pent-2-enoic acid
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With [bis(acetoxy)iodo]benzene; tetraethylammonium bromide In dichloromethane at 20℃; for 10h; | 90% |
A
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With pyridine |
acide dibromo-2,3 pentanoique
A
(E)/(Z)-1-bromo-1-butene
B
2-bromo-pent-2-enoic acid
Conditions | Yield |
---|---|
With pyridine |
butane, 1,1,2-tribromo-
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With ethanol; zinc higher-boiling 1-bromo-butene-(1); | |
With ethanol; zinc lower-boiling 1-bromo-butene-(1); |
butyraldehyde
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With phosphorus trichloride dibromide; sodium ethanolate |
1,2-dibromobutane
A
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With ethanol; sodium phenoxide man trennt das Isomeren-Gemisch durch fraktionierte Destillation mit Alkohol, Zerlegung der erhaltenen Azeotropen mit Wasser und nochmalige Destillation; lower-boiling 1-bromo-butene-(1); |
1,2-dibromobutane
A
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With ethanol; sodium phenoxide man trennt das Isomeren-Gemisch durch fraktionierte Destillation mit Alkohol, Zerlegung der erhaltenen Azeotropen mit Wasser und nochmalige Destillation; higher-boiling 1-bromo-butene-(1); |
trans-2-pentenoic acid
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
(i) Br2, (UV-irradiation), (ii) (heating in Py); Multistep reaction; |
Conditions | Yield |
---|---|
higher-boiling 1-bromo-butene-(1); |
Conditions | Yield |
---|---|
Behandeln des Reaktionsprodukts mit Natriumaethylat; |
1-bromo-2-butanol
A
(E/Z)-crotyl bromide
B
(E)/(Z)-1-bromo-1-butene
diethyl ether
methylmagnesium bromide
1,3-dibromopropene
A
methane
B
(E)/(Z)-1-bromo-1-butene
C
ethane
D
buta-1,3-diene
Conditions | Yield |
---|---|
Produkt5: Octadien-(2.6); |
(E)/(Z)-1-bromo-1-butene
(2S)-O-(tert-butyldiphenylsilyl)-1,2-epoxybutan-4-ol
Conditions | Yield |
---|---|
Stage #1: (E)/(Z)-1-bromo-1-butene With magnesium; ethylene dibromide In tetrahydrofuran Grignard Reaction; Reflux; Inert atmosphere; Stage #2: (2S)-O-(tert-butyldiphenylsilyl)-1,2-epoxybutan-4-ol With copper(l) iodide In tetrahydrofuran at -78 - 0℃; for 1.08333h; Cooling with acetone-dry ice; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 25 - 30℃; Irradiation; | 87.5% |
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile at 25 - 30℃; Irradiation; | 85.6% |
(E)/(Z)-1-bromo-1-butene
(hex-5-enyl)magnesium bromide
deca-3,9-diene
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran at 30℃; | 79.5% |
(E)/(Z)-1-bromo-1-butene
trimethylsilylacetylene
(E)-1-trimethylsilyl-3-hexen-1-yne
Conditions | Yield |
---|---|
Stage #1: trimethylsilylacetylene With ethylmagnesium bromide In tetrahydrofuran at 65℃; for 1h; Substitution; Stage #2: With zinc(II) chloride In tetrahydrofuran at 20℃; for 0.5h; Transmetallation; Stage #3: (E)/(Z)-1-bromo-1-butene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 58h; Cross-coupling; | 66% |
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran at 30℃; | 61% |
(E)/(Z)-1-bromo-1-butene
4-penten-1-ylmagnesium bromide
trans nona-1,3-diene
Conditions | Yield |
---|---|
palladium dichloride In tetrahydrofuran at 30℃; | 57% |
(E)/(Z)-1-bromo-1-butene
