Bis(acetylacetonato)cobalt supplier

Name
Bis(acetylacetonato)cobalt
EINECS 237-855-6
CAS No. 14024-48-7
Article Data1
CAS DataBase
Density 0.83 g/cm3 (20℃)
Solubility 5 g/L (20 °C) in water
Melting Point 165-170 °C
Formula C₁₀H₁₄CoO₄
Boiling Point 138.4ºC at 760mmHg
Molecular Weight 257.212
Flash Point 43.1ºC
Transport Information
Appearance Purple fine crystalline powder
Safety 22-36/37-45-24-37/39-26-7
Risk Codes 42/43-40-22-41-20/21/22
Molecular Structure
Hazard Symbols Xn
Synonyms Cobalt,bis(2,4-pentanedionato)- (6CI,8CI);Cobalt, bis(2,4-pentanedionato-O,O')-,(SP-4-1)-;Cobalt, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- (9CI);Bis(2,4-pentanedionato)cobalt;Bis(2,4-pentanedionato)cobalt(II);Bis(acetylacetonate)cobalt;Bis(acetylacetonato)cobalt;Bis(acetylacetonato)cobalt(II);Cobaltbis(acetylacetonate);Cobalt diacetylacetonate;Cobalt(2+) acetylacetonate;Cobalt(2+) bis(acetylacetonate);Cobalt(II) acetylacetonate;Cobalt(II)bis(acetylacetonate);Cobaltous acetylacetonate;NSC 4652;NSC 52329;NacemCobalt;
PSA 68.28000
LogP 1.10900

Synthetic route

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 776-74-9
Bromodiphenylmethane

: 19672-37-8
3-benzhydryl-pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform for 17h; Heating;	97%

: 872290-35-2
3-bromo-5-methylcyclohex-1-ene

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 3-(5-methyl-2-cyclohexenyl)pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 85℃; for 2h;	95%

: 2746-25-0
p-Methoxybenzyl bromide

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 30881-24-4
3<(p-methoxyphenyl)methyl>-2,4-pentanedione

Conditions

Conditions	Yield
In chloroform for 17h; Heating;	88%

: 768-90-1
1-Adamantyl bromide

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 102402-84-6
3-(adamantan-1-yl)pentane-2,4-dione

Conditions

Conditions	Yield
In chlorobenzene for 24h; Heating;	81%
In chloroform at 80℃; for 17h;	76%

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 585-71-7, 38661-81-3
(1-bromoethyl)benzne

: 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform for 17h; Heating;	75%

: 7318-66-3
5-methylcyclohex-2-enyl chloride

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 3-(5-methyl-2-cyclohexenyl)pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 120℃; for 2h;	71%

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 585-71-7, 38661-81-3
(1-bromoethyl)benzne

A: 1857-74-5, 2726-21-8, 4539-34-8, 4613-11-0, 71606-46-7, 5789-35-5
2,3-diphenylbutane

B: 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 80℃; for 1h;	A 21% B 54%

...Expand

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 585-71-7, 38661-81-3
(1-bromoethyl)benzne

A: 1857-74-5, 2726-21-8, 4539-34-8, 4613-11-0, 71606-46-7, 5789-35-5
2,3-diphenylbutane

B: 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione

C CoBr2: CoBr2

Conditions

Conditions	Yield
In chloroform at 80℃; for 1h; Product distribution; Mechanism; other halogenides;	A 21% B 54% C n/a

...Expand

: 100-39-0
benzyl bromide

: 14024-48-7
bis(acetylacetonato)cobalt(II)

A: 1134-87-8
3-benzyl-pentane-2,4-dione

B: 53316-00-0
3,3-dibenzyl-pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 120℃; for 1h;	A 51% B 15%

...Expand

: 61608-88-6
(1-chlorohex-5-en-1-yl)benzene

: 14024-48-7
bis(acetylacetonato)cobalt(II)

A: 56644-04-3
(E)-1-phenyl-1,5-hexadiene

B: 3-(1-phenyl-5-hexen-1-yl)pentane-2,4-dione

C: 1-chloro-3-phenylcyclohexane

Conditions

Conditions	Yield
In chloroform at 100℃; for 17h;	A 46% B 10% C 42%

...Expand

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 100-11-8
1-bromomethyl-4-nitro-benzene

: 56699-21-9
3-(4-nitrobenzyl)-2,4-pentanedione

Conditions

Conditions	Yield
In chloroform for 17h; Heating;	6%

: 4870-21-7
N-m-Tolyl-aminophthalimid

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 120722-86-3
C12H14NO3

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 107940-72-7
2-<(4-Methoxyphenyl)amino>-1H-isoindol-1,3-(2H)-dion

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 120722-88-5
C12H14NO4

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 4870-16-0
N-anilinophthalimide

: 14024-48-7
bis(acetylacetonato)cobalt(II)

A: 15181-39-2, 67556-21-2, 67556-22-3
3-ethylidene-pentane-2,4-dione

B: 120722-83-0
C11H12NO3

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Yield given. Multistep reaction;
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction. Title compound not separated from byproducts;

