1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride supplier

Name
1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride
EINECS 937-421-2
CAS No. 156028-26-1
Article Data26
CAS DataBase
Density 1.962 g/cm³
Solubility
Melting Point
Formula C₂₄H₄Cl₄O₆
Boiling Point 757.1 °C at 760 mmHg
Molecular Weight 530.104
Flash Point 287.5 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 1,6,7,12-Tetrachloro-3,4:9,10-perylenetetracarboxylicdianhydride;1,6,7,12-Tetrachloroperylene-3,4:9,10-tetracarboxylic aciddianhydride;1,6,7,12-Tetrachloroperylene-3,4:9,10-tetracarboxylic dianhydride;5,6,12,13-Tetrachloroperylenetetracarboxylic dianhydride;Perylo[3,4-cd:9,10-c'd']dipyran-1,3,8,10-tetrone,5,6,12,13-tetrachloro-;
PSA 86.74000
LogP 6.97200

Synthetic route

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With sulfuric acid; chlorine at 120℃;	99%
With chlorosulfonic acid; iodine at 65℃; for 20h;	98%
With chlorosulfonic acid; iodine at 65℃; for 20h;	94%

: tetrabutyl 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylate

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In chlorobenzene for 48h; Reflux;	87%

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

A: C24H5Cl3O6

B: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With chlorosulfonic acid; iodine at 70℃; for 5h;
With chlorosulfonic acid; iodine at 60℃; for 20h;	A 35 %Spectr. B 65 %Spectr.

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

A: 1,2,6,7,12-pentachloroperylene-3,4,9,10-tetracarboxylic acid bisanhydride

B: C24H2Cl6O6

C: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With chlorosulfonic acid; iodine at 70℃; for 20h;

...Expand

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

A: 1,2,6,7,12-pentachloroperylene-3,4,9,10-tetracarboxylic acid bisanhydride

B: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With chlorosulfonic acid; iodine at 70℃; for 10h;
With chlorosulfonic acid; iodine at 70℃; for 20h; Temperature; Time;	A 20 %Spectr. B 80 %Spectr.
With chlorosulfonic acid; iodine at 60℃; for 15h; Temperature; Time; Overall yield = 98 %;

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

A: C24H5Cl3O6

B: 1,2,6,7,12-pentachloroperylene-3,4,9,10-tetracarboxylic acid bisanhydride

C: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With chlorosulfonic acid; iodine at 65℃; for 20h;	A 9 %Spectr. B 7 %Spectr. C 84 %Spectr.

...Expand

: 108-91-8
cyclohexylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 156028-27-2
N,N’-dicyclohexyl-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
With acetic acid In 1-methyl-pyrrolidin-2-one at 90℃; for 11h;	100%
With 1-methyl-pyrrolidin-2-one; acetic acid at 85℃; for 8h; Inert atmosphere;	92%
at 135℃; for 24h; Inert atmosphere;	90%

: 2450-71-7
Propargylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 1419865-47-6
N,N’-bis-propargyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic diimide

Conditions

Conditions	Yield
In isopropyl alcohol at 90℃;	100%
In isopropyl alcohol for 24h; Reflux; Inert atmosphere;	52.8%
In isopropyl alcohol Reflux;

: 107-10-8
propylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N'-bis-n-propyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxdiimide

Conditions

Conditions	Yield
In water; butan-1-ol for 8h;	99%
In water; isopropyl alcohol at 65℃; for 9h; Temperature; Inert atmosphere;

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 2-(3,4,5-tris(dodec-1-yloxy)phenyl)ethylamine

: C112H166Cl4N2O10

Conditions

Conditions	Yield
With quinoline; zinc(II) acetate dihydrate at 180℃; for 5h; Inert atmosphere;	98%

: 929-06-6
2-(2-Aminoethoxy)ethanol

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: bis-N,N′-(2-(2-hydroxyethoxy)ethyl)perylene-3,4,9,10-tetracarboxylic diimide

Conditions

Conditions	Yield
With pyridine for 3h; Reflux;	96%
With pyridine; zinc(II) acetate dihydrate at 120℃; for 3h; Inert atmosphere;	83%

: 111-86-4
n-Octylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 95689-65-9
N,N'-di(n-octyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
In toluene at 100℃; for 8h;	95%
With propionic acid for 7h; Heating;	91%
In toluene at 105℃; for 24h; Inert atmosphere;	90%

: 24544-04-5
2,6-diisopropylbenzenamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 112078-00-9
N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide

