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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Methyl-3-biphenylmethanol Manufacturer/High quality/Best price/In stock

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methyl-3-Biphenylmethanol supplier in China

Cas:76350-90-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & distribution, thinkchem specializes in exp

2-Methyl-3-biphenylmethanol [76350-90-8] in stock

Cas:76350-90-8

Min.Order:10 Kilogram

FOB Price: $10.0 / 12.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory supply 2-Methyl-3-Biphenylmethanol

Cas:76350-90-8

Min.Order:1

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Methyl-3-Biphenylmethyanol

Cas:76350-90-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

2-methyl-3-biphenylmethanol CAS NO.76350-90-8

Cas:76350-90-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-(Hydroxymethyl)-2-methyl-1,1'-biphenyl

Cas:76350-90-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Win-Win chemical Co.Ltd

Stock products, own laboratory Product number 35871 English Name 2-Methyl-3-biphenylmethanol CAS Number 76350-90-8 Purity 98% Molecular f

2-Methyl-3-biphenylmethanol Cas no.76350-90-8 98%

Cas:76350-90-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hubei DiBo chemical co., LTD

Name:2-methyl-3-biphenylmethyanol CAS NO:76350-90-8 Grade:Medical scientific research and export Molecular formula:C14H14O Molecular weight:198.2604 Product Quality 12 years of chemical raw materials Mature operation of the industry System

2-methyl-3-biphenylmethyanol/ CAS:76350-90-8/ raw material/ high-quality

Cas:76350-90-8

Min.Order:25 Kilogram

FOB Price: $2.0 / 3.0

Type:Other

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

[1,1'-Biphenyl]-3-methanol,2-methyl- / LIDE PHARMA- Factory supply / Best price

Cas:76350-90-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: 2-Methyl-3-biphenylmethanol Synonyms: 3-HYDROXYMETHYL-2-METHYLBIPHENYL;2-METHYLBIPHENYL-3-METHANOL;2-METHYL-3-BIPHENYLMETHANOL;2-methyl-3-biphenylmethyanol;Bifenthrin alcohol;2-M

2-Methyl-3-biphenylmethanol 76350-90-8

Cas:76350-90-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 76350-90-8 with fast shipping

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 2-Methyl-3-biphenylmethanol Synonyms 3-Hydroxymethyl-2-methylbiphenyl CAS 76350-90-8 CAS: 76350-90-8 MF: - MW: -

2-Methyl-3-biphenylmethanol CAS: 76350-90-8

Cas:76350-90-8

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Leader Biochemical Group

About Product Details

China Biggest factory Manufacturer Supply High Quality 2-Methyl-3-biphenylmethanol CAS 76350-90-8

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Lab/Research institutions

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Hefei TNJ chemical industry co.,ltd

We are one of the domestic largest manufacturers of API; We are always supplier of products with higher quality and at more competitive price; We are supplier of safe and ecofriendly products ; We provide stable supply and efficient servic

Manufacturer of 2-Methyl-3-biphenylmethanol at Factory Price

Cas:76350-90-8

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

[1,1'-Biphenyl]-3-methanol,2-methyl- 76350-90-8

Cas:76350-90-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present,

2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $70.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

[1,1'-Biphenyl]-3-methanol,2-methyl-

Cas:76350-90-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

JL Pharm is profesional producer and supplier for Hypromellose acetate succinate, we can supply USP for this product, capacity is 10000kg/year. If you want to order produce Favipiravir, please let us know. Appearance:white powder Storage:room tempera

Bifenthrin Alcohol

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $19.0 / 20.0

Type:Trading Company

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 76350-90-8 2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:76350-90-8

Cas:76350-90-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 76350-90-8 ,2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

76350-90-8 2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Hebei Miheng Trading Co., Ltd.

2-Methyl-3-biphenylmethanol CAS 76350-90-8 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to

2-Methyl-3-biphenylmethanol CAS 76350-90-8

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hefei Zhaobo Technology Co., Ltd.

