3,4,9,10-Perylenetetracarboxylicacid supplier

Name
perylene-3,4,9,10-tetracarboxylic acid
EINECS 201-343-0
CAS No. 81-32-3
Article Data22
CAS DataBase
Density 1.739 g/cm³
Solubility
Melting Point
Formula C₂₄H₁₂O₈
Boiling Point 912.4 °C at 760 mmHg
Molecular Weight 428.354
Flash Point 519.4 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 3,4,9,10-Tetracarboxyperylene;NSC 89768;
PSA 149.20000
LogP 4.53000

Synthetic route

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With potassium hydroxide In water for 12h; Heating;	99%
Stage #1: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With potassium hydroxide In water at 20℃; for 6h; Stage #2: With hydrogenchloride In water pH=Ca. 7;	80%
With sodium hydroxide

: 118153-98-3
1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylic acid

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With potassium hydroxide In ethylene glycol at 155 - 160℃; for 4h;	91%

: 107905-43-1
1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With potassium hydroxide In ethylene glycol at 120℃; for 1h;	82%

: dibenzo[cd,lm]perylene-1,3,8,10-tetraone

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With alkaline sodium hypochlorite
With chromium(III) oxide; sulfuric acid

: 857785-32-1
3,10-diamino-dibenzo[cd,lm]perylene-1,8-dione

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With potassium permanganate; sulfuric acid at 20℃;
With sodium dichromate; sulfuric acid at 20℃;

: 38250-80-5
C32H18O

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With nitric acid at 165 - 190℃;

: 21020-04-2
1-Benzoyloxy-peropyren

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With nitric acid at 180 - 200℃;

: 7664-93-9
sulfuric acid

: 81-33-4
3,4,9,10-perylene tetracarboxyxlic acid diimide

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
at 200℃;
at 200℃;

perylene-tetracarboxylic acid-(3.4.9.10)-diimide: perylene-tetracarboxylic acid-(3.4.9.10)-diimide

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
With sulfuric acid at 200℃;

: 7664-93-9
sulfuric acid

: 857785-32-1
3,10-diamino-dibenzo[cd,lm]perylene-1,8-dione

permanganate: permanganate

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield

...Expand

: 7664-93-9
sulfuric acid

: 3,10-diamino-2,9-dimethyl-dibenzo[cd,lm]perylene-1,8-dione

potassium permanganate: potassium permanganate

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield

...Expand

: 7664-93-9
sulfuric acid

: 857785-32-1
3,10-diamino-dibenzo[cd,lm]perylene-1,8-dione

sodium dichromate: sodium dichromate

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield

...Expand

: 118129-58-1
1,7-dichloroperylene-3,4,9,10-tetracarboxylic acid

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 59 percent / Cl2, 3percent oleum / 9 h / 70 - 75 °C 2: 91 percent / KOH / ethane-1,2-diol / 4 h / 155 - 160 °C View Scheme

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 198-55-0
PERYLENE

Conditions

Conditions	Yield
With sodalime at 450 - 500℃; stream of superheated steam;	96%
bei der trocknen Destillation des Calciumsalzes;
With potassium hydroxide at 250℃; beim Erhitzen des Kaliumsalzes im Autoklaven;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 100-36-7
N,N-diethylethylenediamine

: 73528-90-2
N,N'-bis(2-(N'',N''-diethylamino)ethyl)perylene-3,4:9,10-bis(dicarboximide)

Conditions

Conditions	Yield
In water Heating;	88%
1.) DMF, 145 deg C - 150 deg C, 1 h, 2.) 125 deg C - 140 deg C, 2 h; Yield given. Multistep reaction;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 100-44-7
benzyl chloride

: 698998-98-0
perylene 3,4,9,10-tetracarboxylic acid tetrabenzyl ester

Conditions

Conditions	Yield
With dmap; 18-crown-6 ether; potassium carbonate In N,N-dimethyl-formamide at 80℃; for 12h;	86%

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 79750-27-9
1,12-sulfonyloxyperylene-3,4,9,10-tetracarboxylic acid

Conditions

Conditions	Yield
	85%

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 109-73-9
N-butylamine

: 52000-75-6
2,9-dibutylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions

