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Shandong Promise New Material Co., ltd.

We have the best quality of China,our product exports to all over the world. It is widely used in many different kinds of chemical area. We our quality means the best in China,even all over the world. We can export according to customers’ re

3-Fluorophenylboric Acid

Cas:768-35-4

Min.Order:1 Metric Ton

FOB Price: $3654.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-fluorophenylboronic acid supplier in China

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/57.html Product Name 3-Fluorophenylboronic acid CAS No. 768-35-4

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Gram

FOB Price: $23.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

Good quality Good price Promptly delivery Appearance:white powder Storage:dry dondition Package:According to the demand of customer Application:intermediate Transportation:According to the demand of customer Port:shanghai

768-35-4 3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Fluorphenylboric acid

Cas:768-35-4

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 768-35-4 3-Fluorophenylboronic acid Manufacturer

Cas:768-35-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Fluorobenzeneboronic acid

Cas:768-35-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Competitive Price High Quality Fast Delivery custom-made Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble me

3-Fluorophenylboronic acid 768-35-4

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

3-Fluorophenylboronic Acid CAS 768-35-4

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 768-35-4 with best quality

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name:3-Fluorophenylboronic acid Other name:3-Fluorophenylboronic acid Cas:768-35-4 Molecular Formula:C6H6BFO2 Appearance:asking Purity: 98% Stored :store in dry, dark and ventilated place Grade: Industrial Grade Transport: By air o

3-Fluorophenylboronic acid CAS 768-35-4

Cas:768-35-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

3-Fluorophenylboronic acid-CAS NO.: 768-35-4

Cas:768-35-4

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry plac

Supply high quality CAS 768-35-4 3-Fluorophenylboronic Acid

Cas:768-35-4

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-Fluorophenylboronic acid 768-35-4

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

3-Fluorophenylboronic acid 99%

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 25.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

3-Fluorophenylboronic acid CAS:768-35-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

3-Fluorophenylboronic acid CAS:768-35-4

Cas:768-35-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Fluorophenylboronicacid

Cas:768-35-4

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Kunshan Push Trading Co.,LTD

3-Fluorophenylboronic acid 768-35-4 ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good

3-Fluorophenylboronic acid 768-35-4

Cas:768-35-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS768-35-4 3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

3-FLUOROPHENYLBORONIC ACID

Cas:768-35-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-fluorophenylboronic acid

Cas:768-35-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Fluorophenylboronic acid/High quality/Best price

Cas:768-35-4

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-FluoroPhenylboronic acid

Cas:768-35-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:white to light yellow crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Intermediates of Liquid Crystals

3-Fluorophenylboronic acid

Cas:768-35-4

Min.Order:1 Kilogram

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Type:Trading Company

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Synthetic route

3-chlorofluorobenzene
625-98-9

3-chlorofluorobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With diisobutylaluminium hydride; magnesium; lithium chloride In tetrahydrofuran; toluene at 20℃; for 15h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
83%
Stage #1: 3-fluorobromobenzene With n-butyllithium In tetrahydrofuran; toluene at -78℃; for 1.5h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; toluene at -78 - 20℃; for 1h; Inert atmosphere;
70%
Stage #1: 3-fluorobromobenzene With magnesium In diethyl ether Grignard reaction;
Stage #2: With Trimethyl borate In diethyl ether at 3℃; for 3h; boronation;
Stage #3: With hydrogenchloride In diethyl ether Hydrolysis;
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 3h; Microwave irradiation;83%
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); N-ethyl-N,N-diisopropylamine In 2-methyltetrahydrofuran; methanol at 50 - 55℃; Inert atmosphere;85 %Chromat.
Triisopropyl borate
5419-55-6

Triisopropyl borate

1-halo-3-fluorobenzene

1-halo-3-fluorobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane; water; toluene at -78 - 20℃; Inert atmosphere; Schlenk technique;80%
meta-fluoroaniline
372-19-0

meta-fluoroaniline

tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
Stage #1: meta-fluoroaniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
67%
Triisopropyl borate
5419-55-6

Triisopropyl borate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 0.833333h; Inert atmosphere;
65%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

