Benzeneselenenylchloride supplier

Name
PHENYLSELENENYL CHLORIDE
EINECS 227-196-2
CAS No. 5707-04-0
Article Data21
CAS DataBase
Density
Solubility
Melting Point 59-62 °C(lit.)
Formula C₆H₅ClSe
Boiling Point 236.6 °C at 760 mmHg
Molecular Weight 191.519
Flash Point 96.9 °C
Transport Information UN 2928
Appearance crystalline solid
Safety 20/21-28-45-60-61
Risk Codes 23/25-33-50/53
Molecular Structure
Hazard Symbols T； N
Synonyms Benzeneselenylchloride;Chlorophenylselenium;Phenylselenium chloride;Phenylseleniummonochloride;Phenylselenyl chloride;
PSA 0.00000
LogP 1.16990

Synthetic route

: 1666-13-3
diphenyl diselenide

: 42572-42-9
phenylselenium trichloride

: 5707-04-0
Phenylselenyl chloride

Conditions

Conditions	Yield
In tetrachloromethane at 20℃; for 2h;	100%

: 1666-13-3
diphenyl diselenide

: 5707-04-0
Phenylselenyl chloride

Conditions

Conditions	Yield
Stage #1: diphenyl diselenide With thionyl chloride In tetrachloromethane at 20℃; for 0.5h; Inert atmosphere; Stage #2: In tetrachloromethane at -20℃; for 2h; Inert atmosphere;	94%
With (Dichloroiodo)benzene In hexane at 20℃; for 0.333333h; Darkness;	82%
With (Dichloroiodo)benzene In hexane at 20℃; for 0.333333h;	82%

: 67-66-3
chloroform

: 1666-13-3
diphenyl diselenide

: 5707-04-0
Phenylselenyl chloride

: 42572-42-9
phenylselenium trichloride

: 5707-04-0
Phenylselenyl chloride

Conditions

Conditions	Yield
at 170℃; unter vermindertem Druck;

: ethyl-dichloro-phenyl-λ4-selane

A: 5707-04-0
Phenylselenyl chloride

B: 75-00-3
chloroethane

Conditions

Conditions	Yield
at 80℃;

: 78489-00-6
N-phenyldichloroselenobenzeneseleninimidoyl chloride

A: 5707-04-0
Phenylselenyl chloride

B: 42572-42-9
phenylselenium trichloride

Conditions

Conditions	Yield
at 20℃; for 24h; Product distribution;	A 75 % Turnov. B 70 % Turnov.

: 1352563-37-1
C12H10Cl2N2SSe2

: 5707-04-0
Phenylselenyl chloride

Conditions

Conditions	Yield
at 70℃;

: 645-96-5
Benzeneselenol

: 5707-04-0
Phenylselenyl chloride

Conditions

Conditions	Yield
With N-chloro-succinimide In nitromethane at 20℃; for 0.5h; Sealed tube;

: 67-56-1
methanol

: 5707-04-0
Phenylselenyl chloride

: 931-88-4, 931-87-3
(Z)-Cyclooctene

: 73090-30-9
trans-1-phenylseleno-2-methoxycyclooctane

Conditions

Conditions	Yield
at 25℃;	100%

...Expand

: 498-66-8
norborn-2-ene

: 5707-04-0
Phenylselenyl chloride

: 70303-01-4
endo-3-chloro-exo-2-phenylselenobicyclo<2.2.1>heptane

Conditions

Conditions	Yield
In dichloromethane	100%
In water; acetonitrile for 24h; Ambient temperature;	84%
In dichloromethane at 25℃;	100 % Spectr.