2-Methyl-3-biphenylmethanol CAS 76350-90-8 Description Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing

2-Methyl-3-biphenylmethanol CAS 76350-90-8

Cas:76350-90-8

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Hydroxymethyl-2-methylbiphenyl

Cas:76350-90-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Methyl-3-biphenylmethanol/High quality/Best price

Cas:76350-90-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Methyl-3-biphenylmethanol

Cas:76350-90-8

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Synthetic route

3-bromo-2-methylbenzyl alcohol
83647-43-2

3-bromo-2-methylbenzyl alcohol

phenylboronic acid
98-80-6

phenylboronic acid

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium hydrogencarbonate In ethanol; toluene at 80℃; for 0.5h; Suzuki-Miyaura Coupling; Inert atmosphere;98%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium acetate In tetrahydrofuran Suzuki-Miyaura Coupling; Reflux;98%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium hydrogencarbonate In ethanol; toluene at 80℃; for 3h; Inert atmosphere;98%
1,3-dihydro-4-phenylisobenzofuran
502483-86-5

1,3-dihydro-4-phenylisobenzofuran

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Stage #1: 1,3-dihydro-4-phenylisobenzofuran With lithium; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran at -78℃; for 3h;
Stage #2: With water In tetrahydrofuran at -78℃; for 0.333333h;
Stage #3: With water In tetrahydrofuran at -78 - 20℃; Further stages.;
95%
Multi-step reaction with 2 steps
1.1: Li; DTBB / tetrahydrofuran / 3 h / -78 °C
2.1: H2O / 0.5 h / -78 °C
2.2: H2O / -78 - 20 °C
View Scheme
3-chloromethyl-2-methyl-[1,1'-biphenyl]
84541-46-8

3-chloromethyl-2-methyl-[1,1'-biphenyl]

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
With tetrabutylammomium bromide; water; sodium acetate at 100℃; for 15h; Reagent/catalyst;91%
Bifenthrin

Bifenthrin

A

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

B

(1R,3R)-3-((Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2,-dimethylcyclopropane-1-carboxylic acid
76023-99-9

(1R,3R)-3-((Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2,-dimethylcyclopropane-1-carboxylic acid

Conditions
ConditionsYield
With potassium hydroxide In methanol for 2h; Hydrolysis; Heating;
C14H12OLi(1-)*Li(1+)

C14H12OLi(1-)*Li(1+)

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Stage #1: C14H12OLi(1-)*Li(1+) With water at -78℃; for 0.5h;
Stage #2: With water at -78 - 20℃; Further stages.;
4-bromo-1,3-dihydro-2-benzofuran

4-bromo-1,3-dihydro-2-benzofuran

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: palladium
2.1: Li; DTBB / tetrahydrofuran / 3 h / -78 °C
3.1: H2O / 0.5 h / -78 °C
3.2: H2O / -78 - 20 °C
View Scheme
2,3-dimethylbromobenzene
576-23-8

2,3-dimethylbromobenzene

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: N-bromosuccinimide; AIBN
2.1: tetrabutylammonium hydroxide / dioxane
3.1: palladium
4.1: Li; DTBB / tetrahydrofuran / 3 h / -78 °C
5.1: H2O / 0.5 h / -78 °C
5.2: H2O / -78 - 20 °C
View Scheme
1-bromo-2,3-bis(bromomethyl)benzene
127168-82-5

1-bromo-2,3-bis(bromomethyl)benzene

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: tetrabutylammonium hydroxide / dioxane
2.1: palladium
3.1: Li; DTBB / tetrahydrofuran / 3 h / -78 °C
4.1: H2O / 0.5 h / -78 °C
4.2: H2O / -78 - 20 °C
View Scheme
bifenthrin

bifenthrin

A

3-(2-chloro-3,3,3-trifluoroprop-1-en-yl)-2,2-dimethylcyclopropanecarboxylic acid
74609-46-4

