Product Name

  • Name

    Dicyclohexylchlorophosphine

  • EINECS
  • CAS No. 16523-54-9
  • Article Data15
  • CAS DataBase
  • Density 1.054g/mLat 25°C(lit.)
  • Solubility reacts violently with water
  • Melting Point 126-128 °C
  • Formula C12H22ClP
  • Boiling Point 297.5 °C at 760 mmHg
  • Molecular Weight 232.733
  • Flash Point 133.7 °C
  • Transport Information UN 3265 8/PG 2
  • Appearance clear colorless liquid
  • Safety 26-27-36/37/39-45-8
  • Risk Codes 14-34
  • Molecular Structure Molecular Structure of 16523-54-9 (Dicyclohexylchlorophosphine)
  • Hazard Symbols CorrosiveC
  • Synonyms Phosphinouschloride, dicyclohexyl- (6CI,7CI,8CI,9CI);Chlorodicyclohexylphosphine;Dicyclohexylphosphinous chloride;
  • PSA 13.59000
  • LogP 5.28750

Synthetic route

dicyclohexylphosphane
829-84-5

dicyclohexylphosphane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
With Ethyl trichloroacetate In chlorobenzene at 80℃; for 2.46667h; Product distribution / selectivity;80.6%
cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
With phosphorus trichloride
With phosphorus trichloride In diethyl ether
With phosphorus trichloride In toluene at 0℃;
cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

dichlorocyclohexylphosphine
2844-89-5

dichlorocyclohexylphosphine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

cyclohexane
110-82-7

cyclohexane

dichlorocyclohexylphosphine
2844-89-5

dichlorocyclohexylphosphine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Irradiation;
(chloroacetyl)dicyclohexylphosphane

(chloroacetyl)dicyclohexylphosphane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
In chloroform at 20℃;
(dichloroacetyl)dicyclohexylphosphane

(dichloroacetyl)dicyclohexylphosphane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
In chloroform at 20℃;
(trichloroacetyl)dicyclohexylphosphane

(trichloroacetyl)dicyclohexylphosphane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
In chloroform at 20℃;
1-bromocyclohexane
108-85-0

1-bromocyclohexane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Stage #1: 1-bromocyclohexane With magnesium In tetrahydrofuran at 20℃; for 2h; Grignard reaction;
Stage #2: With diethylphosphoramidous dichloride In tetrahydrofuran at 0 - 50℃; for 3h; phosphorylation;
Stage #3: With hydrogenchloride In pentane at 0℃; for 1h; Hydrolysis;
cyclohexyl chloride
542-18-7

cyclohexyl chloride

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Mg / diethyl ether / 2.5 h / Heating
2: PCl3 / diethyl ether
View Scheme
Stage #1: cyclohexyl chloride With magnesium In diethyl ether
Stage #2: With phosphorus trichloride In diethyl ether at -40 - 20℃; for 5.33333h;
Multi-step reaction with 2 steps
1: diethyl ether
2: phosphorus trichloride / diethyl ether / -40 - 20 °C
View Scheme
Stage #1: cyclohexyl chloride With magnesium In diethyl ether
Stage #2: With phosphorus trichloride In tetrahydrofuran; diethyl ether at -40 - 20℃; for 7h;
Multi-step reaction with 2 steps
1: magnesium / diethyl ether
2: phosphorus trichloride / tetrahydrofuran / 7 h / -40 - 20 °C
View Scheme
trimethylsilyldicyclohexylphosphane
104202-80-4

trimethylsilyldicyclohexylphosphane

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 100 percent / diethyl ether / -25 °C
2: CHCl3 / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 100 percent / diethyl ether / -25 °C
2: CHCl3 / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 100 percent / diethyl ether / -25 °C
2: CHCl3 / 20 °C
View Scheme
Chlor-diethylamino-cyclohexyl-phosphan
70530-88-0

Chlor-diethylamino-cyclohexyl-phosphan

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: HCl
View Scheme
cyclohexane
110-82-7

cyclohexane

deuterium

deuterium

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: PCl3 / Irradiation
2: Irradiation
View Scheme
1-phenylpyrrole
635-90-5

