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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methallyl acetate Manufacturer/High quality/Best price/In stock

Cas:820-71-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methallyl Acetate with high purity

Cas:820-71-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methallyl Acetate

Cas:820-71-3

Min.Order:1

Negotiable

Type:Other

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 820-71-3 with competitive price

Cas:820-71-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Propen-1-ol,2-methyl-, 1-acetate 820-71-3

Cas:820-71-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Methallyl acetate CAS:820-71-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Methallyl acetate CAS:820-71-3

Cas:820-71-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Propen-1-ol,2-methyl-, 1-acetate

Cas:820-71-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Propen-1-ol,2-methyl-, 1-acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methallyl Acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methallyl acetate

Cas:820-71-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Methallyl Acetate

Cas:820-71-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Methallyl acetate 820-71-3

Cas:820-71-3

Min.Order:1 Kilogram

FOB Price: $50.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Methallyl acetate

Cas:820-71-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methallyl acetate

Cas:820-71-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Methallyl acetate

Cas:820-71-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Methallyl acetate

Cas:820-71-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methyl-2-propenyl Acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methallyl Acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Propen-1-ol,2-methyl-, 1-acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Methallyl Acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Pharm intermediate

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Methallyl acetate cas 820-71-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methallyl acetate cas 820-71-3

Cas:820-71-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Methallyl acetate

Cas:820-71-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

acetic anhydride
108-24-7

acetic anhydride

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;97%
With ruthenium trichloride at 40℃; for 0.5h; Inert atmosphere; Ionic liquid;93%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;85%
sodium acetate
127-09-3

sodium acetate

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

A

methallyl acetate
820-71-3

methallyl acetate

B

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

Conditions
ConditionsYield
With sodium D-gluconate; copper(II) sulfate In water for 4h; Reagent/catalyst; Reflux;A 92%
B 5.5%
sodium acetate
127-09-3

sodium acetate

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
In acetic acid at 100℃; for 48h;85%
In 1-methyl-pyrrolidin-2-one at 100 - 120℃; for 1.5h;193 g
With copper(l) chloride In water at 70 - 94℃;520 g
acetyl chloride
75-36-5

acetyl chloride

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With pyridine at 5℃; for 0.25h;72%
1,2-dibromo-2-methyl-propane
594-34-3

1,2-dibromo-2-methyl-propane

sodium acetate
127-09-3

sodium acetate

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With acetic acid
acetic acid
64-19-7

acetic acid

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
durch langsame Destillation;
2-methyl-5-methylene-[1,3]dioxane
26170-10-5

2-methyl-5-methylene-[1,3]dioxane

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
at 550℃; for 45h;
acetic acid
64-19-7

acetic acid

isobutene
115-11-7

isobutene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With palladium diacetate
acetic acid
64-19-7

acetic acid

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With trimethylamine
C6H10N2O2

C6H10N2O2

A

4-methyl-1H-pyrazole
7554-65-6

4-methyl-1H-pyrazole

B

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With calcium carbonate In 1,4-dioxane at 85 - 110℃; Yield given;
With calcium carbonate In 1,4-dioxane at 85 - 110℃; Yields of byproduct given;
acetic acid
64-19-7

acetic acid

Methylcyclopropen
3100-04-7

Methylcyclopropen

A

methallyl acetate
820-71-3

methallyl acetate

B

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With hydrogenchloride at 0℃;
Methylcyclopropen
3100-04-7

Methylcyclopropen

A

methallyl acetate
820-71-3

methallyl acetate

B

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

Conditions
ConditionsYield
With hydrogenchloride In acetic acid at 0℃; Product distribution; var. concentration of HCl and reaction times, other substituted cyclopropene;
With hydrogenchloride In acetic acid at 0℃;
2-methyl-allylidene diacetate

2-methyl-allylidene diacetate

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With hydrogen; nickel at 175℃; under 51485.6 Torr;
potassium acetate
127-08-2

potassium acetate

isobutenyl chloride

isobutenyl chloride

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
at 150℃;
2-methylpropenal
78-85-3

