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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Ethylene chlorophosphite with high purity

Cas:822-39-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 822-39-9 with best quality

Cas:822-39-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

2-Chloro-1,3,2-dioxaphospholaneCAS822-39-9

Cas:822-39-9

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,3,2-Dioxaphospholane,2-chloro-

Cas:822-39-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Chloro-1,3,2-dioxaphospholane CAS:822-39-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

2-Chloro-1,3,2-dioxaphospholane CAS:822-39-9

Cas:822-39-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,3,2-Dioxaphospholane,2-chloro-

Cas:822-39-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,3,2-Dioxaphospholane,2-chloro-

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 822-39-9 ,2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Ethylene chlorophosphite

Cas:822-39-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2-Chloro-1,3,2-dioxaphospholane 5g

Cas:822-39-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Ethylene chlorophosphite, 97%

Cas:822-39-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

1,3,2-Dioxaphospholane,2-chloro-

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,3,2-Dioxaphospholane,2-chloro-

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Ethylene chlorophosphite

Cas:822-39-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

2-Chloro-1,3,2-dioxaphospholane Application:2-Chloro-1,3,2-dioxaphospholane

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0

Negotiable

Type:Other

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:clear light yellow liquid Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

822-39-9

Cas:822-39-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-CHLORO-1,3,2-DIOXAPHOSPHOLANEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-CHLORO-1,3,2-DIOXAPHOSPHOLANE

Cas:822-39-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Chloro-1,3,2-dioxaphospholane

Cas:822-39-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ethylene glycol
107-21-1

ethylene glycol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

Conditions
ConditionsYield
With phosphorus trichloride In dichloromethane at 0℃; for 14h;92%
With phosphorus trichloride In dichloromethane at 20℃; for 0.5h; Inert atmosphere;74.7%
With phosphorus trichloride In dichloromethane at 20℃; for 3h; Inert atmosphere;67%
ethylene glycol
107-21-1

ethylene glycol

A

1,1,6,6-tetrachloro-2,5-dioxa-1,6-diphosphahexane
37445-80-0

1,1,6,6-tetrachloro-2,5-dioxa-1,6-diphosphahexane

B

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

Conditions
ConditionsYield
With triethylamine; phosphorus trichloride at 45℃; Reagent/catalyst;A 51.7%
B n/a
With phosphorus trichloride anfangs unter Luehlung,dann bei 60-70grad;
2-methyl-[1,3,2]dioxarsolane
18882-67-2

2-methyl-[1,3,2]dioxarsolane

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

Conditions
ConditionsYield
With phosphorus trichloride In benzene
pyridine
110-86-1

pyridine

diethyl ether
60-29-7

diethyl ether

ethylene glycol
107-21-1

ethylene glycol

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

dichloromethane
75-09-2

dichloromethane

ethylene glycol
107-21-1

ethylene glycol

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

diethyl ether
60-29-7

diethyl ether

ethylene glycol
107-21-1

ethylene glycol

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

ethylene glycol
107-21-1

ethylene glycol

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

1,1,6,6-tetrachloro-2,5-dioxa-1,6-diphosphahexane
37445-80-0

1,1,6,6-tetrachloro-2,5-dioxa-1,6-diphosphahexane

B

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

Conditions
ConditionsYield
anfangs unter Kuehlung, dann bei 60-70grad;
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-azido-1,3,2-dioxaphospholane
85741-80-6

2-azido-1,3,2-dioxaphospholane

Conditions
ConditionsYield
With trimethylsilylazide at 0 - 5℃; for 3h;100%
With (C2H5)3N*NH3
N-methylbenzamide
88070-48-8

N-methylbenzamide

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

ethylene benzoylmethyphosphoramidite

ethylene benzoylmethyphosphoramidite

Conditions
ConditionsYield
In diethyl ether Ambient temperature;97%
2,3-Di(stearoyloxy)-1-propanthiol
127472-90-6

2,3-Di(stearoyloxy)-1-propanthiol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(2,3-Distearoyloxypropyl)-1,3,2-dioxaphospholan-2-sulfid
134152-76-4