3-(2-chloro-3,3,3-trifluoroprop-1-en-yl)-2,2-dimethylcyclopropanecarboxylic acid

B

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
With carboxylesterase EstSt7 from Sulfolobus tokodaii strain 7; water In ethanol at 80℃; pH=9; Kinetics; Enzymatic reaction;
3-bromo-2-methylbenzoic acid
76006-33-2

3-bromo-2-methylbenzoic acid

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: borane-THF / tetrahydrofuran / 20 °C / Cooling with ice
2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium hydrogencarbonate / toluene; ethanol / 0.5 h / 80 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: borane-THF / tetrahydrofuran / 15 h / 0 - 20 °C / Inert atmosphere
2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium hydrogencarbonate / ethanol; toluene / 0.5 h / 80 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: borane-THF / tetrahydrofuran / 15 h / 0 - 20 °C / Inert atmosphere
2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium hydrogencarbonate / toluene; ethanol / 0.5 h / 80 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: sulfuric acid / 60 °C
2.1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 - 20 °C
2.2: 1 h / 0 °C
3.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / 1,4-dioxane; water / 3 h / 100 °C / Inert atmosphere
View Scheme
2-methyl-[1,1'-biphenyl]-3-carbaldehyde
89951-60-0

2-methyl-[1,1'-biphenyl]-3-carbaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol; toluene at 80℃; under 9000.9 Torr; for 2h; Solvent; Temperature; Reagent/catalyst; Pressure; Autoclave;
methyl 3-bromo-2-methylbenzoate
99548-54-6

methyl 3-bromo-2-methylbenzoate

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 - 20 °C
1.2: 1 h / 0 °C
2.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / 1,4-dioxane; water / 3 h / 100 °C / Inert atmosphere
View Scheme
cyhalothrin chloride
78246-90-9

cyhalothrin chloride

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

rel-(1R,3R)-(2-methyl[1,1'-biphenyl]-3-yl)methyl 3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propenyl]-2,2-dimethylcyclopropanecarboxylate
82657-04-3

rel-(1R,3R)-(2-methyl[1,1'-biphenyl]-3-yl)methyl 3-[(1Z)-2-chloro-3,3,3-trifluoro-1-propenyl]-2,2-dimethylcyclopropanecarboxylate

Conditions
ConditionsYield
With hexamethylenetetramine at 40 - 45℃; for 5h; Temperature; Reagent/catalyst; Large scale;98.5%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

3-chloromethyl-2-methyl-[1,1'-biphenyl]
84541-46-8

3-chloromethyl-2-methyl-[1,1'-biphenyl]

Conditions
ConditionsYield
With thionyl chloride In N,N-dimethyl-formamide; toluene at 20℃; for 1h;98%
With thionyl chloride In N,N-dimethyl-formamide; toluene at 20℃; for 1h;98%
With thionyl chloride In acetonitrile87%
With thionyl chloride at 20℃;77%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

[2-methyl-(1,1'-biphenyl)-3-yl]-methyl bromide

[2-methyl-(1,1'-biphenyl)-3-yl]-methyl bromide

Conditions
ConditionsYield
With phosphorus tribromide In tetrahydrofuran at 20℃; for 0.5h;96%
With carbon tetrabromide; triphenylphosphine In tetrahydrofuran at 20℃; for 4h; Cooling with ice;96%
With N-Bromosuccinimide; triphenylphosphine In dichloromethane for 1h; Cooling with ice;95%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

