Butylmagnesium chloride supplier

Name
Butylmagnesium chloride
EINECS 211-739-5
CAS No. 693-04-9
Article Data21
CAS DataBase
Density 0.962 g/mL at 25 °C
Solubility reacts with water
Melting Point -17°C
Formula C₄H₉ClMg
Boiling Point 66 °C
Molecular Weight 116.873
Flash Point 115 °F
Transport Information UN 3399 4.3/PG 2
Appearance green-brown to brown solution
Safety 16-26-29-36/37/39-45-46-62
Risk Codes 11-14/15-19-34-48/20-63-65-67
Molecular Structure
Hazard Symbols F,C
Synonyms Butylmagnesiumchloride (6CI);Butylchloromagnesium;Butylmagnesiumm chloride;n-Butylmagnesium chloride;
PSA 0.00000
LogP 2.44360

Synthetic route

: 109-69-3
n-Butyl chloride

: 693-04-9
butyl magnesium bromide

Conditions

Conditions	Yield
With magnesium In tetrahydrofuran-d8 at 80℃; under 5171.62 Torr; Inert atmosphere; Flow reactor;	95%
With magnesium anthracene * 3 THF 1.) toluene, 90 deg C, 2.) r.t., 12 h; Yield given. Multistep reaction;
With magnesium In tetrahydrofuran at 23℃; Kinetics;

: 109-69-3
n-Butyl chloride

: 86901-19-1
9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

A: 47205-57-2
9,10-dibutyl-9,10-dihydro-anthracene

B: 10394-60-2
9-butyl-9,10-dihydro-anthracene

C: 693-04-9
butyl magnesium bromide

D: 126694-91-5
2-butyl-1,2-dihydroanthracene

Conditions

Conditions	Yield
In toluene for 24h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 109-69-3
n-Butyl chloride

A: 47205-57-2
9,10-dibutyl-9,10-dihydro-anthracene

B: 10394-60-2
9-butyl-9,10-dihydro-anthracene

C: 693-04-9
butyl magnesium bromide

D: 126694-91-5
2-butyl-1,2-dihydroanthracene

Conditions

Conditions	Yield
With magnesium anthracene * 3 THF In toluene at 50 - 80℃; for 2h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 60-29-7
diethyl ether

: 109-69-3
n-Butyl chloride

magnesium: magnesium

: 693-04-9
butyl magnesium bromide

Conditions

Conditions	Yield
Einfluss verschiedener Aktivatoren;

...Expand

: 97-93-8
triethylaluminum

: 62202-86-2
n-butyl-ethylmagnesium

A: 14989-29-8
hydridomagnesium chloride

B: (AlEt3)2*MgEt2

C: 693-04-9
butyl magnesium bromide

D: 2386-64-3
ethylmagnesium chloride

E: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In 2-Methylpentane for 4383h; Reactivity;

...Expand

: 109-69-3
n-Butyl chloride

: 7439-95-4
magnesium

: 693-04-9
butyl magnesium bromide

Conditions

Conditions	Yield
In tetrahydrofuran
With iodine In tetrahydrofuran for 0.5h; Heating / reflux;
With dibutyl ether at 50 - 60℃; for 5h;

: 4781-99-1
butyltriethoxy silane

: EtOMgCl

A: 78-10-4
tetraethoxy orthosilicate

B: 693-04-9
butyl magnesium bromide

Conditions

Conditions	Yield
In tert-butyl methyl ether; toluene at 20℃; Equilibrium constant; Solvent; Inert atmosphere;

...Expand

: 109-69-3
n-Butyl chloride

magnesium: magnesium

: 693-04-9
butyl magnesium bromide

Conditions

Conditions	Yield
With diethyl ether

: 693-58-3
1-Bromononane

: 693-04-9
butyl magnesium bromide

: 629-50-5
Tridecane

Conditions

Conditions	Yield
With buta-1,3-diene; nickel dibromide In tetrahydrofuran at 0℃; for 0.25h; Kinetics; Reagent/catalyst; Temperature; Concentration;	100%
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran at 25℃; for 0.25h;	99 % Chromat.
With LaFe0.80Ni0.20O3; buta-1,3-diene at 20℃; for 5h;	91 %Chromat.
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran at 40℃; for 48h; Catalytic behavior; Temperature;	40 %Chromat.
With dicarbonyl(cyclopentadienyl)iron(II) chloride; buta-1,3-diene In tetrahydrofuran at 0 - 20℃; for 24h; Grignard Reaction; Inert atmosphere; Schlenk technique;	54 %Chromat.