1-phenylpyrrole

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

N–phenyl–2–(dicyclohexylphosphino)pyrrole

N–phenyl–2–(dicyclohexylphosphino)pyrrole

Conditions
ConditionsYield
Stage #1: 1-phenylpyrrole With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane Inert atmosphere; Reflux;
Stage #2: chlorodicyclohexylphosphane In hexane for 1h; Reflux;		99%
Stage #1: 1-phenylpyrrole With n-butyllithium; N,N,N,N,-tetramethylethylenediamine
Stage #2: chlorodicyclohexylphosphane
2-chloro-N,N-diisopropylbenzamide
70657-63-5

2-chloro-N,N-diisopropylbenzamide

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

N,N-diisopropyl 6-chloro-2-dicyclohexylphosphinobenzamide
1053223-43-0

N,N-diisopropyl 6-chloro-2-dicyclohexylphosphinobenzamide

Conditions
ConditionsYield
Stage #1: N,N-diisopropyl 2-chlorobenzamide With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at -78℃; for 0.583333h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;		99%
(R)-(-)-N-benzyl-4-hydroxymethyl-3-azahexan-1-ol
352655-19-7

(R)-(-)-N-benzyl-4-hydroxymethyl-3-azahexan-1-ol

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(2R)-2-[benzyl{(2-((dicyclohexylphosphanyl)oxy)ethyl)}amino]butyldicyclohexylphosphinite
1305343-45-6

(2R)-2-[benzyl{(2-((dicyclohexylphosphanyl)oxy)ethyl)}amino]butyldicyclohexylphosphinite

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;99%
2,6-Diaminopyridine
141-86-6

2,6-Diaminopyridine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

N,N'-bis(dicyclohexyl)-2,6-diaminopyridine

N,N'-bis(dicyclohexyl)-2,6-diaminopyridine

Conditions
ConditionsYield
With triethylamine In toluene at 70℃; for 48h;99%
1-(2,4-dimethoxyphenyl)naphthalene

1-(2,4-dimethoxyphenyl)naphthalene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl(2,6-dimethoxy-3-(naphthalen-1-yl)phenyl)phosphane

dicyclohexyl(2,6-dimethoxy-3-(naphthalen-1-yl)phenyl)phosphane

Conditions
ConditionsYield
Stage #1: 1-(2,4-dimethoxyphenyl)naphthalene With n-butyllithium In tetrahydrofuran; hexane for 1.25h; Cooling with ice;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at 20℃; for 3.66667h; Cooling with ice;		99%
ethylene glycol
107-21-1

ethylene glycol

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

1,2-bis(dicyclohexylphosphinite)ethane

1,2-bis(dicyclohexylphosphinite)ethane

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 74h;98.7%
1,2-bis(3-hydroxyprop-1-yn-1-yl)benzene
116510-02-2

1,2-bis(3-hydroxyprop-1-yn-1-yl)benzene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

3,8-bis(dicyclohexylphosphinyl)-1,2-dihydrocyclobuta[b]naphthalene

3,8-bis(dicyclohexylphosphinyl)-1,2-dihydrocyclobuta[b]naphthalene

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at -78 - 20℃; for 4h;98%
With triethylamine In tetrahydrofuran at 20℃; for 2h;98%
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

C28H46P(1+)*I(1-)

C28H46P(1+)*I(1-)

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C40H67P2(1+)*BF4(1-)

C40H67P2(1+)*BF4(1-)

Conditions
ConditionsYield
Stage #1: C28H46P(1+)*I(1-); chlorodicyclohexylphosphane With n-butyllithium In hexane; toluene at 20℃; for 72h; Inert atmosphere; Schlenk technique;
Stage #2: sodium tetrafluoroborate In acetonitrile at 20℃; Inert atmosphere; Schlenk technique;		98%
...Expand
2,2'-dihydroxybiphenyl
1806-29-7

2,2'-dihydroxybiphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(C6H4OP(cyclohexyl)2)2
872217-45-3

(C6H4OP(cyclohexyl)2)2

Conditions
ConditionsYield
With triethylamine In acetonitrile at 60℃;97%
1-(2,6-diisopropylphenyl)-1H-imidazole
25364-47-0

