2-Methyl-N-(2-methylphenyl)benzamide supplier

Name
2,2''-DIMETHYLBENZANILIDE,99%
EINECS
CAS No. 22978-49-0
Article Data11
CAS DataBase
Density 1.122 g/cm³
Solubility
Melting Point 145 °C
Formula C₁₅H₁₅NO
Boiling Point 289.244 °C at 760 mmHg
Molecular Weight 225.29
Flash Point 172.098 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms o-Tolu-o-toluidide(7CI,8CI);
PSA 32.59000
LogP 3.93970

Synthetic route

: 933-88-0
ortho-toluoyl chloride

: 95-53-4
o-toluidine

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃;	87%
With triethylamine In toluene 1) reflux, 3 h, 2) room temperature, 16 h;	70%
With pyridine

: 615-37-2
ortho-methylphenyl iodide

: 201230-82-2
carbon monoxide

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
With sodium azide; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium dichloride In 1,4-dioxane at 130℃; for 12h;	78%

: 22627-01-6
bis(2-methylphenyl)methanimine

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
Stage #1: bis(2-methylphenyl)methanimine With bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃; for 0.0833333h; Stage #2: With triethylamine In acetonitrile at 20℃;	71%

: 201230-82-2
carbon monoxide

: 95-46-5
2-methylphenyl bromide

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
With sodium azide; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium dichloride In 1,4-dioxane at 130℃; for 12h;	69%

: 118-90-1
ortho-methylbenzoic acid

: 95-53-4
o-toluidine

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
With phosphorus trichloride at 120℃;

: 108714-78-9
bis-o-tolyl N-hydroxyoxime

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
With phosphoric acid; dicyclohexyl-carbodiimide In dimethyl sulfoxide; benzene for 16h;

: 118-90-1
ortho-methylbenzoic acid

potassium hydroxide: potassium hydroxide

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: SOCl2 2: Py View Scheme

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 17372-63-3
2-(o-methylphenyl)phthalimidine

Conditions

Conditions	Yield
Stage #1: 2-methyl-N-(2-methylphenyl)benzamide With iodine; potassium carbonate In acetonitrile at 20℃; for 0.166667h; Sealed tube; Stage #2: With di-tert-butyl peroxide In acetonitrile at 140℃; Sealed tube;	80%

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 123862-46-4
2-methyl-benzoic acid-(4-chloro-2-methyl-anilide)

Conditions

Conditions	Yield
With sulfuryl dichloride; benzene

: 124-38-9
carbon dioxide

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 78987-19-6
2-(2-methylphenyl)-4-phenylisoquinoline-1,3(2H,4H)-dione

Conditions

Conditions	Yield
With n-butyllithium 1) THF, -25 deg C, then room temperature, 3 h; Yield given. Multistep reaction;

: 124-38-9
carbon dioxide

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 78987-18-5
2-<<(2-carboxymethyl)benzoyl>amino>benzeneacetic acid

Conditions

Conditions	Yield
With n-butyllithium 1) THF, -25 deg C, then room temperature, 3 h; Yield given. Multistep reaction;

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 34743-36-7
2-Methyl-thiobenzoyl-(2-methylanilid)

Conditions

Conditions	Yield
With pyridine; phosphorus pentoxide Heating;

: 7791-25-5
sulfuryl dichloride

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 71-43-2
benzene

: 123862-46-4
2-methyl-benzoic acid-(4-chloro-2-methyl-anilide)

...Expand

: 22978-49-0
2-methyl-N-(2-methylphenyl)benzamide

: 34751-81-0
C15H15NOS

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: P2O5, Py / Heating 2: aq. H2O2 / CH2Cl2; methanol View Scheme

2-Methyl-N-(2-methylphenyl)benzamide Specification

The 2-Methyl-N-(2-methylphenyl)benzamide, with the CAS registry number 22978-49-0, is also known as Benzamide, 2-methyl-N-(2-methylphenyl)-. This chemical's molecular formula is C₁₅H₁₅NO and molecular weight is 225.29. What's more, its systematic name is 2-Methyl-N-(2-methylphenyl)benzamide.

Physical properties of 2-Methyl-N-(2-methylphenyl)benzamide are: (1)ACD/LogP: 3.54; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.54; (4)ACD/LogD (pH 7.4): 3.54; (5)ACD/BCF (pH 5.5): 288.75; (6)ACD/BCF (pH 7.4): 288.75; (7)ACD/KOC (pH 5.5): 2008.37; (8)ACD/KOC (pH 7.4): 2008.36; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 29.1 Å²; (13)Index of Refraction: 1.619; (14)Molar Refractivity: 70.478 cm³; (15)Molar Volume: 200.855 cm³; (16)Polarizability: 27.94×10^-24cm³; (17)Surface Tension: 45.7 dyne/cm; (18)Density: 1.122 g/cm³; (19)Flash Point: 172.098 °C; (20)Enthalpy of Vaporization: 52.853 kJ/mol; (21)Boiling Point: 289.244 °C at 760 mmHg; (22)Vapour Pressure: 0.002 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(Nc1ccccc1C)c2ccccc2C
(2)Std. InChI: InChI=1S/C15H15NO/c1-11-7-3-5-9-13(11)15(17)16-14-10-6-4-8-12(14)2/h3-10H,1-2H3,(H,16,17)
(3)Std. InChIKey: KBOSBZUAAMLSFQ-UHFFFAOYSA-N

Product Name

2,2''-DIMETHYLBENZANILIDE,99%

Synthetic route

2-Methyl-N-(2-methylphenyl)benzamide Specification

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