Conditions	Yield
With 1H-imidazole at 120℃; for 4h;	80%

: 6346-09-4
4-aminobutyrylaldehyde diethylacetal

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 1446681-44-2
N,N'-bis(4,4-diethoxybutyl)perylene-3,4,9,10-tetracarboxylic diimide

Conditions

Conditions	Yield
With 1H-imidazole at 120℃; for 4h;	78%

: 24131-32-6
3,5-bis(benzyloxy)benzyl bromide

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: tetrakis[3,5-di(benzyloxy)benzyl] 3,4,9,10-perylenetetracarboxylate

Conditions

Conditions	Yield
With dmap; 18-crown-6 ether; potassium carbonate In N,N-dimethyl-formamide at 85℃; for 12h;	76%

: 1700-31-8
3-benzyloxybenzyl bromide

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: tetrakis[3-(benzyloxy)benzyl] 3,4,9,10-perylenetetracarboxylate

Conditions

Conditions	Yield
With dmap; 18-crown-6 ether; potassium carbonate In N,N-dimethyl-formamide at 85℃; for 12h;	72%

: copper(II) nitrate trihydrate

: 64-17-5
ethanol

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 107-15-3
ethylenediamine

: C32H44Cu2N8O10*3H2O*C2H6O

Conditions

Conditions	Yield
In water at 20℃; for 0.5h;	72%

...Expand

: 74654-07-2
2-[2-(2-methoxyethoxy)ethoxy]ethylamine

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: N,N'-di-[10-(3,6,9-trioxadecyl)]perylene-3,4,9,10-bis(dicarboximide)

Conditions

Conditions	Yield
With 1H-imidazole; zinc diacetate at 160℃; for 18h; Inert atmosphere;	47%

: 546-68-9
titanium(IV) isopropylate

: 66-71-7
1,10-Phenanthroline

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 2Ti(4+)*6C3H7O(1-)*2C12H8N2*C30H22O8(2-)*C3H8O

Conditions

Conditions	Yield
In toluene at 40℃; for 144h; Inert atmosphere; Sealed tube;	38%

...Expand

: 956092-70-9
(2S,3S)-3-amino-4-{4,4’-dimethoxytrityloxy}butan-2-ol

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 75-31-0
isopropylamine

: 1260145-35-4
C52H42N2O8

Conditions

Conditions	Yield
Stage #1: (2S,3S)-3-amino-4-{4,4’-dimethoxytrityloxy}butan-2-ol; perylene-3,4,9,10-tetracarboxylic acid With zinc diacetate; triethylamine In pyridine for 24h; Molecular sieve; Reflux; Stage #2: isopropylamine With zinc diacetate; triethylamine In pyridine for 24h; Molecular sieve; Reflux;	28%

...Expand

: 1402226-20-3
7-amino-1,12-tridecadiene

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 1402226-21-4
N,N'-di(1,12-tridecadiene-7-yl)perylene-3,4,9,10,tetracarboxylic acid bisimide

Conditions

Conditions	Yield
With zinc diacetate In quinoline at 230℃; for 5h; Inert atmosphere;	12%

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 141-43-5
ethanolamine

: 80689-49-2
N-hydroxyethyl-3,4:9,10-perylenetetracarboxylic-3,4-anhydride-9,10-imide

Conditions

Conditions	Yield
Stage #1: perylene-3,4,9,10-tetracarboxylic acid; ethanolamine In water at 0℃; for 5h; Reflux; Stage #2: With sulfuric acid In water at 90℃; for 0.5h;	10%

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 593-51-1
methylamine hydrochloride

: 5521-31-3
N,N'-Dimethylperylene-3,4,9,10-biscarboximide

Conditions

Conditions	Yield
at 180 - 200℃;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 81-33-4
3,4,9,10-perylene tetracarboxyxlic acid diimide

Conditions

Conditions	Yield
at 200 - 230℃; durch Erhitzen des Tetraammoniumsalzes mit Ammoniumcarbonat;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 128-69-8
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

Conditions

Conditions	Yield
With acetic anhydride
With sodium hydroxide
With sulfuric acid at 20℃; for 12h;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 106-47-8
4-chloro-aniline

