2-Bromobutyryl Bromide supplier

Name
2-Bromobutyryl bromide
EINECS 247-441-7
CAS No. 26074-52-2
Density 1.941 g/cm³
Solubility
Melting Point
Formula C₄H₆Br₂O
Boiling Point 176.3 °C at 760 mmHg
Molecular Weight 229.899
Flash Point 66.263 °C
Transport Information UN 3265 8/PG 2
Appearance
Safety 26-36/37/39-45
Risk Codes 34-36/37
Molecular Structure
Hazard Symbols C
Synonyms Butyrylbromide, 2-bromo- (6CI,8CI);2-Bromobutanoyl bromide;a-Bromobutyryl bromide;
PSA 17.07000
LogP 2.08140

Synthetic route

: 5856-82-6
butyryl bromide

: 26074-52-2
2-bromo-butyryl bromide

Conditions

Conditions	Yield
With bromine at 100℃;

: 623-42-7
butanoic acid methyl ester

: 26074-52-2
2-bromo-butyryl bromide

Conditions

Conditions	Yield
With phosphorus; bromine

: 107-92-6
butyric acid

: 26074-52-2
2-bromo-butyryl bromide

Conditions

Conditions	Yield
With phosphorus; bromine at 100℃;
With phosphorus; bromine; sodium hydroxide at 110℃; Hell-Vollard-Zelinsky halogenation; regioselective reaction;

: 7726-95-6
bromine

: 105-54-4
butanoic acid ethyl ester

red phosphorus: red phosphorus

A: 74-96-4
ethyl bromide

B: 26074-52-2
2-bromo-butyryl bromide

...Expand

: 26074-52-2
2-bromo-butyryl bromide

: 157734-48-0
(2,2-Bis-phenylsulfanyl-vinyl)-((S)-1-phenyl-ethyl)-amine

: 2-bromo-N-<(S)-1-phenylethyl>-N-<2,2-bis(phenylthio)ethenyl>butanamide

Conditions

Conditions	Yield
With N,N-diethylaniline In benzene Heating;	100%

: 26074-52-2
2-bromo-butyryl bromide

: 13120-10-0
N,N'-diisopropyl selenourea

: 5-ethyl-3-isopropyl-2-isopropylimino-1,3-selenazolidin-4-one

Conditions

Conditions	Yield
With pyridine In tetrahydrofuran at 0℃;	100%

: 26074-52-2
2-bromo-butyryl bromide

: 138718-06-6
O-3-(2-furyl)propylhydroxylamine

: 1451012-86-4
(±)-1-[O-(3-(2-furyl)propyl)oxyamino]-2-bromo-1-butanone

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 0.5h; Inert atmosphere;	100%

: 26074-52-2
2-bromo-butyryl bromide

: 609-08-5
Diethyl methylmalonate

: C12H19BrO5

Conditions

Conditions	Yield
Stage #1: Diethyl methylmalonate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1.33333h; Inert atmosphere; Stage #2: 2-bromo-butyryl bromide In tetrahydrofuran; mineral oil at 0 - 20℃; for 17h; Inert atmosphere;	100%

: 26074-52-2
2-bromo-butyryl bromide

: 108-69-0
3,5-dimethylaminoaniline

: 2-bromo-N-(3,5-dimethylphenyl)butanamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃;	100%

: 462-06-6
fluorobenzene

: 26074-52-2
2-bromo-butyryl bromide

: 2-bromo-1-(4-fluorophenyl)-1-butanone

Conditions

Conditions	Yield
With aluminum (III) chloride In dichloromethane for 2h; Inert atmosphere; Cooling with ice;	100%
With aluminum (III) chloride In dichloromethane for 2.3h; Cooling with ice; Inert atmosphere;	100%
With aluminum (III) chloride In dichloromethane for 2.33333h; Inert atmosphere; Cooling with ice;	100%

: 26074-52-2
2-bromo-butyryl bromide

: 135-19-3
β-naphthol

: 40491-84-7
2-bromo-butyric acid-[2]naphthyl ester

Conditions

Conditions	Yield
copper; copper dichloride for 0.025h; Alkylation; Irradiation;	99%

