3-(Methylamino)toluene supplier

Name
3-(Methylamino)toluene
EINECS 211-795-0
CAS No. 696-44-6
Article Data68
CAS DataBase
Density 0.968 g/cm³
Solubility insoluble
Melting Point -10.08°C (estimate)
Formula C₈H₁₁N
Boiling Point 204.7 °C at 760 mmHg
Molecular Weight 121.182
Flash Point 77.3 °C
Transport Information UN 2810
Appearance clear yellow liquid
Safety 28-36/37-45-61-28A
Risk Codes 23/24/25-33-52/53
Molecular Structure
Hazard Symbols T
Synonyms m-Toluidine,N-methyl- (6CI,7CI,8CI);N,3-Dimethylaniline;N,3-Dimethylbenzenamine;N-(3-Methylphenyl)methylamine;N-Methyl(3-methylphenyl)amine;N-Methyl-N-(3-methylphenyl)amine;N-Methyl-N-(m-tolyl)amine;N-Methyl-m-toluidine;NSC 9396;m,N-Dimethylaniline;
PSA 12.03000
LogP 2.10970

Synthetic route

: 67-56-1
methanol

: 108-44-1
1-amino-3-methylbenzene

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With C31H30ClIrN3O(1+)*F6P(1-); potassium tert-butylate at 130℃; for 12h;	98%
With C19H37IrN4(2+)*2I(1-); potassium carbonate at 120℃; for 17h; Inert atmosphere; Schlenk technique; Sealed tube;	90%
With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃;
With hydrogen at 55℃; under 750.075 Torr; for 36h; Irradiation; Green chemistry;
With C19H24ClN2Ru; sodium hydroxide at 60℃; for 22h;	99 %Chromat.

: 579-12-4
3-methyl-N-methylacetanilide

A: 15258-50-1
N-ethyl-N-methyl-3-methylaniline

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With triethyl borane; Triethoxysilane; sodium hydroxide In hexane at 80℃; for 6h; Reagent/catalyst; Solvent; Inert atmosphere; Sealed tube;	A 2% B 95%
Stage #1: 3-methyl-N-methylacetanilide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;	A 78% B 11%
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 6h; Inert atmosphere; Schlenk technique; High pressure; Sealed tube;	A n/a B 72%

: 50-00-0
formaldehyd

: 108-44-1
1-amino-3-methylbenzene

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
Stage #1: formaldehyd; 1-amino-3-methylbenzene With sodium methylate In methanol at 65℃; for 1h; Stage #2: With sodium tetrahydroborate at 65℃; for 1.5h;	93%
With sodium tetrahydroborate; sodium methylate In methanol 1) room temp., 5 h, 2) reflux;	89%
With methanol; sodium tetrahydroborate; sodium at 60℃; for 2h;	82%

: 67-56-1
methanol

: 99-08-1
1-methyl-3-nitrobenzene

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With potassium tert-butylate at 130℃; for 24h; Sealed tube;	93%
With [(N,N′-bis(diisopropylphosphino)-2,6-diaminopyridine)Mn(CO)3][Br]; potassium hydroxide at 110℃; for 16h; Molecular sieve; Sealed tube;	80%
With [Ru(2-(6-methoxypyridin-2-yl)-1,10-phenanthroline)(MeCN)2Cl]Cl; sodium methylate at 110℃; for 12h; Green chemistry;	87 %Chromat.
With platinum on carbon; potassium tert-butylate; hydrogen at 150℃; under 1500.15 Torr; for 24h; Autoclave;	93 %Chromat.

: 68-11-1
mercaptoacetic acid

: 211676-01-6
N-methyl-N-nosyl-m-toluidine

A: 3406-75-5
2-(4-nitrophenylthio)acetic acid

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃;	A n/a B 92%

...Expand

: 625-95-6
3-Iodotoluene

: 74-89-5
methylamine

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 25℃; for 24h; Inert atmosphere;	90%

: 67-56-1
methanol

: 108-44-1
1-amino-3-methylbenzene

A: 121-72-2
N,N-dimethyl-m-toluidine

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With copper(I) oxide; hydrogenchloride; titanium(IV) oxide In water for 6h; UV-irradiation;	A 83% B 15%
With aluminum oxide at 350 - 400℃;

...Expand

: tert-butyl-methyl-3-tolylcarbamate

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane at 25℃;	83%
With trifluoroacetic acid In dichloromethane at 40℃; for 48h; Inert atmosphere; Schlenk technique;
With hydrogenchloride In water at 120℃;