2-methylpropenal

diethylzinc
557-20-0

diethylzinc

acetic anhydride
108-24-7

acetic anhydride

A

methallyl acetate
820-71-3

methallyl acetate

B

Acetic acid (S)-1-ethyl-2-methyl-allyl ester

Acetic acid (S)-1-ethyl-2-methyl-allyl ester

C

Acetic acid (R)-1-ethyl-2-methyl-allyl ester

Acetic acid (R)-1-ethyl-2-methyl-allyl ester

Conditions
ConditionsYield
Stage #1: 2-methylpropenal; diethylzinc With (1R,2S)-(+)-1-cyclohexyl-2-phenyl-2-(N-morpholino)ethanol In hexane; toluene at 20℃; for 3h;
Stage #2: acetic anhydride In hexane; toluene Further stages. Title compound not separated from byproducts.;
(acetoxymethyl)cyclopropane
36982-54-4

(acetoxymethyl)cyclopropane

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
Wilkinson's catalyst In toluene at 130℃; for 55h;
vinyl acetate
108-05-4

vinyl acetate

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
With lipase PS-D at 25℃; for 24h;
2-chloro-3-butene
563-52-0

2-chloro-3-butene

sodium acetate
127-09-3

sodium acetate

methallyl acetate
820-71-3

methallyl acetate

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 120℃; for 0.5h; Heating / reflux;
Triethyl orthoacetate
78-39-7

Triethyl orthoacetate

3-hydroxy-2-methyl-1-propene
513-42-8

3-hydroxy-2-methyl-1-propene

A

methallyl acetate
820-71-3

methallyl acetate

B

ethyl 4-methyl-4-pentenoate
4911-54-0

ethyl 4-methyl-4-pentenoate

C

4-methyl-pent-4-enoic acid methallyl ester
86014-96-2

4-methyl-pent-4-enoic acid methallyl ester

Conditions
ConditionsYield
With acetic acid at 218℃; under 18751.9 Torr; for 0.0333333h; Temperature; Johnson-Claisen Rearrangement; Microwave irradiation; Flow reactor;A 12 %Spectr.
B 76 %Spectr.
C 11 %Spectr.
acetic acid
64-19-7

acetic acid

isobutene
115-11-7

isobutene

A

methallyl acetate
820-71-3

methallyl acetate

B

1,3-diacetoxy-2-methylenepropane
3775-29-9

1,3-diacetoxy-2-methylenepropane

Conditions
ConditionsYield
With oxygen at 160℃; under 12001.2 Torr; Temperature; Inert atmosphere;
methallyl acetate
820-71-3

methallyl acetate

ethyl acetoacetate
141-97-9

ethyl acetoacetate

ethyl 2-acetyl-4-methylpent-4-enoate
20962-70-3

ethyl 2-acetyl-4-methylpent-4-enoate

Conditions
ConditionsYield
With isopropylmagnesium chloride; sodium hydride; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran at 160℃; for 72h; Product distribution; other temp./react. time;100%
With isopropylmagnesium chloride; sodium hydride; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran at 160℃; for 72h;100%
With potassium carbonate In tetrahydrofuran at 70℃; for 50h; Tsuji-Trost Allylation;63%
methallyl acetate
820-71-3

methallyl acetate

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

dimethyl 2,2-di(2-methylallyl)malonate
74793-47-8

dimethyl 2,2-di(2-methylallyl)malonate

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); N,O-bis-(trimethylsilyl)-acetamide; 1,3-bis-(diphenylphosphino)propane In tetrahydrofuran at 20℃; for 2h;100%
methallyl acetate
820-71-3

methallyl acetate

N-4-chlorophenylhydrazine
1073-69-4

N-4-chlorophenylhydrazine

A

3-(4-chlorophenyl)-2-hydroperoxy-2-methylpropyl acetate
1621652-06-9

3-(4-chlorophenyl)-2-hydroperoxy-2-methylpropyl acetate

B

1-(4-chlorophenyl)propan-2-one
5586-88-9

1-(4-chlorophenyl)propan-2-one

Conditions
ConditionsYield
With manganese(IV) oxide; acetic acid In acetonitrile at 23℃; for 1h;A n/a
B 100%
methallyl acetate
820-71-3

