1,2-Bis(bromoacetoxy)ethane supplier

Name
1,2-Bis(bromoacetoxy)ethane
EINECS 223-250-4
CAS No. 3785-34-0
Article Data11
CAS DataBase
Density 1.888 g/cm³
Solubility
Melting Point
Formula C₆H₈Br₂O₄
Boiling Point 310.7 °C at 760 mmHg
Molecular Weight 303.935
Flash Point 141.7 °C
Transport Information
Appearance Light yellow clear liquid
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Aceticacid, bromo-, 1,2-ethanediyl ester (9CI);Acetic acid, bromo-, ethylene ester(6CI,7CI,8CI);Ethylene glycol, bis(bromoacetate) (8CI);Bromoacetic acid 1,2-ethanediyl ester;Ethylene bromoacetate;NSC 25854;NSC 406054;Pandurol;
PSA 52.60000
LogP 0.86260

Synthetic route

: 56521-72-3
2-methoxyethyl 2-bromoacetate

: 598-21-0
2-Bromoacetyl bromide

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

Conditions

Conditions	Yield
at 70℃; for 24h;	88%

: 107-21-1
ethylene glycol

: 79-08-3
bromoacetic acid

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

Conditions

Conditions	Yield
In neat (no solvent) at 80℃; for 48h; Inert atmosphere;	68%
With sulfuric acid at 125℃; for 12h;

: 107-21-1
ethylene glycol

: 598-21-0
2-Bromoacetyl bromide

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

Conditions

Conditions	Yield
With pyridine In diethyl ether; toluene at 20℃; Esterification;	62%
With triethylamine In toluene at 23℃; for 18h;
With pyridine; dmap In dichloromethane at -0.01℃; for 12h; Inert atmosphere;

: 13094-51-4
bromoacetic anhydride

: 107-21-1
ethylene glycol

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

Conditions

Conditions	Yield
at 80 - 85℃;

: 598-21-0
2-Bromoacetyl bromide

monosodium salt of glycol: monosodium salt of glycol

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

Conditions

Conditions	Yield
With xylene

: 107-21-1
ethylene glycol

: 598-21-0
2-Bromoacetyl bromide

A: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

B bromoacetic acid β-bromoethyl ester: bromoacetic acid β-bromoethyl ester

Conditions

Conditions	Yield
at 50 - 60℃;

...Expand

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1533519-84-4
4-(4-cyclopropylnaphthalen-1-yl)-4Η-1,2,4-triazole-3-thiol

: ethane-1,2-diyl bis({[4-(4-cyclopropylnaphthalen-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate)

Conditions

Conditions	Yield
With potassium hydrogencarbonate In ethanol at 50 - 55℃; Inert atmosphere;	94%

: (4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II)

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: trans,trans-{(4,4'-di-tert-butyl-2,2'-bipyridine)bromodimethylplatinum(IV)}(μ-CH2COOC2H4OCOCH2)

Conditions

Conditions	Yield
In acetone the bromo-compd. is added to a soln. of the starting complex in acetone; ppt. is filtd., washed with ether, dried under vac., elem. anal.;	61%

: 52594-52-2
dimethyl(2,2'-bipyridine)platinum(II)

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: trans,trans-{(2,2'-bipyridine)bromodimethylplatinum(IV)}(μ-CH2COOC2H4OCOCH2)

Conditions

Conditions	Yield
In acetone the bromo-compd. is added to a soln. of the starting complex in acetone; ppt. is filtd., washed with ether, dried under vac., elem. anal.;	53%

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 149647-23-4
5-(4'-pyridylazo)-25,26,27-tris(ethoxycarbonylmethoxy)-28-hydroxycalix[4]arene

: C86H90O24

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran Heating;

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 149647-22-3
C46H54O10

: C98H114O24

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran Heating;

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1,4,7,8-dioxadithiecane-5,10-dione

Conditions

Conditions	Yield
With sodium disulfide In tetrahydrofuran for 20h; cyclocondensation; Heating;	16 % Spectr.

