4-Vinylbenzyl chloride supplier

Name
4-Vinylbenzyl chloride
EINECS 216-471-2
CAS No. 1592-20-7
Article Data18
CAS DataBase
Density 1.066 g/cm³
Solubility Insoluble in water
Melting Point
Formula C₉H₉Cl
Boiling Point 228.9 °C at 760 mmHg
Molecular Weight 152.623
Flash Point 90.4 °C
Transport Information UN 3265 8/PG 3
Appearance clear yellow liquid
Safety 26-36/37/39-45
Risk Codes 34-43-21/22
Molecular Structure
Hazard Symbols C
Synonyms Styrene,p-(chloromethyl)- (6CI,7CI,8CI);1-(Chloromethyl)-4-vinylbenzene;4-(Chloromethyl)styrene;CMS 14;p-(Chloromethyl)styrene;p-Vinylbenzyl chloride;
PSA 0.00000
LogP 3.06840

Synthetic route

: 35793-35-2
p-chloromethyl-α-bromoethylbenzene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With 18-crown-6 ether; potassium hydroxide In toluene at 40℃; for 4h; Reagent/catalyst; Temperature; Solvent;	95%

: 1074-61-9
(4-vinyl-phenyl)-methanol

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With oxalyl dichloride; Tropone In dichloromethane at 20℃; for 0.25h; Inert atmosphere;	84%

: 53459-40-8
1-(2-chloroethyl)-4-(chloromethyl)benzene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With 4-tert-Butylcatechol; sodium t-butanolate In tetrahydrofuran at 30℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere;	83%

: 24249-98-7
p-chloromethyl-2-bromoethylbenzene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With potassium hydroxide; tetrabutylammomium bromide at 30℃; for 4h; different reagents, solvents and reaction times;	77%
With tetrabutylammomium bromide; potassium hydroxide In tert-butyl alcohol at 30℃; for 4h;	50.1%

: 622-97-9
1-ethenyl-4-methylbenzene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With hydrogenchloride; potassium chloride; tetrabutyl-ammonium chloride In fluorobenzene; water at 20℃; Irradiation; Green chemistry;	68%

poly 4-chlorostyrene: poly 4-chlorostyrene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
at 500 - 650℃;	60%

: 292638-84-7
styrene

: 107-30-2
chloromethyl methyl ether

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With carbon disulfide; zinc(II) chloride at 40℃; for 5h; Reflux;	13%

: 1467-05-6
4-ethylbenzylchloride

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
(i) NBS, (PhCO)2O2, (ii) (heating), benzene-1,4-diol; Multistep reaction;

: 76297-21-7
1-(4-chloromethylphenyl)ethanol

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With potassium hydrogensulfate; 4-tert-Butylcatechol at 210℃;

: 622-97-9
1-ethenyl-4-methylbenzene

A: 42107-37-9
α-chloro-p-methylstyrene

B: 1592-20-7
4-Vinylbenzyl chloride

C di- and trichlorinated products: di- and trichlorinated products

Conditions

Conditions	Yield
With chlorine In water at 560℃; for 0.000222222h; Product distribution; gas phase reaction, oth. isomers;

...Expand

: 73291-09-5
4-chloromethylbenzaldehyde

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 2: KHSO4, 4-tert-butyl-benzene-1,2-diol / 210 °C View Scheme

: 73291-09-5
4-chloromethylbenzaldehyde

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 16h; Wittig Olefination;

: 100-41-4
ethylbenzene

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: bromine / 3 h / Reflux; Inert atmosphere 2: hydrogenchloride; zinc(II) chloride / 20 h / 40 °C / Reflux 3: potassium hydroxide; 18-crown-6 ether / toluene / 4 h / 40 °C View Scheme

: 60-12-8
2-phenylethanol

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: hydrogen bromide; zinc(II) chloride / 6 h / 80 - 90 °C / Reflux 2: hydrogenchloride; zinc(II) chloride / 18 h / 30 °C / Reflux 3: tetrabutylammomium bromide; potassium hydroxide / tert-butyl alcohol / 4 h / 30 °C View Scheme
Multi-step reaction with 3 steps 1: hydrogenchloride / water / 8 h / 120 °C 2: hydrogenchloride; sulfuric acid; zinc(II) chloride / water / 5 h / 90 °C 3: sodium t-butanolate; 4-tert-Butylcatechol / tetrahydrofuran / 1 h / 30 °C / Inert atmosphere View Scheme

: 103-63-9
1-phenyl-2-bromoethane

: 1592-20-7
4-Vinylbenzyl chloride

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrogenchloride; zinc(II) chloride / 18 h / 30 °C / Reflux 2: tetrabutylammomium bromide; potassium hydroxide / tert-butyl alcohol / 4 h / 30 °C View Scheme

: 1592-20-7
4-Vinylbenzyl chloride

: 1,2-dibromo-1-(4-chlorophenyl)ethane

Conditions

Conditions	Yield
With Ph-HMS; bromine In dichloromethane for 5h; Ambient temperature; Irradiation;	100%
With sodium periodate; acetic acid; lithium bromide at 25℃;	96%

