D-(+)-Mannose supplier | CasNO.3458-28-4

Name
D-Mannose
EINECS 222-392-4
CAS No. 3458-28-4
Article Data262
CAS DataBase
Density 1,581 g/cm³
Solubility 2480 g/L (17 ºC)
Melting Point 133-140ºC
Formula C₆H₁₂O₆
Boiling Point 527.1 °C at 760 mmHg
Molecular Weight 180.158
Flash Point 286.7 °C
Transport Information
Appearance White powder
Safety 24/25-36-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms D-Mannose;
PSA 118.22000
LogP -3.37880

Synthetic route

: 7296-15-3
alpha-D-mannopyranoside

: 107-11-9
1-amino-2-propene

A: 3458-28-4
D-Mannose

B: 1-(allylamino)-1-deoxy-α-D-mannopyranose

Conditions

Conditions	Yield
In methanol at 60℃; for 0.166667h; Temperature; Time; Inert atmosphere;	A n/a B 98.6%

...Expand

: cellobiose

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 3458-28-4
D-Mannose

: fructose

: D-glucose

Conditions

Conditions	Yield
With water at 150℃; for 24h; Autoclave; Green chemistry;	A 8.4% B 2.7% C 2.2% D 67.7%

...Expand

: 50-99-7
D-glucose

A: 57-48-7
D-Fructose

B: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
Stage #1: D-glucose With zirconium metal organic framework UiO-66 In propan-1-ol at 90℃; for 24h; Sealed tube; Stage #2: In water at 90℃; for 24h; Catalytic behavior; Mechanism; Solvent;	A 56% B n/a
With SrO(SrTiO3)2 In water at 110℃; for 1h; Reagent/catalyst;	A 34% B 10%
With 5% LaOH/C In water at 100℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Solvent; Autoclave; Inert atmosphere;	A 25.97% B 6.95%

cellulose: cellulose

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 3458-28-4
D-Mannose

C: cellobiose

: fructose

: D-glucose

Conditions

Conditions	Yield
With water at 150℃; for 24h; Activation energy; Reagent/catalyst; Temperature; Autoclave; Green chemistry;	A n/a B n/a C n/a D n/a E 49.9%

...Expand

: 492-62-6
alpha-D-glucopyranose

A: 3458-28-4
D-Mannose

B: 470-23-5, 470-24-6, 10247-46-8, 10489-79-9, 35673-97-3, 36441-90-4, 36441-92-6, 36468-68-5, 37500-17-7, 40461-86-7, 40461-87-8, 41579-20-8, 41846-98-4, 41846-99-5, 41847-00-1, 41847-01-2, 41847-02-3, 41847-03-4, 41847-04-5, 41847-05-6, 41847-06-7, 41847-51-2, 41847-52-3, 42744-42-3
D-fructose

Conditions

Conditions	Yield
With sodium aluminate In water at 60℃; for 0.75h; Reagent/catalyst; Autoclave;	A 14.26% B 47.21%

cellulose: cellulose

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With water; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 100℃; for 0.5h;	A 41.1% B 9.2%

: 133-99-3, 490-37-9, 2152-98-9, 4482-75-1, 5965-66-2, 13299-27-9, 13360-52-6, 14641-93-1, 15548-43-3, 16462-44-5, 16984-36-4, 16984-38-6, 20869-27-6, 22688-72-8, 27452-49-9, 29276-55-9, 30608-12-9, 34481-13-5, 37169-60-1, 37169-64-5, 64234-01-1, 64234-02-2, 75281-88-8, 80446-85-1, 84413-57-0, 92344-56-4, 93221-87-5, 93301-77-0, 94799-29-8, 100427-98-3, 100428-00-0, 101312-82-7, 102046-24-2, 102046-25-3, 109432-00-0, 109432-02-2, 109432-04-4, 109432-08-8, 135268-49-4, 138231-26-2, 140461-59-2, 145414-22-8, 145414-26-2, 146339-75-5, 146339-76-6, 149116-55-2, 528-50-7
Cellobiose

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 3458-28-4
D-Mannose

C: 50-99-7
D-glucose

Conditions

Conditions	Yield
With aluminium(III) chloride hexahydrate at 130℃; for 4h;	A 11.3% B 19% C 40%
With HNbMoO6 In water at 119.84℃; for 3h;

...Expand

: 13360-52-6
Cellobiose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

Conditions

Conditions	Yield
With water at 160℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Microwave irradiation; Sealed tube;	A 10.5% B 32.6%
With water at 160℃; under 18751.9 Torr; for 1.5h; Reagent/catalyst; Autoclave; Inert atmosphere;	A 8.8% B 25.6%