Conditions

Conditions	Yield
In propionic acid for 8h; Heating;	95%
In propionic acid for 24h; Reflux; Inert atmosphere;	91%
With propionic acid; zinc(II) chloride at 25 - 120℃; for 20h; Temperature; Reagent/catalyst; Inert atmosphere;	85%

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 671753-65-4
2-undec-10-enyl-tridec-12-enoic acid

: C58H68Cl4N2O6

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane for 2h; Inert atmosphere;	95%

: 108-00-9
N,N-dimethylethylenediamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 5,6,12,13-tetrachloro-2,9-bis(2-(dimethylamino)ethyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions

Conditions	Yield
With acetic acid In N,N-dimethyl-formamide at 200℃; for 0.166667h; Microwave irradiation;	95%
With acetic acid In 1-methyl-pyrrolidin-2-one at 120℃; for 24h; Inert atmosphere;	71%

: 5036-48-6
3-(1H-imidazol-1-yl)propan-1-amine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 2,9-bis(3-(1H-imidazol-1-yl)propyl)-5,6,12,13-tetrachloroanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions

Conditions	Yield
With acetic acid In N,N-dimethyl-formamide at 200℃; for 0.166667h; Microwave irradiation;	95%

: 444315-15-5
3-(3,5,7,9,11,13,15-heptaisobutylpentacyclo[9,5,1,1(3,9),1(7,13),1(5,15)]octasiloxane-1-yl)propylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: C86H142Cl4N2O28Si16

Conditions

Conditions	Yield
In toluene at 100℃; for 8h;	95%

: 87120-72-7
1-(tert-butoxycarbonyl)-4-aminopiperidine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N’-bis((N’’-tert-butoxycarbonyl)piperidin-4-yl)-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic diimide

Conditions

Conditions	Yield
Stage #1: 1-(tert-butoxycarbonyl)-4-aminopiperidine; 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With 1,4-diaza-bicyclo[2.2.2]octane In N,N-dimethyl-formamide at 110℃; for 1h; Inert atmosphere; Microwave irradiation; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide for 1h; Inert atmosphere;	95%

: 110-58-7
1-pentanamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 696601-54-4
N,N'-dipentyl-1,6,7,12-tetrachloroperylene-3,4:9,10-bis(dicarboximide)

Conditions

Conditions	Yield
In toluene at 105℃; for 24h; Inert atmosphere;	92%
With propionic acid at 140℃; for 24h;	86.1%
With propionic acid at 140℃; for 24h;	86.1%
With propionic acid Reflux;

: 88-05-1
2,4,6-trimethylaniline

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: C42H26Cl4N2O4

Conditions

Conditions	Yield
In propionic acid for 16h; Heating;	92%
With propionic acid at 140℃; for 24h;	25.99 g

: 106-40-1
4-bromo-aniline

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N'-bis(4'-bromophenyl)-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxdiimide

Conditions

Conditions	Yield
With propionic acid for 12h; Heating;	91%

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 115662-06-1
N,N-dihydro-1,6,7,12-tetrachloro-3,4,9,10-tetracarboxyl perylene bisimide

Conditions

Conditions	Yield
With ammonium acetate; propionic acid at 140℃; for 8h;	90%

: 4282-40-0
1-Iodoheptane

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 1569101-23-0
tetraheptyl 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylate

Conditions

Conditions	Yield
Stage #1: 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With sodium hydroxide In water at 70℃; for 0.5h; Inert atmosphere; Stage #2: With Aliquat 336 In water at 70℃; for 0.166667h; Inert atmosphere; Stage #3: 1-Iodoheptane In water for 2h; Reflux; Inert atmosphere;	90%
Stage #1: 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With sodium hydroxide In water at 70℃; for 0.5h; Inert atmosphere; Stage #2: With Aliquat 336 In water at 70℃; for 0.166667h; Inert atmosphere; Stage #3: 1-Iodoheptane In water for 2h; Reflux; Inert atmosphere;	90%

: C24H57NO12Si8

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: C48H59Cl4NO17Si8

Conditions

Conditions	Yield
In toluene at 110℃; for 3h;	90%

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N’-dihydroxyl-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
Stage #1: 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With hydroxylamine hydrochloride; sodium hydroxide In ethanol at 90℃; for 48h; Stage #2: With hydrogenchloride In water pH=1;	89%

