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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Cedrol Manufacturer/High quality/Best price/In stock

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Cedrol supplier in China

Cas:77-53-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Cedrol HACCP manufacturer

Cas:77-53-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Cedrol

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Cedrol

Cas:77-53-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Cedrol cas77-53-2 C15H26O

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

China factory supply CAS 77-53-2 with high quality products

Cas:77-53-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

Cedrol Manufacturer/High quality/Best price/In stock CAS NO.77-53-2

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $2.0 / 6.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Cedrol 77-53-2

Cas:77-53-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Cedrol Terpenol

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 20.0

Type:Trading Company

inquiry

Hubei CuiRan Biotechnology Co., Ltd

Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)

Cedrol

Cas:77-53-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

PRODUCT DETAILS

China Largest Factory Manufacturer sales Cedrol CAS 77-53-2

Cas:77-53-2

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Cedrol

Cas:77-53-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

CEDROL

Cas:77-53-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi New nine Material Technology Co., Ltd.

Our Advantage: 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good quali

Cedrol

Cas:77-53-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

TIANFUCHEM--77-53-2--Cedrol

Cas:77-53-2

Min.Order:1 Metric Ton

FOB Price: $500.0

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Cedrol;(1S,2R,5S,7R,8R)-2,6,6,8-Tetramethyltricyclo[5.3.1.0]undecan-8-ol.99%

Cas:77-53-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

(+)-cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Other

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Cedrol CAS 77-53-2

Cas:77-53-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best quality in your re

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Cedrol 20mg

Cas:77-53-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Cedrol

Cas:77-53-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

methyllithium
917-54-4

methyllithium

15-nor-3-oxo cedrane
52153-97-6

15-nor-3-oxo cedrane

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
In diethyl ether Heating;
(3R,3aS,6R,7R,8aR)-6-Hydroxy-3,6,8-trimethyl-octahydro-3a,7-methano-azulene-8-carbaldehyde

(3R,3aS,6R,7R,8aR)-6-Hydroxy-3,6,8-trimethyl-octahydro-3a,7-methano-azulene-8-carbaldehyde

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
(i) KOH, N2H4, HOCH2CH2OH, (ii) (heating); Multistep reaction;
(3R,3aS,6R,7R,8aR)-8-Hydroxymethyl-3,6,8-trimethyl-octahydro-3a,7-methano-azulen-6-ol

(3R,3aS,6R,7R,8aR)-8-Hydroxymethyl-3,6,8-trimethyl-octahydro-3a,7-methano-azulen-6-ol

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CrO3, Py
2: (i) KOH, N2H4, HOCH2CH2OH, (ii) (heating)
View Scheme
3-Nor-cedrol
109507-91-7

3-Nor-cedrol

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: CrO3, Py
2: diethyl ether / Heating
View Scheme
3-Norcedr-2-en-3-on
40768-85-2, 109312-44-9

3-Norcedr-2-en-3-on

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2 / Pd-C / ethanol
2: diethyl ether / Heating
View Scheme
(3aR)-2c-acetyl-1,1,4c-trimethyl-(6ac)-hexahydro-pentalene-3ar-carboxylic acid methyl ester
76679-86-2, 101262-59-3

(3aR)-2c-acetyl-1,1,4c-trimethyl-(6ac)-hexahydro-pentalene-3ar-carboxylic acid methyl ester

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: (i) LiAlH4, (ii) CrO3, Py, (iii) aq. KOH
2: H2 / Pd-C / ethanol
3: diethyl ether / Heating
View Scheme
(3aR)-1.1.4c-trimethyl-(6acH)-hexahydro-3H-pentalene-dicarboxylic acid-(2c.3ar)
70639-04-2

(3aR)-1.1.4c-trimethyl-(6acH)-hexahydro-3H-pentalene-dicarboxylic acid-(2c.3ar)

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 6 steps
2: KOH, EtOH / Heating
4: (i) LiAlH4, (ii) CrO3, Py, (iii) aq. KOH
5: H2 / Pd-C / ethanol
6: diethyl ether / Heating
View Scheme
(-)-Norcedren-dicarbonsaeuredimethylester
70639-05-3