: 1071227-13-8
[3S,5S,7aR]-5-isopropyl-3-phenyl-hexahydropyrrolo[2,1-b]oxazole

: 693-04-9
butyl magnesium bromide

: 1071226-98-6
(2S)-2-((2R,5S)-2-butyl-5-isopropylpyrrolidin-1-yl)-2-phenylethanol

Conditions

Conditions	Yield
Stage #1: [3S,5S,7aR]-5-isopropyl-3-phenyl-hexahydropyrrolo[2,1-b]oxazole; butyl magnesium bromide In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Stage #2: With ammonium chloride In tetrahydrofuran optical yield given as %de;	100%

: 620-02-0
5-Methylfurfural

: 693-04-9
butyl magnesium bromide

: 70396-63-3, 14313-18-9
1-(5-methylfuran-2-yl)pentan-1-ol

Conditions

Conditions	Yield
In diethyl ether at -10 - 10℃; Grignard reaction; Inert atmosphere;	100%

: 1056176-21-6
1-(tert-butyldiphenylsilyloxy)-5-(methoxymethoxy)-3-pentanone

: 693-04-9
butyl magnesium bromide

: 1056176-26-1
1-(tert-butyldiphenylsilyloxy)-3-(2-(methoxymethyl)oxyethyl)heptan-3-ol

Conditions

Conditions	Yield
Stage #1: 1-(tert-butyldiphenylsilyloxy)-5-(methoxymethoxy)-3-pentanone; butyl magnesium bromide With cerium(III) chloride In tetrahydrofuran at -78℃; Grignard reaction; Stage #2: With water; ammonium chloride In tetrahydrofuran at -78 - 20℃;	100%
With cerium(III) chloride In tetrahydrofuran at -78℃;	100%

: 693-04-9
butyl magnesium bromide

: 111757-80-3
(-)-(2S)-trifluoromethanesulfonyloxy-propionic acid tert-butyl ester

: 1059043-96-7
(+)-(2S)-methyl-hexanoic acid tert-butyl ester

Conditions

Conditions	Yield
With zinc(II) chloride In tetrahydrofuran at 0℃; for 3h; Product distribution / selectivity; Inert atmosphere;	100%

: C23H36ClNNiP2

: 693-04-9
butyl magnesium bromide

: C23H37NNiP2

Conditions

Conditions	Yield
In tetrahydrofuran at -35 - 20℃; Inert atmosphere;	100%

: 693-04-9
butyl magnesium bromide

: 118623-64-6
(R)-(+)-2,3-epoxypropanoic acid benzyl ester

: 917613-27-5
(R)-2-hydroxyheptanoic acid benzyl ester

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide With copper(I) bromide dimethylsulfide complex In tetrahydrofuran; diethyl ether at -78℃; for 0.5h; Stage #2: (R)-(+)-2,3-epoxypropanoic acid benzyl ester In tetrahydrofuran; diethyl ether at -78 - -5℃; for 1.5h;	100%
Stage #1: butyl magnesium bromide With copper(I) bromide dimethylsulfide complex In tetrahydrofuran; diethyl ether at -78℃; for 0.5h; Inert atmosphere; Stage #2: (R)-(+)-2,3-epoxypropanoic acid benzyl ester In tetrahydrofuran; diethyl ether at -78 - -5℃; for 1.5h; Inert atmosphere;	100%
Stage #1: butyl magnesium bromide With copper(I) bromide dimethylsulfide complex In tetrahydrofuran; diethyl ether at -78℃; for 0.5h; Inert atmosphere; Stage #2: (R)-(+)-2,3-epoxypropanoic acid benzyl ester In tetrahydrofuran; diethyl ether at -78 - -5℃; for 1.5h; Inert atmosphere;	100%
Stage #1: butyl magnesium bromide With copper(I) bromide dimethylsulfide complex In tetrahydrofuran; diethyl ether at -78℃; for 0.5h; Inert atmosphere; Stage #2: (R)-(+)-2,3-epoxypropanoic acid benzyl ester In tetrahydrofuran; diethyl ether at -78 - -5℃; for 1.5h; Inert atmosphere;	11.1 g