: 26074-52-2
2-bromo-butyryl bromide

: 5-(4-bromophenyl)-6H-1,3,4-thiadiazin-2-amine

: 1064666-89-2
C13H13Br2N3OS

Conditions

Conditions	Yield
With pyridine In acetonitrile at 20℃;	98%

: 26074-52-2
2-bromo-butyryl bromide

: 615-36-1
2-bromoaniline

: 1037586-23-4
2-bromo-N-(2-bromophenyl)-butyramide

Conditions

Conditions	Yield
With sodium hydroxide In water; toluene at 20℃; Inert atmosphere;	98%

: 26074-52-2
2-bromo-butyryl bromide

: 1451012-80-8
O-[o-(2-furyl)phenyl]methylhydroxylamine

: 1451012-93-3
(±)-1-{O-([o-(2-furyl)phenyl]methyl)oxyamino}-2-bromo-1-butanone

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 0.5h; Inert atmosphere;	98%

: 26074-52-2
2-bromo-butyryl bromide

: 30857-76-2
Cyclohexyl-[2,2-diphenyl-eth-(E)-ylidene]-amine

: 134987-75-0
2-Bromo-N-cyclohexyl-N-(2,2-diphenyl-vinyl)-butyramide

Conditions

Conditions	Yield
With pyridine In benzene 1) 30 min, 2) r.t., 16h;	97%

: 26074-52-2
2-bromo-butyryl bromide

: 100-51-6
benzyl alcohol

: 42115-51-5
2-bromobutyric acid benzyl ester

Conditions

Conditions	Yield
With pyridine In tetrahydrofuran at 0℃; Schlenk technique; Inert atmosphere;	96%

: 26074-52-2
2-bromo-butyryl bromide

: 90319-52-1
(4R)-phenyl-2-oxazolidinone

: 369624-75-9
(4'R)-2-bromo-1-(2'-oxo-4'-phenyloxazolidin-3'-yl)butan-1-one

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at -78℃; for 1.5h;	95%

: 497-25-6
dimethylenecyclourethane

: 26074-52-2
2-bromo-butyryl bromide

: 189103-39-7
3-(2-Bromo-butyryl)-oxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: dimethylenecyclourethane With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Stage #2: 2-bromo-butyryl bromide In tetrahydrofuran at -78℃; for 3h; Further stages.;	95%

: 26074-52-2
2-bromo-butyryl bromide

: 4358-87-6
(RS)-methyl mandelate

: 2-Bromo-butyric acid methoxycarbonyl-phenyl-methyl ester

Conditions

Conditions	Yield
With pyridine In diethyl ether at 0℃;	94%

: 26074-52-2
2-bromo-butyryl bromide

: 131793-05-0
(S)-(-)-1-(Cyanomethyl)-1,2,3,4-tetrahydroisoquinoline

: 131793-02-7, 131793-09-4
[(S)-2-(2-Bromo-butyryl)-1,2,3,4-tetrahydro-isoquinolin-1-yl]-acetonitrile

Conditions

Conditions	Yield
With diethyl-pyridin-4-yl-amine; triethylamine In dichloromethane at 0℃;	91.4%

: 26074-52-2
2-bromo-butyryl bromide

: 1885-29-6
anthranilic acid nitrile

: 88629-04-3
N-(α-bromobutyryl)-2-cyanoanilide

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane at 0 - 20℃;	91%
With potassium carbonate In dichloromethane; water Ambient temperature;	74%

: 26074-52-2
2-bromo-butyryl bromide

: 100-61-8
N-methylaniline

: 116496-46-9
2-bromo-N-methyl-N-phenylbutanamide

Conditions

Conditions	Yield
Stage #1: N-methylaniline With triethylamine In tetrahydrofuran at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 2-bromo-butyryl bromide In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere;	90%
Stage #1: N-methylaniline With triethylamine In tetrahydrofuran at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 2-bromo-butyryl bromide In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere;	73%
With diethyl ether

: 26074-52-2
2-bromo-butyryl bromide

: 30488-11-0
silver(I) dimesylamide

: N-(2-Brombutyryl)-dimesylamin

Conditions

Conditions	Yield
In acetonitrile for 14h; Ambient temperature;	90%

: 26074-52-2
2-bromo-butyryl bromide

: 105-13-5
4-Methoxybenzyl alcohol

: 4-methoxybenzyl 2-bromobutanoate

Conditions

Conditions	Yield
With pyridine In acetonitrile at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;	90%