(-)-Norcedren-dicarbonsaeuredimethylester

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: KOH, EtOH / Heating
3: (i) LiAlH4, (ii) CrO3, Py, (iii) aq. KOH
4: H2 / Pd-C / ethanol
5: diethyl ether / Heating
View Scheme
(3aR)-1,1,4c-trimethyl-(6acH)-hexahydro-3H-pentalene-dicarboxylic acid-(2c.3ar)-3a-methyl ester

(3aR)-1,1,4c-trimethyl-(6acH)-hexahydro-3H-pentalene-dicarboxylic acid-(2c.3ar)-3a-methyl ester

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
2: (i) LiAlH4, (ii) CrO3, Py, (iii) aq. KOH
3: H2 / Pd-C / ethanol
4: diethyl ether / Heating
View Scheme
C19H30O4S2

C19H30O4S2

(+)-cedrol
77-53-2

(+)-cedrol

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: (i) Raney-Ni, (ii) aq. KOH, EtOH, (iii) (racemate resolution using quinine)
3: KOH, EtOH / Heating
5: (i) LiAlH4, (ii) CrO3, Py, (iii) aq. KOH
6: H2 / Pd-C / ethanol
7: diethyl ether / Heating
View Scheme

A

β-(+)-cedrene
546-28-1

β-(+)-cedrene

B

(+)-cedrol
77-53-2

(+)-cedrol

C

alpha-cedrene
469-61-4

alpha-cedrene

D

(-)-(3R,3aS,6S,7R,8aS)-isocedrol
19903-73-2

(-)-(3R,3aS,6S,7R,8aS)-isocedrol

Conditions
ConditionsYield
With epicedrol synthase In aq. buffer at 30℃; for 1h; pH=8.5; Enzymatic reaction;
Conditions
ConditionsYield
With cedrol synthase gene from the transcriptome of the glandular trichomes of a woody Lamiaceae plant Leucosceptrum canum In aq. buffer at 30℃; for 3h; pH=7.4; Enzymatic reaction;
(+)-cedrol
77-53-2

(+)-cedrol

1-cyano-2-methoxynaphthalene
16000-39-8

1-cyano-2-methoxynaphthalene

2-(((3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl)oxy)-1-naphthonitrile

2-(((3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl)oxy)-1-naphthonitrile

Conditions
ConditionsYield
With potassium hexamethylsilazane In 1,4-dioxane at 20℃; for 16h; Inert atmosphere; Sealed tube; Glovebox;98%
methylene chloride
74-87-3

methylene chloride

(+)-cedrol
77-53-2

(+)-cedrol

cedrol methyl ether
67874-81-1

cedrol methyl ether

Conditions
ConditionsYield
Stage #1: (+)-cedrol With potassium tert-butylate In toluene; tert-butyl alcohol at 85 - 110℃; Green chemistry;
Stage #2: methylene chloride In tert-butyl methyl ether at 60℃; under 1875.19 Torr; Reagent/catalyst; Temperature; Pressure; Autoclave; Green chemistry;
96.3%
difluorosulfoacetic acid sodium salt
912289-98-6

difluorosulfoacetic acid sodium salt

(+)-cedrol
77-53-2

(+)-cedrol

C17H25F2O5S(1-)*Na(1+)

C17H25F2O5S(1-)*Na(1+)

Conditions
ConditionsYield
With p-toluenesulfonic acid monohydrate In toluene for 42h; Reflux;91%
(+)-cedrol
77-53-2

(+)-cedrol

ethyl bromoacetate
105-36-2

ethyl bromoacetate

C19H32O3

C19H32O3

Conditions
ConditionsYield
Stage #1: (+)-cedrol With sodium hydroxide In tetrahydrofuran at 0℃; for 0.333333h; Inert atmosphere;
Stage #2: ethyl bromoacetate In tetrahydrofuran at 25℃; for 6.33333h;
88%
(+)-cedrol
77-53-2