: 2379-77-3
3,4,9,10-perylenetetracarboxylic acid N,N'-di(4-chlorophenyl)diimide

Conditions

Conditions	Yield
at 100 - 120℃;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 62-53-3
aniline

: 128-65-4
2,9-diphenylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions

Conditions	Yield
With acetic acid at 100 - 120℃;
at 100 - 120℃;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

: 108-00-9
N,N-dimethylethylenediamine

: 73528-89-9
2,9-bis(2-(dimethylamino)ethyl)anthra[2,1,9-def:6,5,10-d′e′f ′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

Conditions

Conditions	Yield
1.) DMF, 145 deg C - 150 deg C, 1 h, 2.) 125 deg C - 140 deg C, 2 h; Yield given. Multistep reaction;

: 81-32-3
perylene-3,4,9,10-tetracarboxylic acid

KOH-solution: KOH-solution

A: 198-55-0
PERYLENE

B: 7350-88-1
Perylene-3-carboxylic acid

C: perylene-3,4,9-tricarboxylic acid

D perylene-dicarboxylic acid-(3.9 or 3.10): perylene-dicarboxylic acid-(3.9 or 3.10)

Conditions

Conditions	Yield
at 190 - 250℃; im Autoklaven;

...Expand

3,4,9,10-Perylenetetracarboxylicacid Specification

The 3,4,9,10-Perylenetetracarboxylicacid, with the CAS registry number 81-32-3, is also known as tri-n-Propylamine. Its EINECS registry number is 201-343-0. This chemical's molecular formula is C₂₄H₁₂O₈ and molecular weight is 428.34728. What's more, both its IUPAC name and systematic name are the same which is called Perylene-3,4,9,10-tetracarboxylic acid.

Physical properties about 3,4,9,10-Perylenetetracarboxylicacid are: (1)ACD/LogP: 3.46; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.46; (4)ACD/LogD (pH 7.4): -2.68; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 8; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 105.2 Å²; (13)Index of Refraction: 1.939; (14)Molar Refractivity: 118.02 cm³; (15)Molar Volume: 246.2 cm³; (16)Surface Tension: 112.5 dyne/cm; (17)Density: 1.739 g/cm³; (18)Flash Point: 519.4 °C; (19) Enthalpy of Vaporization: 138.97 kJ/mol; (20)Boiling Point: 912.4 °C at 760 mmHg; (21)Vapour Pressure: 0 mmHg at 25 °C.

Preparation of 3,4,9,10-Perylenetetracarboxylicacid: this chemical can be prepared by 1,6,7,12-Tetrachloroperylene-3,4,9,10-tetracarboxylic acid. This reaction needs reagent KOH and solvent Ethane-1,2-diol at temperature of 155 - 160 °C. The reaction time is 4 hours. The yield is 91 %.

3,4,9,10-Perylenetetracarboxylicacid can be prepared by 1,6,7,12-Tetrachloroperylene-3,4,9,10-tetracarboxylic acid

Uses of 3,4,9,10-Perylenetetracarboxylicacid: it is used to produce other chemicals. For example, it is used to produce Perylene. The reaction occurs with reagent KOH-solution at temperature of 250 °C and other condition of beim Erhitzen des Kaliumsalzes im Autoklaven.

3,4,9,10-Perylenetetracarboxylicacid is used to produce Perylene.

You can still convert the following datas into molecular structure:
(1) SMILES: O=C(O)c3c5c2c(c1ccc(c4c1c(c2cc3)ccc4C(=O)O)C(=O)O)ccc5C(=O)O
(2) InChI: InChI=1/C24H12O8/c25-21(26)13-5-1-9-10-2-6-15(23(29)30)20-16(24(31)32)8-4-12(18(10)20)11-3-7-14(22(27)28)19(13)17(9)11/h1-8H,(H,25,26)(H,27,28)(H,29,30)(H,31,32)
(3) InChIKey: FVDOBFPYBSDRKH-UHFFFAOYAV

Product Name

perylene-3,4,9,10-tetracarboxylic acid

Synthetic route

3,4,9,10-Perylenetetracarboxylicacid Specification

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