2-(2,3-Distearoyloxypropyl)-1,3,2-dioxaphospholan-2-sulfid

Conditions
ConditionsYield
With triethylamine In benzene for 3h; Ambient temperature;96%
lithium 2-(diphenylphosphanyl)pyrrolide

lithium 2-(diphenylphosphanyl)pyrrolide

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-diphenylphosphino-1-(1,3,2-dioxaphospholane)pyrrole

2-diphenylphosphino-1-(1,3,2-dioxaphospholane)pyrrole

Conditions
ConditionsYield
In diethyl ether at 23℃; for 25h; Glovebox; Inert atmosphere;96%
methanol
67-56-1

methanol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

methoxy-2 dioxaphospholane-1,3,2
3741-36-4

methoxy-2 dioxaphospholane-1,3,2

Conditions
ConditionsYield
Stage #1: methanol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
95%
With pyridine
With 2,3-Dimethylaniline
With triethylamine
ethanol
64-17-5

ethanol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-Ethoxy-1,3,2-dioxaphospholan
695-11-4

2-Ethoxy-1,3,2-dioxaphospholan

Conditions
ConditionsYield
Stage #1: ethanol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
95%
With triethylamine
2,2,2-trichloro-1-(2-oxo-1-aza-1-cyclopentyl)ethanol
7042-60-6

2,2,2-trichloro-1-(2-oxo-1-aza-1-cyclopentyl)ethanol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

ethylene 2,2,2-trichloro-1-(2-oxo-1-aza-1-cyclopentyl)ethyl phosphite

ethylene 2,2,2-trichloro-1-(2-oxo-1-aza-1-cyclopentyl)ethyl phosphite

Conditions
ConditionsYield
With triethylamine In benzene at 0℃;95%
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

1-butyn-4-ol
927-74-2

1-butyn-4-ol

2-(3-butynyloxy)-1,3,2-dioxaphospholane

2-(3-butynyloxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 3-Butyn-1-ol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
95%
1,1,1-trifluoro-2,4-pentanediol
400-32-8

1,1,1-trifluoro-2,4-pentanediol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

C9H15F3O6P2

C9H15F3O6P2

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 8h;95%
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

(R)-oxiranemethanol
57044-25-4

(R)-oxiranemethanol

(R)-2-(oxiran-2-ylmethoxy)-1,3,2-dioxaphospholane

(R)-2-(oxiran-2-ylmethoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
With triethylamine In diethyl ether at 0 - 20℃; for 3h; Reagent/catalyst; Solvent;94.8%
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

allyl alcohol
107-18-6

allyl alcohol

2-allyloxy-1,3,2-dioxaphospholane
53969-10-1

2-allyloxy-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: allyl alcohol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
With pyridine; diethyl ether
With triethylamine
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

phenol
108-95-2

phenol

2-phenoxy-[1,3,2]dioxaphospholane
1077-05-0

2-phenoxy-[1,3,2]dioxaphospholane

Conditions
ConditionsYield
Stage #1: phenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 13.5h;
94%
With triethylamine
With triethylamine In hexane
α-naphthol
90-15-3

α-naphthol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(1-naphthalenoxy)-1,3,2-dioxaphospholane
110232-62-7

2-(1-naphthalenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: α-naphthol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
With triethylamine In benzene
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

diisopropylamine
108-18-9

diisopropylamine

2-Diisopropylamino-1,3,2-dioxaphospholane
28623-31-6

2-Diisopropylamino-1,3,2-dioxaphospholane

Conditions
ConditionsYield
In dichloromethane Cooling with ice; Inert atmosphere;94%
In dichloromethane at 20℃; for 16h; Amination;93%
In diethyl ether at 0℃;
2-(N-benzylidenamino)ethanol
770-37-6

2-(N-benzylidenamino)ethanol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(benzylideneamino)ethyl ethylene phosphite

2-(benzylideneamino)ethyl ethylene phosphite

Conditions
ConditionsYield
With triethylamine In diethyl ether at 20℃;94%
4-cyanophenol
767-00-0

