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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

(S)-(+)-2,2-Dimethylcyclopropane Carboxamide

Cas:75885-58-4

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality S-(+)-2,2-Dimethylcyclopropame Carboxamide supplier in China

Cas:75885-58-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

(S)-(+)-2,2-DiMethylcyclopropanecarboxaMide

Cas:75885-58-4

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply S-(+)-2,2-Dimethylcyclopropame Carboxamide

Cas:75885-58-4

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% (S)-(+)-2,2-dimethylcyclopropane-carboxamide 75885-58-4 Producer

Cas:75885-58-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

(S)-(+)-2,2-dimethylcyclopropane-carboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Henan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com

TIANFU-CHEM - (S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Gram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 75885-58-4 with best quality

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide Chemical name:(S)-(+)-2,2-Dimethylcyclopropanecarboxamide Molecular formula:C6H11NO Molecular weight:113.16 CAS:75885-58-4 Application:In

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide CAS:75885-58-4

Cas:75885-58-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide/ LIDE PHARMA- Factory supply / Best price

Cas:75885-58-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Cyclopropanecarboxamide,2,2-dimethyl-, (1S)- 75885-58-4

Cas:75885-58-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: (S)-(+)-2,2-Dimethylcyclopropanecarboxamide CAS: 75885-58-4 MF: C6H11NO MW: 113.16 EINECS: 278-334-3 Mol File: 75885-58-4.mol (S)-(+)-2,2-Dimethylcyclopropanecarboxamide Structure (S)-(+)-2,2-Dimethylcyclopropanecarb

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 75885-58-4 (S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

S-(+)-2,2-dimethylcyclopropane carboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Cyclopropanecarboxamide,2,2-dimethyl-, (1S)-

Cas:75885-58-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

S-(+)-2,2-Dimethylcyclopropame Carboxamide

Cas:75885-58-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Appearance/Colour:white to light yellow crystal powder Vapor Pressure:0.088mmHg at 25°C Melting Point:135-137 °C(lit.) Refractive Index:83 ° (C=1, MeOH) Boiling Point:225.1 °C at 760 mmHg PKA:16.61±0.40(Predicted)

75885-58-4 (S)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Gram

FOB Price: $6.0

Type:Trading Company

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white to light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:as per your request Application:Used as Pharmaceutical Int

S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: (S)-(+)-2,2-Dimethylcyclopropanecarboxamide CAS No.: 75885-58-4 Molecule Formula:C6H11NO Molecule Weight:113.16 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Stan

Lower Price (S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Huarong Industrial Group Limited established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World.

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

(S)-(+)-2,2-Dimethylcyclopropanecarboxamide

Cas:75885-58-4

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

inquiry

Synthetic route

(+)-1S-2,2-dimethylcyclopropane-carboxylic acid
14590-53-5

(+)-1S-2,2-dimethylcyclopropane-carboxylic acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
Stage #1: (+)-1S-2,2-dimethylcyclopropane-carboxylic acid With thionyl chloride In dichloromethane at 20℃;
Stage #2: With ammonia In dichloromethane at -15℃;
92.1%
Multi-step reaction with 2 steps
1: 93 percent / pyridine / 1.5 h / Ambient temperature
2: 83 percent / 3 M NH3 / ethanol / 0.75 h
View Scheme
(S)-ethyl 2,2-dimethylcyclopropanecarboxylate
89007-61-4

(S)-ethyl 2,2-dimethylcyclopropanecarboxylate

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With thionyl chloride; ammonia In dichloromethane90.7%
With ammonia; calcium chloride In methanol at 100 - 110℃;10 g
(+)-N-<<(2,2-dimethylcyclopropyl)carbonyl>oxy>succinimide
107871-21-6

(+)-N-<<(2,2-dimethylcyclopropyl)carbonyl>oxy>succinimide

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonium hydroxide In ethanol for 0.75h;83%
2,2,2-Trichloro-1-((S)-2,2-dimethyl-cyclopropyl)-ethanone
220263-88-7

2,2,2-Trichloro-1-((S)-2,2-dimethyl-cyclopropyl)-ethanone

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With aminolysis72%
(RS)-2,2-dimethylcyclopropanecarboxamide
1759-55-3

(RS)-2,2-dimethylcyclopropanecarboxamide

A

(R)-2,2-dimethylcyclopropanecarboxylic acid
28624-52-4

(R)-2,2-dimethylcyclopropanecarboxylic acid

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With water In acetonitrile at 30℃; for 2.33333h; pH=8.2; Solvent; Concentration; Enzymatic reaction; enantioselective reaction;A n/a
B 43.5%
With R-amidase from Delftia tsuruhatensis CCTC M 205114 at 35℃; for 18h; Large scale reaction; Enzymatic reaction; optical yield given as %ee; enantioselective reaction;A n/a
B 34.2%
2,2-dimethylcyclopropane carboxylic acid 2,2,2-trifluoroethyl ester
645413-67-8