methallyl acetate

4-hydrazinobenzonitrile
17672-27-4

4-hydrazinobenzonitrile

A

4-(2-oxopropyl)benzonitrile
58949-75-0

4-(2-oxopropyl)benzonitrile

B

3-(4-cyanophenyl)-2-hydroperoxy-2-methylpropyl acetate
1621652-07-0

3-(4-cyanophenyl)-2-hydroperoxy-2-methylpropyl acetate

Conditions
ConditionsYield
With manganese(IV) oxide; acetic acid In acetonitrile at 23℃; for 1h;A 100%
B n/a
methallyl acetate
820-71-3

methallyl acetate

Benzylidenemalononitrile
2700-22-3

Benzylidenemalononitrile

2-[2-(2-methyl-allyl)-2H-tetrazol-5-yl]-3-phenyl-acrylonitrile

2-[2-(2-methyl-allyl)-2H-tetrazol-5-yl]-3-phenyl-acrylonitrile

Conditions
ConditionsYield
With trimethylsilylazide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 100℃; for 24h; cyclocondensation;99%
methallyl acetate
820-71-3

methallyl acetate

diethyl malonate
105-53-3

diethyl malonate

ethyl 4-methyl-4-pentenoate
4911-54-0

ethyl 4-methyl-4-pentenoate

Conditions
ConditionsYield
Stage #1: methallyl acetate With tetrakis(triphenylphosphine) palladium(0); triphenylphosphine In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; Reflux;
Stage #2: diethyl malonate With sodium hydride In tetrahydrofuran for 24h; Inert atmosphere; Reflux;
Stage #3: With sodium chloride In water; dimethyl sulfoxide at 180 - 200℃; for 48h;
99%
methallyl acetate
820-71-3

methallyl acetate

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

A

dimethyl (2-methyl-2-propenyl)-propanedioate
50598-40-8

dimethyl (2-methyl-2-propenyl)-propanedioate

B

dimethyl 2,2-di(2-methylallyl)malonate
74793-47-8

dimethyl 2,2-di(2-methylallyl)malonate

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); N,O-bis-(trimethylsilyl)-acetamide; N,N'-bis(diphenylphosphino)-N,N'-dimethylethane-1,2-diamine In tetrahydrofuran at 20℃; for 0.316667h; Title compound not separated from byproducts;A 98.7%
B 1.3%
methallyl acetate
820-71-3

methallyl acetate

acetic anhydride
108-24-7

acetic anhydride

C10H16O6
911800-80-1

C10H16O6

Conditions
ConditionsYield
With peracetic acid; palladium diacetate; acetic acid at 60℃; for 0.0833333h; Green chemistry;96%
1-methyl-pyrrolidin-2-one
872-50-4

1-methyl-pyrrolidin-2-one

2-chloro-3-butene
563-52-0

2-chloro-3-butene

methallyl acetate
820-71-3

methallyl acetate

4-Chlorobutanoyl chloride
4635-59-0

4-Chlorobutanoyl chloride

2-(4-(4-chloro-1-oxo-butyl))-phenyl-2-methyl propanyl acetate

2-(4-(4-chloro-1-oxo-butyl))-phenyl-2-methyl propanyl acetate

Conditions
ConditionsYield
With sodium acetate; aluminium trichloride In dichloromethane; benzene95.6%
With sodium acetate; aluminium trichloride In dichloromethane; benzene95.6%
methallyl acetate
820-71-3

methallyl acetate

butyl ester of α-nitropropionic acid
106306-42-7

butyl ester of α-nitropropionic acid

butyl 2,4-dimethyl-2-nitro-4-pentenoate
113747-73-2

butyl 2,4-dimethyl-2-nitro-4-pentenoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 6h;94.4%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

methallyl acetate
820-71-3

methallyl acetate

1-methoxy-4-(2-methylallyl)benzene
20849-82-5

1-methoxy-4-(2-methylallyl)benzene

Conditions
ConditionsYield
With pyridine; nickel(II) iodide; 4-chloro-2-(4,5-dihydro-1H-imidazol-2-yl)pyridine; tetrabutylammomium bromide; magnesium chloride; zinc In N,N-dimethyl acetamide at 60℃; for 12h; Schlenk technique; Inert atmosphere; regioselective reaction;94%
Stage #1: 1-bromo-4-methoxy-benzene With magnesium; lithium chloride In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;
Stage #2: With iron(III)-acetylacetonate In tetrahydrofuran for 0.0833333h; Inert atmosphere;
Stage #3: methallyl acetate In tetrahydrofuran at 0℃; for 0.75h; Inert atmosphere;
4‐hydroxycoumarin
22105-09-5