: 1-methylamino-2-methyl-4,6-diphenylpyridinium tetrafluoroborate

A: 1912-16-9
2-methyl-4,6-diphenyl-pyridine

B: 623-08-5
N-methyl-p-toluidine

C: 696-44-6
N-methyl-m-toluidine

D: 611-21-2
N,2-dimethylaniline

Conditions

Conditions	Yield
In trifluoroacetic acid for 17h; Ambient temperature; Irradiation;	A 81% B n/a C n/a D n/a

...Expand

: 616-38-6
carbonic acid dimethyl ester

: 108-44-1
1-amino-3-methylbenzene

A: 121-72-2
N,N-dimethyl-m-toluidine

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With 0.72KNaX-BS zeolite at 150℃; for 1h; Temperature;	A 77% B 22%
With NaY-BS zeolite at 150℃; for 1h;	A 32% B 43%

...Expand

: 67-56-1
methanol

: 71313-13-8
3-methylbenzoyl azide

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
Stage #1: methanol; 3-methylbenzoyl azide at 70℃; for 3h; Inert atmosphere; Stage #2: With C54H43ClN3P2Ru(1+)*F6P(1-); potassium carbonate at 140℃; Inert atmosphere;	77%

: 579-12-4
3-methyl-N-methylacetanilide

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;	72%
With hydrogenchloride In water; ethylene glycol at 20℃; for 3h; Inert atmosphere;

: 616-38-6
carbonic acid dimethyl ester

: 108-44-1
1-amino-3-methylbenzene

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With 0.94 HY-BS zeolite at 150℃; for 1h;	67%
With binder-free FeHY-mmm zeolite In neat (no solvent) Sealed tube;

: tert-butyl 1-allyl-2-methyl-2-(m-tolyl)hydrazinecarboxylate

A: (E)-tert-butyl (3-(methyl(m-tolyl)amino)prop-1-en-1-yl)carbamate

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 3h; [1,2]-Wittig Rearrangement;	A 62% B 9%

: 5827-78-1
N-methyl-N-phenylpropanamide

A: 13395-54-5
N-methyl-N-n-propylaniline

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
Stage #1: N-methyl-N-phenylpropanamide With triethyl borane; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; potassium hydroxide In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;	A 61% B 11%

: 74-89-5
methylamine

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With copper In water at 100℃;	52%

: 87117-15-5
1-methoxy-2,6-dimethylpyridinium methyl sulfate

A: 108-48-5
2,6-dimethylpyridine

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With Dimethylammonium sulphite In water at 150℃; for 24h;	A 20% B 42%

: 108-44-1
1-amino-3-methylbenzene

: 74-88-4
methyl iodide

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
man befreit das Produkt durch Ausfaellen seiner aether.Loesung mit Schwefelsaeure vom Toluidin, dampft die aether.Loesung ein, erhitzt den Rueckstand mit Eissigsaeureanhydrid und verseift das entstandene N-Methyl-;
Stage #1: 1-amino-3-methylbenzene With n-butyllithium In tetrahydrofuran; hexane at -40℃; for 0.25h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran; hexane at -60 - 20℃; for 8h; Inert atmosphere;

: 108-44-1
1-amino-3-methylbenzene

: 74-88-4
methyl iodide

A: 121-72-2
N,N-dimethyl-m-toluidine

B: 696-44-6
N-methyl-m-toluidine

...Expand

: 108-44-1
1-amino-3-methylbenzene

: 149-73-5
trimethyl orthoformate

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With sulfuric acid unter Entfernen des entstehenden Methanols auf 180grad und Erhitzen des danach isolierten Reaktionsprodukts mit wss.Salzsaeure;

: 39970-42-8
N-methyl-N-(3-methylphenyl)carboxamide

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With water Heating; Yield given;
With hydrogenchloride In water at 100℃; for 2.5h;

: 39970-42-8
N-methyl-N-(3-methylphenyl)carboxamide

A: 71-47-6
formate

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With sodium hydroxide In water at 30℃; Rate constant; Mechanism; also aq. DMSO;

: 579-12-4
3-methyl-N-methylacetanilide

A: 71-50-1
acetate

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With sodium hydroxide In water; dimethyl sulfoxide at 90℃; Rate constant; Mechanism;

: 79431-18-8
(Dimethoxy-phenyl-methyl)-methyl-m-tolyl-amine

A: 38092-03-4, 102651-95-6
α,α-dimethoxybenzyl cation

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With water In 1,4-dioxane at 25℃; Rate constant;

: 108-44-1
1-amino-3-methylbenzene

: 2258-42-6
Acetic formic anhydride

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With dimethylsulfide borane complex 1) THF, r.t., 2 h, 2) THF, reflux, 3 h; Multistep reaction;