: 13360-52-6
Cellobiose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

C: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
With water at 160℃; under 18751.9 Torr; for 1.5h; Reagent/catalyst; Autoclave; Inert atmosphere;	A 20.6% B 32% C 7.1%

...Expand

: 133-99-3, 490-37-9, 2152-98-9, 4482-75-1, 5965-66-2, 13299-27-9, 13360-52-6, 14641-93-1, 15548-43-3, 16462-44-5, 16984-36-4, 16984-38-6, 20869-27-6, 22688-72-8, 27452-49-9, 29276-55-9, 30608-12-9, 34481-13-5, 37169-60-1, 37169-64-5, 64234-01-1, 64234-02-2, 75281-88-8, 80446-85-1, 84413-57-0, 92344-56-4, 93221-87-5, 93301-77-0, 94799-29-8, 100427-98-3, 100428-00-0, 101312-82-7, 102046-24-2, 102046-25-3, 109432-00-0, 109432-02-2, 109432-04-4, 109432-08-8, 135268-49-4, 138231-26-2, 140461-59-2, 145414-22-8, 145414-26-2, 146339-75-5, 146339-76-6, 149116-55-2, 6363-53-7
Maltose

A: 57-48-7
D-Fructose

B: 3458-28-4
D-Mannose

C: 50-99-7
D-glucose

D: 642-88-6, 27452-48-8, 58166-24-8, 58166-25-9, 60426-80-4, 81802-09-7, 81802-10-0, 81802-12-2
maltulose

Conditions

Conditions	Yield
With water In ethanol at 200℃; under 75007.5 Torr; for 0.138889h; Kinetics; Solvent; Concentration; Temperature; Supercritical conditions;	A n/a B n/a C n/a D 28%

...Expand

: 50-99-7
D-glucose

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With molybdic acid In water for 0.05h; Bilik reaction; microwave irradiation;	27%
With water at 160℃; for 0.5h; Reagent/catalyst;	22.8%
With triply sodium-exchanged zeolite tin-Beta In methanol at 79.84℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Solvent;	7.9%

: 492-62-6
alpha-D-glucopyranose

A: 64-18-6
formic acid

B: 3458-28-4
D-Mannose

C: 470-23-5, 470-24-6, 10247-46-8, 10489-79-9, 35673-97-3, 36441-90-4, 36441-92-6, 36468-68-5, 37500-17-7, 40461-86-7, 40461-87-8, 41579-20-8, 41846-98-4, 41846-99-5, 41847-00-1, 41847-01-2, 41847-02-3, 41847-03-4, 41847-04-5, 41847-05-6, 41847-06-7, 41847-51-2, 41847-52-3, 42744-42-3
D-fructose

Conditions

Conditions	Yield
With sodium aluminate In N,N-dimethyl acetamide; water at 60℃; for 0.75h; Autoclave;	A 5.61% B 8.23% C 26.6%

...Expand

cellulose: cellulose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

C: 123-76-2
levulinic acid

Conditions

Conditions	Yield
With H3N2H(1+)TeW6O21(2-); water at 175℃; for 2h; Autoclave;	A 7.8% B 25.8% C 8.5%

...Expand

: 50-99-7
D-glucose

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 57-48-7
D-Fructose

C: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With 0.06-Fe/β zeolite In water at 150℃; under 3750.38 Torr; for 1.5h; Autoclave; High pressure; Inert atmosphere; Green chemistry;	A 6% B 22% C 7%
With water at 140℃; for 2h; Inert atmosphere;
With lithium bromide trihydrate In water at 130℃; for 1h; Green chemistry;

...Expand

cellulose: cellulose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

Conditions

Conditions	Yield
With H3N2H(1+)TeW6O21(2-); water at 175℃; for 2h; Autoclave;	A 7.2% B 19%

: 13360-52-6
Cellobiose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

C: glucopyranosyl-glucitol

Conditions

Conditions	Yield
With water at 160℃; under 18751.9 Torr; for 1.5h; Reagent/catalyst; Autoclave; Inert atmosphere;	A 6.9% B 17.3% C 6.8%

...Expand

: 504-29-0
2-aminopyridine

: 57-48-7
D-Fructose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

Conditions

Conditions	Yield
Stage #1: D-Fructose With 2-aminopyridine; acetic acid at 90℃; Lobry de Bruyn-van Ekenstein transformation; Sealed tube; Stage #2: 2-aminopyridine With acetic acid at 90℃; Sealed tube; Stage #3: With trifluoroacetic acid at 100℃; for 3h;	A 12% B 8%