: 821-41-0
5-Hexen-1-ol

: 5707-04-0
Phenylselenyl chloride

: 75526-73-7
(2-(phenylselanylmethyl)oxane)

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With zinc(II) chloride In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	100%

: 5707-04-0
Phenylselenyl chloride

: 931-88-4, 931-87-3
(Z)-Cyclooctene

: (+/-)-rel-((1RS,2SR)-2-chlorocyclooctyl)phenylselenide

Conditions

Conditions	Yield
In dichloromethane at 25℃;	100%
In dichloromethane at 0 - 20℃; Inert atmosphere;

: 5707-04-0
Phenylselenyl chloride

: 821-09-0
n-Pent-4-enyl alcohol

: 65539-72-2
2-(phenylselanylmethyl)oxolane

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	99%
at 20℃; for 0.116667h; Ionic liquid;	95%

: 5707-04-0
Phenylselenyl chloride

: 1614-73-9
4-cycloheptene-1-carboxylic acid

(1α,4α,5α)-4-(phenylseleno)-6-oxabicyclo<3.2.2>nonan-7-one: 63048-50-0
(1α,4α,5α)-4-(phenylseleno)-6-oxabicyclo<3.2.2>nonan-7-one

Conditions

Conditions	Yield
With base In dichloromethane at -78 - 25℃; Product distribution; Mechanism; phenylselenolactonizations of unsaturated substrates (SN2 reactions);	100%
With base In dichloromethane at -78 - 25℃;	100%

: 5707-04-0
Phenylselenyl chloride

: 22508-64-1
4-methyl-4-penten-1-ol

: 114524-28-6
2-Methyl-2-phenylselanylmethyl-tetrahydro-furan

Conditions

Conditions	Yield
With silver(l) oxide In dichloromethane at 20℃;	100%
In dichloromethane at -78℃; for 2h;	93%

: 5707-04-0
Phenylselenyl chloride

: 32779-58-1
2,6-dimethyl-hept-6-en-2-ol

: 114524-35-5
2,6,6-trimethyl-2-(phenylselenomethyl)tetrahydropyran

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	96%
In dichloromethane at -78℃; for 2h;	73%

: 5707-04-0
Phenylselenyl chloride

: 17263-64-8
2-diazo-1-(4-methylphenyl)ethanone

: 75608-70-7
α-chloro-α-phenylselenomethyl p-tolyl ketone

Conditions

Conditions	Yield
In dichloromethane for 0.5h; Ambient temperature;	100%
In dichloromethane Ambient temperature; Yield given;

: 5707-04-0
Phenylselenyl chloride

: 4250-02-6
1-diazo-3-phenyl-2-propanone

: 75608-71-8
benzyl α-chloro-α-phenylselenomethyl ketone

Conditions

Conditions	Yield
In dichloromethane for 0.5h; Ambient temperature;	100%
In dichloromethane Ambient temperature;

: 5707-04-0
Phenylselenyl chloride

: 2627-86-3
(S)-1-phenyl-ethylamine

: 101685-17-0
N-<(S)-1-Phenylethyl>benzeneselenamide

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0℃; for 2h;	100%

: 5707-04-0
Phenylselenyl chloride

: 10420-89-0
(S)-1-(1-Naphthyl)ethylamine

: 101685-18-1
N-<(S)-1-(1-Naphthyl)-ethyl>benzeneselenamide

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0℃; for 2h;	100%

: 5707-04-0
Phenylselenyl chloride

: 24261-90-3
N,N,N'-tris(trimethylsilyl)benzamidine

A: 1666-13-3
diphenyl diselenide

B: 127666-88-0, 136276-66-9
C26H20N4Se2

Conditions

Conditions	Yield
In dichloromethane at 23℃; for 3h;	A 100% B 55%

...Expand

: 5707-04-0
Phenylselenyl chloride

: 14268-23-6
potassium trinitromethanide

: 78743-52-9
phenyl trinitromethyl selenide

Conditions

Conditions	Yield
In dichloromethane at 0℃; for 1.5h;	100%

: 5707-04-0
Phenylselenyl chloride

: 104515-33-5
2-(1,1-dimethylbut-3-enyl)oxazoline

: 107515-52-6
1-(2-Chloro-ethyl)-3,3-dimethyl-5-phenylselanylmethyl-pyrrolidin-2-one

