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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

trimethylsilane

Cas:993-07-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

T he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service Appearance:White or

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trimethylsilane

Cas:993-07-7

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 993-07-7 Trimethylsilane Manufacturer

Cas:993-07-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Silane, trimethyl-

Cas:993-07-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

TRIMETHYLSILANE CAS:993-07-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

TRIMETHYLSILANE CAS:993-07-7

Cas:993-07-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Silane, trimethyl-

Cas:993-07-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Silane, trimethyl-

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Silane, trimethyl-

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

trimethylsilane

Cas:993-07-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Trimethylsilane

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trimethylsilane

Cas:993-07-7

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Silane, trimethyl-

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

Trimethysilane993-07-7

Cas:993-07-7

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Silane, trimethyl-

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Trimethylsilane

Cas:993-07-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

Trimethylsilane CAS NO.993-07-7 Application:Trimethylsilane CAS NO.993-07-7

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

best seller Application:API

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Trimethylsilane CAS NO.993-07-7Appearance:detailed see specifications Storage:Keep in dry and cool place Package:according to clients requirement Application:It is an important raw material and intermediate used in Organic Synthesis,Pharmaceuticals,

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

TRIMETHYLSILANE

Cas:993-07-7

Min.Order:0

Negotiable

Type:Other

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Stable supply of goods and provision of high-quality services Application:As raw materials in the field of medicine and biology

Trimethylsilane CAS NO.993-07-7

Cas:993-07-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
aluminum (III) chloride; lithium chloride In xylene at 80℃; for 0.166667h; Product distribution / selectivity;95.4%
In toluene at 80℃; for 0.166667h; Product distribution / selectivity;92.5%
lithium tetrachloroaluminate In toluene at 80℃; for 0.166667h; Product distribution / selectivity;92.7%
1-(Trimethylsilyloxy)cyclohexene
6651-36-1

1-(Trimethylsilyloxy)cyclohexene

A

trimethylsilan
993-07-7

trimethylsilan

B

cyclohexanone
108-94-1

cyclohexanone

Conditions
ConditionsYield
With hydrogen; [RuCl(η2-H2)(dppe)2]OTf In 1,2-dichloro-ethane at 50℃; under 760 Torr; for 48h; Product distribution; Further Variations:; Catalysts;A n/a
B 95%
With hydrogen; [RuCl(dppe)2]OTf In benzene-d6 at 50℃; for 3h; Hydrogenolysis; Title compound not separated from byproducts;
trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With C35H37IrN2P(1+)*C24BF20(1-); hydrogen; N-ethyl-N,N-diisopropylamine; triphenylphosphine In (2)H8-toluene at 20℃; under 760.051 Torr; for 4.5h;94%
With [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at -196 - 60℃; under 3040.2 Torr; for 48h;95 %Spectr.
With 1,4-bis-(trimethylsilyl)benzene; [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at 60℃; under 3040.2 Torr; for 48h; Reagent/catalyst;95 %Spectr.
With [Ru(H)2CO(HN(CH2CH2P(iPr)2)2)]; hydrogen; triethylamine In benzene-d6 at 20℃; under 3000.3 Torr; for 18h; Catalytic behavior; Pressure;85 %Spectr.
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With lithium aluminium tetrahydride; calcium hydride In diethylene glycol dimethyl ether for 11h; Inert atmosphere; Reflux;92%
With lithium aluminium tetrahydride In toluene at 80℃; for 0.916667h; Inert atmosphere;82%
With lithium aluminium tetrahydride In hexane at 40℃; for 3h; Irradiation; ultrasonic irradiation;80%
C10H26OSi3
83268-94-4

C10H26OSi3

A

trimethyl(prop-1-ynyl)silane
6224-91-5

trimethyl(prop-1-ynyl)silane

B

trimethylsilan
993-07-7

trimethylsilan

C

Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

D

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
at 650℃; under 0.0001 Torr;A 18%
B n/a
C 87%
D 28%
1,1,2,2-tetramethyldisilane
814-98-2