...Expand

: 4870-23-9
2-p-toluidino-isoindoline-1,3-dione

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 120722-84-1
C12H14NO3

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 7318-66-3
5-methylcyclohex-2-enyl chloride

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: trans-3-(5-methyl-2-cyclohexenyl)pentane-2,4-dione

: cis-3-(5-methyl-2-cyclohexenyl)pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 120℃; for 2h; Product distribution; Mechanism; other halogenides, regioselectivity, stereoselectivity;

...Expand

: 107940-74-9
N-(N-4-chlorophenylamino)phthalimide

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 120722-87-4
C11H11ClNO3

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 39212-17-4
1-(4-chlorophenyl)-3-(4-nitrophenyl)-2-propen-1-ol

: 14024-48-7
bis(acetylacetonato)cobalt(II)

A: 3-(3-(4-chlorophenyl)-1-(4-nitrophenyl)-2-propenyl)pentane-2,4-dione

B: 3-(1-(4-chlorophenyl)-3-(4-nitrophenyl)-2-propenyl)pentane-2,4-dione

Conditions

Conditions	Yield
With thionyl chloride 1) room temperature, 6 h, 2) CHCl3, 100 deg C, 24 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 100873-75-4
2-<(4-Nitrophenyl)amino>-1H-isoindol-1,3(2H)-dion

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 120722-89-6
C11H11N2O5

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 117359-11-2
2-<(2-Methoxyphenyl)amino>-1H-isoindol-1,3-(2H)-dion

: 120722-90-9
C12H14NO4

Conditions

Conditions	Yield
With methanol; tert.-butylhydroperoxide benzene; Multistep reaction;

: 14024-48-7
bis(acetylacetonato)cobalt(II)

: 672-65-1
(1-chloroethyl)benzene

A: 1857-74-5, 2726-21-8, 4539-34-8, 4613-11-0, 71606-46-7, 5789-35-5
2,3-diphenylbutane

B: 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione

Conditions

Conditions	Yield
In chloroform at 80℃; for 6.25h; Yield given. Yields of byproduct given;

...Expand

Bis(acetylacetonato)cobalt Chemical Properties

IUPAC: cobalt(2+); (Z)-4-oxopent-2-en-2-olate
CAS:14024-48-7
The Molecular formula of COBALT(III) ACETYLACETONATE (14024-48-7):C₁₅H₂₁CoO₆
The Molecular Weight of COBALT(III) ACETYLACETONATE (14024-48-7):356.26
EINECS:244-527-6
Synonyms: TRIS(ACETYLACETONATO)COBALT(III) ; TRIS(2,4-PENTANEDIONATO)COBALT ; TRIS(2,4-PENTANEDIONATO)COBALT(III) ; TRIS(2,4-PENTANEDIONATO)COBALT(3) ; 4-pentanedionato-o,o’)-bis((beta-4)-cobal ; Acetylacetone cobalt(II) ; Bis(2,4-pentanedionato)cobalt ; bis(2,4-pentanedionato-O,O’)-,(T-4)-Cobalt
Melting Point:165-170^oC
Boiling Point:138.4^oC at 760mmHg
Flash Point:43.1^oC
Vapour Pressure:0.174 mmHg at 25^oC
Water Solubility:5 g/L (20^oC)
Appearance:Purple solid.
Product Categories:Pharmaceutical Intermediates;Classes of Metal Compounds;Co (Cobalt) Compounds;Transition Metal Compounds
Mol File:14024-48-7.mol

Bis(acetylacetonato)cobalt Uses

COBALT(III) ACETYLACETONATE (14024-48-7) is an important catalyst for organic reactions. It is also used as a paint drier.

Bis(acetylacetonato)cobalt Safety Profile

Safty informations about COBALT(III) ACETYLACETONATE (14024-48-7):
Hazard Codes:Xn
Risk Statements:42/43-40-22-41-20/21/22
42/43(May cause sensitization by inhalation and skin contact)
40(Limited evidence of a carcinogenic effect)
22(Harmful if swallowed)
41(Risk of serious damage to eyes)
20/21/22(Harmful by inhalation, in contact with skin and if swallowed)
Safety Statements:22-36/37-45-24-37/39-26-7
22(Do not breathe dust)
36/37(Wear suitable protective clothing and gloves)
45(In case of accident or if you feel unwell, seek medical advice immediately (show label where possible))
24(Avoid contact with skin)
37/39(Wear suitable gloves and eye/face protection)
26(In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
7(Keep container tightly closed)
WGK Germany:3
F:21
TSCA:Yes
HS Code:29420000

Bis(acetylacetonato)cobalt Specification

Handling and Storage:
Storage:Store in a cool, dry place. Store in a tightly closed container.
Handling:Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
First Aid Measures:
Ingestion:Get medical aid. Wash mouth out with water.
Inhalation:Remove from exposure to fresh air immediately. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Product Name

Bis(acetylacetonato)cobalt

Synthetic route

Bis(acetylacetonato)cobalt Chemical Properties

Bis(acetylacetonato)cobalt Uses

Bis(acetylacetonato)cobalt Safety Profile

Bis(acetylacetonato)cobalt Specification

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