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 17754-90-4
4-(Diethylamino)salicylaldehyde

: 877178-48-8
C28H36N2O8

Conditions

Conditions	Yield
With potassium iodide; potassium bromide In butanone for 24h; Heating / reflux;

: 4271-27-6
diethyllaurylamine

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 2,2'-[ethane-1,2-diylbis(oxy)]bis(N-dodecyl-N,N-diethyl-2-oxoethanaminium) dibromide

Conditions

Conditions	Yield
In chloroform at 60℃; for 5h;

: 5917-47-5
1-dodecylpiperidine

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1,1'-(ethane-1,2-diylbis(oxy))bis(2-oxoethane-1,2-diyl)bis(1-dodecylpiperidin-1-ium)dibromide

Conditions

Conditions	Yield
In chloroform at 60℃; for 5h;

: 2915-94-8
1-dodecyl-pyrrolidine

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1,1'-(ethane-1,2-diylbis(oxy))bis(2-oxoethane-1,2-diyl)bis(1-dodecylpyrrolidin-1-ium)-dibromide

Conditions

Conditions	Yield
In chloroform at 60℃; for 5h;

: 1541-81-7
4-dodecyl-morpholine

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 4,4'-((ethane-1,2-diylbis(oxy))bis(2-oxoethane-2,1-diyl))bis(4-dodecylmorpholin-4-ium) dibromide

Conditions

Conditions	Yield
In chloroform at 60℃; for 5h;

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 54004-47-6
1-tetradecylimidazole

: C38H68N4O4(2+)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide; acetonitrile at 80℃; for 24h; Temperature; Concentration;

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: C14H24O4S2(2+)*2C13H17F2O6S(1-)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: acetonitrile / 20 h / 23 °C 2: water; chloroform / 15 h / 23 °C View Scheme

: 110-01-0
thiophene

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: C14H24O4S2(2+)*2Br(1-)

Conditions

Conditions	Yield
In acetonitrile at 23℃; for 20h;

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1533519-84-4
4-(4-cyclopropylnaphthalen-1-yl)-4Η-1,2,4-triazole-3-thiol

: C36H30Br2N6O4S2

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium hydrogencarbonate / ethanol / 50 - 55 °C / Inert atmosphere 2: N-Bromosuccinimide / dichloromethane; water; dimethyl sulfoxide / 0 - 5 °C View Scheme

: 998-40-3
tributylphosphine

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: 1,2-ethanediol bis[(tri-n-butylphosphonium)acetyrate] dibromide

Conditions

Conditions	Yield
In acetone at 40℃; for 48h;	1 g

: 3785-34-0
ethane-1,2-diyl bis(2-bromoacetate)

: N-[3-(1H-imidazol-1-yl)propyl] dodecanamide

: 3,3′-{ethane-1,2-diylbis[oxy(2-oxoethane-2,1-diyl)]}bis{1-[3(dodecanoylamino)propyl]-1H-imidazol-3-ium} dibromide

Conditions

Conditions	Yield
at 59.99℃; for 6h; Inert atmosphere;

1,2-Bis(bromoacetoxy)ethane Chemical Properties

Chemical Name: 1,2-Bis(bromoacetoxy)ethane
IUPAC NAME: 2-(2-Bromoacetyl)oxyethyl 2-bromoacetate
CAS No.: 3785-34-0
EINECS: 223-250-4
Molecular Formula: C₆H₈Br₂O₄
Molecular Weight: 303.93 g/mol
Density: 1.888 g/cm³
Flash Point: 141.7 °C
Boiling Point: 310.7 °C at 760 mmHg
Following is the structure of 1,2-Bis(bromoacetoxy)ethane (3785-34-0):

The chemical synonymous of 1,2-Bis(bromoacetoxy)ethane (3785-34-0) are BBAE ; Ethylene glycol bis(bromoacetate) ; 1,2-Bis(bromoacetoxy)ethane ; 1,2-Ethanediylbromoacetate ; Aceticacid,bromo-,1,2-ethanediylester ; Bromoaceticacidethyleneester ; Bromo-aceticacidiesterwithethyleneglycol ; Bromo-aceticaciethyleneester

1,2-Bis(bromoacetoxy)ethane Uses

1,2-Bis(bromoacetoxy)ethane (3785-34-0) is a highly effective antiseptic fungicide, widely used as industrial circulating water, industrial cooling water, water treatment agents, sterilizing agents algae.

1,2-Bis(bromoacetoxy)ethane Toxicity Data With Reference

1.	ipr-mus LD50:39 mg/kg	JNCIAM Journal of the National Cancer Institute. 31 (1963),297.
2.	ivn-mus LD50:56 mg/kg	CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#03918 .
3.	ivn-dog LD50:15 mg/kg	JNCIAM Journal of the National Cancer Institute. 31 (1963),297.

1,2-Bis(bromoacetoxy)ethane Safety Profile

Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of Br⁻. See also BROMIDES and ESTERS.

Product Name

1,2-Bis(bromoacetoxy)ethane

Synthetic route

1,2-Bis(bromoacetoxy)ethane Chemical Properties

1,2-Bis(bromoacetoxy)ethane Uses

1,2-Bis(bromoacetoxy)ethane Toxicity Data With Reference

1,2-Bis(bromoacetoxy)ethane Safety Profile

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