1,1,2,2-tetramethyldisilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

C

dimethylsilane
1111-74-6

dimethylsilane

D

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With tetra-n-butylphosphonium chloride at 180℃; for 17h; Sealed tube;A 2%
B 4%
C 87%
D 7%
pentamethylchlorodisilane
1560-28-7

pentamethylchlorodisilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With 2-methylimidazole; tetra-n-butylphosphonium chloride at 175℃; for 89h; Sealed tube;A 85%
B 11%
Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

3-dimethylaminophenyl-trimethylsilane
17961-91-0

3-dimethylaminophenyl-trimethylsilane

A

trimethylsilan
993-07-7

trimethylsilan

B

3-(dimethyl(phenyl)silyl)-N,N-dimethylaniline

3-(dimethyl(phenyl)silyl)-N,N-dimethylaniline

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate In chlorobenzene at 100℃; for 24h; Mechanism; Glovebox; Inert atmosphere; chemoselective reaction;A n/a
B 81%
3-(dimethylsilyl)-N,N-dimethylaniline

3-(dimethylsilyl)-N,N-dimethylaniline

A

trimethylsilan
993-07-7

trimethylsilan

B

3,3′-(dimethylsilanediyl)-bis(N,N-dimethylaniline)

3,3′-(dimethylsilanediyl)-bis(N,N-dimethylaniline)

Conditions
ConditionsYield
With trimethylphenylsilane; tris(pentafluorophenyl)borate In chlorobenzene at 100℃; for 24h; Mechanism; Glovebox; chemoselective reaction;A n/a
B 78%
2-cyclopropyl-2-methoxyhexamethyltrisilane
83268-89-7

2-cyclopropyl-2-methoxyhexamethyltrisilane

A

trimethyl(prop-1-ynyl)silane
6224-91-5

trimethyl(prop-1-ynyl)silane

B

trimethylsilan
993-07-7

trimethylsilan

C

Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

D

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
at 590℃; under 0.0001 Torr;A 18%
B n/a
C 72%
D 27%
N,N-diethyl-1,1,1-trimethylsilanamine
996-50-9

N,N-diethyl-1,1,1-trimethylsilanamine

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With lithium aluminium tetrahydride In hexane at 40℃; for 3h; Irradiation; ultrasonic irradiation;70%
Al(SiMe3)3*OEt2

Al(SiMe3)3*OEt2

diphenylphosphane
829-85-6

diphenylphosphane

A

{((CH3)3Si)2AlP(C6H5)2}2
111920-15-1

{((CH3)3Si)2AlP(C6H5)2}2

B

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
In hexane combining Ph2PH soln. with (Me3Si)Al.Et2O soln. at -78 °C, warming to 25 °C, evapn. after several h, redissolution of resulting oil in hexane, refluxing for 48 h ; under inert gas; cooling, decantation, washing of residue with hexane twice (improvement of yield by collection of decanted liquids and filtrates and crystn. from hexane at -20 °C) ; elem. anal.;A 65%
B n/a
(C6H5)3PNP(C6H5)3(1+)*(CO)4FeSi(CH3)3(1-)=(C6H5)3PNP(C6H5)3[(CO)4FeSi(CH3)3]
78465-74-4

(C6H5)3PNP(C6H5)3(1+)*(CO)4FeSi(CH3)3(1-)=(C6H5)3PNP(C6H5)3[(CO)4FeSi(CH3)3]

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

A

dihydridotetracarbonyliron
71564-37-9, 22763-20-8, 12002-28-7

dihydridotetracarbonyliron

B

trimethylsilan
993-07-7

trimethylsilan

C

(CO)4FeH(Si(CH3)3)
63022-27-5

(CO)4FeH(Si(CH3)3)