: 1592-20-7
4-Vinylbenzyl chloride

: 2-bromo-1-(4-chloromethylphenyl)ethanol

Conditions

Conditions	Yield
With N-Bromosuccinimide; water In acetonitrile at 20℃;	100%
With sodium periodate; sulfuric acid; lithium bromide In water; acetonitrile at 25℃; pH=6.12;	85%
With N-Bromosuccinimide; water In acetone at 0 - 20℃;

: 123-75-1
pyrrolidine

: 1592-20-7
4-Vinylbenzyl chloride

: 60472-54-0
1-[(4-ethenylphenyl)methyl]-pyrrolidine

Conditions

Conditions	Yield
In hexane at 0 - 20℃;	100%
In hexane at 20℃; for 20h; Cooling with ice;	98%
In hexane at 0 - 20℃;
In hexane

: 1592-20-7
4-Vinylbenzyl chloride

: dimethylamino-methanesulfonic acid ; sodium salt

: 1273544-34-5
4-vinylbenzyldimethylammonio methanesulfonate

Conditions

Conditions	Yield
In ethanol; water at 45℃; for 24h; Inert atmosphere;	100%

: 1592-20-7
4-Vinylbenzyl chloride

: 75-50-3
trimethylamine

: 7538-38-7
N,N,N-trimethyl-1-(4-vinylphenyl)methanaminium chloride

Conditions

Conditions	Yield
In ethanol at 20℃; for 18h;	100%
In water at 0℃; for 72h;
In N,N-dimethyl-formamide at 60℃; for 24h; Autoclave;

: 51-80-9
bis-(dimethylamino)methane

: 1592-20-7
4-Vinylbenzyl chloride

: N,N'-(methylene)bis(N,N-dimethyl-1-(4-vinylphenyl)methanaminium) chloride

Conditions

Conditions	Yield
In acetonitrile at 50℃; for 48h; Inert atmosphere;	100%

: 1592-20-7
4-Vinylbenzyl chloride

: 127-09-3
sodium acetate

: 1592-12-7
4-acetoxymethylstyrene

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In tetrahydrofuran for 48h; Heating;	99%
In dimethyl sulfoxide at 50℃; for 47h;
In dimethyl sulfoxide at 45℃; for 24h; Inert atmosphere;

: 1592-20-7
4-Vinylbenzyl chloride

: 45817-37-6
4-vinylbenzyl iodide

Conditions

Conditions	Yield
With sodium iodide In acetone for 20h; Inert atmosphere; Reflux;	99%
With sodium iodide In acetonitrile for 12h; Inert atmosphere; Reflux;	92%
With sodium iodide In butanone at 20℃; for 8h;	91%

: 1592-20-7
4-Vinylbenzyl chloride

: 121-44-8
triethylamine

: 14350-43-7
triethyl-(4-vinylbenzyl)ammonium chloride

Conditions

Conditions	Yield
In methanol at 30℃;	99%
In acetonitrile at 40℃; for 93h;	94%
With 2,6-di-tert-butyl-4-methyl-phenol at 50℃; for 48h; Inert atmosphere;
In N,N-dimethyl-formamide at 60℃; for 24h; Autoclave;

: 4731-53-7
TOP

: 1592-20-7
4-Vinylbenzyl chloride

: trioctyl(4-vinylbenzyl)phosphonium chloride

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol In toluene at 20℃; for 48h; Inert atmosphere;	99%
With 2,6-di-tert-butyl-4-methyl-phenol In toluene at 20℃; for 48h; Inert atmosphere;

: 102-82-9
tributyl-amine

: 1592-20-7
4-Vinylbenzyl chloride

: tri-n-butyl-(4-vinylbenzyl)ammonium chloride

Conditions

Conditions	Yield
In acetonitrile at 40℃; for 68h;	99%
In dichloromethane at 20℃; for 48h;	85%
In acetonitrile at 50℃; for 48h;	82%
In acetonitrile at 40℃; for 24h; Inert atmosphere;	80%

: 1592-20-7
4-Vinylbenzyl chloride

: 98-59-9
p-toluenesulfonyl chloride

: C16H16Cl2O2S

Conditions

Conditions	Yield
With [Cu(2,9-bis(p-anisyl)-1,10-phenanthroline)Cl2] In acetonitrile at 25 - 30℃; for 24h; Reagent/catalyst; Inert atmosphere; Irradiation; regioselective reaction;	99%

: 1120-24-7
N,N-dimethyldecylamine

: 1592-20-7
4-Vinylbenzyl chloride

: decyldimethyl-(4-vinylbenzyl)ammonium chloride

Conditions

Conditions	Yield
In acetonitrile at 40℃; for 239h;	99%

: 1592-20-7
4-Vinylbenzyl chloride

: 1074-82-4
potassium phtalimide

: 63413-74-1
2-(4-ethenylbenzyl)-1H-isoindole-1,3(2H)-dione

Conditions

Conditions	Yield
In N,N-dimethyl-formamide	98%
In N,N-dimethyl-formamide at 110℃; for 5h;	88%
In N,N-dimethyl-formamide at 55℃; for 17h;	81%

