Product Name

  • Name

    (chlorooxy)chlorane trioxide

  • EINECS
  • CAS No. 27218-16-2
  • Article Data3
  • CAS DataBase
  • Density g/cm3
  • Solubility
  • Melting Point
  • Formula Cl2O4
  • Boiling Point °Cat760mmHg
  • Molecular Weight 134.904
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety A shock-sensitive explosive. Potentially explosive reaction with chlorotrifluoroethylene, perfluoroalkyl iodides (e.g., perfluoromethyl iodide, 1,2-diiodoperfluoroethane, 1,3-diiodoperfluoropropane). When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINE and PERCHLORATES.
  • Risk Codes
  • Molecular Structure Molecular Structure of 27218-16-2 ((chlorooxy)chlorane trioxide)
  • Hazard Symbols
  • Synonyms Chlorineoxide (Cl2O4) (8CI);Chlorine chlorate oxide [Cl(ClO3)O];Chlorine perchlorate;
  • PSA
  • LogP

Chlorine perchlorate Chemical Properties

IUPAC Name: Chloro perchlorate 
Empirical Formula: Cl2O4
Molecular Weight: 134.9036g/mol
XLogP3-AA :3.6
H-Bond Donor: 0
H-Bond Acceptor: 4
Rotatable Bond Count: 0
Exact Mass: 133.917364
MonoIsotopic Mass: 133.917364
Topological Polar Surface Area: 60.4
Heavy Atom Count: 6
Formal Charge: 0
Complexity: 128
SMILES: ClOCl(=O)(=O)=O
InChI: InChI=1/Cl2O4/c1-6-2(3,4)5
InChIKey: JRONPIZRZBBOBR-UHFFFAOYAQ 
Structure of Chlorine perchlorate (CAS NO.27218-16-2):

Chlorine perchlorate Safety Profile

A shock-sensitive explosive. Potentially explosive reaction with chlorotrifluoroethylene, perfluoroalkyl iodides (e.g., perfluoromethyl iodide, 1,2-diiodoperfluoroethane, 1,3-diiodoperfluoropropane). When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINE and PERCHLORATES.

Chlorine perchlorate Specification

  Chlorine perchlorate  , its cas register number is 27218-16-2. It also can be called Chlorine perchlorate is the chemical compound with the formula Cl2O4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in oxidation state +1 and the other +7, with proper formula ClOClO3. 
2 ClO2 + UV(λ=436nm) → ClOClO3
Chlorine perchlorate reacts with metal chlorides forming anhydrous perchlorates:
CrO2Cl2 + 2ClOClO3 → 2Cl2 + CrO2(ClO4)2
TiCl4 + 4ClOClO3 → 4Cl2 + Ti(ClO4)4 
 Chlorine perchlorate (CAS NO.27218-16-2) is pale greenish liquid which decomposes at room temperature. When heated to decomposition it emits toxic fumes of Cl−.

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