...Expand

: 110-86-1
pyridine

: 50-99-7
D-glucose

A: 57-48-7
D-Fructose

B: 3458-28-4
D-Mannose

...Expand

: 69-65-8
mannitol

A: 57-48-7
D-Fructose

B: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With water; chlorine
bei Einw.von Acetobacter pasteurianum;

: 69-65-8
mannitol

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With para-xylene; water; oxygen im Sonnenlicht;
With bromine im Sonnenlicht(?);
With nitrogen oxides; water; iron(II)

: 3416-24-8
2-amino-2-deoxyglucose

: 3458-28-4
D-Mannose

: 14199-83-8
1-deoxy-1-nitro-D-manno-hexitol

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With sodium hydroxide anschliessend mit wss.Schwefelsaeure;

: 69-65-8
mannitol

: 106-51-4
p-benzoquinone

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
bei gleichzeitiger Belichtung;

: 617-04-9
(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With sulfuric acid
With hydrogenchloride
With CuGGH metallopeptide based glycosidase; dihydrogen peroxide; sodium L-ascorbate In methanol; aq. phosphate buffer; water at 37℃; for 8h; pH=7; Enzymatic reaction;

: 26301-79-1
D-mannono-1,4-lactone

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With sodium amalgam; water; benzoic acid
With sodium amalgam; water; sodium hydrogen oxalate

: 57-48-7
D-Fructose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

Conditions

Conditions	Yield
With potassium hydroxide In water at 25℃; for 336h; Product distribution; Kinetics;

: 2864-54-2, 5112-34-5, 15548-39-7, 16790-30-0, 20429-79-2, 20880-64-2, 21973-63-7, 23178-92-9, 26887-94-5, 37169-66-7, 37169-67-8, 50271-58-4, 50271-62-0, 50271-63-1, 75880-63-6, 80339-57-7, 84413-56-9, 87982-90-9, 87982-91-0, 88929-16-2, 89253-87-2, 100430-39-5, 103477-05-0, 109432-07-7, 117249-70-4, 117249-71-5, 117249-75-9, 117249-76-0, 117249-79-3, 117249-80-6, 117249-84-0, 117249-85-1, 117249-88-4, 117249-89-5, 117249-93-1, 117249-97-5, 117249-98-6, 117249-99-7, 117250-01-8, 117250-02-9, 117250-06-3, 117250-07-4, 117250-11-0, 117250-12-1, 117250-15-4, 117250-16-5, 117305-48-3, 117306-19-1, 117306-20-4, 117306-24-8, 117306-25-9, 117306-28-2, 117306-29-3, 117306-33-9, 117306-34-0, 117306-38-4, 117306-39-5, 117306-43-1, 117306-44-2, 117469-02-0, 117469-03-1, 117469-08-6, 117469-09-7, 119720-41-1, 119720-44-4, 119720-52-4, 119720-53-5, 119720-57-9, 119785-94-3, 119785-95-4, 123050-22-6, 143120-89-2, 143120-90-5, 143120-91-6, 147923-33-9
O-β-D-mannopyranosyl-(1->2)-D-mannopyranose

: 3458-28-4
D-Mannose

Conditions

Conditions	Yield
With sulfuric acid at 100℃; for 3h; in a sealed tube;

: 551-68-8
D-psicose

A: 79-14-1
glycolic Acid

B: 849585-22-4
LACTIC ACID

C: 57-48-7
D-Fructose

D: 3458-28-4
D-Mannose

E: 50-99-7
D-glucose

F: 64-19-7
acetic acid

Conditions

Conditions	Yield
With potassium hydroxide In water at 78℃; for 0.333333h; Rate constant; Product distribution; Mechanism; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M;

...Expand

: 50-99-7
D-glucose

A: 79-14-1
glycolic Acid

B: 849585-22-4
LACTIC ACID

C: 57-48-7
D-Fructose

D: 3458-28-4
D-Mannose

E: 551-68-8
D-psicose

F: 64-19-7
acetic acid

Conditions

Conditions	Yield
With potassium hydroxide In water at 78℃; for 0.333333h; Rate constant; Product distribution; Mechanism; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M;

