Product Name

  • Name

    ARSENIC (III) BROMIDE

  • EINECS 232-057-4
  • CAS No. 7784-33-0
  • Article Data59
  • CAS DataBase
  • Density 3.54 g/cm3
  • Solubility decomposed in H2O, forming HBr, As2O3; miscible with ether, benzene [MER06]
  • Melting Point 31 °C
  • Formula AsBr3
  • Boiling Point 221 °C
  • Molecular Weight 314.634
  • Flash Point
  • Transport Information
  • Appearance
  • Safety Confirmed human carcinogen. A poison. See also ARSENIC COMPOUNDS and BROMIDES. When heated to decomposition it emits very toxic fumes of As and Br.
  • Risk Codes 50/53-45-34-23/25
  • Molecular Structure Molecular Structure of 7784-33-0 (ARSENIC (III) BROMIDE)
  • Hazard Symbols N-T,N,T
  • Synonyms Arsenicbromide (AsBr3) (6CI,8CI); Arsenic tribromide; Arsenous bromide; Tribromoarsine
  • PSA 0.00000
  • LogP 2.15600

Synthetic route

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

arsenic(III) trioxide

arsenic(III) trioxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
at 100℃; for 0.5h; Temperature;92%
In hydrogen bromide aq. HBr; As2O3 dissoln. with heating;
tributoxyarsane
3141-10-4

tributoxyarsane

boron tribromide
10294-33-4

boron tribromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) dropwise addn. of BBr3 with continuous stirring to tributyl arsenite at -5 to -7°C under dry Ar or N2, additional stirring (20 min), decanting the liquid phase; distg. the solid at reduced pressure in a CO2 stream; elem. anal.;68.9%
arsenic

arsenic

selenium oxibromide

selenium oxibromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In further solvent(s) byproducts: Se2Br2; from SeOBr2 and As;;
arsenic

arsenic

bromine
7726-95-6

bromine

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) from As and bromine vapor;;
In carbon disulfide from As and bromine dild. with CS2;;
In neat (no solvent) addition of small amounts of powdered As to Br2, until no more inflammation takes place;; distillation;;
bromine
7726-95-6

bromine

arsenic(III) trioxide

arsenic(III) trioxide

A

arsenic(V) oxide

arsenic(V) oxide

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: O2;
In neat (no solvent) byproducts: O2; room temperature;;
In neat (no solvent) byproducts: O2; room temperature;;
bromine
7726-95-6

bromine

arsenic(III) trioxide

arsenic(III) trioxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
With sulfur In neat (no solvent) byproducts: SO2;
With sulfur In neat (no solvent) byproducts: SO2; heating of a mixture of As, Br2 and S for 7 hours;; pptn.; melting and filtation through glass wool;;>99
With S In neat (no solvent) byproducts: SO2; heating of a mixture of As, Br2 and S for 7 hours;; pptn.; melting and filtation through glass wool;;>99
With sulfur In not given as in: G. Oddo and U.Giachery, Gazz. Chim. Ital., 1924, 53, 56;
arsenic trichloride
7784-34-1

arsenic trichloride

potassium bromide
7558-02-3

potassium bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
byproducts: KCl; heated for some hours at 200 °C in closed tube;
In neat (no solvent) heating, exclusion of H2O and O2;;
arsenic

arsenic

ethyl bromide
74-96-4

ethyl bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: C2H4;
arsenic

arsenic

disulphur dibromide
13172-31-1

disulphur dibromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In further solvent(s) byproducts: As sulfide; from S2Br2 and excess of As;;
In further solvent(s) byproducts: As sulfide; from S2Br2 and excess of As;;
In neat (no solvent) byproducts: arsenic sulfide; exothermic reaction;;
boron tribromide
10294-33-4

boron tribromide

arsenic trichloride
7784-34-1

arsenic trichloride

A

boron trichloride
10294-34-5

boron trichloride

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

BBr3*AsH3

BBr3*AsH3

A

arsenic

arsenic

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
With O2 In neat (no solvent) byproducts: B2O3, BO(OH), HBr; slow addn. of O2; cooling;;
BBr3*AsH3