3,5-Octadiene
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; (2,2'-bipyridine)nickel(II) dibromide In various solvent(s) at 20℃; electrochemical reaction, magnesium anode, gold gauze cathode, -1,2 V; | 50% |
Conditions | Yield |
---|---|
With palladium diacetate; acetic anhydride; triethylamine; 1,4-di(diphenylphosphino)-butane In N,N-dimethyl-formamide at 100℃; Inert atmosphere; Schlenk technique; | 39% |
(E)/(Z)-1-bromo-1-butene
but-1-yne
Conditions | Yield |
---|---|
With potassium hydroxide; ethanol at 180℃; |
(E)/(Z)-1-bromo-1-butene
Conditions | Yield |
---|---|
With bromine |
(E)/(Z)-1-bromo-1-butene
tris(1-butenyl)boroxine
Conditions | Yield |
---|---|
(i) Mg, (ii) B(OMe)3, (iii) phenothiazine; Multistep reaction; |
(E)/(Z)-1-bromo-1-butene
2-methyl-6-n-propylpyrazine
A
cis-3-methyl-5-n-propyl-2-(1-butenyl)-pyrazine
B
trans-3-methyl-5-n-propyl-2-(1-butenyl)-pyrazine
C
cis-5-methyl-3-n-propyl-2-(1-butenyl)-pyrazine
D
trans-5-methyl-3-n-propyl-2-(1-butenyl)-pyrazine
Conditions | Yield |
---|---|
With tert.-butyl lithium In tetrahydrofuran; diethyl ether; pentane 1.) -78 deg C, 15 min; 2.) r.t., 20 min; Title compound not separated from byproducts; |
(E)/(Z)-1-bromo-1-butene
11-dodecyn-1-yl acetate
A
(Z)-13-hexadecene-11-yn-1-yl acetate
B
(E)-13-hexadecene-11-yn-1-yl acetate
Conditions | Yield |
---|---|
With propylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) 1.) benzene, 2.) 16 h, RT; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
(E)/(Z)-1-bromo-1-butene
chloroform
bromine
butane, 1,1,2-tribromo-
Conditions | Yield |
---|---|
lower-boiling 1-bromo-butene-(1); | |
higher-boiling 1-bromo-butene-(1); |
(E)/(Z)-1-bromo-1-butene
bromine
Conditions | Yield |
---|---|
am Sonnenlicht; Gleichgewicht.Irradiation; lower-boiling 1-bromo-butene-(1); |
Conditions | Yield |
---|---|
at 120 - 125℃; lower-boiling 1-bromo-butene-(1); | |
at 120 - 125℃; higher-boiling 1-bromo-butene-(1); |
The 1-Butene, 1-bromo-, with the CAS registry number 31844-98-1 and EINECS registry number 250-836-7, has the systematic name and IUPAC name of (1E)-1-bromobut-1-ene. It is a kind of organics, and should be stored in the dry and cool environment. And the molecular formula of the chemical is C4H7Br.
The characteristics of 1-Butene, 1-bromo- are as followings: (1)ACD/LogP: 2.66; (2)# of Rule of 5 Violations: 0 ; (3)#H bond acceptors: 0; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 1; (6)Polar Surface Area: 0 Å2; (7)Index of Refraction: 1.471; (8)Molar Refractivity: 28.36 cm3; (9)Molar Volume: 101.3 cm3; (10)Polarizability: 11.24×10-24cm3; (11)Surface Tension: 26.8 dyne/cm; (12)Density: 1.331 g/cm3; (13)Flash Point: 14.5 °C; (14)Enthalpy of Vaporization: 32.05 kJ/mol; (15)Boiling Point: 94.7 °C at 760 mmHg; (16)Vapour Pressure: 53.4 mmHg at 25°C.
Uses of 1-Butene, 1-bromo-: It can react with propylmagnesium bromide to produce hept-3t-ene. This reaction will need catalyst PdCl2(dppf), and the menstruum tetrahydrofuran. The temperature is 30°C, and the yield is about 61%.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: Br[C@H]=CCC
(2)InChI: InChI=1/C4H7Br/c1-2-3-4-5/h3-4H,2H2,1H3/b4-3+
(3)InChIKey: IUXHPSPHPKXTPA-ONEGZZNKBB
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