acrylic acid
potassium acrylate
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel(0); 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 50 - 100℃; under 23272.3 Torr; Solvent; Pressure; Autoclave; | |
With RuP(CH2CH2P(C6H5)2)3(C2H4); potassium tert-butylate In N,N-dimethyl acetamide at 140℃; under 22502.3 Torr; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Inert atmosphere; Autoclave; | |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; 1,2-bis-(dicyclohexylphosphino)ethane at 120℃; under 7500.75 - 22502.3 Torr; for 18h; Autoclave; |
ethene
potassium ethoxide
A
RuP(CH2CH2P(C6H5)2)3(C2H4)
B
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide at 60℃; under 750.075 Torr; for 2h; Inert atmosphere; Sealed tube; | A 96 %Spectr. B 68 %Spectr. |
2-(n-perfluorooctyl)ethyl iodide
potassium acrylate
1H,1H,2H,2H-heptadecafluorodecyl acrylate
Conditions | Yield |
---|---|
With 4-methoxy-phenol; hydroquinone In tert-butyl alcohol at 180℃; for 6h; Conversion of starting material; | 99% |
Conditions | Yield |
---|---|
With tyrosamine; methyltriphenylphosphonium chloride In N,N-dimethyl-formamide at 115℃; for 2h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With N1,N4-di(naphthalen-1-yl)benzene-1,4-diamine; butyltriphenylphosphonium chloride In N,N-dimethyl-formamide at 120℃; for 1.5h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-4-methyl-phenol; ethyltriphenylphosphonium bromide In N,N-dimethyl-formamide at 125℃; for 1h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With tyrosamine; tetraphenyl phosphonium chloride In toluene at 110℃; for 2.5h; Inert atmosphere; | 98% |
N,N'-diphenyl-1,4-phenylenediamine
potassium acrylate
N-neopentyl-4-(4-methylpiperidinyl)-pyridinium chloride
3-Chloropropyltrimethoxysilan
3-(trimethoxysilyl)propyl acrylate
Conditions | Yield |
---|---|
In methanol | 92.7% |
diethyl 3-(bromopropyl)phosphonic acid
potassium acrylate
1,3-dibromo-propane
diethyl 3-acryloyloxypropylphosphonate
Conditions | Yield |
---|---|
With triethyl phosphite In N,N-dimethyl-formamide | 92% |
triisopropylsilyl chloride
potassium acrylate
tri(isopropyl)silyl acrylate
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-4-methyl-phenol In toluene at 45 - 50℃; for 6h; Reagent/catalyst; Inert atmosphere; | 86% |
potassium acrylate
3-Chloropropyltrimethoxysilan
3-(trimethoxysilyl)propyl acrylate
Conditions | Yield |
---|---|
With tetrabutylammomium bromide at 125 - 130℃; for 5h; Temperature; Large scale; | 85.6% |
trimethylsilyl methanesulfonate
potassium acrylate
trimethylsilyl acrylate
Conditions | Yield |
---|---|
With 2,2-diphenyl-1-picrylhydrazine at 150℃; for 1h; | 82.7% |
potassium acrylate
3-[(chlorosulfinyl)oxy]-1,1,2,2-tetrafluoropropane
acrylate de trihydro-1,1,3 tetrafluoropropyle
Conditions | Yield |
---|---|
76.2% |
Conditions | Yield |
---|---|
76.1% |
potassium acrylate
5-[(chlorosulfinyl)oxy]-1,1,2,2,3,3,4,4-octafluoropentane
acrylate de trihydro-1,1,5 octafluoropentyle
Conditions | Yield |
---|---|
76% |
Conditions | Yield |
---|---|
tetrabutylammomium bromide In dichloromethane at 30℃; for 50h; | 75% |
potassium acrylate
5-Bromo-pentanoic acid 4-[(R)-1-(3,4-dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-butyl ester
5-Acryloyloxy-pentanoic acid 4-[(R)-1-(3,4-dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-butyl ester
Conditions | Yield |
---|---|