BBr3*AsH3

arsenic trichloride
7784-34-1

arsenic trichloride

A

arsenic

arsenic

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: HCl, BCl3; also at -50°C;;
bromine
7726-95-6

bromine

arsenic trisulfide

arsenic trisulfide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given at ambient temp.;;
arsenic trisulfide

arsenic trisulfide

boron tribromide
10294-33-4

boron tribromide

A

diboron trisulfide

diboron trisulfide

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
heating several h at 120-140°C;A >99
B n/a
heating several h at 120-140°C;A >99
B n/a
selenyl bromide
7789-51-7

selenyl bromide

arsenic trisulfide

arsenic trisulfide

A

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

B

diselenium dibromide
1015938-55-2, 7789-52-8

diselenium dibromide

Conditions
ConditionsYield
In not given
In not given
arsenic (III) oxide

arsenic (III) oxide

bromine
7726-95-6

bromine

A

arsenic(V) oxide

arsenic(V) oxide

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: O2;
arsenic

arsenic

bromine
7726-95-6

bromine

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) passing very pure Br2 vapor over metallic As;; repeated distillation; removal of Br2 by distillation over Cu; very pure;;
In neat (no solvent) passing very pure Br2 vapor over metallic As;; repeated distillation; removal of Br2 by distillation over Cu; very pure;;
arsenic trichloride
7784-34-1

arsenic trichloride

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
With antimony bromide or titanium bromide In not given byproducts: SnCl4;
With antimony bromide or titanium bromide In not given byproducts: SnCl4;
phosphorus tribromide
7789-60-8

phosphorus tribromide

arsenic trichloride
7784-34-1

arsenic trichloride

A

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

B

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) mixing starting material;;
arsenic trichloride
7784-34-1

arsenic trichloride

stannic bromide
7789-67-5

stannic bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: SnCl4;
In not given byproducts: SnCl4;
carbon tetrabromide
558-13-4

carbon tetrabromide

arsenic trichloride
7784-34-1

arsenic trichloride

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) heating to 105 - 216°C for some weeks;;
{PCl4}(1+)*{PCl5Br}(1-)={PCl4}{PCl5Br}

{PCl4}(1+)*{PCl5Br}(1-)={PCl4}{PCl5Br}

arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

A

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6}
16919-35-0

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6}

B

arsenic trichloride
7784-34-1

arsenic trichloride

C

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent)
{PCl4}(1+)*{PCl5Br}(1-)={PCl4}{PCl5Br}

{PCl4}(1+)*{PCl5Br}(1-)={PCl4}{PCl5Br}

arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

phosphorus pentafluoride
7647-19-0, 874483-74-6

phosphorus pentafluoride

B

arsenic trichloride
7784-34-1

arsenic trichloride

C

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) vigorous reaction with excess AsF3;;
arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

phosphorus tribromide
7789-60-8

phosphorus tribromide

A

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

B

trifluorophosphane
7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent)
phenylarsinic acid
25400-22-0

phenylarsinic acid

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent)
In neat (no solvent)
hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

(4-aminophenyl)arsenous acid

(4-aminophenyl)arsenous acid

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent)
In neat (no solvent)
AsBr4(1+)*AlBr4(1-)={AsBr4}{AlBr4}
119484-32-1

AsBr4(1+)*AlBr4(1-)={AsBr4}{AlBr4}

A

bromine
7726-95-6

bromine

B

aluminium bromide
7727-15-3

aluminium bromide

C

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
equilibrium at room temp.;
AgAsS

AgAsS

bromine
7726-95-6

bromine

A

silver(I) bromide

silver(I) bromide

B

disulphur dibromide
13172-31-1

disulphur dibromide

C

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

{PBr4}(1+)*{PF6}(1-)={PBr4}{PF6}
12514-48-6

{PBr4}(1+)*{PF6}(1-)={PBr4}{PF6}

arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

phosphorus pentafluoride
7647-19-0, 874483-74-6

phosphorus pentafluoride

B

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In neat (no solvent) reaction at ambient temperature;;
Phosphorus - arsenic

Phosphorus - arsenic

bromine
7726-95-6

bromine

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

Conditions
ConditionsYield
In not given byproducts: PBr3;
In not given byproducts: PBr3;
4-methylpyridine-1-oxide
1003-67-4