3-fluorobenzenediazonium tetrafluoroborate
1996-38-9

3-fluorobenzenediazonium tetrafluoroborate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.25h;59%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

3-fluoro-phenyl magnesium bromide

3-fluoro-phenyl magnesium bromide

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
With diethyl ether und anschliessenden Hydrolyse;
Trimethyl borate
121-43-7

Trimethyl borate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran N2; BuLi dropping into org. compd. soln. at -78°C, mixt. keeping 3 h, B-compd. soln. addn. dropwise at -78°C, mixt. allowing to warm to room temp. overnight , stirring 1 h with 10% HCl, extn. (Et2O); org. extracts washing (water), drying, solvent vac. removal;
With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
boric acid tributyl ester
688-74-4

boric acid tributyl ester

bromo(3-fluorophenyl)magnesium
17318-03-5

bromo(3-fluorophenyl)magnesium

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C8H10BFO2

C8H10BFO2

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 20℃; Inert atmosphere; Schlenk technique;
meta-fluoroaniline
372-19-0

meta-fluoroaniline

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: water / 0.03 h / 20 °C
1.2: 0.25 h / 0 °C
2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C
View Scheme
Triisopropyl borate
5419-55-6

Triisopropyl borate

C11H13FO2Zn

C11H13FO2Zn

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

Conditions
ConditionsYield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

2',3',5'-tris-O-(tert-butyldimethylsilyl)-2'-deoxyinosine
110526-62-0

2',3',5'-tris-O-(tert-butyldimethylsilyl)-2'-deoxyinosine

N1-(3-fluorophenyl)-2',3',5'-tris-(O-tert-butyldimethylsilyl)-inosine
864847-17-6

N1-(3-fluorophenyl)-2',3',5'-tris-(O-tert-butyldimethylsilyl)-inosine

Conditions
ConditionsYield
With pyridine; pyridine N-oxide; oxygen; 4 A molecular sieve; copper diacetate In dichloromethane at 20℃; under 760 Torr; for 24h;100%
With pyridine; pyridine N-oxide; oxygen; copper diacetate In dichloromethane at 20℃; for 24h; 4Å molecular sieves;67%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

2-(3-fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

2-(3-fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

Conditions
ConditionsYield
With magnesium sulfate In diethyl ether at 20℃; for 20h;100%
In toluene at 20℃; for 2h;55%
In benzene Reflux;
In toluene at 20℃; for 12h;
With magnesium sulfate In dichloromethane at 20℃; Inert atmosphere;
3-chloro-5-fluoro-benzoic acid
25026-64-6

3-chloro-5-fluoro-benzoic acid

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

3-fluoro-5-(3-fluorophenyl)benzoic acid
1214352-53-0

3-fluoro-5-(3-fluorophenyl)benzoic acid

Conditions
ConditionsYield
Stage #1: 3-chloro-5-fluoro-benzoic acid; 3-fluorophenylboronic acid With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; potassium carbonate; palladium diacetate In water at 20℃; for 96h; Inert atmosphere;
Stage #2: With hydrogenchloride In water pH=4;
100%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

4-chloro-3-iodophenol
202982-72-7

4-chloro-3-iodophenol

6-chloro-3'-fluorobiphenyl-3-ol
1354787-35-1

6-chloro-3'-fluorobiphenyl-3-ol

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 70℃; for 5h; Suzuki Coupling; Inert atmosphere;100%
tert-butyl 8-bromo-2,3-dihydrothieno[2,3-f][1,4]oxazepine-4(5H)-carboxylate
1263795-03-4

tert-butyl 8-bromo-2,3-dihydrothieno[2,3-f][1,4]oxazepine-4(5H)-carboxylate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

tert-butyl 8-(3-fluorophenyl)-2,3-dihydrothieno[2,3-f][1,4]oxazepine-4(5H)-carboxylate
1263795-09-0

tert-butyl 8-(3-fluorophenyl)-2,3-dihydrothieno[2,3-f][1,4]oxazepine-4(5H)-carboxylate

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 100℃; for 12h; Inert atmosphere;100%
5-bromo-2,3-dimethyl-benzoic acid
5613-27-4