2,2-dimethylcyclopropane carboxylic acid 2,2,2-trifluoroethyl ester

A

C8H11F3O2

C8H11F3O2

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; Candida antarctica Type B lipase In tert-butyl alcohol at 30 - 40℃; for 20h; Product distribution / selectivity; Enzymatic reaction;A n/a
B 40%
(R)-2,2,2-Trichloro-1-((S)-2,2-dimethyl-cyclopropyl)-ethanol
220263-87-6

(R)-2,2,2-Trichloro-1-((S)-2,2-dimethyl-cyclopropyl)-ethanol

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 72 percent / Na2Cr2O7, H2SO4 / acetic acid
2: 72 percent / aminolysis
View Scheme
2,2-dimethylcyclopropane-1-carboxylic acid
75885-59-5

2,2-dimethylcyclopropane-1-carboxylic acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
Multi-step reaction with 3 steps
2: 93 percent / pyridine / 1.5 h / Ambient temperature
3: 83 percent / 3 M NH3 / ethanol / 0.75 h
View Scheme
C9H16O3

C9H16O3

A

C9H16O3

C9H16O3

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; Candida antarctica Type B lipase In tert-butyl alcohol at 30℃; for 20h; Product distribution / selectivity; Enzymatic reaction;A n/a
B n/a
C8H13BrO2

C8H13BrO2

A

C8H13BrO2

C8H13BrO2

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; Candida antarctica Type B lipase In tert-butyl alcohol at 30℃; for 20h; Product distribution / selectivity; Enzymatic reaction;A n/a
B n/a
C8H13ClO2

C8H13ClO2

A

C8H13ClO2

C8H13ClO2

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; Candida antarctica Type B lipase In tert-butyl alcohol at 30℃; for 20h; Product distribution / selectivity; Enzymatic reaction;A n/a
B n/a
ethyl (E)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoate
1022895-93-7

ethyl (E)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoate

A

ethyl-7-Chloro-2-oxoheptanoate
78834-75-0

ethyl-7-Chloro-2-oxoheptanoate

B

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
Stage #1: ethyl (E)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoate With toluene-4-sulfonic acid In dichloromethane at 20℃;
Stage #2: With sodium hydroxide; water In dichloromethane pH=8 - 9; Product distribution / selectivity;
Stage #1: ethyl (E)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoate With methanesulfonic acid In toluene at 30℃;
Stage #2: With sodium hydroxide; water In toluene pH=8 - 9; Product distribution / selectivity;
(S)-isopropyl 2,2-dimethylcyclopropanecarboxylate

(S)-isopropyl 2,2-dimethylcyclopropanecarboxylate

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; calcium chloride In methanol at 100 - 110℃;10 g
(S)-methyl 2,2-dimethylcyclopropanecarboxylate

(S)-methyl 2,2-dimethylcyclopropanecarboxylate

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

Conditions
ConditionsYield
With ammonia; calcium chloride In methanol at 100 - 110℃; Solvent; Reagent/catalyst; Temperature;9 g
ethyl-7-Chloro-2-oxoheptanoate
78834-75-0

ethyl-7-Chloro-2-oxoheptanoate

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(Z)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoic acid ethyl ester
877758-94-6

(Z)-7-chloro-2-((S)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoic acid ethyl ester

Conditions
ConditionsYield
Stage #1: ethyl-7-Chloro-2-oxoheptanoate; (S)-2,2-dimethylcyclopropanecarboxamide With toluene-4-sulfonic acid In toluene for 10h; Reflux;
Stage #2: at 30℃; for 1h; Solvent; Temperature; Irradiation;
99.5%
5,10,15,20-tetrakis(3-bromophenyl)porphyrin

5,10,15,20-tetrakis(3-bromophenyl)porphyrin

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

C68H66N8O4

C68H66N8O4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h; Inert atmosphere; Schlenk technique;97%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(3,5-dimethoxyphenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(3,5-dimethoxyphenyl)porphyrin

C72H74N8O8

C72H74N8O8

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 48h;88%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis[4-(tert-butyl)phenyl]porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis[4-(tert-butyl)phenyl]porphyrin

C76H82N8O4

C76H82N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 40h;86%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

β-bromo-5,10,15,20-tetraphenylporphyrin

β-bromo-5,10,15,20-tetraphenylporphyrin

(S)-(+)-2,2-dimethylcyclopropanecarboxylic acid (5,10,15,20-tetraphenylporphyrin-2-yl)amide

(S)-(+)-2,2-dimethylcyclopropanecarboxylic acid (5,10,15,20-tetraphenylporphyrin-2-yl)amide

Conditions
ConditionsYield
With caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate In tetrahydrofuran at 100℃; for 24h;86%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis[3,5-di(tert-butyl)phenyl]porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis[3,5-di(tert-butyl)phenyl]porphyrin