(+)-cedrol

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl 2,2,2-trifluoroacetate

(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl 2,2,2-trifluoroacetate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;83%
(+)-cedrol
77-53-2

(+)-cedrol

(1R,3aS,3bR,6R)-1,3a,6-trimethyl-octahydro-1H-1,6a-cedarane[1,2-c]furan
18319-31-8

(1R,3aS,3bR,6R)-1,3a,6-trimethyl-octahydro-1H-1,6a-cedarane[1,2-c]furan

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; iodine In cyclohexane at 23℃; for 1.5h; Irradiation; Inert atmosphere;73%
With diphenylselenium hydroxyacetate; iodine In cyclohexane at 50℃; for 12h; Irradiation;67%
With [bis(acetoxy)iodo]benzene; iodine In cyclohexane at 20℃; for 1.5h; Irradiation; Inert atmosphere; regioselective reaction;
(+)-cedrol
77-53-2

(+)-cedrol

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol
67152-03-8

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol

Conditions
ConditionsYield
Stage #1: (+)-cedrol With cis-RuCl2(4,4'-di-tert-butyl-2,2'-bipyridine)2; acetic acid In water for 0.0333333h; Darkness;
Stage #2: With periodic acid In water for 4h; Darkness; chemoselective reaction;
55%
With iodosylbenzene; C40H39ClN4OPRu(1+)*Cl(1-); trifluoroacetic acid In 1,1,2,2-tetrachloroethane at 35℃; for 18h; regioselective reaction;53%
With 1,3,5-trichlorobenzene; iodosylbenzene; C38H35ClN4OPRu(1+)*Cl(1-); trifluoroacetic acid In 1,1,2,2-tetrachloroethane at 30℃; for 48h;36.5%
With ammonium cerium (IV) nitrate; 2C7H7O3S(1-)*C20H30N4O2Ru(2+) In water; tert-butyl alcohol at 20℃; for 0.666667h;
2,3,5-p-Nitrobenzoyl-D-ribofuranosylbromid
63527-43-5

2,3,5-p-Nitrobenzoyl-D-ribofuranosylbromid

(+)-cedrol
77-53-2

(+)-cedrol

(Cedran-8-yl)-2,3,5-tri-O-(p-nitrobenzoyl)-β-D-ribofuranosid
99049-93-1

(Cedran-8-yl)-2,3,5-tri-O-(p-nitrobenzoyl)-β-D-ribofuranosid

Conditions
ConditionsYield
With molecular sieve; silver silicate In dichloromethane for 24h;43%
(+)-cedrol
77-53-2

(+)-cedrol

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide
572-09-8

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

(Cedran-8-yl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranosid
99049-91-9

(Cedran-8-yl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranosid

Conditions
ConditionsYield
With calcium sulfate; silver carbonate In dichloromethane for 1.5h; Ambient temperature;40%
methyl pyridine-3-acetate
39998-25-9

methyl pyridine-3-acetate

(+)-cedrol
77-53-2

(+)-cedrol

(1S,2R,5S,8R)-cedryl 3-pyridylacetate

(1S,2R,5S,8R)-cedryl 3-pyridylacetate

Conditions
ConditionsYield
With n-butyllithium In hexane for 24h; Ambient temperature;38%
(+)-cedrol
77-53-2

(+)-cedrol

A

((3aR)-1.1.4c-trimethyl-2c-acetyl-(6acH)-hexahydro-3H-pentalenyl-(3ar))-acetic acid
142864-21-9

((3aR)-1.1.4c-trimethyl-2c-acetyl-(6acH)-hexahydro-3H-pentalenyl-(3ar))-acetic acid

B

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol
67152-03-8

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol

Conditions
ConditionsYield
With ruthenium trichloride; sodium periodate In tetrachloromethane; water; acetonitrile at 70℃; for 24h;A n/a
B 29%
(+)-cedrol
77-53-2

(+)-cedrol

trimethylaluminum
75-24-1

trimethylaluminum

C34H62Al2O2

C34H62Al2O2

Conditions
ConditionsYield
With 4-Fluorobenzoic acid In octane at 85℃; for 144h;28%
(+)-cedrol
77-53-2