5-bromo-2,3-dimethyl-benzoic acid

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

5-bromo-2,3-dimethyl-benzoic acid
1427407-47-3

5-bromo-2,3-dimethyl-benzoic acid

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; N,N-dimethyl-formamide at 95℃; Inert atmosphere;100%
5-bromo-2-methoxy-1,3-dimethylbenzene
14804-38-7

5-bromo-2-methoxy-1,3-dimethylbenzene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C15H15FO

C15H15FO

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 70℃; for 18h; Inert atmosphere;100%
With potassium phosphate; C43H47Cl3N4O2Pd In N,N-dimethyl-formamide at 80℃; for 22h; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Schlenk technique;
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

tert-butyl ((1S,4s)-4-((6-chloro-2-(((R)-1-methoxypropan-2-yl)amino)pyrido[3,2-d]pyrimidin-4-yl)amino)cyclohexyl)carbamate

tert-butyl ((1S,4s)-4-((6-chloro-2-(((R)-1-methoxypropan-2-yl)amino)pyrido[3,2-d]pyrimidin-4-yl)amino)cyclohexyl)carbamate

tert-butyl ((1S,4s)-4-((6-(3-fluorophenyl)-2-(((R)-1-methoxypropan-2-yl)amino)pyrido[3,2-d]pyrimidin-4-yl)amino)cyclohexyl)carbamate

tert-butyl ((1S,4s)-4-((6-(3-fluorophenyl)-2-(((R)-1-methoxypropan-2-yl)amino)pyrido[3,2-d]pyrimidin-4-yl)amino)cyclohexyl)carbamate

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 130℃; for 0.5h; Microwave irradiation;100%
2-(4-bromophenyl)-5,6,7-trimethoxy-4H-chromen-4-one
1355483-74-7

2-(4-bromophenyl)-5,6,7-trimethoxy-4H-chromen-4-one

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C24H19FO5

C24H19FO5

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 120℃; Inert atmosphere;100%
2-bromo-4-fluoroaniline
1003-98-1

2-bromo-4-fluoroaniline

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

3',5-difluoro-[1,1'-biphenyl]-2-amine

3',5-difluoro-[1,1'-biphenyl]-2-amine

Conditions
ConditionsYield
With palladium diacetate; diisopropylamine In water at 100℃; for 0.5h; Suzuki-Miyaura Coupling;100%
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;
potassium hydrogenfluoride
1279123-63-5

potassium hydrogenfluoride

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

potassium 3-fluorophenyl trifluoroborate

potassium 3-fluorophenyl trifluoroborate

Conditions
ConditionsYield
In methanol; water for 0.5h;100%
In diethyl ether; water at 20℃; for 3h;99%
7-{[methoxy(methyl)amino]carbonyl}quinolin-8-yl trifluoromethanesulfonate
1312684-68-6

7-{[methoxy(methyl)amino]carbonyl}quinolin-8-yl trifluoromethanesulfonate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

8-(3-fluorophenyl)-N-methoxy-N-methylquinoline-7-carboxamide

8-(3-fluorophenyl)-N-methoxy-N-methylquinoline-7-carboxamide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water at 100℃; for 3h; Inert atmosphere;100%
5-bromo-3-isopropyl(trans-4-methylcyclohexylcarbonyl)amino-thiophene-2-carboxylic acid methyl ester

5-bromo-3-isopropyl(trans-4-methylcyclohexylcarbonyl)amino-thiophene-2-carboxylic acid methyl ester

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

5-(3-fluoro-phenyl)-3-[isopropyl-(4-methyl-cyclohexanecarbonyl)-amino]-thiphene-2-carboxylic acid methyl ester

5-(3-fluoro-phenyl)-3-[isopropyl-(4-methyl-cyclohexanecarbonyl)-amino]-thiphene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In methanol; water; toluene at 70℃; for 18h; Heating / reflux;99%
5-acetyl-4-[(3,5-dichlorophenyl)amino]-2-ethyl-6-phenylpyridazin-3(2H)-one

5-acetyl-4-[(3,5-dichlorophenyl)amino]-2-ethyl-6-phenylpyridazin-3(2H)-one

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

5-acetyl-4-[N-(3,5-dichlorophenyl)-N-(3-fluorophenyl)amino]-2-ethyl-6-phenylpyridazin-3(2H)-one

