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inquiry2-Bromo-3-chloro-5-(trifluoromethyl)pyridine CAS:75806-84-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
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inquiry2-Bromo-3-chloro-5-(trifluoromethyl)pyridine Chemical Properties Boiling point 88 °C density 1.83 refractive index 1.4990 to 1.5030 pka -3.92±0.20(Predicted) CAS DataBase Reference 75806-84-7(CAS DataBase Reference)
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inquiryHigh quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
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inquiryCapability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti
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inquiry2,3-dichloro-5-trifluoromethylpyridine
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
With trimethylsilyl bromide at 100℃; for 15h; Inert atmosphere; | 90% |
3-chloro-2-hydroxy-5-(trifluoromethyl)pyridine
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
With phosphorus(V) oxybromide at 150℃; for 6h; Temperature; | 58% |
6-hydroxy-3-pyridinecarboxylic acid
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: hydrogen fluoride; sulfur tetrafluoride / 12 h / 100 °C / 1125.11 Torr / Autoclave 2: N-chloro-succinimide / N,N-dimethyl-formamide; 1-methyl-pyrrolidin-2-one / 8 h / 20 °C 3: phosphorus(V) oxybromide / 6 h / 150 °C View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
2-anilineboronic acid pinacol ester
2-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]aniline
Conditions | Yield |
---|---|
With water; sodium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In dimethyl sulfoxide for 16h; | 95% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
2-(trifluoromethyl)-N-vinylbenzamide
fluopyram
Conditions | Yield |
---|---|
With Cyclohexanethiol; 10-phenyl-10H-phenothiazine; sodium formate In water; dimethyl sulfoxide at 23℃; for 16h; Irradiation; Inert atmosphere; Sealed tube; Cooling; regioselective reaction; | 93% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
lithium cyanide
3-chloro-2-cyano-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
Stage #1: 2-bromo-3-chloro-5-(trifluoromethyl)pyridine With 4-pyrrolidin-1-ylpyridine In ethanol for 6h; Reflux; Large scale; Stage #2: lithium cyanide In water; 1,2-dichloro-ethane at 80℃; for 2h; Large scale; | 88.1% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
(1-(tert-butoxycarbonyl)azetidin-3-yl)zinc(II) iodide
Conditions | Yield |
---|---|
Stage #1: 2-bromo-3-chloro-5-(trifluoromethyl)pyridine; (1-(tert-butoxycarbonyl)azetidin-3-yl)zinc(II) iodide With trifuran-2-yl-phosphane; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 50℃; for 18h; Stage #2: With hydrogenchloride In methanol; water at 20℃; for 60h; | 88% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
(7‐methyl‐2‐nitro‐6,7‐dihydro‐5H‐imidazo[2,1‐b][1,3]oxazin‐7‐yl)methanol
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 2.33333h; Inert atmosphere; | 88% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
N-benzoylethyleneimine
Conditions | Yield |
---|---|
With Cyclohexanethiol; 10-phenyl-10H-phenothiazine; sodium formate In water; dimethyl sulfoxide at 23℃; for 16h; Irradiation; Inert atmosphere; Sealed tube; Cooling; regioselective reaction; | 82% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
N-(2-(3-chloro-5-(trifluoromethyl)pyridin-2-yl)ethyl)-4-(trifluoromethyl)benzamide
Conditions | Yield |
---|---|
With Cyclohexanethiol; 10-phenyl-10H-phenothiazine; sodium formate In water; dimethyl sulfoxide at 23℃; for 16h; Irradiation; Inert atmosphere; Sealed tube; Cooling; regioselective reaction; | 82% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In tetrahydrofuran at 80℃; for 24h; Reagent/catalyst; Temperature; Time; Solvent; Inert atmosphere; | 71% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0) In toluene at 110℃; for 16h; Inert atmosphere; Sealed tube; | 70% |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 70℃; for 3h; | 67% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
10-chloro-7-(1-ethylpropyl)-2,3,4,5-tetrahydro-1H-[1,3]diazepino[1,2-a]benzimidazole
10-Chloro-1-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]-7-(1-ethylpropyl)-2,3,4,5-tetrahydro-1H-[1,3]diazepino[1,2-a]benzimidazole
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; caesium carbonate; copper(l) iodide In 1-methyl-pyrrolidin-2-one at 150℃; for 16h; | 43% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
3-(difluoromethyl)-N-(1-hydroxypropan-2-yl)-1-methyl-1H-pyrazole-4-carboxamide
3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2-(3-chloro-5-trifluoromethyl-pyridin-2-yloxy)-1-methyl-ethyl]amide
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 20 - 100℃; for 3h; | 34% |
N-(2-iodophenyl)-2-(trifluoromethyl)benzamide
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
Stage #1: N-(2-iodophenyl)-2-(trifluoromethyl)benzamide With potassium acetate; bis(pinacol)diborane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In dimethyl sulfoxide at 90℃; for 2h; Stage #2: 2-bromo-3-chloro-5-(trifluoromethyl)pyridine With water; sodium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In dimethyl sulfoxide at 20 - 90℃; for 16h; | 13% |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
3-chloro-2-cyano-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
In N-methyl-acetamide; diethyl ether |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
3-chloro-5-trifluoromethylpyridine-2-carboxylic acid
Conditions | Yield |
---|---|
With n-butyllithium In diethyl ether; hexane; nitrogen; water |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2 / water; 1,4-dioxane / 0.5 h / 20 °C / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2 / water; 1,4-dioxane / 0.5 h / 20 °C / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme | |
Multi-step reaction with 3 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2 / water; 1,4-dioxane / 20 °C / Inert atmosphere; Heating 3: palladium diacetate; ruphos; sodium t-butanolate / 1,4-dioxane / 22 h / 20 °C / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
A
5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
B
C21H18ClF3N2
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; ruphos; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) / water; 1,4-dioxane / 22 h / 20 °C / Inert atmosphere; Heating View Scheme | |
Multi-step reaction with 3 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2 / water; 1,4-dioxane / 20 °C / Inert atmosphere; Heating 3: palladium diacetate; ruphos; sodium t-butanolate / 1,4-dioxane / 22 h / 20 °C / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
5-(2-fluorophenyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
1-(3-(3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepin-5-yl)phenyl)ethanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
5-(3,5-dimethoxyphenyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
4-(3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepin-5-yl)benzonitrile
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
7-methyl-5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
7-methoxy-5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
7-fluoro-5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
2-bromo-3-chloro-5-(trifluoromethyl)pyridine
5-(p-tolyl)-3,8-bis(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / tetrahydrofuran / 24 h / 80 °C / Inert atmosphere 2: potassium carbonate; [Rh(OH)(cod)]2; chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II); XPhos / water; 1,4-dioxane / 22 h / Inert atmosphere; Heating View Scheme |
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