4-methylpyridine-1-oxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

2 arsenic tribromide * 3 γ-picoline-N-oxide

2 arsenic tribromide * 3 γ-picoline-N-oxide

Conditions
ConditionsYield
In tetrachloromethane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;88%
In tetrachloromethane; hexane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;88%
In chloroform described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;88%
tetrahydrofuran
109-99-9

tetrahydrofuran

silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate
428441-32-1

silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

A

[((CF3)3CO)2Al(μ-F)(THF)]2
851428-34-7

[((CF3)3CO)2Al(μ-F)(THF)]2

B

AsBr2(1+)*Al(OC(CF3)3)4(1-)=AsBr2Al(OC(CF3)3)4
851428-58-5

AsBr2(1+)*Al(OC(CF3)3)4(1-)=AsBr2Al(OC(CF3)3)4

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: AgBr; (Ar); keeping a mixt. of silver salt and AsBr3 at room temp.; extn. with pentane, concn., evapn., dissolving in CH2Cl2/THF 3:1, storage at -30°C;A 88%
B 0%
arsenic(III) bromide
7784-33-0

arsenic(III) bromide

triethylamine hydrobromide
636-70-4

triethylamine hydrobromide

3(C2H5)3NH(1+)*{As3Br12}(3-)={(C2H5)3NH}3{As3Br12}

3(C2H5)3NH(1+)*{As3Br12}(3-)={(C2H5)3NH}3{As3Br12}

Conditions
ConditionsYield
In nitromethane cooling;86%
In nitromethane all manipulations under inert atmosphere; adding (Et3NH)Br to a soln. of AsBr3 (molar ratio), stirring (3 h, room temp.); filtering, crystn. (cooling to -20°C, 2 - 3 d); elem. anal.;
piperidine hydrobromide
14066-85-4

piperidine hydrobromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

(pipH)3(As2Br9)*(pipH)Br

(pipH)3(As2Br9)*(pipH)Br

Conditions
ConditionsYield
In acetonitrile (Ar); addn. of AsBr3 in absolute CH3CN to suspension of (pipH)Br in CH3CN; a stirred suspension was heated under reflux for 3 d; filtn. at room temp.; slowly cooling of the yellow soln. to -30°C; yielded crystals; elem. anal.;83%
arsenic(III) bromide
7784-33-0

arsenic(III) bromide

tetraphenylphosphonium bromide
2751-90-8

tetraphenylphosphonium bromide

(Ph4P)2(As2Br8)

(Ph4P)2(As2Br8)

Conditions
ConditionsYield
In acetonitrile (Ar); addn. of AsBr3 in absolute CH3CN to suspension of (Ph4P)2Br in CH3CN; stirred suspension is heated under reflux for 3 d; filtn. at room temp.; slow cooling of the yellow soln. to -30°C; elem. anal.;82%
3-picoline-N-oxide
1003-73-2

3-picoline-N-oxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

arsenic tribromide * β-picoline-N-oxide

arsenic tribromide * β-picoline-N-oxide

Conditions
ConditionsYield
In tetrachloromethane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;78%
In tetrachloromethane; hexane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;78%
In chloroform described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;78%
tetra-n-propylammonium bromide
1941-30-6

tetra-n-propylammonium bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

{(n-prop)4N}2(As2Br8)

{(n-prop)4N}2(As2Br8)

Conditions
ConditionsYield
In acetonitrile (Ar); addn. of AsBr3 in absolute CH3CN to suspension of ((n-prop)4N)Br in CH3CN; a stirred suspension was heated under reflux for 3 d; filtn. at room temp.; slowly cooling of the yellow soln. to -30°C; yielded crystals; elem. anal.;72%
arsenic(III) bromide
7784-33-0

arsenic(III) bromide

(tert-butylimino)(2,2,6,6-tetramethylpiperidino)borane
89201-97-8

(tert-butylimino)(2,2,6,6-tetramethylpiperidino)borane

tert-butyl-((bromo(2,2,6,6-tetramethylpiperidino)boryl)amino)arsenic dibromide
113748-60-0

tert-butyl-((bromo(2,2,6,6-tetramethylpiperidino)boryl)amino)arsenic dibromide

Conditions
ConditionsYield
In hexane oxygen and moisture exclusion, stirring (room temp., 2 h); solvent removal, recrystn. (hexane, -78°C); elem. anal.;71%
tetraethylammonium bromide
71-91-0

tetraethylammonium bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

(Et4N)3(As3Br12)

(Et4N)3(As3Br12)

Conditions
ConditionsYield
In acetonitrile (Ar); addn. of AsBr3 in absolute CH3CN to suspension of (Et4N)3Br in CH3CN; a stirred suspension was heated under reflux for 3 d; filtn. at room temp.; slowly cooling of the yellow soln. to -30°C; yielded crystals; elem. anal.;70%
2-methylpyridine N-oxide
931-19-1