Conditions
ConditionsYield
With Hexamethylbenzene In dichloromethane-d2 mixt. of Fe-complex, hexamethylbenzene standard (molar ratio 1:0.25) and CD2Cl2 cooled to -40°C, 1 equiv of CF3SO3H added; without isolation; monitored by (1)H NMR spectra;A n/a
B 0%
C 65%
ethyl trimethylsilyl ether
1825-62-3

ethyl trimethylsilyl ether

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; borane-THF In tetrahydrofuran at 20℃; for 48h;64%
trimethylsilyl iodide
16029-98-4

trimethylsilyl iodide

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
With C35H37IrN2P(1+)*C24BF20(1-); hydrogen; N-ethyl-N,N-diisopropylamine; triphenylphosphine In (2)H8-toluene at 20℃; under 760.051 Torr; for 432h;61%
With [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at -196 - 60℃; under 3040.2 Torr; for 48h; Mechanism; Reagent/catalyst;91 %Spectr.
With 1,4-bis-(trimethylsilyl)benzene; [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at 60℃; under 3040.2 Torr; for 48h; Reagent/catalyst;91 %Spectr.
1,1-Dimethyl-2,3-bis-trimethylsilanyl-[1,3]disiletane
86997-49-1

1,1-Dimethyl-2,3-bis-trimethylsilanyl-[1,3]disiletane

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

trimethylsilan
993-07-7

trimethylsilan

B

2,2,6,7-Tetramethyl-1-trimethylsilanyl-2,4-disila-spiro[3.4]oct-6-ene
86997-51-5

2,2,6,7-Tetramethyl-1-trimethylsilanyl-2,4-disila-spiro[3.4]oct-6-ene

Conditions
ConditionsYield
In benzene at 450℃; in a vertical Pyrex tube packed with Pyrex chips;A n/a
B 57%

A

trimethyl(prop-1-ynyl)silane
6224-91-5

trimethyl(prop-1-ynyl)silane

B

trimethylsilan
993-07-7

trimethylsilan

C

Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

D

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
at 650℃; under 0.0001 Torr;A 17%
B n/a
C 55%
D 16%
trimethylsilyldiethylgermane
100460-02-4

trimethylsilyldiethylgermane

triethylgermylcesium
51639-33-9

triethylgermylcesium

A

pentaethyldigermane
993-84-0

pentaethyldigermane

B

trimethylsilan
993-07-7

trimethylsilan

C

Triethylgerman
1188-14-3

Triethylgerman

D

hexaethyldigermane
993-62-4

hexaethyldigermane

E

trimethylsilyltriethylgermane
7749-85-1

trimethylsilyltriethylgermane

Conditions
ConditionsYield
With water In benzene byproducts: Me3SiGeEt2H; Mixt. of Me3SiGe(H) and Et3GeCs in benzene is stirred for 72 h at 25°C.; After hydrolysis mixt. is examined by GLC, gas chromy. and mass spectrometry.;A 53.2%
B 7.7%
C 18.9%
D 4.4%
E 3%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

A

trimethylsilan
993-07-7

trimethylsilan

B

N-(2-trimethylsilylbenzylidene)methylamine

N-(2-trimethylsilylbenzylidene)methylamine

C

N-<2,6-bis(trimethylsilyl)benzylidene>methylamine

N-<2,6-bis(trimethylsilyl)benzylidene>methylamine

Conditions
ConditionsYield
tris(dibenzylideneacetone)diplatinum(0); 3 P(OCH2)3CEt In toluene at 160℃; for 120h;A n/a
B 23%
C 52%
tris(dibenzylideneacetone)diplatinum(0); 3 P(OCH2)3CEt In toluene at 160℃; for 120h; Product distribution; Mechanism; var. of ratio imine:silane, time;A n/a
B 38%
C 27%
tris(dibenzylideneacetone)diplatinum(0); 3 P(OCH2)3CEt In toluene at 160℃; for 120h; Yield given. Yields of byproduct given;
Al(SiMe3)3*OEt2

Al(SiMe3)3*OEt2

phenyl(trimethylsilyl)phosphine
32796-33-1

phenyl(trimethylsilyl)phosphine

A

{((CH3)3Si)2AlP(C6H5)Si(CH3)3}2
118334-37-5

{((CH3)3Si)2AlP(C6H5)Si(CH3)3}2

B

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
In hexane combining (Me3Si)PhPH soln. with (Me3Si)Al.Et2O soln. at -78 °C, warming to 25 °C, stirring 4 h, evapn. of solvent, redissolution of resulting oil in hexane, refluxing for 48 h ; under inert gas; concn., decantation, washing of residue with cold hexane (improvement of yield by collection of decanted liquids and filtrates and crystn. from hexane at -20 °C), drying in vacuo;A 50%
B n/a
1,1,1,3,3,3-hexamethyltrisilane
5089-32-7

