4-Vinylbenzyl glycidyl ether supplier

Name
4-Vinylbenzyl glycidyl ether
EINECS
CAS No. 113538-80-0
Article Data14
CAS DataBase
Density 1.088g/cm³
Solubility
Melting Point
Formula C₁₂H₁₄O₂
Boiling Point 299.221 °C at 760 mmHg
Molecular Weight 190.242
Flash Point 121.095 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 4-Vinylbenzyl glycidyl ether;2-{[(4-ethenylphenyl)Methoxy]Methyl}oxirane
PSA 21.76000
LogP 2.24500

Synthetic route

: 1592-20-7
4-Vinylbenzyl chloride

: 556-52-5
oxiranyl-methanol

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 4h;	86%
Stage #1: oxiranyl-methanol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Inert atmosphere; Stage #2: 4-Vinylbenzyl chloride In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h; Inert atmosphere;	86%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 1h;	85%

: 292638-84-7
styrene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

Conditions

Conditions	Yield
In toluene

: 2488-01-9
1,4-bis(dimethylsilyl)benzene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 1,4-bis(dimethyl(4-((oxiran-2-ylmethoxy)methyl)phenethyl)silyl)benzene

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene at 0 - 20℃; for 3.16667h; Inert atmosphere;	90%

: 124-38-9
carbon dioxide

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 4-vinylbenzyl 2,5-dioxoran-3-ylmethyl ether

Conditions

Conditions	Yield
With lithium bromide In N,N-dimethyl-formamide at 100℃; for 24h;	81%

: 75-15-0
carbon disulfide

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 1414436-28-4
4-vinylbenzyl 1,3-oxathiolane-2-thione-5-ylmethyl ether

Conditions

Conditions	Yield
With lithium bromide In tetrahydrofuran at 0 - 20℃;	81%

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 114689-61-1
2-(2-(2-(2-(4-vinylbenzyloxy)ethoxy)ethoxy)ethoxy)ethanol

polymer, Mw = 29168, Mn = 14023, Mw/Mn = 2.08; monomer(s): 4-vinyl benzyl tetraethyleneglycol ether; 4-vinyl benzyl glycidyl ether: polymer, Mw = 29168, Mn = 14023, Mw/Mn = 2.08; monomer(s): 4-vinyl benzyl tetraethyleneglycol ether; 4-vinyl benzyl glycidyl ether

Conditions

Conditions	Yield
With 2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile In chloroform at 45℃; for 48h;	77%

: 96-48-0
4-butanolide

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 1470595-49-3
C16H20O4

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 4.5h;	66%

: 502-44-3
hexahydro-2H-oxepin-2-one

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 1470595-51-7
C18H24O4

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 4.5h;	63%

: 292638-84-7
styrene

: 1-(4-vinylbenzyl)-2-pyrrolidinone

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 515881-62-6
tetraethylene glycol mono-2-phenyl-2-propenyl ether

Reaxys ID: 11364530: Reaxys ID: 11364530

Conditions

Conditions	Yield
2,2'-azobis(isobutyronitrile) In chloroform for 48h; Heating / reflux;	61%

...Expand

: 21911-69-3
N-(p-tolyl)glycine

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: NTG-VBE sodium salt

Conditions

Conditions	Yield
Stage #1: N-(p-tolyl)glycine With sodium hydroxide In tetrahydrofuran; water at 20℃; for 0.5h; pH=8.7; Stage #2: 2-(4-vinyl-benzyloxymethyl)-oxirane In tetrahydrofuran; water at 20℃; for 48h;	57%

: 292638-84-7
styrene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 114689-61-1
2-(2-(2-(2-(4-vinylbenzyloxy)ethoxy)ethoxy)ethoxy)ethanol

polymer, Mw 44664, Mw/Mn 1.80 by gel permeation chromatography; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; 2-(2-(2-(2-(4-vinylbenzyloxy)ethoxy)ethoxy)ethoxy)ethanol: polymer, Mw 44664, Mw/Mn 1.80 by gel permeation chromatography; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; 2-(2-(2-(2-(4-vinylbenzyloxy)ethoxy)ethoxy)ethoxy)ethanol

Conditions

Conditions	Yield
With 2,2'-azobis(4-methoxy)-2,4-dimethylvaleronitrile In chloroform at 20℃; for 72h;	56%