2-methylpyridine N-oxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

arsenic tribromide * 2 α-picoline-N-oxide

arsenic tribromide * 2 α-picoline-N-oxide

Conditions
ConditionsYield
In tetrachloromethane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;68%
In tetrachloromethane; hexane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;68%
In chloroform described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;68%
bis(trifluoromethylseleno)mercury
870-61-1

bis(trifluoromethylseleno)mercury

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

tris(trifluoromethylseleno)arsine

tris(trifluoromethylseleno)arsine

Conditions
ConditionsYield
In carbon disulfide 0°C, 3 h;65.7%
arsenic pentafluoride
7784-36-3

arsenic pentafluoride

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

A

AsBr4(1+)*AsF6(1-)={AsBr4}{AsF6}
119484-31-0

AsBr4(1+)*AsF6(1-)={AsBr4}{AsF6}

B

arsenic(III) fluoride
7784-35-2

arsenic(III) fluoride

Conditions
ConditionsYield
With bromine Condensing of AsF5 onto Br2 and AsBr3 at -196°C, warming to -5°C until a clear soln. is formed (1 min), cooling (-196°C), repeating of process in excess of 10 times.; Evapn. of volatiles in vac (-5°C, 10 min).;A 60%
B n/a
2-methylpyridine N-oxide
931-19-1

2-methylpyridine N-oxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

arsenic tribromide * α-picoline-N-oxide

arsenic tribromide * α-picoline-N-oxide

Conditions
ConditionsYield
In tetrachloromethane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;60%
In tetrachloromethane; hexane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;60%
In chloroform described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;60%
silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate
428441-32-1

silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate

bromine
7726-95-6

bromine

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

AsBr4(1+)*Al(OC(CF3)3)4(1-)=AsBr4Al(OC(CF3)3)4
825633-59-8

AsBr4(1+)*Al(OC(CF3)3)4(1-)=AsBr4Al(OC(CF3)3)4

Conditions
ConditionsYield
In dichloromethane byproducts: AgBr; (N2 or Ar); addn. of AsBr3 and Br2 to silver salt, addn. of CH2Cl2 at -78°C, storage at -80°C for 3 d; filtration, concn., crystn. (CH2Cl2);54%
In dichloromethane-d2 byproducts: AgBr; (N2 or Ar); addn. of CD2Cl2 to silver salt and AsBr3 in NMR tube at -78°C, addn. of Br2, sealing, storage overnight at -78°C, warming to -20°C; detected by NMR;
pyridine N-oxide
694-59-7

pyridine N-oxide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

arsenic tribromide * 2 pyridine-N-oxide

arsenic tribromide * 2 pyridine-N-oxide

Conditions
ConditionsYield
In tetrachloromethane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;50%
In tetrachloromethane; hexane described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;50%
In chloroform described by Dunston, P. O. and Airoldi, C., J. Chem. Eng. Data, 33 (1983) 93 and Dunstan, P. O. and Santos, L. C. R. dos, Thermochim. Acta, 156 (1989) 163;; elem. anal.;;50%
(2,6-diisopropylphenylimino)(2,2,6,6-tetramethylpiperidino)borane
113748-54-2

(2,6-diisopropylphenylimino)(2,2,6,6-tetramethylpiperidino)borane

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)arsenic dibromide
113748-66-6

((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)arsenic dibromide

Conditions
ConditionsYield
In hexane oxygen and moisture exclusion, mixing of solns. (room temp.), stirring (12 h); conc. (pptn.), washing (hexane), drying (high vacuum); elem. anal.;41%
dipotassium sulfur diimide

dipotassium sulfur diimide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

As4S5N10*0.5CH2Cl2

As4S5N10*0.5CH2Cl2

Conditions
ConditionsYield
In diethyl ether; acetonitrile byproducts: KBr; addn. of AsBr3 in Et2O to suspn. of K2SN2 in MeCN (-40°C), warming to room temp., stirring (2 h); filtration (over Na2SO4), crystn. by concn. and cooling (-30°C),recrystn. (CH2Cl2 or ether/CH2Cl2 (5:1));40%
arsenic(III) bromide
7784-33-0

arsenic(III) bromide

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

μ-Bromoarsandiyl-bis(pentacarbonylchrom)

μ-Bromoarsandiyl-bis(pentacarbonylchrom)

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran Irradiation (UV/VIS); Cr-comlex irradiated in THF, AsBr3 was added, the soln. was stirred for10 h at 20°C under N2; evapd. in vac., dissolved in toluene, filtered (silicagel), crystd. from CH2Cl2; elem anal.;40%
gallium(III) trichloride

gallium(III) trichloride

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

2,4,6-tri-tert-butyl-1,3,5-triphosphinine
173166-52-4

2,4,6-tri-tert-butyl-1,3,5-triphosphinine

C15H27AsBr2P3(1+)*Cl4Ga(1-)