1,1,1,3,3,3-hexamethyltrisilane

A

trimethylsilan
993-07-7

trimethylsilan

B

1-methyl-1,3-disilacyclobutane
80540-80-3

1-methyl-1,3-disilacyclobutane

Conditions
ConditionsYield
at 750℃; under 0.05 Torr;A n/a
B 45%
1,2-dichlorotetramethylsilane
4342-61-4

1,2-dichlorotetramethylsilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

C

trimethylsilan
993-07-7

trimethylsilan

D

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With tetra-n-butylphosphonium chloride at 220℃; for 24h; Sealed tube;A 16%
B 30%
C 5%
D 44%
bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

bis(trifluoromethyl)phosphine
460-96-8

bis(trifluoromethyl)phosphine

A

(CH3)3SiP(H)CF3

(CH3)3SiP(H)CF3

B

trimethylsilan
993-07-7

trimethylsilan

C

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

D

Trimethylsilyl-bis-(trifluormethyl)-phosphin
21658-00-4

Trimethylsilyl-bis-(trifluormethyl)-phosphin

E

mercury

mercury

Conditions
ConditionsYield
A n/a
B n/a
C n/a
D 40%
E n/a
bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

bis(trifluoromethyl)phosphinic chloride
646-71-9

bis(trifluoromethyl)phosphinic chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

trimethylsilan
993-07-7

trimethylsilan

C

bis(trifluoromethyl)chlorophosphine
650-52-2

bis(trifluoromethyl)chlorophosphine

D

Bistrifluormethyltrimethylsiloxyphosphinoxid
32114-80-0

Bistrifluormethyltrimethylsiloxyphosphinoxid

Conditions
ConditionsYield
warming up from -84°C to 20°C;A n/a
B n/a
C n/a
D 38%
warming up from -84°C to 20°C;A n/a
B n/a
C n/a
D 38%
(dimethylphenylgermyl)trimethylsilane
37899-63-1

(dimethylphenylgermyl)trimethylsilane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylsilan
993-07-7

trimethylsilan

C

trimethylphenylsilane
768-32-1

trimethylphenylsilane

D

dimethylphenylgermane
7366-21-4

dimethylphenylgermane

E

1,1,2,2-tetramethyl-1,2-diphenyldigermane
22702-72-3

1,1,2,2-tetramethyl-1,2-diphenyldigermane

Conditions
ConditionsYield
With methanol In benzene Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;A <1
B n/a
C 37%
D <1
E <1
In cyclohexane Irradiation (UV/VIS); irradiation of catenate in cyclohexane with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;A <1
B 4%
C 24%
D <1
E <1
triethylsilane
617-86-7

triethylsilane

2-(pentamethyldisilanyl)furan
156116-66-4

2-(pentamethyldisilanyl)furan

A

2-furyltrimethylsilane
1578-33-2

2-furyltrimethylsilane

B

trimethylsilan
993-07-7

trimethylsilan

C

triethyldimethyldisilane
31732-54-4

triethyldimethyldisilane

Conditions
ConditionsYield
In cyclohexane at 19.9℃; Rate constant; Irradiation;A 1%
B 35%
C 2%
1,2-dichlorotetramethylsilane
4342-61-4

1,2-dichlorotetramethylsilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

C

dimethylsilane
1111-74-6

dimethylsilane

D

trimethylsilan
993-07-7

trimethylsilan

E

dichloro[(chlorodimethylsilyl)methyl]methylsilane
4519-04-4

dichloro[(chlorodimethylsilyl)methyl]methylsilane

F

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With n-Butyl chloride; tributylphosphine at 220℃; for 70h; Sealed tube;A 13%
B 30%
C 2%
D 2%
E 18%
F 35%
trimethyl(prop-1-ynyl)silane
6224-91-5

trimethyl(prop-1-ynyl)silane

pentaborane(9)

pentaborane(9)