: 108-44-1
1-amino-3-methylbenzene

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With dimethylsulfide borane complex 1.) THF, RT, 2h, 2.) THF, reflux, 3 h; Multistep reaction;
Multi-step reaction with 3 steps 1: benzene / Heating 2: anhydrous potassium carbonate, sodium hydroxide, tetrabutylammonium hydrogensulphate / benzene / 1 h / 5 - 10 °C / Heating 3: water / Heating View Scheme
Multi-step reaction with 3 steps 1.1: tert-butyl alcohol / 24 h / 40 °C / Inert atmosphere; Schlenk technique 2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.33 h / 0 °C / Inert atmosphere; Schlenk technique 2.2: 20 °C / Inert atmosphere; Schlenk technique 3.1: trifluoroacetic acid / dichloromethane / 48 h / 40 °C / Inert atmosphere; Schlenk technique View Scheme

: 537-92-8
3-Methylacetanilide

: 77-78-1
dimethyl sulfate

: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride 1.) benzene, water, 30 min, 2.) 2 h.; Multistep reaction;

: 67-56-1
methanol

: 108-44-1
1-amino-3-methylbenzene

aluminium oxide: aluminium oxide

A: 121-72-2
N,N-dimethyl-m-toluidine

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
at 350 - 400℃;

...Expand

N-m-tolyl-glycine nitrile: N-m-tolyl-glycine nitrile

A: 14088-79-0
N-(2-aminoethyl)-3-methylaniline

B: 696-44-6
N-methyl-m-toluidine

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether

: 696-44-6
N-methyl-m-toluidine

: 17485-25-5
3-methyl-N-nitroso-N-methylaniline

Conditions

Conditions	Yield
With sodium azide In water; acetonitrile at 20℃;	100%
With nitromethane; oxygen; copper(II) bis(trifluoromethanesulfonate); 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; for 20h; Sealed tube;	63%
With hydrogenchloride; sodium nitrite at 0 - 5℃;	2.5%

: 696-44-6
N-methyl-m-toluidine

: 586-75-4
4-chlorobenzoyl chloride

: 4-bromo-N-methyl-N-(m-tolyl)benzamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; Inert atmosphere;	100%
With triethylamine In dichloromethane at 0 - 20℃;	99%

: 696-44-6
N-methyl-m-toluidine

: 51154-06-4
(S)-2,5-dihydropyrrole-1,2-dicarboxylic acid 1-tert-butyl ester

: tert-butyl (2S)-2-[methyl(m-tolyl)carbamoyl]-2,5-dihydropyrrole-1-carboxylate

Conditions

Conditions	Yield
With pyridine; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 0 - 20℃; for 4h;	100%

: 696-44-6
N-methyl-m-toluidine

: 108-44-1
1-amino-3-methylbenzene

Conditions

Conditions	Yield
With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine In acetonitrile at -78℃; for 24h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation;	100%

: 696-44-6
N-methyl-m-toluidine

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 39970-42-8
N-methyl-N-(3-methylphenyl)carboxamide

Conditions

Conditions	Yield
With zinc(II) phthalocyanine; carbon dioxide; phenylsilane at 25℃; under 3750.38 Torr; for 6h; Autoclave; chemoselective reaction;	99%

: 696-44-6
N-methyl-m-toluidine

: 3433-80-5
1-Bromo-2-bromomethyl-benzene

: 436845-45-3
N-(2-bromobenzyl)-N-methyl-m-tolylamine

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile for 4h; Heating;	98%

: 31555-60-9
5-bromothiophene-2-carbonyl chloride

: 696-44-6
N-methyl-m-toluidine

: 1252464-84-8
5-bromo-N-methyl-N-(3-methylphenyl)thiophene-2-carboxamide

Conditions

Conditions	Yield
With triethylamine at 0℃; for 3h;	97%
With triethylamine In dichloromethane at 0℃; for 0.5h; Inert atmosphere;

: 696-44-6
N-methyl-m-toluidine

: 95-64-7
4-amino-o-xylene

Conditions

Conditions	Yield
With aluminum oxide; aluminium trichloride for 0.0666667h; microwave irradiation;	96%

: 124-38-9
carbon dioxide

: 696-44-6
N-methyl-m-toluidine

: 121-72-2
N,N-dimethyl-m-toluidine

Conditions

Conditions	Yield
With diphenylsilane; caesium carbonate In acetonitrile at 80℃; under 750.075 Torr; for 72h; Schlenk technique; Inert atmosphere;	95%
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry;	93%
With dimanganese decacarbonyl; phenylsilane; C29H33N2P In acetonitrile at 100℃; under 750.075 Torr; for 15h;	88%