5-acetyl-4-[N-(3,5-dichlorophenyl)-N-(3-fluorophenyl)amino]-2-ethyl-6-phenylpyridazin-3(2H)-one

Conditions
ConditionsYield
With oxygen; copper diacetate; triethylamine In dichloromethane at 20℃; for 72h; Molecular sieve;99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

N-(3-tert-butylphenyl)-2-chloronicotinamide
64794-30-5

N-(3-tert-butylphenyl)-2-chloronicotinamide

N-(3-tert-butylphenyl)-2-(3-fluorophenyl)nicotinamide
1231732-11-8

N-(3-tert-butylphenyl)-2-(3-fluorophenyl)nicotinamide

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 90℃; for 3h; Inert atmosphere;99%
6-acetyl-4-chloro-2-cyano-3-methylphenyl trifluoromethanesulfonate
1312686-23-9

6-acetyl-4-chloro-2-cyano-3-methylphenyl trifluoromethanesulfonate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

6-acetyl-4-chloro-3'-fluoro-3-methylbiphenyl-2-carbonitrile
1312686-24-0

6-acetyl-4-chloro-3'-fluoro-3-methylbiphenyl-2-carbonitrile

Conditions
ConditionsYield
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 80℃; for 2h;99%
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 80℃; for 2h; Inert atmosphere;99%
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In water; toluene at 80℃; for 2h; Inert atmosphere;98.5%
4-bromo-13,15-dimethyl-14-oxa-10,15-diazatetracyclo[8.7.0.0(2,7).0(12,16)]heptadeca-2,4,6-trien-11-one

4-bromo-13,15-dimethyl-14-oxa-10,15-diazatetracyclo[8.7.0.0(2,7).0(12,16)]heptadeca-2,4,6-trien-11-one

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C22H23FN2O2

C22H23FN2O2

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); caesium carbonate In 1,4-dioxane at 100℃; Suzuki coupling;99%
N-methylmaleimide
930-88-1

N-methylmaleimide

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

(R)-3-(3-fluorophenyl)-1-methyl-2,5-pyrrolidinedione
1314427-25-2

(R)-3-(3-fluorophenyl)-1-methyl-2,5-pyrrolidinedione

Conditions
ConditionsYield
With [Rh(OH)(cod)]2; (R)-MeO-F12-BIPHEP In diethyl ether; water at 0℃; for 36h; Schlenk technique; Inert atmosphere;99%
8-bromo-N-(2-(methylsulfonyl)ethyl)-1,6-naphthyridine-2-carboxamide
1611473-65-4

8-bromo-N-(2-(methylsulfonyl)ethyl)-1,6-naphthyridine-2-carboxamide

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

8-(3-fluorophenyl)-N-(2-(methylsulfonyl)ethyl)-1,6-naphthyridine-2-carboxamide
1611473-13-2

8-(3-fluorophenyl)-N-(2-(methylsulfonyl)ethyl)-1,6-naphthyridine-2-carboxamide

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate In 1,4-dioxane; water at 80℃; for 3h;99%
3-amino-N-(6-chloropyridin-3-yl)-4-(trifluoromethoxy)benzamide

3-amino-N-(6-chloropyridin-3-yl)-4-(trifluoromethoxy)benzamide

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

3-amino-N-[6-(3-fluorophenyl)pyridin-3-yl]-4-(trifluoromethoxy)benzamide

3-amino-N-[6-(3-fluorophenyl)pyridin-3-yl]-4-(trifluoromethoxy)benzamide

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,2-dimethoxyethane; water at 90℃; Inert atmosphere; Sealed tube;99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

5-bromo-3(2H)-benzofuranone
54450-20-3

5-bromo-3(2H)-benzofuranone

5-(3-fluorophenyl)benzofuran-3(2H)-one

5-(3-fluorophenyl)benzofuran-3(2H)-one

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In toluene at 80℃; Schlenk technique; Inert atmosphere; Sealed tube;99%
2-methylbenzyl carbamate

2-methylbenzyl carbamate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C14H13F

C14H13F

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Green chemistry;99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

