Product Name

  • Name

    2,6-DICHLORODIPHENYLAMINE

  • EINECS 239-349-0
  • CAS No. 15307-93-4
  • Article Data14
  • CAS DataBase
  • Density 1.327 g/cm3
  • Solubility
  • Melting Point 50-53 °C(lit.)
  • Formula C12H9Cl2N
  • Boiling Point 309.795 °C at 760 mmHg
  • Molecular Weight 238.116
  • Flash Point 141.159 °C
  • Transport Information
  • Appearance Off white to cream coloured Crystalline solid
  • Safety 26-36
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 15307-93-4 (2,6-DICHLORODIPHENYLAMINE)
  • Hazard Symbols IrritantXi
  • Synonyms Diphenylamine,2,6-dichloro- (8CI);2,6-Dichlorodiphenylamine;N-(2,6-Dichlorophenyl)aniline;N-Phenyl-2,6-dichloroaniline;
  • PSA 12.03000
  • LogP 4.81000

Synthetic route

chlorobenzene
108-90-7

chlorobenzene

2,6-Dichloroaniline
608-31-1

2,6-Dichloroaniline

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With copper(II) oxide In 1,4-dioxane at 130℃; for 20h; Reagent/catalyst; Solvent;95%
bromobenzene
108-86-1

bromobenzene

2,6-Dichloroaniline
608-31-1

2,6-Dichloroaniline

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With johnphos; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene for 1h; Heating;94%
2-(2,6-dichlorophenoxy)-N-phenylacetamide
146607-19-4

2-(2,6-dichlorophenoxy)-N-phenylacetamide

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With sodium hydroxide In water; toluene at 80 - 90℃; for 4h; Reagent/catalyst; Temperature;93%
2,6-Dichlorophenol
87-65-0

2,6-Dichlorophenol

Mesitol
527-60-6

Mesitol

2-chloro-2-phenylacetamide
7462-76-2

2-chloro-2-phenylacetamide

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With sodium hydroxide In water; N,N-dimethyl-formamide; toluene90.75%
...Expand
N-phenyl-2,2,6,6-tetrachlorocyclohexaneimine
123066-65-9

N-phenyl-2,2,6,6-tetrachlorocyclohexaneimine

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With sodium hydroxide In chlorobenzene85%
With triethylamine In N,N-dimethyl-formamide at 95 - 100℃; for 5h; Dehydrochlorination;
1-bromo-2,6-dichlorobenzene
19393-92-1

1-bromo-2,6-dichlorobenzene

aniline
62-53-3

aniline

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With potassium phosphate; DavePhos; tris-(dibenzylideneacetone)dipalladium(0)
Stage #1: 1-bromo-2,6-dichlorobenzene; aniline With sodium t-butanolate In toluene for 0.5h; Inert atmosphere;
Stage #2: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In toluene for 18h; Reflux;
2,2,6,6-tetrachlorocyclohexanone
3776-30-5

2,2,6,6-tetrachlorocyclohexanone

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 99 percent / TiCl4 / toluene / 2 h / 20 °C
2: Et3N / dimethylformamide / 5 h / 95 - 100 °C
View Scheme
aniline
62-53-3

aniline

Wang resin-bound styrene 4

Wang resin-bound styrene 4

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 99 percent / TiCl4 / toluene / 2 h / 20 °C
2: Et3N / dimethylformamide / 5 h / 95 - 100 °C
View Scheme
C15H13Cl2NO2

C15H13Cl2NO2

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 2h;138 mg
diclofenac sodium
15307-79-6

diclofenac sodium

A

2-oxoindole
59-48-3

2-oxoindole

B

2,6-Dichlorophenol
87-65-0

2,6-Dichlorophenol

C

1-(2,6-dichlorophenyl)indolin-2-one
15362-40-0

1-(2,6-dichlorophenyl)indolin-2-one

D

4-chloro-10(H)acridin-9-one
69220-40-2

4-chloro-10(H)acridin-9-one

E

2,6-dichloronitrobenzene
601-88-7

2,6-dichloronitrobenzene

F

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

G

N-(2,6-dichlorophenyl)-formamide
10113-35-6

N-(2,6-dichlorophenyl)-formamide

H

1,3-dichloro-2-isocyanobenzene
6697-95-6

1,3-dichloro-2-isocyanobenzene

I

2,6-dichlorophenylisocyanate
39920-37-1

2,6-dichlorophenylisocyanate

J

4-chloro-1,3-benzoxazol-2(3H)-one
13603-93-5

4-chloro-1,3-benzoxazol-2(3H)-one

K

2,6-Dichloroaniline
608-31-1

2,6-Dichloroaniline

Conditions
ConditionsYield
With dihydrogen peroxide; iron(II) In water at 20℃; pH=2; Fenton Reaction;
...Expand
2,6-Dichlorophenol
87-65-0

2,6-Dichlorophenol

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: benzene / 3 h / 20 °C / Reflux
1.2: polyethylene glycol-400 / 24 h / 80 °C
2.1: sodium hydroxide / toluene; water / 4 h / 80 - 90 °C
View Scheme
aniline
62-53-3

aniline

N-phenyl-2,6-dichloroaniline
15307-93-4

N-phenyl-2,6-dichloroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: benzene / 3 h / 20 °C / Reflux
1.2: polyethylene glycol-400 / 24 h / 80 °C
2.1: sodium hydroxide / toluene; water / 4 h / 80 - 90 °C
View Scheme

2,6-Dichlorodiphenylamine Specification

The Benzenamine,2,6-dichloro-N-phenyl- is an organic compound with the formula C12H9Cl2N. The IUPAC name of this chemical is 2,6-Dichloro-N-phenylaniline. With the CAS registry number 15307-93-4, it is also named as (2,6-Dichlorophenyl)phenylamine. The product's categories are Anilines, Aromatic Amines and Nitro Compounds. Besides, its molecular weight is 238.11.

Physical properties about Benzenamine,2,6-dichloro-N-phenyl- are: (1)ACD/LogP: 4.77; (2)ACD/LogD (pH 5.5): 4.77; (3)ACD/LogD (pH 7.4): 4.77; (4)ACD/BCF (pH 5.5): 2492.27; (5)ACD/BCF (pH 7.4): 2492.27; (6)ACD/KOC (pH 5.5): 9394.62; (7)ACD/KOC (pH 7.4): 9394.62; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 3.24 Å2; (12)Index of Refraction: 1.649; (13)Molar Refractivity: 65.41 cm3; (14)Molar Volume: 179.3 cm3; (15)Polarizability: 25.93×10-24 cm3; (16)Surface Tension: 48 dyne/cm; (17)Density: 1.327 g/cm3; (18)Flash Point: 141.2 °C; (19)Enthalpy of Vaporization: 55.06 kJ/mol; (20)Boiling Point: 309.8 °C at 760 mmHg; (21)Vapour Pressure: 0.000625 mmHg at 25 °C. 

Uses of Benzenamine,2,6-dichloro-N-phenyl-: it can be used to produce 2-Chloro-N-(2',6'-dichlorophenyl)-N-phenylacetamide. The reaction time is 16 hours. The yield is about 66%.

When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C12H9Cl2N/c13-10-7-4-8-11(14)12(10)15-9-5-2-1-3-6-9/h1-8,15H
(2)InChIKey: HDUUZPLYVVQTKN-UHFFFAOYAC
(3)Std. InChI: InChI=1S/C12H9Cl2N/c13-10-7-4-8-11(14)12(10)15-9-5-2-1-3-6-9/h1-8,15H
(4)Std. InChIKey: HDUUZPLYVVQTKN-UHFFFAOYSA-N

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