: 693-04-9
butyl magnesium bromide

: 98-88-4
benzoyl chloride

: 2782-40-3
N-butylbenzamide

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(I) cyanide*lithium chloride; 4,4'-bis(4-trifluoromethyl)benzophenone O-methylsulfonyloxime In tetrahydrofuran at 0℃; for 1h; Substitution; Stage #2: With hydrogenchloride In water; acetone at 25℃; for 0.5h; Hydrolysis; Stage #3: benzoyl chloride With triethylamine In water; acetone at 25℃; for 0.5h; Acylation;	99%

Yield

Stage #1: butyl magnesium bromide With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(I) cyanide*lithium chloride; 4,4'-bis(4-trifluoromethyl)benzophenone O-methylsulfonyloxime In tetrahydrofuran at 0℃; for 1h; Substitution;
Stage #2: With hydrogenchloride In water; acetone at 25℃; for 0.5h; Hydrolysis;
Stage #3: benzoyl chloride With triethylamine In water; acetone at 25℃; for 0.5h; Acylation;

99%

: 4011-20-5
(2Z,4Z,6Z)-9-Oxa-bicyclo[6.1.0]nona-2,4,6-triene

: 693-04-9
butyl magnesium bromide

: (2Z,4Z,7Z)-(1R,6R)-6-Butyl-cycloocta-2,4,7-trienol

Conditions

Conditions	Yield
With CuCN In tetrahydrofuran at -18 - 0℃;	99%

: 693-04-9
butyl magnesium bromide

: 609-65-4
o-chlorobenzoyl chloride

: 103562-92-1
1-(2-butyl-phenyl)-pentan-1-one

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide With lithium chloride; manganese(ll) chloride In tetrahydrofuran at -30℃; Stage #2: o-chlorobenzoyl chloride In tetrahydrofuran at -30℃; for 0.333333h;	99%

: 89-95-2
2-methyl-benzyl alcohol

: 693-04-9
butyl magnesium bromide

: 110349-82-1
2-(1-hydroxypentyl)phenol

Conditions

Conditions	Yield
With ammonium chloride In tetrahydrofuran; diethyl ether	99%

: 579490-55-4
chloro[bis(2-diphenylphosphinophenyl)amide]nickel(II)

: 693-04-9
butyl magnesium bromide

: 579490-65-6
n-butyl[bis(2-diphenylphosphinophenyl)amide]nickel(II)

Conditions

Conditions	Yield
In tetrahydrofuran n-BuMgCl (1 equiv.) added to Ni complex in THF at -35°C;	99%

: 172823-06-2
(Sp)-O-(+)-menthyl-H-phosphinate

: 693-04-9
butyl magnesium bromide

: (-)-n-butyl(phenyl)phosphine oxide

Conditions

Conditions	Yield
In tetrahydrofuran at -80℃; for 11h; Inert atmosphere; optical yield given as %ee;	99%

: 112043-57-9
2-(3-iodopropyl)furan

: 693-04-9
butyl magnesium bromide

: 3777-71-7
2-heptylfuran

Conditions

Conditions	Yield
With [((Me)NN2)NiCl] In tetrahydrofuran; ISOPROPYLAMIDE at -35 - 20℃; Inert atmosphere;	99%

: 33884-43-4
2-(2-Bromoethyl)-1,3-dioxane

: 693-04-9
butyl magnesium bromide

: 6290-20-6
2-hexyl-1,3-dioxolane

Conditions

Conditions	Yield
With [((Me)NN2)NiCl] In tetrahydrofuran; ISOPROPYLAMIDE at -35 - 20℃; Inert atmosphere;	99%
With buta-1,3-diene; nickel dichloride In tetrahydrofuran at -78 - 0℃; for 1h; Inert atmosphere;	86%
With 1-Phenylprop-1-yne; copper In tetrahydrofuran at 25℃; for 3h; Schlenk technique; Glovebox;	74%
With buta-1,3-diene; copper dichloride In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;	73 %Chromat.