4‐hydroxycoumarin

methallyl acetate
820-71-3

methallyl acetate

2,2-dimethyl-2,3-dihydrofuro[3,2-c]chromen-4-one
109797-44-6

2,2-dimethyl-2,3-dihydrofuro[3,2-c]chromen-4-one

Conditions
ConditionsYield
With indium(III) triflate In nitromethane for 17h; Solvent; Schlenk technique; Inert atmosphere; Reflux;94%
methallyl acetate
820-71-3

methallyl acetate

rac-methylbenzylamine
618-36-0

rac-methylbenzylamine

A

(2-Methyl-allyl)-(1-phenyl-ethyl)-amine

(2-Methyl-allyl)-(1-phenyl-ethyl)-amine

B

Bis-(2-methyl-allyl)-(1-phenyl-ethyl)-amine

Bis-(2-methyl-allyl)-(1-phenyl-ethyl)-amine

Conditions
ConditionsYield
Pd(OAc)2 + tppts In water; acetonitrile at 45℃; for 10h;A 92%
B 8%
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

methallyl acetate
820-71-3

methallyl acetate

ethyl 2,2-bis(2-methylallyl)-2-nitroacetate
144783-07-3

ethyl 2,2-bis(2-methylallyl)-2-nitroacetate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 50℃; for 8h;92%
methallyl acetate
820-71-3

methallyl acetate

4-fluorobenzenediazonium tetrafluoroborate
459-45-0

4-fluorobenzenediazonium tetrafluoroborate

acetic acid 3-(4-fluorophenyl)-2-(4-fluorophenylazo)-2-methylpropyl ester
1053269-75-2

acetic acid 3-(4-fluorophenyl)-2-(4-fluorophenylazo)-2-methylpropyl ester

Conditions
ConditionsYield
With ferrous(II) sulfate heptahydrate In water; dimethyl sulfoxide at 20℃; for 0.333333h; Inert atmosphere;91%
With ferrous(II) sulfate heptahydrate In water; dimethyl sulfoxide Inert atmosphere;62%
With ferrous(II) sulfate heptahydrate In water; dimethyl sulfoxide for 0.25h; Inert atmosphere;62%
methallyl acetate
820-71-3

methallyl acetate

2,2,2-trichloroethyl acetate
625-24-1

2,2,2-trichloroethyl acetate

1,5-diacetoxy-2,2,4-trichloro-4-methylpentane

1,5-diacetoxy-2,2,4-trichloro-4-methylpentane

Conditions
ConditionsYield
With iron(III) chloride; iron In N,N-dimethyl-formamide at 100℃; for 24h;90%
methallyl acetate
820-71-3

methallyl acetate

1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

(R)-1-phenethyl acetate
16197-92-5

(R)-1-phenethyl acetate

Conditions
ConditionsYield
With potassium tert-butylate; sodium carbonate; Candida antarctica lipase B; chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl) ruthenium (II) In toluene at 20 - 70℃; for 12 - 30h; Product distribution / selectivity;90%
With potassium tert-butylate; sodium carbonate; Candida antarctica lipase B; N-isopropylamino-2,3,4,5-tetraphenylcyclopentadienyl ruthenium dicarbonyl hydride In toluene at 20℃; for 30h; Product distribution / selectivity;88%
methallyl acetate
820-71-3

methallyl acetate

N,N-diphenylphenylacetamide
33675-70-6

N,N-diphenylphenylacetamide

C24H23NO

C24H23NO

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); C40H41FeN2O3P; lithium chloride; lithium hexamethyldisilazane In tetrahydrofuran at 20℃; optical yield given as %ee; enantioselective reaction;90%
methallyl acetate
820-71-3

methallyl acetate

benzene
71-43-2

benzene

(2-acetoxy-1,1-dimethylethyl)benzene
18755-52-7

(2-acetoxy-1,1-dimethylethyl)benzene

Conditions
ConditionsYield
With aluminum (III) chloride; propylene glycol In acetic acid methyl ester at 0 - 5℃;89.7%
With aluminium trichloride at 0 - 10℃; for 1h;193 g
With aluminum (III) chloride at 0 - 3℃; for 0.5h;
nitroacetic acid ethyl ester
626-35-7