A

2-(trimethylsilyl)-3-(methyl)-2,3-dicarba-nido-hexaborane(8)

2-(trimethylsilyl)-3-(methyl)-2,3-dicarba-nido-hexaborane(8)

B

{CH3CHCSi(CH3)3}3B
91793-61-2

{CH3CHCSi(CH3)3}3B

C

trimethylsilan
993-07-7

trimethylsilan

Conditions
ConditionsYield
from -196°C to 135°C, 48 h at 135°C; fractionated by trap-to-trap destillation;A 33.4%
B n/a
C n/a
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,1-Dilithioethan
86901-29-3

1,1-Dilithioethan

A

trimethylsilan
993-07-7

trimethylsilan

B

1,1-bis(trimethylsilyl)ethane
18406-29-6

1,1-bis(trimethylsilyl)ethane

C

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
In tetrahydrofuran for 24h; Ambient temperature;A 19%
B 30%
C n/a
1,1,2,2-tetramethyl-1,2-disilacyclohex-4-ene
51043-84-6

1,1,2,2-tetramethyl-1,2-disilacyclohex-4-ene

A

1,1-Dimethylsilacyclopent-3-en
16054-12-9

1,1-Dimethylsilacyclopent-3-en

B

trimethylsilan
993-07-7

trimethylsilan

C

1,1-dimethyl-1,3-disilacyclobutanes
38512-90-2

1,1-dimethyl-1,3-disilacyclobutanes

D

1,3-dimethyl-1,3-disilacyclobutane
1628-01-9

1,3-dimethyl-1,3-disilacyclobutane

Conditions
ConditionsYield
at 750℃; under 0.01 Torr; Further byproducts given;A 25%
B 0.5%
C 16%
D 9%
trimethylsilan
993-07-7

trimethylsilan

2(μ-CO)(μ-C=C(CH3)CH2CH3) (3)

2(μ-CO)(μ-C=C(CH3)CH2CH3) (3)

A

Trimethyl-((E)-2-methyl-but-1-enyl)-silane
116597-17-2, 116663-37-7

Trimethyl-((E)-2-methyl-but-1-enyl)-silane

B

12, 13

12, 13

Conditions
ConditionsYield
In benzene-d6 for 2h; Irradiation;A 100%
B n/a
5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-bicyclo[2.2.2]octan-2-one
929097-27-8

5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-bicyclo[2.2.2]octan-2-one

trimethylsilan
993-07-7

trimethylsilan

5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-4-methyl-3-(trimethyl-silanyloxy)-bicyclo[2.2.2]octan-2-one
929097-32-5

5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-4-methyl-3-(trimethyl-silanyloxy)-bicyclo[2.2.2]octan-2-one

Conditions
ConditionsYield
With 1H-imidazole In dichloromethane at 0 - 20℃; for 1h;100%
{C5H5(CO)Fe}2(μ-CC(CH3)C2H5)

{C5H5(CO)Fe}2(μ-CC(CH3)C2H5)

trimethylsilan
993-07-7

trimethylsilan

A

cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

B

(CH3)3Si(CH3)CC(CH3)C2H5

(CH3)3Si(CH3)CC(CH3)C2H5

C

[(η(5)-Cp)Fe(CO)]4

[(η(5)-Cp)Fe(CO)]4

Conditions
ConditionsYield
In benzene-d6 Irradiation (UV/VIS); Fe complex and trimethylsilane were photolyzed (black light bulb, emission max. 366 nm) for 2 h; monitored by NMR, 4,4'-dimethylbiphenyl as internal standard;A 53%
B 100%
C 37%
{Ru2(CO)(MeCN)(μ-CH2)(μ-CO)(η-C5H5)2}

{Ru2(CO)(MeCN)(μ-CH2)(μ-CO)(η-C5H5)2}

trimethylsilan
993-07-7

trimethylsilan

(C5H5)2Ru2(μ-CH2)(H)(SiMe3)(CO)2

(C5H5)2Ru2(μ-CH2)(H)(SiMe3)(CO)2

Conditions
ConditionsYield
In benzene inert atmosphere; evapn. (reduced pressure); detd. by NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14CH3)