...Expand

: 292638-84-7
styrene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 515881-62-6
tetraethylene glycol mono-2-phenyl-2-propenyl ether

polymer, Mw = 69985, Mn = 12098; Monomer(s): styrene; 4-vinylbenzyl glycidyl ether; tetraethyleneglycol mono-2-phenyl-2-propenyl ether: polymer, Mw = 69985, Mn = 12098; Monomer(s): styrene; 4-vinylbenzyl glycidyl ether; tetraethyleneglycol mono-2-phenyl-2-propenyl ether

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform for 48h; Heating;	53%

...Expand

: 14-phenylpentadec-14-en-1-ol

: 292638-84-7
styrene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

Polymer, Mw: 23843, Mn: 18857, Mw/Mn: 1.26, ratio of monomers: 79/11/10; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; 14-phenylpentadec-14-en-1-ol: Polymer, Mw: 23843, Mn: 18857, Mw/Mn: 1.26, ratio of monomers: 79/11/10; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; 14-phenylpentadec-14-en-1-ol

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform for 24h; Heating;	48%

...Expand

: 292638-84-7
styrene

: 40538-11-2
diphenyl(4-vinylphenyl)phosphine

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 515881-62-6
tetraethylene glycol mono-2-phenyl-2-propenyl ether

polymer, Mw = 49330, Mn = 25692, Mw/Mn = 1.92; monomer(s): styrene, 72 mol percent; 4-vinylbenzyl glycidyl ether, 12 mol percent; tetraethylene glycol mono-2-phenyl-2-propenyl ether, 5 mol percent; diphenyl(4-vinylphenyl)phosphine, 11 mol percent: polymer, Mw = 49330, Mn = 25692, Mw/Mn = 1.92; monomer(s): styrene, 72 mol percent; 4-vinylbenzyl glycidyl ether, 12 mol percent; tetraethylene glycol mono-2-phenyl-2-propenyl ether, 5 mol percent; diphenyl(4-vinylphenyl)phosphine, 11 mol percent

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 70℃; for 24h;

...Expand

: 292638-84-7
styrene

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: 515881-62-6
tetraethylene glycol mono-2-phenyl-2-propenyl ether

polymer, Mw 42798, Mn 14649 by GPC; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; tetraethyleneglycol mono-2-phenyl-2-propenyl ether: polymer, Mw 42798, Mn 14649 by GPC; monomer(s): styrene; 4-vinylbenzyl glycidyl ether; tetraethyleneglycol mono-2-phenyl-2-propenyl ether

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform for 24h; Heating;	37.0 g

...Expand

: N-(p-tolyl)glycine sodium salt

: 113538-80-0
2-(4-vinyl-benzyloxymethyl)-oxirane

: NTG-VBE sodium salt

Conditions

Conditions	Yield
With 2,4,6-tri-tert-butylphenoxol; sodium hydroxide In methanol; water pH=9;

4-Vinylbenzyl glycidyl ether Specification

The 4-Vinylbenzyl glycidyl ether, with CAS registry number 113538-80-0, has the systematic name of 2-{[(4-ethenylbenzyl)oxy]methyl}oxirane. Besides this, it is also called oxiran-2-yl[(4-vinylphenyl)methoxy]methane. And the chemical formula of tihs chemical is C₁₂H₁₄O₂.

Physical properties of 4-Vinylbenzyl glycidyl ether: (1)ACD/LogP: 2.21; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 2; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 5; (6)Polar Surface Area: 21.76 Å²; (7)Index of Refraction: 1.569; (8)Molar Refractivity: 57.312 cm³; (9)Molar Volume: 174.867 cm³; (10)Polarizability: 22.72×10^-24cm³; (11)Surface Tension: 42.164 dyne/cm; (12)Density: 1.088 g/cm³; (13)Flash Point: 121.095 °C; (14)Enthalpy of Vaporization: 51.763 kJ/mol; (15)Boiling Point: 299.221 °C at 760 mmHg; (16)Vapour Pressure: 0.002 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O(Cc1ccc(\C=C)cc1)CC2OC2
(2)InChI: InChI=1/C12H14O2/c1-2-10-3-5-11(6-4-10)7-13-8-12-9-14-12/h2-6,12H,1,7-9H2
(3)InChIKey: ZADXFVHUPXKZBJ-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C12H14O2/c1-2-10-3-5-11(6-4-10)7-13-8-12-9-14-12/h2-6,12H,1,7-9H2
(5)Std. InChIKey: ZADXFVHUPXKZBJ-UHFFFAOYSA-N

Product Name

4-Vinylbenzyl glycidyl ether

Synthetic route

4-Vinylbenzyl glycidyl ether Specification

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