Conditions

Conditions	Yield
In acetonitrile for 12h; Ambient temperature;	100%

: 5707-04-0
Phenylselenyl chloride

: 118989-21-2
2,3,6-trimethyl-7-octen-3-ol

: 118989-25-6
6-isopropyl-3,6-dimethyl-2-(phenylselenomethyl)tetrahydropyran

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	97%
In dichloromethane at -78℃; for 2h;	66%

: 5707-04-0
Phenylselenyl chloride

: (2aR,5aR,8aR,8bR)-3-(2-Hydroxy-ethoxy)-6,6,8b-trimethyl-2a,5,5a,6,7,8,8a,8b-octahydro-naphtho[1,8-bc]furan-2-one

: C22H28O4Se

Conditions

Conditions	Yield
With N,N-diethyl-N-isopropylamine In dichloromethane at 25℃; for 0.5h;	100%

: 5707-04-0
Phenylselenyl chloride

1-((1S,5S,10S,13R)-10,13-Dimethyl-17-octyl-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-1-yl)-2-methyl-isourea: 1-((1S,5S,10S,13R)-10,13-Dimethyl-17-octyl-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-1-yl)-2-methyl-isourea

: 1-((1R,2S,3S,5S,10S,13R)-3-Hydroxy-10,13-dimethyl-17-octyl-2-phenylselanyl-hexadecahydro-cyclopenta[a]phenanthren-1-yl)-2-methyl-isourea

Conditions

Conditions	Yield
With silica gel In chloroform at 25℃; for 16h;	100%

: 5707-04-0
Phenylselenyl chloride

: 821-10-3
1,4-Dichloro-2-butyne

: 85972-08-3
(E)-2-(Phenylseleno)-1,3,4-trichlorobut-2-ene

Conditions

Conditions	Yield
In acetonitrile at 25℃; for 20h;	100%

: 5707-04-0
Phenylselenyl chloride

: 5817-26-5
ethyl (2S)-pyrrolidine-2-carboxylate

: 101685-19-2
N-Benzeneselenenyl-(S)-proline ethyl ester

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0℃; for 2h;	100%

: 5707-04-0
Phenylselenyl chloride

: 10472-24-9
methyl 2-oxocyclopentane-1-carboxylate

: 105405-22-9
methyl 2-oxo-1-(phenylselanyl)cyclopentane-1-carboxylate

Conditions

Conditions	Yield
With pyridine In dichloromethane 1.) 0 deg C, 90 min, 2.) up to RT;	100%
With pyridine In dichloromethane	10.1 g
With pyridine In dichloromethane at 0℃;

: 5707-04-0
Phenylselenyl chloride

: 556-82-1
3-methyl-2-buten-1-ol

: 99018-46-9
3-methyl-2-(phenylselenyl)-1,3-butanediol

Conditions

Conditions	Yield
With water In acetonitrile at 20℃; for 24h;	100%
In water; acetonitrile for 2h; Ambient temperature;	86%

: 5707-04-0
Phenylselenyl chloride

: 115-18-4
2-methyl-3-buten-2-ol

: 99018-46-9
3-methyl-2-(phenylselenyl)-1,3-butanediol

Conditions

Conditions	Yield
In water; acetonitrile for 2h; Ambient temperature;	100%
With water In acetonitrile at 20℃; for 24h;	86%

: 5707-04-0
Phenylselenyl chloride

: 72017-00-6
Thallous Phenyl Selenide

A: 1666-13-3
diphenyl diselenide

B thallous chloride: thallous chloride

Conditions

Conditions	Yield
In diethyl ether for 0.00833333h; Ambient temperature;	A 100% B n/a

...Expand

: 5707-04-0
Phenylselenyl chloride

: 129056-32-2
(5R)-1-Benzoyl-5-benzyl-3-[(4E,6S,8E,10E,12E)-4,6,12-trimethyl-1-oxotetradecatetra-4,8,10,12-enyl]pyrrolidin-2-one

: 259136-36-2
(5R)-1-Benzoyl-5-benzyl-3-phenylseleno-3-[(4E,6S,8E,10E,12E)-4,6,12-trimethyl-1-oxotetradecatetra-4,8,10,12-enyl]pyrrolidin-2-one