: 26074-52-2
2-bromo-butyryl bromide

: 61042-20-4, 93249-65-1
2-[(methoxyimino)methyl]phenol

: 2-{[(methoxy)imino]methyl}phenyl 2-bromobutanoate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃;	89%

: 26074-52-2
2-bromo-butyryl bromide

: 131831-92-0
((S)-9-Methoxymethyl-2,3,4,9-tetrahydro-1H-β-carbolin-1-yl)-acetonitrile

: 131792-89-7, 131831-93-1
[(S)-2-(2-Bromo-butyryl)-9-methoxymethyl-2,3,4,9-tetrahydro-1H-β-carbolin-1-yl]-acetonitrile

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 0℃; for 0.5h;	88.8%

: 26074-52-2
2-bromo-butyryl bromide

: 131831-92-0
((S)-9-Methoxymethyl-2,3,4,9-tetrahydro-1H-β-carbolin-1-yl)-acetonitrile

: 131792-90-0
(S)-2-Amino-3-ethyl-12-methoxymethyl-6,7,12,12b-tetrahydro-1H-indolo[2,3-a]quinolizin-4-one

Conditions

Conditions	Yield
With silver; zinc	88%

: 26074-52-2
2-bromo-butyryl bromide

: 115106-43-9
4-(N-methyl)amino-3-methylcarbamoylisothiazole

: 119452-20-9
4-[(2-Bromo-butyryl)-methyl-amino]-isothiazole-3-carboxylic acid methylamide

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane for 0.0333333h;	88%

: 26074-52-2
2-bromo-butyryl bromide

: 2-amino-5-(4-methylphenyl)-6H-1,3,4-thiazine

: 1064666-88-1
C14H16BrN3OS

Conditions

Conditions	Yield
With pyridine In acetonitrile at 20℃;	88%

: 26074-52-2
2-bromo-butyryl bromide

: 90-15-3
α-naphthol

: 219749-59-4
2-bromo-butyric acid-[1]naphthyl ester

Conditions

Conditions	Yield
copper; copper dichloride for 0.025h; Alkylation; Irradiation;	87%

: 26074-52-2
2-bromo-butyryl bromide

: 873-75-6
4-bromobenzenemethanol

: 1610949-18-2
C11H12Br2O2

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 16h; Inert atmosphere; Schlenk technique;	87%

: 26074-52-2
2-bromo-butyryl bromide

: 119452-15-2
4-methylamino-3-methylcarbamoylisoselenazole

: 119452-18-5
4-[(2-Bromo-butyryl)-methyl-amino]-isoselenazole-3-carboxylic acid methylamide

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane for 0.0333333h;	86%

2-Bromobutyryl Bromide Chemical Properties

Chemistry informtion about 2-Bromobutyryl Bromide (CAS NO.26074-52-2) is:
IUPAC Name: 2-Bromobutyryl Bromide
Synonyms: Alpha-Bromobutyryl Bromide ; A-Bromo-N-Butyryl Bromide ; 2-Bromobutyryl Bromide ; 2-Bromo-N-Butyryl Bromide ; Bromobutyrylbromide ; 2-Bromobutyryl Bromide, Tech., 90% ; 2-Bromo-N-Butyryl Bromide (Alpha-) 95+%
MF: C₄H₆Br₂O
MW: 229.9
EINECS: 247-441-7
Density: 1.941 g/cm³
Flash Point: 66.3 °C
Boiling Point: 176.3 °C at 760 mmHg
Vapour Pressure: 1.1 mmHg at 25°C
Enthalpy of Vaporization: 41.27 kJ/mol
Refractive Index: n20/D 1.512(lit.)
Following is the molecular structure of 2-Bromobutyryl Bromide (CAS NO.26074-52-2) is:

2-Bromobutyryl Bromide Safety Profile

Hazard Codes:
C: Corrosive
Risk Statements:
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F:
F 19: Lachrymator.
F 21: Sensitive to humidity.
HazardClass: 8
PackingGroup: III

2-Bromobutyryl Bromide Specification

2-Bromobutyryl Bromide (CAS NO.26074-52-2) is a colorless or yellowish liquid.

Product Name

2-Bromobutyryl bromide

Synthetic route

2-Bromobutyryl Bromide Chemical Properties

2-Bromobutyryl Bromide Safety Profile

2-Bromobutyryl Bromide Specification

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