(2-methyl-[1,1′-biphenyl]-3-yl)methanamine
1061650-37-0

(2-methyl-[1,1′-biphenyl]-3-yl)methanamine

Conditions
ConditionsYield
Stage #1: (2-methyl-[1,1'-biphenyl]-3-yl)methanol With hydrazine hydrate In ethanol for 3h; Reflux;
Stage #2: With hydrogenchloride In ethanol; water for 0.5h; Reflux;
96%
1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

trimethyl[(2-methylbiphenyl-3-yl)methoxy]silane
1316808-61-3

trimethyl[(2-methylbiphenyl-3-yl)methoxy]silane

Conditions
ConditionsYield
With asymmetric salen type di-Schiff base-based zinc complex supported on Fe3O4 nanoparticles at 20℃; for 0.25h;95%
With cross-linked poly((30percent)4-vinylpyridine/(70percent)styrene) copolymer-supported bismuth(III) triflate In dichloromethane at 20℃; for 0.166667h;91%
phthalimide
136918-14-4

phthalimide

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-((2-methyl-[1,1′-biphenyl]-3-yl)methyl)isoindoline-1,3-dione

2-((2-methyl-[1,1′-biphenyl]-3-yl)methyl)isoindoline-1,3-dione

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;92%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

(2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
107686-57-7

(2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate

Conditions
ConditionsYield
In pyridine; diethyl ether for 3h; Ambient temperature;85%
2,5-dibromopyridine
624-28-2

2,5-dibromopyridine

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyridine

5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyridine

Conditions
ConditionsYield
With 1,4,7,10,13,20-Hexaoxa<13.1>(1,2)benzenophan; potassium hydroxide In toluene for 1.5h; Reflux; Dean-Stark;84%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-chloro-4,6-dimethoxypyrimidine
13223-25-1

2-chloro-4,6-dimethoxypyrimidine

4,6-dimethoxy-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

4,6-dimethoxy-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

Conditions
ConditionsYield
Stage #1: (2-methyl[1,1'-biphenyl]-3-yl)methanol With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 0.5h;
Stage #2: 2-chloro-4,6-dimethoxypyrimidine In N,N-dimethyl-formamide at 0 - 20℃; for 2h;
83%
methanol
67-56-1

methanol

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

methyl 2-methyl-[1,1’-biphenyl]-3-carboxylate

methyl 2-methyl-[1,1’-biphenyl]-3-carboxylate

Conditions
ConditionsYield
With oxygen at 70℃; under 750.075 Torr; for 48h;81%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-methyl-[1,1'-biphenyl]-3-carbaldehyde
89951-60-0

2-methyl-[1,1'-biphenyl]-3-carbaldehyde

Conditions
ConditionsYield
With Dess-Martin periodane In dichloromethane at 20℃; for 0.5h;80%
With Dess-Martin periodane In dichloromethane for 0.5h;57.2%
With Dess-Martin periodane In dichloromethane at 20℃; for 0.5h;
3-bromo-4-hydroxybenzylaldehyde
2973-78-6

3-bromo-4-hydroxybenzylaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

3-bromo-4-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)benzaldehyde

3-bromo-4-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)benzaldehyde

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0℃; for 17h; Inert atmosphere;77%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 20h; Mitsunobu Displacement; Cooling with ice;35%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 20h; Cooling with ice;35%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃;106.9 mg
6-chloro-2-methoxy-3-pyridinecarboxaldehyde
95652-81-6

6-chloro-2-methoxy-3-pyridinecarboxaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-methoxy-6-[(2-methyl-3-phenyl-phenyl)methoxy]pyridine-3-carbaldehyde

2-methoxy-6-[(2-methyl-3-phenyl-phenyl)methoxy]pyridine-3-carbaldehyde

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; tert-butyl XPhos In toluene at 80℃; Buchwald-Hartwig Coupling;71%
With palladium diacetate; caesium carbonate; tert-butyl XPhos In toluene at 80℃; for 24h; Inert atmosphere;41%
With palladium diacetate; caesium carbonate; tert-butyl XPhos In toluene at 80℃; for 4h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube;38%
With palladium diacetate; caesium carbonate; tert-butyl XPhos In toluene at 80℃; Inert atmosphere;
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-methyl-[1,1’-biphenyl]-3-carboxylic acid
115363-11-6