4-cyanophenol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(4-cyanophenoxy)-1,3,2-dioxaphospholane

2-(4-cyanophenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 4-cyanophenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
homoalylic alcohol
627-27-0

homoalylic alcohol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(but-3-en-1-yloxy)-1,3,2-dioxaphospholane

2-(but-3-en-1-yloxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: homoalylic alcohol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
pentafluoroethyl alcohol
7057-80-9

pentafluoroethyl alcohol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(1,1,2,2,2-pentafluoroethoxy)-1,3,2-dioxaphospholane

2-(1,1,2,2,2-pentafluoroethoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: pentafluoroethyl alcohol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
1,1,1,3',3',3'-hexafluoro-propanol
920-66-1

1,1,1,3',3',3'-hexafluoro-propanol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)-1,3,2-dioxaphospholane
85762-88-5

2-((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 1,1,1,3',3',3'-hexafluoro-propanol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

β-naphthol
135-19-3

β-naphthol

2-(2-naphthalenoxy)-1,3,2-dioxaphospholane

2-(2-naphthalenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: β-naphthol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
94%
2-methyl-1.3-propanediol
2163-42-0

2-methyl-1.3-propanediol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

C8H16O6P2

C8H16O6P2

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 12h;94%
2,4-dimethylpentane-2,4-diol
24892-49-7, 139687-48-2

2,4-dimethylpentane-2,4-diol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

C11H22O6P2

C11H22O6P2

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 12h;94%
propylene glycol
57-55-6

propylene glycol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2,2'-(1-methyl-ethane-1,2-diyldioxy)-bis-[1,3,2]dioxaphospholane
92304-17-1

2,2'-(1-methyl-ethane-1,2-diyldioxy)-bis-[1,3,2]dioxaphospholane

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 12h;93%
With triethylamine
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

trimethyleneglycol
504-63-2

trimethyleneglycol

2,2'-propane-1,3-diyldioxy-bis-[1,3,2]dioxaphospholane
92304-16-0

2,2'-propane-1,3-diyldioxy-bis-[1,3,2]dioxaphospholane

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 12h;93%
With triethylamine
2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

dimethylglyoxal
431-03-8

dimethylglyoxal

2-(β-Chloroaethoxi)-2-oxo-4,5-dimethyl-1,3,2λ5-dioxaphospholen
76266-23-4

2-(β-Chloroaethoxi)-2-oxo-4,5-dimethyl-1,3,2λ5-dioxaphospholen

Conditions
ConditionsYield
Mechanism;93%
In neat (no solvent) at 80℃;93%
p-cresol
106-44-5

p-cresol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(4-methylphenoxy)-1,3,2-dioxaphospholane
857367-49-8

2-(4-methylphenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: p-cresol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
93%
With pyridine In chloroform-d1
2-fluorophenol
367-12-4

2-fluorophenol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(2-fluorophenoxy)-1,3,2-dioxaphospholane

2-(2-fluorophenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 2-fluorophenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
93%
4-Fluorophenol
371-41-5

4-Fluorophenol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(4-fluorophenoxy)-1,3,2-dioxaphospholane

2-(4-fluorophenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 4-Fluorophenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
93%
3-fluorophenol
372-20-3

3-fluorophenol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(3-fluorophenoxy)-1,3,2-dioxaphospholane

2-(3-fluorophenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 3-fluorophenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
93%
2-(trifluoromethyl)phenol
444-30-4

2-(trifluoromethyl)phenol

2-chloro-1,3,2-dioxaphospholan
822-39-9

2-chloro-1,3,2-dioxaphospholan

2-(2-trifluoromethylphenoxy)-1,3,2-dioxaphospholane

2-(2-trifluoromethylphenoxy)-1,3,2-dioxaphospholane

Conditions
ConditionsYield
Stage #1: 2-(trifluoromethyl)phenol In dichloromethane at 20℃; for 0.5h;
Stage #2: 2-chloro-1,3,2-dioxaphospholan In dichloromethane at 0 - 20℃; for 12h;
93%

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