C15H27AsBr2P3(1+)*Cl4Ga(1-)

Conditions
ConditionsYield
In hexane; dichloromethane at 35℃; for 40h; Inert atmosphere; Schlenk technique; Glovebox;40%
tris(4-fluorophenyl)phosphine selenide
54300-47-9

tris(4-fluorophenyl)phosphine selenide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

C18H12F3PSe*AsBr3
1394247-61-0

C18H12F3PSe*AsBr3

Conditions
ConditionsYield
In diethyl ether at 20℃; for 48h; Inert atmosphere;39%
dipotassium tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diferrate

dipotassium tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diferrate

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

bis-(dibromoarsenido)tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diiron * THF

bis-(dibromoarsenido)tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diiron * THF

Conditions
ConditionsYield
In tetrahydrofuran under Ar: dropwise addn. of a soln. of AsBr3 in THF to a soln. of the diiron compound in THF at -40°C; stirring for 3 d at room temperature; distillation of the solvent in vac.;; dissolving of the residue in dichloromethane; filtration; reducing and covering with petroleum ether; cooling to -30°C; recrystallization in THF/petroleum ether; elem. anal.;;19%
[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]
317322-17-1

[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

A

HC[C(Me)N(2,6-iPr2-C6H3)]2(Br)GaSiBr3
879329-55-2

HC[C(Me)N(2,6-iPr2-C6H3)]2(Br)GaSiBr3

B

C58H82AsBrGa2N4

C58H82AsBrGa2N4

Conditions
ConditionsYield
Stage #1: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]; arsenic(III) bromide In toluene for 240h;
Stage #2: In hexane at 20℃; for 21h;
A n/a
B 10%
silver(I) bromide

silver(I) bromide

arsenic(III) bromide
7784-33-0

arsenic(III) bromide

AgAlBr4

AgAlBr4

Conditions
ConditionsYield
With aluminum tri-bromide

Arsenic(II) bromide Chemical Properties

Molecule structure of Arsenic(II) bromide (CAS NO.7784-33-0):

IUPAC Name: Tribromoarsane 
Molecular Weight: 314.6336 g/mol
Molecular Formula: AsBr3 
Density: 3.54 g/cm3
Melting Point: 31 °C
Boiling Point: 221 °C
Exact Mass: 313.674563
MonoIsotopic Mass: 311.676609 
Heavy Atom Count: 4
Complexity: 8
Canonical SMILES: [As](Br)(Br)Br
InChI: InChI=1S/AsBr3/c2-1(3)4
InChIKey: JMBNQWNFNACVCB-UHFFFAOYSA-N
EINECS: 232-057-4

Arsenic(II) bromide Consensus Reports

Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Right-To-Know List.

Arsenic(II) bromide Safety Profile

Hazard Codes: DangerousN, ToxicT
Risk Statements: 50/53-45-34-23/25 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R45:May cause cancer. 
R34:Causes burns. 
R23/25:Toxic by inhalation and if swallowed.
Safety Statements: 61-60-53-36/37/39-28A-20/21 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S60:This material and its container must be disposed of as hazardous waste. 
S53:Avoid exposure - obtain special instructions before use. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S20:When using, do not eat or drink. 
S21:When using do not smoke.
RIDADR: 1555
HazardClass: 6.1(a)
PackingGroup: II
Confirmed human carcinogen. A poison. See also ARSENIC COMPOUNDS and BROMIDES. When heated to decomposition it emits very toxic fumes of As and Br.

Arsenic(II) bromide Standards and Recommendations

OSHA PEL: TWA 0.01 mg(As)/m3; Cancer Hazard
ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 μ (As)/L inorganic arsenic and methylated metabolites in urine
NIOSH REL: (Arsenic, Inorganic) CL 2 µg(As)/m3/15 M
DOT Classification:  6.1; Label: Poison

Arsenic(II) bromide Specification

 Arsenic(II) bromide (CAS NO.7784-33-0) is also named as Arsenic bromide (AsBr3) ; Arsenic tribromide ; Arsenious bromide ; Arsenous bromide ; Arsenous tribromide ; HSDB 425 ; Tribromoarsine ; UNII-41CN475O7F . It is faintly yellow solid. Arsenic(II) bromide (CAS NO.7784-33-0) is toxic. It is not flammable. It can emit toxic gases such as hydrogen bromide when contact with water. It will produce toxic arsenic and bromide fumes by hest. So the storage environment should be ventilate, low-temperature and dry. Keep Arsenic(II) bromide (CAS NO.7784-33-0) separate from raw materials of food.

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