: 109-73-9
N-butylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 95689-64-8
N,N’-dibutyl-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
In isopropyl alcohol for 8h; Reflux; Inert atmosphere;	88%
In isopropyl alcohol for 8h; Inert atmosphere; Reflux;	88%
With propionic acid at 140℃; for 8h;	84%

: 103-67-3
benzyl-methyl-amine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 946612-29-9
N,N'-bis(α-methylbenzyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
Stage #1: benzyl-methyl-amine; 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With zinc diacetate In quinoline at 180℃; for 4h; Stage #2: With hydrogenchloride In quinoline; water	88%

: 693-57-2
12-Aminododecanoic acid

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: C48H50Cl4N2O8

Conditions

Conditions	Yield
With propionic acid at 140℃; for 36h; Inert atmosphere; Schlenk technique;	87%
In 1-methyl-pyrrolidin-2-one at 20 - 65℃; for 1.5h;

: 27532-96-3
glycine tert-butyl ester hydrochloride

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N’-bis-(t-butoxycarbonylmethyl)-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic diimide

Conditions

Conditions	Yield
With triethylamine In isopropyl alcohol at 90℃;	87%

: 124-22-1
n-Dodecylamine

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N'-di-n-dodecyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide

Conditions

Conditions	Yield
In toluene at 105℃; for 24h; Inert atmosphere;	86%
With propionic acid at 150℃;	85%
In quinoline at 150℃; for 24h; Inert atmosphere;	55%
In quinoline at 150℃; for 36h; Inert atmosphere;	55%

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 1402905-24-1
9,10-dibromo-1,6,7,12-tetrachloro-3,4-perylenedicarboxylic acid anhydride

Conditions

Conditions	Yield
Stage #1: 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride With sodium hydroxide In water at 80℃; Stage #2: With bromine; acetic acid In water at 80℃; for 2h;	86%
With bromine; acetic acid; sodium hydroxide In water at 80℃; for 2h;	86%
With bromine; acetic acid; sodium hydroxide In water at 80℃; for 2h;	72%

: 55396-63-9
5-amino-2-(α-pyridyl)benzimidazoles

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: N,N'-bis(2-(2'-pyridyl)-1H-benzimidazole)-1,6,7,12-tetrachloro-3,4,9,10-perylenetetracarboxylic acid diimide

Conditions

Conditions	Yield
With propionic acid at 140℃; for 24h; Inert atmosphere;	86%

: 1384449-05-1
3,5-di(9H-carbazol-9-yl)aniline

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: C84H42Cl4N6O4

Conditions

Conditions	Yield
With propionic acid at 150℃; for 24h;	85.7%

: 623-33-6
glycine ethyl ester hydrochloride

: 156028-26-1
1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

: 1349192-35-3
C32H18Cl4N2O8

Conditions

Conditions	Yield
In toluene for 24h; Reflux;	85%

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Chemical Properties

Empirical Formula: C₂₄H₄Cl₄O₆
Molecular Weight: 530.097g/mol
Structure of 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride (CAS NO.156028-26-1):

Index of Refraction: 1.931
Molar Refractivity: 128.74 cm³
Molar Volume: 270.1 cm³
Polarizability: 51.03×10^-24cm³
Surface Tension: 103 dyne/cm
Density: 1.962 g/cm³
Flash Point: 287.5 °C
Enthalpy of Vaporization: 110.3 kJ/mol
Boiling Point: 757.1 °C at 760 mmHg
Vapour Pressure: 8.19E-23 mmHg at 25 °C
SMILES: c1c2c3c(cc(c4c3c(c1Cl)c5c(cc6c7c5c4c(cc7C(=O)OC6=O)Cl)Cl)Cl)C(=O)OC2=O
InChI: InChI=1/C24H4Cl4O6/c25-9-1-5-13-6(22(30)33-21(5)29)2-11(27)17-18-12(28)4-8-14-7(23(31)34-24(8)32)3-10(26)16(20(14)18)15(9)19(13)17/h1-4H
InChIKey: YGRXZLAMYLGXMF-UHFFFAOYAS

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Specification

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride , its cas register number is 156028-26-1. It also can be called 5,6,12,13-Tetrachloroisochromeno[4',5',6':6,5,10]anthra[2,1,9-def]isochromene-1,3,8,10-tetrone ; Peryleno[10,9-cd:3,4-c'd']dipyran-1,3,8,10-tetrone, 5,6,12,13-tetrachloro- .

Product Name

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride

Synthetic route

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Chemical Properties

1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Specification

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