2-methyl-[1,1’-biphenyl]-3-carboxylic acid

Conditions
ConditionsYield
With sodium bromate; sodium hydrogen sulfate In acetonitrile for 1.5h; Reflux;70%
With sodium bromate; sodium hydrogensulfate monohydrate In acetonitrile for 1.5h; Reflux;
With Jones reagent In acetone at 25℃; for 6h;28 g
(S)-tert-butyl 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(3-bromo-4-hydroxyphenyl)propanoate

(S)-tert-butyl 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(3-bromo-4-hydroxyphenyl)propanoate

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

(S)-tert-butyl 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-{3-bromo-4-[(2-methyl-1,1’-biphenyl-3-yl)methoxy]phenyl}propanoate

(S)-tert-butyl 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-{3-bromo-4-[(2-methyl-1,1’-biphenyl-3-yl)methoxy]phenyl}propanoate

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0℃; Inert atmosphere;66%
(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2,4-Dihydroxybenzaldehyde
95-01-2

2,4-Dihydroxybenzaldehyde

2-hydroxy-4-((2-methyl-[1,1′-biphenyl]-3-yl)methoxy)benzaldehyde

2-hydroxy-4-((2-methyl-[1,1′-biphenyl]-3-yl)methoxy)benzaldehyde

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; Cooling with ice;64%
ethyl 4-((2',3,3',5-tetrafluoro-5'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)butanoate

ethyl 4-((2',3,3',5-tetrafluoro-5'-hydroxy-[1,1'-biphenyl]-4-yl)oxy)butanoate

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

ethyl 4-((2',3,3',5-tetrafluoro-5'-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-[1,1'-biphenyl]-4-yl)oxy)butanoate

ethyl 4-((2',3,3',5-tetrafluoro-5'-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-[1,1'-biphenyl]-4-yl)oxy)butanoate

Conditions
ConditionsYield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In tetrahydrofuran; toluene at 0 - 20℃; for 11h; Mitsunobu Displacement; Inert atmosphere;64%
3-((5-amino-2-formylphenoxy)methyl)benzonitrile

3-((5-amino-2-formylphenoxy)methyl)benzonitrile

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

3-((2-formyl-5-(((2-methyl-[1,1′-biphenyl]-3-yl)methyl)amino)phenoxy)methyl)benzonitrile

3-((2-formyl-5-(((2-methyl-[1,1′-biphenyl]-3-yl)methyl)amino)phenoxy)methyl)benzonitrile

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide; acetonitrile for 11h; Reflux;57%
syringaldehyde
22080-96-2

syringaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2,6-dimethoxy-4-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)benzaldehyde

2,6-dimethoxy-4-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)benzaldehyde

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 20h; Mitsunobu Displacement; Cooling with ice;56%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 20h; Cooling with ice;56%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 23℃; for 18.1667h; Inert atmosphere;27%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃;
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃; for 22h; Mitsunobu Displacement; Inert atmosphere;699 mg
5-bromo-2-(methylsulfonyl)-4-(2,2,2-trifluoroethoxy)pyrimidine

5-bromo-2-(methylsulfonyl)-4-(2,2,2-trifluoroethoxy)pyrimidine

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-4-(2,2,2-trifluoroethoxy)pyrimidine

5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-4-(2,2,2-trifluoroethoxy)pyrimidine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 12h;53%
5-bromo-4-(4-((tert-butyldimethylsilyl)oxy)butoxy)-2-chloropyrimidine

5-bromo-4-(4-((tert-butyldimethylsilyl)oxy)butoxy)-2-chloropyrimidine

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-bromo-4-(4-((tert-butyldimethylsilyl)oxy)butoxy)-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

5-bromo-4-(4-((tert-butyldimethylsilyl)oxy)butoxy)-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