4-methoxybenzyl N,N-dimethylcarbamate
84640-24-4

4-methoxybenzyl N,N-dimethylcarbamate

1-fluoro-3-(4-methoxybenzyl)benzene

1-fluoro-3-(4-methoxybenzyl)benzene

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Green chemistry;99%
3-methylbenzyl N,N-dimethylcarbamate
16605-27-9

3-methylbenzyl N,N-dimethylcarbamate

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C14H13F

C14H13F

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Green chemistry;99%
2-bromo-4-methoxypyridine
89488-29-9

2-bromo-4-methoxypyridine

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

2-(3-fluorophenyl)-4-methoxypyridine

2-(3-fluorophenyl)-4-methoxypyridine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 85℃; Inert atmosphere;99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

ethyl 4-bromo-1-(4-(3,4-dichlorophenyl)-5-(isopropylthio)thiazol-2-yl)-3-isopropyl-1H-pyrazole-5-carboxylate

ethyl 4-bromo-1-(4-(3,4-dichlorophenyl)-5-(isopropylthio)thiazol-2-yl)-3-isopropyl-1H-pyrazole-5-carboxylate

ethyl 1-(4-(3,4-dichlorophenyl)-5-(isopropylthio)thiazol-2-yl)-4-(3-fluorophenyl)-3-isopropyl-1H-pyrazole-5-carboxylate

ethyl 1-(4-(3,4-dichlorophenyl)-5-(isopropylthio)thiazol-2-yl)-4-(3-fluorophenyl)-3-isopropyl-1H-pyrazole-5-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water at 85℃; for 16h; Inert atmosphere; Sealed tube;99%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water at 20 - 85℃; for 16h; Inert atmosphere; Sealed tube;99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

2-benzyl-1,2,6-thiadiazine 1,1-dioxide
717-41-9

2-benzyl-1,2,6-thiadiazine 1,1-dioxide

(S)-6-benzyl-3-(3-fluorophenyl)-3,6-dihydro-2H-1,2,6-thiadiazine 1,1-dioxide

(S)-6-benzyl-3-(3-fluorophenyl)-3,6-dihydro-2H-1,2,6-thiadiazine 1,1-dioxide

Conditions
ConditionsYield
Stage #1: 3-fluorophenylboronic acid; 2-benzyl-1,2,6-thiadiazine 1,1-dioxide With chlorobis(cyclooctene)rhodium(I) dimer; C18H23NOS In toluene at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide In water; toluene at 60℃; Inert atmosphere; enantioselective reaction;
99%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

2-chloro-N-phenylquinazolin-4-amine
144511-93-3

2-chloro-N-phenylquinazolin-4-amine

4-anilino-2-(3-fluorophenyl)quinazoline
1304764-81-5

4-anilino-2-(3-fluorophenyl)quinazoline

Conditions
ConditionsYield
With C34H48Cl2N4Pd; potassium hydroxide In ethanol at 60℃; for 36h; Inert atmosphere;99%
With NHC-Pd(II)-Im; potassium hydroxide In ethanol at 20℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique;98%
3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

C19H17NO3

C19H17NO3

C25H22FNO3

C25H22FNO3

Conditions
ConditionsYield
With nickel(II) acetate tetrahydrate; (S)-4-tert-butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-1,3-oxazol In 2,2,2-trifluoroethanol at 80℃; for 24h; enantioselective reaction;99%
1-phenyl-3-(2-pyridyl)propen-1-one
5325-66-6, 20890-12-4, 72491-18-0

1-phenyl-3-(2-pyridyl)propen-1-one

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

(S)-3-(3-fluorophenyl)-1-phenyl-3-(pyridin-2-yl)propan-1-one

(S)-3-(3-fluorophenyl)-1-phenyl-3-(pyridin-2-yl)propan-1-one

Conditions
ConditionsYield
With (R)-(+)-(4,4'-bi-1,3-benzodioxole)-5,5'-diylbis(di(3,5-dimethylphenyl)phosphine); di-μ-chloro-bis[bis(cyclo-octene)rhodium]; potassium hydroxide In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere; Schlenk technique; enantioselective reaction;99%

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