...Expand

: 3458-28-4
D-Mannose

: 69-65-8
mannitol

Conditions

Conditions	Yield
With hydrogen In water at 120℃; under 15001.5 Torr; for 1h;	100%
With sodium tetrahydroborate In water at 20℃; for 2h;	78%
With water; hydrogen at 99.84℃; under 37503.8 Torr; for 0.5h;	8.7%

: 75-77-4
chloro-trimethyl-silane

: 3458-28-4
D-Mannose

: 55529-69-6
trimethylsilyl 2,3,4,6-tetra-O-trimethylsilyl-D-mannopyranoside

Conditions

Conditions	Yield
With pyridine at 20℃; for 4h; Inert atmosphere;	100%
With pyridine; 1,1,1,3,3,3-hexamethyl-disilazane at 20℃; for 0.583333h;
With triethylamine In N,N-dimethyl-formamide at 0 - 25℃; Inert atmosphere;

: 3458-28-4
D-Mannose

: 108-24-7
acetic anhydride

: 4163-65-9
per-O-acetyl-α-D-mannopyranose

Conditions

Conditions	Yield
With iodine at 20℃; for 1h; optical yield given as %de;	100%
With pyridine; dmap at 0 - 20℃;	100%
With pyridine; dmap at 20℃; Inert atmosphere;	100%
With pyridine; dmap at 0 - 20℃;	100%
With sulfuric acid at 0 - 20℃; for 0.666667h;	80.4%

: 75-77-4
chloro-trimethyl-silane

: 3458-28-4
D-Mannose

: 24707-99-1
1,2,3,4,6-penta-O-(trimethylsilyl)-α-D-mannopyranose

Conditions

Conditions	Yield
With pyridine; 1,1,1,3,3,3-hexamethyl-disilazane at 75℃; for 1.5h; Inert atmosphere;	100%
With pyridine at 0 - 23℃; for 24h;	64%

: 3458-28-4
D-Mannose

: 75-04-7
ethylamine

: 68045-28-3
N-ethyl-β-D-mannopyranosylamine

Conditions

Conditions	Yield
In ethanol	99%

: 71-23-8
propan-1-ol

: 3458-28-4
D-Mannose

: 118245-34-4
1-propyl D-mannopyranoside

Conditions

Conditions	Yield
With Dowex-50W X-8H+-400 for 12h; Heating;	97%

: 67-56-1
methanol

: 3458-28-4
D-Mannose

: 617-04-9
(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

Conditions

Conditions	Yield
With acetyl chloride for 6h; Inert atmosphere; Reflux;	97%
In dimethyl sulfoxide at 20℃; Reflux;

: carbonic acid bis(1-isopropylhydrazide) dihydrochloride

: 3458-28-4
D-Mannose

: 1'R,2'R,3'R,4'R-2,4-diisopropyl-6-(1',2',3',4',5'-pentahydroxypentyl)-1,2,4,5-tetrazinan-3-one

Conditions

Conditions	Yield
With sodium acetate In water at 20℃;	97%

: 3458-28-4
D-Mannose

: 771-97-1
2,3-Diaminonaphthalene

: 1027103-24-7
(1'R,2'R,3'R,4'R)-2-[1',2',3',4',5'-pentahydroxypentyl]-1H-naphthimidazole

Conditions

Conditions	Yield
With air; iodine; acetic acid at 20℃; for 18h;	96%

: 3458-28-4
D-Mannose

: D-mannonitrile

Conditions

Conditions	Yield
With phenoxyamine hydrochloride In aq. phosphate buffer; water-d2 at 20℃; for 24h;	96%

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
2,3,5,6-di-O-isopropylidene-D-mannofuranose

Conditions

Conditions	Yield
With camphorsulfonic acid In acetone at 20℃;	95%
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 20℃; Inert atmosphere;	76%
With toluene-4-sulfonic acid In acetone	73%
With toluene-4-sulfonic acid at 40℃; for 4h;

: 3458-28-4
D-Mannose

: 479-27-6
naphthalene-1,8-diamine

: 73858-36-3
(1R,2R,3R,4R)-1-(2,3-Dihydro-1H-perimidin-2-yl)-pentane-1,2,3,4,5-pentaol

Conditions

Conditions	Yield
In ethanol; water; acetic acid for 2h; Heating;	95%
In ethanol; water at 20℃;	68%

: 120-72-9
indole

: 3458-28-4
D-Mannose

: 108-24-7
acetic anhydride

: Acetic acid (1R,2R,3R,4R)-2,3,4,5-tetraacetoxy-1-[bis-(1H-indol-2-yl)-methyl]-pentyl ester