: 1444336-77-9
3-(benzyloxy)-6-bromo-2,4,5-trimethylpyridine

: 696-44-6
N-methyl-m-toluidine

: 5-(benzyloxy)-N,3,4,6-tetramethyl-N-m-tolylpyridin-2-amine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene for 3h; Reflux;	95%

: 124-38-9
carbon dioxide

: 696-44-6
N-methyl-m-toluidine

: 39970-42-8
N-methyl-N-(3-methylphenyl)carboxamide

Conditions

Conditions	Yield
With 1,10-Phenanthroline; phenylsilane; zinc diacetate In acetonitrile at 25℃; under 3750.38 Torr; for 4h; Autoclave;	95%
With 2K(1+)*VOF4(2-)=K2{VOF4}; HSiPh3 In acetonitrile at 20℃; under 750.075 Torr; for 10h; Sealed tube; Autoclave;	95%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 30℃; under 760.051 Torr; for 72h; Schlenk technique;	93%

: 696-44-6
N-methyl-m-toluidine

: 76-05-1
trifluoroacetic acid

: N,3-dimethyl-N-(2,2,2-trifluoroethyl)aniline

Conditions

Conditions	Yield
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique;	95%

: 111-66-0
oct-1-ene

: 696-44-6
N-methyl-m-toluidine

: 1227053-80-6
3-methyl-N-(2-methyloctyl)aniline

Conditions

Conditions	Yield
Stage #1: N-methyl-m-toluidine With N,N'-bis(2,6-dicyclopentyl-4-methoxyphenyl)formamidine; tetrabenzyl titanium at 20℃; for 0.333333h; Glovebox; Inert atmosphere; Stage #2: oct-1-ene at 155℃; for 0.116667h; Sealed tube;	94%
With bis(indenyl)dimethyl-titanium In toluene at 105℃; for 24h; Inert atmosphere; regioselective reaction;	84%

: 696-44-6
N-methyl-m-toluidine

: C8H8(2)H3N

Conditions

Conditions	Yield
With water-d2; silver trifluoromethanesulfonate In chloroform-d1 at 90℃; for 18h; regioselective reaction;	94%

: 292638-84-7
styrene

: 201230-82-2
carbon monoxide

: 696-44-6
N-methyl-m-toluidine

: (S)-N-methyl-2-phenyl-N-(m-tolyl)propanamide

Conditions

Conditions	Yield
With C52H52NO5P; palladium(II) iodide In tetrahydrofuran at 20℃; under 38002.6 Torr; for 72h; Autoclave; enantioselective reaction;	94%

...Expand

: 372-09-8
cyanoacetic acid

: 696-44-6
N-methyl-m-toluidine

: 2-cyano-N-methyl-N-(m-tolyl)acetamide

Conditions

Conditions	Yield
Stage #1: cyanoacetic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h; Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane at 0 - 20℃;	93%
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃; for 1h; Inert atmosphere; Schlenk technique;	81%
Stage #1: cyanoacetic acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 3h; Stage #2: N-methyl-m-toluidine With triethylamine In dichloromethane; N,N-dimethyl-formamide at 0℃;

: 292638-84-7
styrene

: 696-44-6
N-methyl-m-toluidine

: 1041517-59-2
3-methyl-N-(2-phenylpropyl)aniline

Conditions

Conditions	Yield
With pentakis(dimethylamido)tantalum In hexane at 140℃; for 96h; Inert atmosphere; Sealed tube; regioselective reaction;	93%

: 50-00-0
formaldehyd

: C12H12N2O

: 696-44-6
N-methyl-m-toluidine

: C21H23N3O

Conditions

Conditions	Yield
With C38H38N4O2Rh(1+)*F6P(1-) In acetonitrile at 20℃; for 7h; Mannich Aminomethylation; enantioselective reaction;	93%

...Expand

: 35349-68-9
9-hydroxycalabaxanthone

: 32315-10-9
bis(trichloromethyl) carbonate

: 696-44-6
N-methyl-m-toluidine

: C33H33NO7

Conditions

Conditions	Yield
Stage #1: bis(trichloromethyl) carbonate; N-methyl-m-toluidine With triethylamine In dichloromethane at 20℃; for 4h; Cooling with ice; Stage #2: 9-hydroxycalabaxanthone With dmap In dichloromethane at 20℃; Cooling with ice;	92%