With 18-crown-6 ether In N,N,N,N,N,N-hexamethylphosphoric triamide at 40℃; for 24h; | 73% |
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 8h; | 72% |
Conditions | Yield |
---|---|
In ethanol at 30-40°C; | 70% |
In ethanol at 30-40°C; | 70% |
Conditions | Yield |
---|---|
In ethanol byproducts: KCl; equimolar amts. of educts, gentle warming; recrystn. in petroleum ether; | 66% |
In ethanol byproducts: KCl; equimolar amts. of educts, gentle warming; recrystn. in petroleum ether; | 66% |
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 8h; | 61% |
potassium acrylate
Conditions | Yield |
---|---|
In chlorobenzene at 120℃; for 10h; | 52% |
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 8h; | 41% |
potassium acrylate
1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane
1,3-bis-acryloyloxymethyl-1,1,3,3-tetramethyl-disiloxane
Conditions | Yield |
---|---|
With hydroquinone In N,N-dimethyl-formamide for 6h; boiling; | 40% |
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 8h; | 36% |
potassium acrylate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 8h; | 35% |
C10H4F17Cl
potassium acrylate
1H,1H,2H,2H-heptadecafluorodecyl acrylate
Conditions | Yield |
---|---|
With 4-methoxy-phenol; hydroquinone In tert-butyl alcohol at 180℃; for 6h; | 12% |
2-Chlormethyl-1,4,6-trioxa-spiro-<4,4>-nonan
potassium acrylate
2-acryloyloxymethyl-1,4,6-trioxaspiro<4,4>nonane
Conditions | Yield |
---|---|
N-benzyl-N,N,N-triethylammonium chloride In N,N-dimethyl-formamide at 110 - 115℃; for 7h; | 7% |
potassium acrylate
2-bromomethyl-1,4,6-trioxaspiro<4.4>nonane
2-acryloyloxymethyl-1,4,6-trioxaspiro<4,4>nonane
Conditions | Yield |
---|---|
N-benzyl-N,N,N-triethylammonium chloride In N,N-dimethyl-formamide at 110 - 115℃; for 7h; | 7% |
diethyl phosphorylchloridite
potassium acrylate
acryloyl diethyl phosphite
Conditions | Yield |
---|---|
In diethyl ether |
2-fluoro-2,2-dinitroethylsulfuric acid
potassium acrylate
2-fluoro-2,2-dinitroethyl acrylate
dipropyl phosphorochloridite
potassium acrylate
Phosphorigesaeure-dipropylester-acryloylester
Conditions | Yield |
---|---|
In diethyl ether |
The 2-Propenoic acid,potassium salt (1:1), with the CAS registry number 10192-85-5, is also known as Potassium acrylate. Its EINECS number is 233-473-9. This chemical's molecular formula is C3H4O2.K and molecular weight is 110.15. What's more, its systematic name is Potassium prop-2-enoate. The product should be sealed and stored in cool and dry places.
Physical properties of 2-Propenoic acid,potassium salt (1:1) are: (1)ACD/LogP: 0.28; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.99; (4)ACD/LogD (pH 7.4): -2.77; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1.8; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 37.3 Å2; (13)Flash Point: 61.6 °C; (14)Enthalpy of Vaporization: 41.72 kJ/mol; (15)Boiling Point: 141 °C at 760 mmHg; (16)Vapour Pressure: 3.42 mmHg at 25°C.
Uses of 2-Propenoic acid,potassium salt: it can be used to produce acrylic acid allyl ester at the temperature of 30 °C. It will need catalyst Bu4NBr and solvent CH2Cl2 with the reaction time of 50 hours. The yield is about 75%.
When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C=CC(=O)[O-].[K+]
(2)InChI: InChI=1S/C3H4O2.K/c1-2-3(4)5;/h2H,1H2,(H,4,5);/q;+1/p-1
(3)InChIKey: ZUBIJGNKOJGGCI-UHFFFAOYSA-M
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