ClHB(C9H14CH3)

ClHB(C9H14CH3)*C4H8O

ClHB(C9H14CH3)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; -10°C (0.25 - 0.5 h); detd. by (11)B NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14C2H5)

ClHB(C9H14C2H5)

ClHB(C9H14C2H5)*C4H8O

ClHB(C9H14C2H5)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; stirring (15 min); detd. by (11)B NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14CH(CH3)2)

ClHB(C9H14CH(CH3)2)

ClHB(C9H14CH(CH3)2)*C4H8O

ClHB(C9H14CH(CH3)2)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; -10°C (0.25 - 0.5 h); detd. by (11)B NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14C3H7)

ClHB(C9H14C3H7)

ClHB(C9H14C3H7)*C4H8O

ClHB(C9H14C3H7)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; -10°C (0.25 - 0.5 h); detd. by (11)B NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14CH2CH(CH3)2)

ClHB(C9H14CH2CH(CH3)2)

ClHB(C9H14CH2CH(CH3)2)*C4H8O

ClHB(C9H14CH2CH(CH3)2)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; -10°C (0.25 - 0.5 h); detd. by (11)B NMR spectroscopy;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

trimethylsilan
993-07-7

trimethylsilan

ClHB(C9H14C6H5)

ClHB(C9H14C6H5)

ClHB(C9H14C6H5)*C4H8O

ClHB(C9H14C6H5)*C4H8O

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; -10°C (0.25 - 0.5 h); detd. by (11)B NMR spectroscopy;100%
trimethylsilan
993-07-7

trimethylsilan

Ru(CO)2(CH3P(C(CH3)3)2)2
167774-59-6

Ru(CO)2(CH3P(C(CH3)3)2)2

cis,cis,trans-Ru(H)2(CO)2(P((t)Bu)2Me)2
167774-62-1

cis,cis,trans-Ru(H)2(CO)2(P((t)Bu)2Me)2

Conditions
ConditionsYield
15 h;100%
In benzene-d6 (Ar); room temp. (2 days);
trimethylsilan
993-07-7

trimethylsilan

1-acetyl-(2S,3aS,7aS)-octahydroindole-2-carboxylic acid

1-acetyl-(2S,3aS,7aS)-octahydroindole-2-carboxylic acid

methyl 1-acetyl-(2S,3aS,7aS)-octahydroindole-2-carboxylate

methyl 1-acetyl-(2S,3aS,7aS)-octahydroindole-2-carboxylate

Conditions
ConditionsYield
In methanol100%
trimethylsilan
993-07-7

trimethylsilan

[Ru2(CO)2(NCCH3)(C5H5)2(CHSi(CH3)3)]

[Ru2(CO)2(NCCH3)(C5H5)2(CHSi(CH3)3)]

(C5H5)2Ru2(μ-CH2)(SiMe3)2(CO)2

(C5H5)2Ru2(μ-CH2)(SiMe3)2(CO)2

Conditions
ConditionsYield
In not given room temp.;99%
trimethylsilan
993-07-7

trimethylsilan

(C(C6H5)3)(1+)*CHB11F11(1-)=(C(C6H5)3)CHB11F11

(C(C6H5)3)(1+)*CHB11F11(1-)=(C(C6H5)3)CHB11F11

(CH3)3Si(1+)*HCB11F11(1-)=((CH3)3Si)(HCB11F11)

(CH3)3Si(1+)*HCB11F11(1-)=((CH3)3Si)(HCB11F11)

Conditions
ConditionsYield
In neat (no solvent) byproducts: (C6H5)3CH; B-compd. treated in the fitration apparatus with (CH3)3SiH; washed with (CH3)3SiH, sublimed at 110°C under high vac. (p<1E-2 mbar);99%
trimethylsilan
993-07-7

trimethylsilan

(C6H5)3C(1+)*C2H5CB11F11(1-)=((C6H5)3C)(C2H5CB11F11)

(C6H5)3C(1+)*C2H5CB11F11(1-)=((C6H5)3C)(C2H5CB11F11)

(CH3)3Si(1+)*C2H5CB11F11(1-)=((CH3)3Si)(C2H5CB11F11)