...Expand

: 696-44-6
N-methyl-m-toluidine

: (+/-)-methyl 4-phenylbut-3-yn-2-yl carbonate

: (R)-N,3-dimethyl-N-(4-phenylbut-3-yn-2-yl)aniline

Conditions

Conditions	Yield
With bis(1,5-cyclooctadiene)nickel (0); (R)-segphos In tert-Amyl alcohol at 60℃; for 48h; Glovebox; enantioselective reaction;	91%

: 455-24-3
4-trifluoromethylbenzoic acid

: 696-44-6
N-methyl-m-toluidine

: N,3-dimethyl-N-(4-(trifluoromethyl)benzyl)aniline

Conditions

Conditions	Yield
With potassium phosphate; 18-crown-6 ether; phenylsilane In tetrahydrofuran at 80℃; for 12h; Glovebox; Molecular sieve; Schlenk technique;	90%

: 884866-01-7
1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole

: 696-44-6
N-methyl-m-toluidine

: N-methyl-2-phenyl-N-(m-tolyl)-N'-tosylacetimidamide

Conditions

Conditions	Yield
In toluene at 120℃; for 12h; Inert atmosphere;	89%

: 667-27-6
Ethyl bromodifluoroacetate

: 696-44-6
N-methyl-m-toluidine

: 39970-42-8
N-methyl-N-(3-methylphenyl)carboxamide

Conditions

Conditions	Yield
With water In N,N-dimethyl-formamide at 110℃; for 6h; Schlenk technique;	89%
With copper (I) acetate; caesium carbonate; XPhos In N,N-dimethyl-formamide at 110℃; for 12h;	79%
With copper (I) acetate; caesium carbonate; XPhos In water; N,N-dimethyl-formamide at 110℃; for 12h; Schlenk technique;	79%

: 1955-39-1
5-phenyl-3H-furan-2-one

: 696-44-6
N-methyl-m-toluidine

: 1056199-48-4
N-methyl-N-(3-methylphenyl)-4-oxo-4-phenylbutanamide

Conditions

Conditions	Yield
for 3h; Heating;	87%

3-(Methylamino)toluene Chemical Properties

Molecule structure of 3-(Methylamino)toluene (CAS NO.696-44-6):

IUPAC Name: N,3-Dimethylaniline
Molecular Weight: 121.17964 g/mol
Molecular Formula: C₈H₁₁N
Density: 0.968 g/cm³
Boiling Point: 204.7 °C at 760 mmHg
Flash Point: 77.3 °C
Index of Refraction: 1.563
Molar Refractivity: 40.68 cm³
Molar Volume: 125.1 cm³
Surface Tension: 34.7 dyne/cm
Enthalpy of Vaporization: 44.1 kJ/mol
Vapour Pressure: 0.259 mmHg at 25 °C
Water Solubility: insoluble
XLogP3: 2.6
H-Bond Donor: 1
H-Bond Acceptor: 1
Rotatable Bond Count: 1
Exact Mass: 121.089149
MonoIsotopic Mass: 121.089149
Topological Polar Surface Area: 12
Heavy Atom Count: 9
Canonical SMILES: CC1=CC(=CC=C1)NC
InChI: InChI=1S/C8H11N/c1-7-4-3-5-8(6-7)9-2/h3-6,9H,1-2H3
InChIKey: FBGJJTQNZVNEQU-UHFFFAOYSA-N
EINECS: 211-795-0

3-(Methylamino)toluene Uses

3-(Methylamino)toluene (CAS NO.696-44-6) is used as dye intermediates.

3-(Methylamino)toluene Safety Profile

Hazard Codes: Toxic T
Risk Statements: 23/24/25-33-52/53
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R33:Danger of cumulative effects.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 28-36/37-45-61-28A
S28:After contact with skin, wash immediately with plenty of soap-suds.
S36/37:Wear suitable protective clothing and gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
HazardClass: 6.1(a)
PackingGroup: II

3-(Methylamino)toluene Specification

3-(Methylamino)toluene (CAS NO.696-44-6) is also named as Aniline, N,m-dimethyl- ; N,3-Dimethylaniline ; N-3-Dimethylbenzenamine ; N-Methyl-3-methylaniline ; N-Methyl-m-toluidine ; NSC 9396 ; m,N-Dimethylaniline ; Benzenamine, N,3-dimethyl- . 3-(Methylamino)toluene (CAS NO.696-44-6) is clear yellow liquid.

Product Name

3-(Methylamino)toluene

Synthetic route

3-(Methylamino)toluene Chemical Properties

3-(Methylamino)toluene Uses

3-(Methylamino)toluene Safety Profile

3-(Methylamino)toluene Specification

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