Conditions

Conditions	Yield
Stage #1: (5R)-1-Benzoyl-5-benzyl-3-[(4E,6S,8E,10E,12E)-4,6,12-trimethyl-1-oxotetradecatetra-4,8,10,12-enyl]pyrrolidin-2-one With lithium hexamethyldisilazane In tetrahydrofuran; hexane at -70℃; for 1h; Metallation; Stage #2: Phenylselenyl chloride In tetrahydrofuran; hexane at -70℃; for 2h; Phenylselenenylation;	100%

: 5707-04-0
Phenylselenyl chloride

: 312612-67-2
1-(2-(methylthio)phenyl)-2-phenylacetylene

: 2-phenyl-3-(phenylselanyl)benzo[b]thiophene

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 0.166667h;	100%
In dichloromethane at 25℃; for 0.166667h;	100%

: 5707-04-0
Phenylselenyl chloride

: 415680-02-3
trimethyl{[2-(methylsulfanyl)phenyl]ethynyl}silane

: 3-(phenylselenenyl)-2-trimethylsilylbenzo[b]thiophene

Conditions

Conditions	Yield
In dichloromethane at 25℃; for 0.166667h;	100%
In dichloromethane at 20℃; Inert atmosphere;	100%
In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;	100%

: 5707-04-0
Phenylselenyl chloride

: 32779-60-5
6-methylhept-6-en-2-ol

: 114524-34-4
2,6-Dimethyl-2-phenylselanylmethyl-tetrahydro-pyran

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	100%

: 5707-04-0
Phenylselenyl chloride

: 98-55-5
terpineol

: 92691-96-8
1,3,3-trimethyl-6-(phenylseleno)-2-oxabicyclo[2.2.2]octane

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With triethylamine In dichloromethane Reagent/catalyst;	100%
With pyridine at 20℃; for 2h; Ionic liquid;	71%

Benzeneselenenylchloride Specification

The Benzeneselenenylchloride, with CAS registry number 5707-04-0, belongs to the following product categories: (1)Classes of Metal Compounds; (2)Se (Selenium) Compounds; (3)Semimetal Compounds. It has the systematic name of benzeneselenenyl chloride. This chemical is a kind of crystalline solid. And the chemical formula of this chemical is C₆H₅ClSe. What's more, its EINECS is 227-196-2.

Physical properties of Benzeneselenenylchloride: (1)ACD/LogP: 3.88; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.88; (4)ACD/LogD (pH 7.4): 3.88; (5)ACD/BCF (pH 5.5): 521.37; (6)ACD/BCF (pH 7.4): 521.37; (7)ACD/KOC (pH 5.5): 3065.73; (8)ACD/KOC (pH 7.4): 3065.73; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 0 Å²; (13)Flash Point: 96.9 °C; (14)Enthalpy of Vaporization: 45.42 kJ/mol; (15)Boiling Point: 236.6 °C at 760 mmHg; (16)Vapour Pressure: 0.0722 mmHg at 25°C.

Uses of Benzeneselenenylchloride: it can be used to produce N-(phenyldichloroseleno)morpholine. This reaction will need reagent solvent CCl₄. The reaction temperature is 20 ℃. The yield is about 89%.

When you are using this chemical, please be cautious about it as the following:
The Benzeneselenenylchloride is toxic by inhalation and if swallowed. It has danger of cumulative effects. And it is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so avoid release it to the environment. Refer to special instructions / safety data sheets. This material and its container must be disposed of as hazardous waste. When using, do not eat or drink and do not smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Se]c1ccccc1
(2)InChI: InChI=1/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
(3)InChIKey: WJCXADMLESSGRI-UHFFFAOYAE
(4)Std. InChI: InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
(5)Std. InChIKey: WJCXADMLESSGRI-UHFFFAOYSA-N

Product Name

PHENYLSELENENYL CHLORIDE

Synthetic route

Benzeneselenenylchloride Specification

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