(CH3)3Si(1+)*C2H5CB11F11(1-)=((CH3)3Si)(C2H5CB11F11)

Conditions
ConditionsYield
In neat (no solvent) byproducts: (C6H5)3CH; B-compd. treated in the fitration apparatus with (CH3)3SiH; washed with (CH3)3SiH, sublimed at 110°C under high vac. (p<1E-2 mbar);99%
(η5-C5H5)Fe(CO)2CH2CH2C6H5

(η5-C5H5)Fe(CO)2CH2CH2C6H5

trimethylsilan
993-07-7

trimethylsilan

A

3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

B

C5H5Fe(CO)H(Si(CH3)3)2

C5H5Fe(CO)H(Si(CH3)3)2

C

C5H5Fe(CO)4

C5H5Fe(CO)4

D

Propylbenzene
103-65-1

Propylbenzene

E

trimethyl(3-phenylpropoxy)silane
14629-60-8

trimethyl(3-phenylpropoxy)silane

Conditions
ConditionsYield
In benzene-d6 react. of Fe complex and HSiMe3 in benzene, 90°C, 9 h; yields detd. by (1)H-NMR (C5H5Fe(CO)H(SiMe3)2; elem. anal.) and GL-chromy. (other products);A 0%
B 91%
C 10%
D 0%
E 98%
(η5-C5H5)Fe(CO)2CH2CH2C6H5

(η5-C5H5)Fe(CO)2CH2CH2C6H5

trimethylsilan
993-07-7

trimethylsilan

A

cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

B

C5H5Fe(CO)H(Si(CH3)3)2

C5H5Fe(CO)H(Si(CH3)3)2

C

[(cyclopentadienyl)4Fe4(CO)4]

[(cyclopentadienyl)4Fe4(CO)4]

D

trimethyl(3-phenylpropoxy)silane
14629-60-8

trimethyl(3-phenylpropoxy)silane

Conditions
ConditionsYield
In benzene-d6 under Ar; 90°C, 9 h; not isolated; NMR;A 10%
B 90%
C 10%
D 98%
[((Me)Cp)2MoH2]
61112-91-2

[((Me)Cp)2MoH2]

trimethylsilan
993-07-7

trimethylsilan

(trimethylsilyl)hydrido(methylcyclopentadienyl)2molybdenum

(trimethylsilyl)hydrido(methylcyclopentadienyl)2molybdenum

Conditions
ConditionsYield
In benzene Irradiation (UV/VIS); soln. of starting materials in benzene is photolyzed (350 nm, N2) for 36 h at 10°C; removal of volatiles under vac., purified by sublimation (60°C 1E-3 Torr), elem. anal.;98%
trimethylsilan
993-07-7

trimethylsilan

[((C5H3N)CH2(C5H3N)CH2(C5H3N)C2H4)PtH(CH3)2](1+)*[B((CF3)2C6H3)4](1-) = (C19N3H17)PtH(CH3)2(B((CF3)2C6H3)4)

[((C5H3N)CH2(C5H3N)CH2(C5H3N)C2H4)PtH(CH3)2](1+)*[B((CF3)2C6H3)4](1-) = (C19N3H17)PtH(CH3)2(B((CF3)2C6H3)4)

[((C5H3N)CH2(C5H3N)CH2(C5H3N)C2H4)PtH2CH3](1+)*[B((CF3)2C6H3)4](1-) = [(C19N3H17)PtH2CH3][B((CF3)2C6H3)4]

[((C5H3N)CH2(C5H3N)CH2(C5H3N)C2H4)PtH2CH3](1+)*[B((CF3)2C6H3)4](1-) = [(C19N3H17)PtH2CH3][B((CF3)2C6H3)4]

Conditions
ConditionsYield
In methanol byproducts: CH4, CH3OSi(CH3)3; at room temp. for 5 h; detd. by NMR;98%
trimethylsilan
993-07-7

trimethylsilan

Cp*Ni(PEt3)NH(p-C6H4Me)
198903-13-8

Cp*Ni(PEt3)NH(p-C6H4Me)