nitroacetic acid ethyl ester

methallyl acetate
820-71-3

methallyl acetate

A

ethyl (4-methyl-2-nitro) pent-4-enoate
93500-38-0

ethyl (4-methyl-2-nitro) pent-4-enoate

B

ethyl 2,2-bis(2-methylallyl)-2-nitroacetate
144783-07-3

ethyl 2,2-bis(2-methylallyl)-2-nitroacetate

Conditions
ConditionsYield
With triethylamine; Pd(OAc)2 + tppts In water; acetonitrile at 25℃; for 10h;A 88%
B 12%
methallyl acetate
820-71-3

methallyl acetate

tert-butyl 5-oxo-4-phenylisoxazolidine-2-carboxylate

tert-butyl 5-oxo-4-phenylisoxazolidine-2-carboxylate

tert-butyl (S)-4-(2-methylallyl)-5-oxo-4-phenylisoxazolidine-2-carboxylate

tert-butyl (S)-4-(2-methylallyl)-5-oxo-4-phenylisoxazolidine-2-carboxylate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium carbonate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane In tetrahydrofuran at 0℃; Inert atmosphere; enantioselective reaction;88%
methallyl acetate
820-71-3

methallyl acetate

N-Phenylhydroxylamine
100-65-2

N-Phenylhydroxylamine

N-(2-methylallyl)-N-phenylhydroxylamine

N-(2-methylallyl)-N-phenylhydroxylamine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;87%
With tetrakis(triphenylphosphine) palladium(0) In toluene at 25℃; for 1h; Inert atmosphere;
methallyl acetate
820-71-3

methallyl acetate

4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

3-(4-(methoxycarbonyl)phenyl)-2-methylpropene

3-(4-(methoxycarbonyl)phenyl)-2-methylpropene

Conditions
ConditionsYield
With pyridine; nickel(II) iodide; 4-chloro-2-(4,5-dihydro-1H-imidazol-2-yl)pyridine; tetrabutylammomium bromide; magnesium chloride; zinc In N,N-dimethyl acetamide at 60℃; for 12h; Schlenk technique; Inert atmosphere; regioselective reaction;86%
methallyl acetate
820-71-3

methallyl acetate

tert-butyl glycolate
50595-15-8

tert-butyl glycolate

tert-butyl 2-hydroxy-4-methylpent-4-enoate

tert-butyl 2-hydroxy-4-methylpent-4-enoate

Conditions
ConditionsYield
Stage #1: tert-butyl glycolate With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - 20℃; for 0.666667h; Inert atmosphere;
Stage #2: With zinc(II) chloride In tetrahydrofuran; hexane at -78 - 20℃; for 0.666667h; Inert atmosphere;
Stage #3: methallyl acetate With (2-methylallyl)palladium-chloride dimer; triphenylphosphine In tetrahydrofuran; hexane at -78 - 20℃; for 16h; Inert atmosphere;
86%
methallyl acetate
820-71-3

methallyl acetate

2-allyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide
41335-56-2

2-allyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

2-(2,5-dimethylhex-5-en-1-yl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide

2-(2,5-dimethylhex-5-en-1-yl)benzo[d]isothiazol-3(2H)-one 1,1-dioxide

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In 2-methyltetrahydrofuran; n-heptane at -40 - 0℃; for 24h; Inert atmosphere; regioselective reaction;86%
methallyl acetate
820-71-3

methallyl acetate

N,N-diphenylpropionamide
20619-23-2

N,N-diphenylpropionamide

2,4-dimethyl-N,N-diphenylpent-4-enamide

2,4-dimethyl-N,N-diphenylpent-4-enamide

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); C40H41FeN2O3P; lithium chloride; lithium hexamethyldisilazane In tetrahydrofuran at 20℃; optical yield given as %ee; enantioselective reaction;85%
methallyl acetate
820-71-3

methallyl acetate

tributyltin methoxide
1067-52-3

tributyltin methoxide

2-methylallyltributyltin
67883-62-9

2-methylallyltributyltin

Conditions
ConditionsYield
With manganese; chloro-trimethyl-silane; 4,4'-di-tert-butyl-2,2'-bipyridine; nickel dibromide In N,N-dimethyl-formamide at 25℃; Inert atmosphere; Schlenk technique; diastereoselective reaction;85%

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