: 39186-58-8
4-bromo-2,2-diphenylbutyronitrile

: 693-04-9
butyl magnesium bromide

: 5558-70-3
2,2-diphenyloctanenitrile

Conditions

Conditions	Yield
With [((Me)NN2)NiCl] In tetrahydrofuran; ISOPROPYLAMIDE at -35 - 20℃; Inert atmosphere;	99%

: 7335-27-5
ethyl 4-chlorobenzoate

: 693-04-9
butyl magnesium bromide

: 85100-62-5
4-n-butylbenzoic acid ethyl ester

Conditions

Conditions	Yield
With Fe(S-2-naphthyl)2 In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;	99%
With iron(III) chloride; ethanol; isopropylmagnesium chloride In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere; Green chemistry;	99%

: 4224-70-8
6-bromohexanoic acid

: 693-04-9
butyl magnesium bromide

: 334-48-5
1-decanoic acid

Conditions

Conditions	Yield
With 1-methyl-pyrrolidin-2-one; buta-1,3-diene; nickel dichloride In tetrahydrofuran at -78 - 0℃; for 1h; Inert atmosphere;	99%

: 1448529-14-3
C14H25BrO2

: 693-04-9
butyl magnesium bromide

: 693-72-1
trans-Vaccenic acid

Conditions

Conditions	Yield
Stage #1: C14H25BrO2 With tert-butylmagnesium chloride In tetrahydrofuran at -78℃; for 0.166667h; Inert atmosphere; Stage #2: butyl magnesium bromide With 1-methyl-pyrrolidin-2-one; buta-1,3-diene; nickel dichloride In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;	99%

: (E)-(1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl 4-(tert-butyldimethylsilyl)-2-((4-methoxyphenyl)imino)but-3-ynoate

: 693-04-9
butyl magnesium bromide

: C37H55NO3Si

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide With trimethylsilylmethyllithium; zinc(II) chloride In tetrahydrofuran at 20℃; for 1h; Schlenk technique; Stage #2: (E)-(1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl 4-(tert-butyldimethylsilyl)-2-((4-methoxyphenyl)imino)but-3-ynoate In tetrahydrofuran at -78℃; for 0.0833333h; Schlenk technique; diastereoselective reaction;	99%

: 17452-27-6
pyridin-3-yl isothiocyanate

: 693-04-9
butyl magnesium bromide

: N-(pyridin-3-yl)pentanethioamide

Conditions

Conditions	Yield
In tetrahydrofuran at 0 - 20℃; for 2h;	99%

: 21758-34-9
(1R,2S,5R)-(-)-menthyl 4-chlorobenzoate

: 693-04-9
butyl magnesium bromide

: methyl p-butylbenzoate

Conditions

Conditions	Yield
With iron(III) chloride; ethanol; isopropylmagnesium chloride In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere; Green chemistry;	99%

: 125617-35-8
(E)-3-(3-Methoxyphenyl)-2-propen-1-ol

: 693-04-9
butyl magnesium bromide

: (E)-1-(hept-1-en-1-yl)-3-methoxybenzene

Conditions

Conditions	Yield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In toluene at 50℃; for 5h; Inert atmosphere; Schlenk technique;	99%

: 155071-29-7
3-methoxy-1-methyl-1H-pyrrole-2,5-dione

: 693-04-9
butyl magnesium bromide

: 5-butyl-5-hydroxy-4-methoxy-1-methylpyrrol-2(5H)-one

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at -78 - 25℃; for 2h;	98%

: 1-Phenoxycarbonyl-3-triisopropylsilanyl-pyridinium; chloride

: 693-04-9
butyl magnesium bromide

: 123507-17-5
2-Butyl-5-triisopropylsilanyl-2H-pyridine-1-carboxylic acid phenyl ester