Cp*Ni(PEt3)H
198903-12-7

Cp*Ni(PEt3)H

Conditions
ConditionsYield
In benzene inert atmosphere; freezing, evacuation, warming (1 d, room temp.), colorchange; removal of volatile materials (vac.), vac. (overnight), extn. (pentane),filtration, concn.(vac.), cooling (-30°C); elem. anal.;97%
trimethylsilan
993-07-7

trimethylsilan

ethylamine
75-04-7

ethylamine

N,N-bis(trimethylsilyl)ethanamine
2477-39-6

N,N-bis(trimethylsilyl)ethanamine

Conditions
ConditionsYield
96.9%
trimethylsilan
993-07-7

trimethylsilan

Diethylaminodichloroborane
868-30-4

Diethylaminodichloroborane

diethylaminoborane dimer
93458-84-5

diethylaminoborane dimer

Conditions
ConditionsYield
150-180°C; sublimation at 50°C;96.5%
150-180°C; sublimation at 50°C;96.5%
trimethylsilan
993-07-7

trimethylsilan

bis(trifluoromethyl)ketene
684-22-0

bis(trifluoromethyl)ketene

A

(1-hydrohexafluoroisobutenyloxy)trimethylsilane
857899-86-6

(1-hydrohexafluoroisobutenyloxy)trimethylsilane

B

1-hydrohexafluoroisobutenyl 2-hydrohexafluoroisobutyrate

1-hydrohexafluoroisobutenyl 2-hydrohexafluoroisobutyrate

C

trimethylsilyl 2-hydrohexafluoroisobutyrate
64637-86-1

trimethylsilyl 2-hydrohexafluoroisobutyrate

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate at -78 - 40℃; Title compound not separated from byproducts;A 96%
B 0.4 % Spectr.
C 0.2 % Spectr.
trimethylsilan
993-07-7

trimethylsilan

Tris(phenylseleno)borane
29680-62-4

Tris(phenylseleno)borane

A

phenyl trimethylsilyl selenide
33861-17-5

phenyl trimethylsilyl selenide

B

diborane
19287-45-7

diborane

Conditions
ConditionsYield
In neat (no solvent) excess of SiMe3H, 60°C (closed ampoule); low-temp. fractionation (traps at -23, -126 and -196°C);A 96%
B n/a
trimethylsilan
993-07-7

trimethylsilan

1,4-bis(trimethylsilyl)-1,3-butadiyne
4526-07-2

1,4-bis(trimethylsilyl)-1,3-butadiyne

1,1,3,4-tetrakis(trimethylsilyl)-1,2-butadiene
103716-80-9

1,1,3,4-tetrakis(trimethylsilyl)-1,2-butadiene

Conditions
ConditionsYield
RhCl(PPh3)3 at 100℃; for 19h;95%
trimethylsilan
993-07-7

trimethylsilan

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With sodium hydroxide; ethanol at 60℃; for 4h;95%
trimethylsilan
993-07-7

trimethylsilan

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

acetone
67-64-1

acetone

A

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
31469-15-5

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

B

3-trimethylsiloxy-2,2,3-trimethylbutyrate
115579-81-2

3-trimethylsiloxy-2,2,3-trimethylbutyrate

Conditions
ConditionsYield
rhodium(III) chloride Ambient temperature;A 5%
B 95%
With BTH; rhodium(III) chloride Ambient temperature;A 5%
B 95%
rhodium(III) chloride Mechanism; Ambient temperature; other catalysts;
trimethylsilan
993-07-7

trimethylsilan

(E)-4-bromo-4'-methoxystilbene
58358-51-3

(E)-4-bromo-4'-methoxystilbene

{4-[(E)-2-(4-Methoxy-phenyl)-vinyl]-phenyl}-trimethyl-silane

{4-[(E)-2-(4-Methoxy-phenyl)-vinyl]-phenyl}-trimethyl-silane

Conditions
ConditionsYield
Stage #1: (E)-4-bromo-4'-methoxystilbene With n-butyllithium In diethyl ether at 3℃; for 2h; Metallation;
Stage #2: trimethylsilan With water at -40 - 20℃; Substitution; hydrolysis;
95%

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