: 292638-84-7
styrene

: 105-06-6
1,4-Divinylbenzene

: 1592-20-7
4-Vinylbenzyl chloride

polymer; Monomer(s): styrene; 4-chloromethylstyrene; 1,4-divinylbenzene: polymer; Monomer(s): styrene; 4-chloromethylstyrene; 1,4-divinylbenzene

Conditions

Conditions	Yield
With dibenzoyl peroxide at 80℃; for 24h;	98%

...Expand

: 1592-20-7
4-Vinylbenzyl chloride

: 1074-61-9
(4-vinyl-phenyl)-methanol

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide; water at 125℃; for 0.333333h;	98%
With cetyltrimethylammonim bromide; sodium hydroxide In water at 125℃; for 0.666667h;	95%
With tetrabutylammomium bromide; sodium hydroxide In water at 125℃; for 2h; Inert atmosphere;	57%

: 1592-20-7
4-Vinylbenzyl chloride

: 16635-23-7
phenyltriisopropoxytitanium(IV)

: 15866-31-6
phenyl(p-vinylphenyl)methane

Conditions

Conditions	Yield
With palladium diacetate; Tri(p-tolyl)phosphine In toluene at 25℃; for 2h; Inert atmosphere;	98%

: 1592-20-7
4-Vinylbenzyl chloride

: 132328-89-3
undecyl 4'-hydroxybiphenyl-4-carboxylate

: 1104078-17-2
undecyl 4'-(4-vinylbenzyloxy)biphenyl-4-carboxylate

Conditions

Conditions	Yield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 70℃; for 8h;	98%

: 1592-20-7
4-Vinylbenzyl chloride

: 60-24-2
2-hydroxyethanethiol

: 129509-07-5
2-(4-vinyl-benzylsulfanyl)-ethanol

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol; sodium hydroxide In tetrahydrofuran; water Reflux;	98%

: 288-32-4
1H-imidazole

: 1592-20-7
4-Vinylbenzyl chloride

: 78430-91-8
1-(4-vinylbenzyl)-1H-imidazole

Conditions

Conditions	Yield
Stage #1: 1H-imidazole With sodium hydroxide In tetrahydrofuran for 2h; Reflux; Stage #2: 4-Vinylbenzyl chloride In tetrahydrofuran at 20℃;	98%
With sodium hydrogencarbonate In water; acetone at 20 - 50℃; for 20h;	71%
With sodium hydrogencarbonate In acetonitrile at 50℃; for 20h;	71%

: 1592-20-7
4-Vinylbenzyl chloride

: 107-19-7
propargyl alcohol

: 132679-16-4
1-((prop-2-yn-1-yloxy)methyl)-4-vinylbenzene

Conditions

Conditions	Yield
Stage #1: propargyl alcohol With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.75h; Stage #2: 4-Vinylbenzyl chloride With tetra-(n-butyl)ammonium iodide for 12h; Reflux;	98%
Stage #1: propargyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Inert atmosphere; Stage #2: 4-Vinylbenzyl chloride In N,N-dimethyl-formamide at 0 - 20℃; for 3h; Inert atmosphere;	71%
Stage #1: propargyl alcohol With sodium hydride In tetrahydrofuran for 0.25h; Cooling with ice; Stage #2: 4-Vinylbenzyl chloride With tetrabutylammomium bromide In tetrahydrofuran at 20℃; for 5h;	59%

4-Vinylbenzyl chloride Chemical Properties

IUPAC Name: 1-(Chloromethyl)-4-ethenylbenzene
Synonyms of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): EINECS 216-471-2 ; 1-(Chloromethyl)-4-vinylbenzene
CAS NO: 1592-20-7
Molecular Formula: C₉H₉Cl
Molecular Weight: 152.6208
Molecular Structure:

ProductCategories: Intermediates of Dyes and Pigments
Index of Refraction: 1.57
Molar Refractivity: 46.94 cm³
Molar Volume: 143 cm³
Surface Tension: 34.7 dyne/cm
Density of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): 1.066 g/cm³
Flash Point: 90.4 °C
Enthalpy of Vaporization: 44.66 kJ/mol
Boiling Point: 228.9 °C at 760 mmHg
Vapour Pressure: 0.108 mmHg at 25°C

4-Vinylbenzyl chloride Safety Profile

Hazard Codes of Benzene,1-(chloromethyl)-4-ethenyl- (CAS NO.1592-20-7): Corrosive C
Risk Statements: 34-43-21/22
R34: Causes burns.
R43: May cause sensitization by skin contact.
R21/22: Harmful in contact with skin and if swallowed.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3265 8/PG 3
WGK Germany: 3
F: 8-19
HazardClass: 8
PackingGroup: III

Product Name

4-Vinylbenzyl chloride

Synthetic route

4-Vinylbenzyl chloride Chemical Properties

4-Vinylbenzyl chloride Safety Profile

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