Conditions
ConditionsYield
Stage #1: (2-methyl[1,1'-biphenyl]-3-yl)methanol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h;
Stage #2: 5-bromo-4-(4-((tert-butyldimethylsilyl)oxy)butoxy)-2-chloropyrimidine In tetrahydrofuran; mineral oil at 20℃; for 3h;
49%
5-(((5-bromo-2-chloropyrimidin-4-yl)oxy)methyl)nicotinonitrile

5-(((5-bromo-2-chloropyrimidin-4-yl)oxy)methyl)nicotinonitrile

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-(((5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidin-4-yl)oxy)methyl)nicotinonitrile

5-(((5-bromo-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidin-4-yl)oxy)methyl)nicotinonitrile

Conditions
ConditionsYield
Stage #1: (2-methyl[1,1'-biphenyl]-3-yl)methanol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h;
Stage #2: 5-(((5-bromo-2-chloropyrimidin-4-yl)oxy)methyl)nicotinonitrile In tetrahydrofuran; mineral oil at 20℃; for 3h;
47%
4-amino-5-chloro-2-methoxybenzaldehyde
145742-50-3

4-amino-5-chloro-2-methoxybenzaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-chloro-2-methoxy-4-(((2-methyl-[1,1′-biphenyl]-3-yl)methyl)amino)benzaldehyde

5-chloro-2-methoxy-4-(((2-methyl-[1,1′-biphenyl]-3-yl)methyl)amino)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 18h; Reflux;47%
5-bromo-4-methoxy-2-(methylsulfonyl)pyrimidine

5-bromo-4-methoxy-2-(methylsulfonyl)pyrimidine

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

5-bromo-4-methoxy-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

5-bromo-4-methoxy-2-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)pyrimidine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 12h;40.8%
6-hydroxynaphthalene-2-carbaldehyde
78119-82-1

6-hydroxynaphthalene-2-carbaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

6-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-2-naphthaldehyde

6-((2-methyl-[1,1'-biphenyl]-3-yl)methoxy)-2-naphthaldehyde

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 25℃;40%
Stage #1: 6-hydroxynaphthalene-2-carbaldehyde; (2-methyl[1,1'-biphenyl]-3-yl)methanol With triphenylphosphine In tetrahydrofuran for 0.25h;
Stage #2: With di-isopropyl azodicarboxylate In tetrahydrofuran for 10h;
3 g
4-bromo-3-methoxy-1-(methylsulfonyl)-6,7-dihydro-5H-cyclopenta[c]pyridine

4-bromo-3-methoxy-1-(methylsulfonyl)-6,7-dihydro-5H-cyclopenta[c]pyridine

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

4-bromo-3-methoxy-1-((2-methyl-[1,1‘-biphenyl]-3-yl)methoxy)-6,7-dihydro-5H-cyclopenta[c]pyridine

4-bromo-3-methoxy-1-((2-methyl-[1,1‘-biphenyl]-3-yl)methoxy)-6,7-dihydro-5H-cyclopenta[c]pyridine

Conditions
ConditionsYield
Stage #1: (2-methyl[1,1'-biphenyl]-3-yl)methanol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h;
Stage #2: 4-bromo-3-methoxy-1-(methylsulfonyl)-6,7-dihydro-5H-cyclopenta[c]pyridine In N,N-dimethyl-formamide at 20℃; for 6h;
39%
2,4-dihydroxy-5-methylbenzaldehyde
39828-37-0

2,4-dihydroxy-5-methylbenzaldehyde

(2-methyl-[1,1'-biphenyl]-3-yl)methanol
76350-90-8

(2-methyl-[1,1'-biphenyl]-3-yl)methanol

2-hydroxy-5-methyl-4-[(2-methyl-[1,1'-biphenyl]-3-yl)methoxy]benzaldehyde

2-hydroxy-5-methyl-4-[(2-methyl-[1,1'-biphenyl]-3-yl)methoxy]benzaldehyde

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 40℃; Mitsunobu Displacement;37%

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