C84H98N8O4

C84H98N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 48h;85%
With caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; palladium diacetate In tetrahydrofuran at 100℃; for 48h;85%
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene Inert atmosphere;85%
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 72h; Schlenk technique; Inert atmosphere; Sealed tube;
5,15-bis(2,6-dibromophenyl)-10,20-bis[3,5-di(tert-butyl)phenyl]porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis[3,5-di(tert-butyl)phenyl]porphyrin

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

C20H8N4H2(C6H3(C(CH3)3)2)2(C6H3(NHCOC3H3(CH3)2)2)2

C20H8N4H2(C6H3(C(CH3)3)2)2(C6H3(NHCOC3H3(CH3)2)2)2

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; Schlenk technique; Inert atmosphere; Sealed tube; Molecular sieve;85%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrin

C74H78N8O4

C74H78N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 56h;84%
5,15-bis(2,6-dibromophenyl)-10,20-bis(3,5-di(2,4,6-trimethylphenyl)phenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(3,5-di(2,4,6-trimethylphenyl)phenyl)porphyrin

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

C104H106N8O4

C104H106N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 72h; Inert atmosphere;82%
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 72h; Inert atmosphere; Schlenk technique;82%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)porphyrin

5,15-bis(2,6-dibromophenyl)porphyrin

C56H58N8O4

C56H58N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;79%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-diphenylporphyrin

5,15-bis(2,6-dibromophenyl)-10,20-diphenylporphyrin

C68H66N8O4

C68H66N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;78%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(4-trifluoromethylphenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(4-trifluoromethylphenyl)porphyrin

C70H64F6N8O4

C70H64F6N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;77%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bisheptylporphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bisheptylporphyrin

C70H86N8O4

C70H86N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;74%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(4-acetylphenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(4-acetylphenyl)porphyrin

C72H70N8O6

C72H70N8O6

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;66%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,6-dimethoxyphenyl)-porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,6-dimethoxyphenyl)-porphyrin

C72H74N8O8

C72H74N8O8

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;59%
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 72h; Schlenk technique; Inert atmosphere; Sealed tube;
5,15-bis(2,6-dibromophenyl)-10,20-bis(2,6-dimethoxyphenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,6-dimethoxyphenyl)porphyrin

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

C20H8N4H2(C6H3(OCH3)2)2(C6H3(NHCOC3H3(CH3)2)2)2

C20H8N4H2(C6H3(OCH3)2)2(C6H3(NHCOC3H3(CH3)2)2)2

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; Schlenk technique; Inert atmosphere; Sealed tube; Molecular sieve;59%
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,3,4,5,6-pentafluorophenyl)porphyrin

5,15-bis(2,6-dibromophenyl)-10,20-bis(2,3,4,5,6-pentafluorophenyl)porphyrin

C68H56F10N8O4

C68H56F10N8O4

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 100℃; for 60h;46%
8-bromo-2-oxooctanoic acid

8-bromo-2-oxooctanoic acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(Z)-8-Bromo-2-[((S)-2,2-dimethyl-cyclopropanecarbonyl)-amino]-oct-2-enoic acid
107912-87-8

(Z)-8-Bromo-2-[((S)-2,2-dimethyl-cyclopropanecarbonyl)-amino]-oct-2-enoic acid

Conditions
ConditionsYield
In toluene Heating;44%
C40H28Br4N4O3

C40H28Br4N4O3

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

A

C52H48Br2N6O5

C52H48Br2N6O5

B

C64H68N8O7

C64H68N8O7

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 125℃; for 65h; Inert atmosphere;A 21%
B 41%
2-oxooctanoic acid
328-51-8

2-oxooctanoic acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(+)-(Z)-2-(2,2-dimethylcyclopropanecarboxamido)-2-octenoic acid

(+)-(Z)-2-(2,2-dimethylcyclopropanecarboxamido)-2-octenoic acid

Conditions
ConditionsYield
In toluene for 17h; Heating;31%
7-bromo-2-oxoheptanoic acid
107872-93-5

7-bromo-2-oxoheptanoic acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(Z)-7-bromo-2 ((2s)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoic acid
78834-80-7

(Z)-7-bromo-2 ((2s)-2,2-dimethylcyclopropanecarboxamido)-2-heptenoic acid

Conditions
ConditionsYield
In toluene Heating;28%
2-Oxobutyric acid
600-18-0

2-Oxobutyric acid

(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(Z)-2-[((S)-2,2-Dimethyl-cyclopropanecarbonyl)-amino]-but-2-enoic acid

(Z)-2-[((S)-2,2-Dimethyl-cyclopropanecarbonyl)-amino]-but-2-enoic acid

Conditions
ConditionsYield
In toluene Heating;
(S)-2,2-dimethylcyclopropanecarboxamide
75885-58-4

(S)-2,2-dimethylcyclopropanecarboxamide

(+)-1S-2,2-dimethylcyclopropane-carboxylic acid
14590-53-5

(+)-1S-2,2-dimethylcyclopropane-carboxylic acid

Conditions
ConditionsYield
hydrolysis;

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