.33 h / 0 °C / Inert atmosphere; Schlenk technique 2.2: 20 °C / Inert atmosphere; Schlenk technique 3.1: trifluoroacetic acid / dichloromethane / 48 h / 40 °C / Inert atmosphere; Schlenk technique View Scheme |
Conditions | Yield |
---|---|
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride 1.) benzene, water, 30 min, 2.) 2 h.; Multistep reaction; |
methanol
1-amino-3-methylbenzene
A
N,N-dimethyl-m-toluidine
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
at 350 - 400℃; |
A
N-(2-aminoethyl)-3-methylaniline
B
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; diethyl ether |
N-methyl-m-toluidine
3-methyl-N-nitroso-N-methylaniline
Conditions | Yield |
---|---|
With sodium azide In water; acetonitrile at 20℃; | 100% |
With nitromethane; oxygen; copper(II) bis(trifluoromethanesulfonate); 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; for 20h; Sealed tube; | 63% |
With hydrogenchloride; sodium nitrite at 0 - 5℃; | 2.5% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; Inert atmosphere; | 100% |
With triethylamine In dichloromethane at 0 - 20℃; | 99% |
N-methyl-m-toluidine
(S)-2,5-dihydropyrrole-1,2-dicarboxylic acid 1-tert-butyl ester
Conditions | Yield |
---|---|
With pyridine; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 0 - 20℃; for 4h; | 100% |
Conditions | Yield |
---|---|
With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine In acetonitrile at -78℃; for 24h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation; | 100% |
N-methyl-m-toluidine
N,N-dimethyl-formamide
N-methyl-N-(3-methylphenyl)carboxamide
Conditions | Yield |
---|---|
With zinc(II) phthalocyanine; carbon dioxide; phenylsilane at 25℃; under 3750.38 Torr; for 6h; Autoclave; chemoselective reaction; | 99% |
N-methyl-m-toluidine
1-Bromo-2-bromomethyl-benzene
N-(2-bromobenzyl)-N-methyl-m-tolylamine
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile for 4h; Heating; | 98% |
5-bromothiophene-2-carbonyl chloride
N-methyl-m-toluidine
5-bromo-N-methyl-N-(3-methylphenyl)thiophene-2-carboxamide
Conditions | Yield |
---|---|
With triethylamine at 0℃; for 3h; | 97% |
With triethylamine In dichloromethane at 0℃; for 0.5h; Inert atmosphere; |
Conditions | Yield |
---|---|
With aluminum oxide; aluminium trichloride for 0.0666667h; microwave irradiation; | 96% |
Conditions | Yield |
---|---|
With diphenylsilane; caesium carbonate In acetonitrile at 80℃; under 750.075 Torr; for 72h; Schlenk technique; Inert atmosphere; | 95% |
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry; | 93% |
With dimanganese decacarbonyl; phenylsilane; C29H33N2P In acetonitrile at 100℃; under 750.075 Torr; for 15h; | 88% |
3-(benzyloxy)-6-bromo-2,4,5-trimethylpyridine
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene for 3h; Reflux; | 95% |
carbon dioxide
N-methyl-m-toluidine
N-methyl-N-(3-methylphenyl)carboxamide
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; phenylsilane; zinc diacetate In acetonitrile at 25℃; under 3750.38 Torr; for 4h; Autoclave; | 95% |
With 2K(1+)*VOF4(2-)=K2{VOF4}; HSiPh3 In acetonitrile at 20℃; under 750.075 Torr; for 10h; Sealed tube; Autoclave; | 95% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 30℃; under 760.051 Torr; for 72h; Schlenk technique; | 93% |
Conditions | Yield |
---|---|
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique; | 95% |
Conditions | Yield |
---|---|
Stage #1: N-methyl-m-toluidine With N,N'-bis(2,6-dicyclopentyl-4-methoxyphenyl)formamidine; tetrabenzyl titanium at 20℃; for 0.333333h; Glovebox; Inert atmosphere; Stage #2: oct-1-ene at 155℃; for 0.116667h; Sealed tube; | 94% |
With bis(indenyl)dimethyl-titanium In toluene at 105℃; for 24h; Inert atmosphere; regioselective reaction; | 84% |
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With water-d2; silver trifluoromethanesulfonate In chloroform-d1 at 90℃; for 18h; regioselective reaction; | 94% |
Conditions | Yield |
---|---|
With C52H52NO5P; palladium(II) iodide In tetrahydrofuran at 20℃; under 38002.6 Torr; for 72h; Autoclave; enantioselective reaction; | 94% |
Conditions | Yield |
---|---|
Stage #1: cyanoacetic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h; Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane at 0 - 20℃; | 93% |
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃; for 1h; Inert atmosphere; Schlenk technique; | 81% |
Stage #1: cyanoacetic acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 3h; Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane; N,N-dimethyl-formamide at 0℃; |
Conditions | Yield |
---|---|
With pentakis(dimethylamido)tantalum In hexane at 140℃; for 96h; Inert atmosphere; Sealed tube; regioselective reaction; | 93% |
Conditions | Yield |
---|---|
With C38H38N4O2Rh(1+)*F6P(1-) In acetonitrile at 20℃; for 7h; Mannich Aminomethylation; enantioselective reaction; | 93% |
9-hydroxycalabaxanthone
bis(trichloromethyl) carbonate
N-methyl-m-toluidine
Conditions | Yield |
---|---|
Stage #1: bis(trichloromethyl) carbonate; N-methyl-m-toluidine With triethylamine In dichloromethane at 20℃; for 4h; Cooling with ice; Stage #2: 9-hydroxycalabaxanthone With dmap In dichloromethane at 20℃; Cooling with ice; | 92% |
N-methyl-m-toluidine
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); (R)-segphos In tert-Amyl alcohol at 60℃; for 48h; Glovebox; enantioselective reaction; | 91% |
Conditions | Yield |
---|---|
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique; | 90% |
1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole
N-methyl-m-toluidine
Conditions | Yield |
---|---|
In toluene at 120℃; for 12h; Inert atmosphere; | 89% |
Ethyl bromodifluoroacetate
N-methyl-m-toluidine
N-methyl-N-(3-methylphenyl)carboxamide
Conditions | Yield |
---|---|
With water In N,N-dimethyl-formamide at 110℃; for 6h; Schlenk technique; | 89% |
With copper (I) acetate; caesium carbonate; XPhos In N,N-dimethyl-formamide at 110℃; for 12h; | 79% |
With copper (I) acetate; caesium carbonate; XPhos In water; N,N-dimethyl-formamide at 110℃; for 12h; Schlenk technique; | 79% |
5-phenyl-3H-furan-2-one
N-methyl-m-toluidine
N-methyl-N-(3-methylphenyl)-4-oxo-4-phenylbutanamide
Conditions | Yield |
---|---|
for 3h; Heating; | 87% |
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