Conditions

Conditions	Yield
Stage #1: indole; D-Mannose; scandium tris(trifluoromethanesulfonate) In ethanol; water at 50℃; for 48h; Stage #2: acetic anhydride With pyridine; dmap at 20℃;	95%

...Expand

: 3458-28-4
D-Mannose

: 98-88-4
benzoyl chloride

: 96996-90-6
1,2,3,4,6-penta-O-benzoyl-α,β-D-mannopyranoside

Conditions

Conditions	Yield
With pyridine at 20℃; for 12h;	95%
With pyridine at 0 - 20℃; Inert atmosphere;
With pyridine; dmap at 20℃; Cooling with ice;
With pyridine at 0 - 20℃;

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 78964-16-6
2,3;5,6-di-O-isopropylidene-β-D-mannofuranose

Conditions

Conditions	Yield
Stage #1: D-Mannose; 2,2-dimethoxy-propane With sulfuric acid In acetone at 0 - 20℃; for 24h; Stage #2: With triethylamine In acetone	95%

: 3458-28-4
D-Mannose

: 98-88-4
benzoyl chloride

: 2592-58-7, 3006-48-2, 3006-49-3, 13526-09-5, 14679-57-3, 22415-91-4, 29884-70-6, 41545-55-5, 41545-56-6, 41569-33-9, 96996-90-6, 121570-85-2, 121570-86-3
1,2,3,4,6-penta-O-benzoyl-α-D-mannopyranoside

Conditions

Conditions	Yield
With dmap In pyridine at 20℃;	95%
With pyridine at 20℃; for 24h; Inert atmosphere;

: 3458-28-4
D-Mannose

: 67-64-1
acetone

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
2,3:5,6-di-O-isopropylidene-α-D-mannofuranose

Conditions

Conditions	Yield
With sulfuric acid at 20℃; for 2h;	95%
Acidic conditions;
With sulfuric acid; copper(II) sulfate

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 40036-82-6
[2,3:5,6]-di-O-isopropylidene-D-mannose

Conditions

Conditions	Yield
With camphosulfonic acid In acetone at 0 - 20℃; Inert atmosphere;	95%
With toluene-4-sulfonic acid In acetone at 0 - 20℃;

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 67-64-1
acetone

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
(3aR,4R,6R,6aR)-6-(2,2-dimethyl-1,3-dioxolane-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol

Conditions

Conditions	Yield
With sulfuric acid at 0 - 20℃; for 24h;	95%

...Expand

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 67-64-1
acetone

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
2,3,5,6-di-O-isopropylidene-D-mannofuranose

Conditions

Conditions	Yield
With camphor-10-sulfonic acid at 0 - 20℃; for 24h; Inert atmosphere;	95%

...Expand

: 3458-28-4
D-Mannose

: 67-64-1
acetone

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
2,3,5,6-di-O-isopropylidene-D-mannofuranose

Conditions

Conditions	Yield
With sulfuric acid; copper(II) sulfate	93.5%
With sulfuric acid for 4h; Ambient temperature;	90%
With sulfuric acid; copper(II) sulfate for 8h;	85%

: 3458-28-4
D-Mannose

: 77-76-9
2,2-dimethoxy-propane

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
O2,O3,O5,O6-diisopropylidene D-mannofuranose

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In acetone at 20℃; for 2h;	93%

: 3458-28-4
D-Mannose

: 108-24-7
acetic anhydride

: 104-94-9
4-methoxy-aniline

: 123-54-6
acetylacetone

: 1020540-83-3
[(5R,6S)-3-acetyl-6-acetyloxy-1-(4-methoxyphenyl)-2-methyl-1,5,6,7-tetrahydropyrano[3,2-b]pyrrol-5-yl]methyl acetate

Conditions

Conditions	Yield
Stage #1: D-Mannose; 4-methoxy-aniline; acetylacetone With indium(III) chloride In water at 80℃; for 6h; Stage #2: acetic anhydride With dmap In dichloromethane at 20℃; for 1h; Further stages.;	93%

...Expand

: 3458-28-4
D-Mannose

: 108-44-1
1-amino-3-methylbenzene

: 1096700-48-9
N-m-tolyl-β-D-mannopyranosylamine

Conditions

Conditions	Yield
In water Reflux;	93%

: 3458-28-4
D-Mannose

: 16596-41-1
N-aminopyrrolidine

: (2R,3R,4R,5R)-6-(pyrrolidin-1-ylimino)hexane-1,2,3,4,5-pentol

Conditions

Conditions	Yield
In methanol for 3.5h; Reflux;	93%

: 3458-28-4
D-Mannose

: 67-64-1
acetone

: 7757-38-2, 14131-84-1, 23262-78-4, 27108-13-0, 33823-04-0, 34685-42-2, 57819-52-0, 78039-08-4, 78039-12-0, 78964-16-6, 94842-76-9, 149342-31-4
O2,O3,O5,O6-diisopropylidene D-mannofuranose