Conditions

Conditions	Yield
In tetrahydrofuran	98%

: 693-04-9
butyl magnesium bromide

: 135987-27-8
(E)-2-decenyl 1-diphenylphosphate

: 58177-71-2
3-butyl-1-decene

Conditions

Conditions	Yield
CuCN*2LiCl In tetrahydrofuran at -78℃; for 1h;	98%
CuCN*2LiCl In tetrahydrofuran at -78℃; for 1h; Product distribution; var. Grignard reagents;	98%

: 693-04-9
butyl magnesium bromide

: 370867-96-2
(+/-)-(E)-2-[2-(diphenylphosphanyl)benzoyloxy]-1-phenyl-3-pentene

A: 17261-28-8
ortho-diphenylphosphinobenzoic acid

B: (+/-)-(E)-4-methyl-1-phenyl-2-octene

C: [((E)-2-Propenyl)-hexyl]-benzene

Conditions

Conditions	Yield
With copper(I) bromide dimethylsulfide complex In diethyl ether at 20℃; for 2h;	A n/a B 98% C n/a

...Expand

: 693-04-9
butyl magnesium bromide

: 620-22-4
3-Methylbenzonitrile

: 20359-57-3
1-(3-methylphenyl)pentan-1-one

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide; 3-Methylbenzonitrile In toluene Stage #2: With sulfuric acid In toluene	98%
With copper(l) iodide In tetrahydrofuran for 22h; Grignard Reaction; Inert atmosphere;	76%

: 870298-23-0
oxo-phenylacetic acid (1R,2S)-2-(2-methoxyethoxy)-1,2-diphenylethyl ester

: 693-04-9
butyl magnesium bromide

: (S)-2-hydroxy-2-phenylhexanoic acid, (1R,2S)-2-(2-methoxyethoxy)-1,2-diphenylethyl ester

Conditions

Conditions	Yield
Stage #1: butyl magnesium bromide With zinc(II) chloride In tetrahydrofuran at 0℃; for 2h; Stage #2: oxo-phenylacetic acid (1R,2S)-2-(2-methoxyethoxy)-1,2-diphenylethyl ester In tetrahydrofuran at -90 - -20℃; for 3h;	98%

: 693-04-9
butyl magnesium bromide

: 370867-96-2
(+/-)-(E)-2-[2-(diphenylphosphanyl)benzoyloxy]-1-phenyl-3-pentene

: (+/-)-(E)-4-methyl-1-phenyl-2-octene

Conditions

Conditions	Yield
With copper(I) bromide dimethylsulfide complex In diethyl ether at 25℃; for 2h;	98%

Butylmagnesium chloride Specification

This chemical is called Magnesium, butylchloro-, and its CAS registry number is 693-04-9. With the molecular formula of C₄H₉ClMg, its product categories are Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry;T ypical Metal Compounds; AlkylChemical Synthesis; Organic Bases; Organometallic Reagents; Synthetic Reagents. In addition, this chemical should be sealed in the cool and dry place, away from oxides, acid , H₂O, CO_2.

Other characteristics of the Magnesium, butylchloro- can be summarised as followings: (1)#H bond acceptors: 0 #H bond donors: 0; (2)#Freely Rotating Bonds: 3.

Uses of this chemical: The Magnesium, butylchloro- could react with benzoic acid methyl ester, and obtain the 5-phenyl-nonan-5-ol. This reaction needs the solvent of diethyl ether. The yield is 60 %.

When you are using this chemical, please be cautious about it as the following: This chemical is flammable. It causes burns. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1.SMILES: CCCC[Mg]Cl
2.InChI: InChI=1/C4H9.ClH.Mg/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1/rC4H9ClMg/c1-2-3-4-6-5/h2-4H2,1H3
3.InChIKey: UUNGXYVLXYGZKH-PEDMJPSNAP

Product Name

Butylmagnesium chloride

Synthetic route

Butylmagnesium chloride Specification

Related Products

Hot Products