(+)-cedrol

ethyl acrylate
140-88-5

ethyl acrylate

ethyl 3-((3R,3aS,6S,7S,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl)propanoate

ethyl 3-((3R,3aS,6S,7S,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl)propanoate

Conditions
ConditionsYield
With cyclopentadienyl titanium(IV) trichloride; triethylsilyl chloride; zinc In tetrahydrofuran at 60℃; for 12h; Molecular sieve; Sealed tube; Inert atmosphere; enantioselective reaction;27%
(+)-cedrol
77-53-2

(+)-cedrol

2,3,5-tri-O-benzoyl-D-ribofuranosyl bromide
22860-91-9

2,3,5-tri-O-benzoyl-D-ribofuranosyl bromide

(Cedran-8-yl)-2,3,5-tri-O-benzoyl-β-D-ribofuranosid
99049-94-2

(Cedran-8-yl)-2,3,5-tri-O-benzoyl-β-D-ribofuranosid

Conditions
ConditionsYield
With molecular sieve; silver silicate In dichloromethane for 1h;14%
methyl 4-pyridineacetate
29800-89-3

methyl 4-pyridineacetate

(+)-cedrol
77-53-2

(+)-cedrol

(1S,2S,5S,8R)-cedryl 4-pyridylacetate

(1S,2S,5S,8R)-cedryl 4-pyridylacetate

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane for 24h; Ambient temperature;13%
(+)-cedrol
77-53-2

(+)-cedrol

A

3α,8β-dihydroxycedrane
50539-24-7

3α,8β-dihydroxycedrane

B

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol
67152-03-8

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol

C

3β,8β-dihydroxycedrane

3β,8β-dihydroxycedrane

D

8β,12-dihydroxycedrane

8β,12-dihydroxycedrane

Conditions
ConditionsYield
With Mucor plumbeus In ethanol for 144h; Further byproducts given;A 5 mg
B 3%
C 5 mg
D 2%
(+)-cedrol
77-53-2

(+)-cedrol

A

3α,8β-dihydroxycedrane
50539-24-7

3α,8β-dihydroxycedrane

B

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol
67152-03-8

(3S,3aR,6R,7R,8aS) -3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene-3,6-diol

C

3β,8β-dihydroxycedrane

3β,8β-dihydroxycedrane

D

8β,12-dihydroxycedrane

8β,12-dihydroxycedrane

E

3β,8β,10-trihydroxycedrane

3β,8β,10-trihydroxycedrane

Conditions
ConditionsYield
With Mucor plumbeus In ethanol for 144h; Product distribution; microbiological hydroxylation of cedrol and related compounds by Mucor plumbeus;A 5 mg
B 3%
C 6 mg
D 2%
E n/a
(+)-cedrol
77-53-2

(+)-cedrol

8-β-hydroxycedran-10-one

8-β-hydroxycedran-10-one

Conditions
ConditionsYield
With pyridine; zinc; Fe3O(OAc)6Pyr3.5 In water; acetic acid for 6h; Ambient temperature;1.3%
formic acid
64-18-6

formic acid

(+)-cedrol
77-53-2

(+)-cedrol

(-)-α-cedrene
469-61-4

(-)-α-cedrene

(+)-cedrol
77-53-2

(+)-cedrol

N-chlorobetainyl chloride
53684-57-4

N-chlorobetainyl chloride

O-trimethylammonioacetyl-cedrol; chloride

O-trimethylammonioacetyl-cedrol; chloride

Conditions
ConditionsYield
With chloroform; N,N-dimethyl-aniline
(+)-cedrol
77-53-2

(+)-cedrol

(8aS)-6c-(3.5-dinitro-benzoyloxy)-3c.6t.8.8-tetramethyl-(8arH)-octahydro-3H-3at.7t-methano-azulene

(8aS)-6c-(3.5-dinitro-benzoyloxy)-3c.6t.8.8-tetramethyl-(8arH)-octahydro-3H-3at.7t-methano-azulene

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