Conditions

Conditions	Yield
With malonic acid; choline chloride for 0.333333h; Reflux; Green chemistry;	93%

: 3458-28-4
D-Mannose

: 95-53-4
o-toluidine

: N-(o-tolyl)-β-D-mannopyranosylamine

Conditions

Conditions	Yield
In water Reflux;	92.8%

: 109-80-8
1.3-propanedithiol

: 3458-28-4
D-Mannose

: 173207-36-8
D-mannose propane-1,3-diyl dithioacetal

Conditions

Conditions	Yield
With trifluoroacetic acid at 50 - 60℃; 30-50 min;	92%

: 3458-28-4
D-Mannose

: 108-24-7
acetic anhydride

: 83-87-4, 604-68-2, 604-69-3, 2152-77-4, 4026-35-1, 4163-59-1, 4163-60-4, 4163-61-5, 4163-65-9, 4257-94-7, 4257-96-9, 16299-15-3, 19186-39-1, 19189-55-0, 25878-60-8, 25941-03-1, 32445-48-0, 32445-49-1, 32445-53-7, 32445-54-8, 34685-58-0, 34685-59-1, 43168-42-9, 43168-44-1, 43169-22-8, 43169-25-1, 66966-07-2, 70749-17-6, 80184-01-6, 93221-01-3, 93221-02-4, 99630-88-3, 109215-53-4, 115792-70-6, 115792-73-9, 139894-92-1, 139973-25-4, 144071-49-8, 147648-81-5
D-Mannose pentaacetate

Conditions

Conditions	Yield
With pyridine at 0 - 20℃;	92%
With iodine for 2h; cooling;	89%
With potassium acetate at 90℃; for 4h;	63%

D-(+)-Mannose Specification

The D-(+)-Mannose, with the CAS register number 3458-28-4, has other names as carubinose;d-mannopyranose;d-(+)-mannose;d-mannose;d-man;mannose, d-(+)-;seminose;d-mannos .Its product categories are including the following: Sugars, Carbohydrates & Glucosides. It is a kind of white crystalline powder and it is sweet with afteraste of bitter. And it is soluble in water and slightly soluble in ethanol but insoluble in diethyl [ethyl] ether. Besides, it has two types of α- and β-. The α- is the crystallize of methyl with the melting point of 133℃ while the β- is the crystallize of ethyl with the melting point of 132℃. As for its usage, it is usually used for being the biochemical reagents and sweet taste reagents. What's more, the simple way to get it is following:hydrolyze the cocoanut husk with sulfuric acid and then you could α- type of D-Mannose.

The physical properties of D-(+)-Mannose are as followings:
(1) ACD/LogP: -2.49; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -2.49; (4)ACD/LogD (pH 7.4): -2.49; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.05; (8)ACD/KOC (pH 7.4): 1.05; (9)#H bond acceptors: 6; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 6; (12)Index of Refraction: 1.635; (13)Molar Refractivity: 37.254 cm³; (14)Molar Volume: 104.015 cm³; (15)Surface Tension: 81.7509994506836 dyne/cm; (16)Density: 1.732 g/cm³; (17)Flash Point: 202.243 °C; (18)Enthalpy of Vaporization: 76.626 kJ/mol; (19)Boiling Point: 410.797 °C at 760 mmHg; (20)Vapour Pressure: 0 mmHg at 25°C.

Safety information of D-(+)-Mannose:
Being an irritant chemical to eyes, respiratory system and skin, it may cause inflammation to the skin or other mucous membranes. So while using this chemical, take the following instrction to protect your self: Wear suitable protective clothing and avoid contact with skin and eyes; If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And you could also obtain the safety information from WGK Germany 3.

You can still convert the following datas into molecular structure:
(1)SMILES:O[C@H]1[C@H](O)[C@H](OC(O)[C@H]1O)CO;
(2)Std. InChI:InChI=1S/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3-,4+,5+,6?/m1/s1;
(3)Std. InChIKey:WQZGKKKJIJFFOK-QTVWNMPRSA-N.

Product Name

D-Mannose

Synthetic route

D-(+)-Mannose Specification

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