1-(2,6-diisopropylphenyl)-1H-imidazole

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2-(dicyclohexylphosphino)-1-(2,6-diisopropylphenyl)-1H-imidazole
1138156-50-9

2-(dicyclohexylphosphino)-1-(2,6-diisopropylphenyl)-1H-imidazole

Conditions
ConditionsYield
Stage #1: 1-(2,6-diisopropylphenyl)-1H-imidazole With n-butyllithium In tetrahydrofuran; hexane at -30℃; for 0.5h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -30 - 50℃; Inert atmosphere;		97%
Stage #1: 1-(2,6-diisopropylphenyl)-1H-imidazole With n-butyllithium In tetrahydrofuran; hexane at 30℃; for 0.5h; Glovebox; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at 50℃; for 1h; Glovebox; Inert atmosphere;		44%
C19H17N5

C19H17N5

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C31H38N5P

C31H38N5P

Conditions
ConditionsYield
Stage #1: C19H17N5 With n-butyllithium In tetrahydrofuran at -80 - 0℃; for 1h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane at -80 - 20℃; Inert atmosphere;		96.1%
C19H17N5

C19H17N5

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C31H38N5P

C31H38N5P

Conditions
ConditionsYield
Stage #1: C19H17N5 With n-butyllithium In tetrahydrofuran; ethanol at -80 - 0℃; for 1h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; ethanol at -80 - 20℃; Inert atmosphere;		96.1%
(R)-[(α-(dimethylamino)ethyl)-η(6)-benzene]chromium tricarbonyl

(R)-[(α-(dimethylamino)ethyl)-η(6)-benzene]chromium tricarbonyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

[η6-(R,R)-((NMe2)CHMe)C6H4PCy2]Cr(CO)3

[η6-(R,R)-((NMe2)CHMe)C6H4PCy2]Cr(CO)3

Conditions
ConditionsYield
With t-BuLi In diethyl ether byproducts: LiCl; under N2; to a stirred soln. of Cr-contg. compd. (8.77 mmol) in dry Et2O, t-BuLi (10.53 mmol, in hexane) was added dropwise for 1 h at -80°C; the mixt. was stirred for 1 h; the lithiated complex was dissolved in THF; ClPCy2 (10.53 mmol) was added; after warming to room temp., LiCl was filtered off and the solvent was removed in vac.; column chromy. on alumina (eluent: pentane, Et2O); elem.anal.;96%
1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine
1070663-82-9

dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine

Conditions
ConditionsYield
Stage #1: 1,3-Dimethoxybenzene With n-butyllithium In tetrahydrofuran at 20℃; for 5h;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran at 20℃; for 12h;		96%
Stage #1: 1,3-Dimethoxybenzene With n-butyllithium In tetrahydrofuran; hexanes at 0 - 20℃; for 5.17h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran at 0 - 20℃; for 12.17h; Inert atmosphere;		96%
4,5-dihydro-4,4-dimethyl-2-phenoxazole
19312-06-2

4,5-dihydro-4,4-dimethyl-2-phenoxazole

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2-[2-(dicyclohexylphosphino)phenyl]-4,5-dihydro-4,4-dimethyloxazole
226088-99-9

2-[2-(dicyclohexylphosphino)phenyl]-4,5-dihydro-4,4-dimethyloxazole

Conditions
ConditionsYield
Stage #1: 4,5-dihydro-4,4-dimethyl-2-phenoxazole With N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium In cyclohexane; pentane at -78 - 20℃; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In cyclohexane; pentane at -78 - 20℃; Inert atmosphere;		96%
2'-bromo-6-methoxy-N,N-dimethylbiphenyl-2-amine
1160556-60-4

2'-bromo-6-methoxy-N,N-dimethylbiphenyl-2-amine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2'-(dicyclohexylphosphino)-6-methoxy-N,N-dimethylbiphenyl-2-amine
1160556-61-5

2'-(dicyclohexylphosphino)-6-methoxy-N,N-dimethylbiphenyl-2-amine

Conditions
ConditionsYield
Stage #1: 2'-bromo-6-methoxy-N,N-dimethylbiphenyl-2-amine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.75h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 20℃;		96%
ferrocene
102-54-5

ferrocene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

1-di(2-(5-methylfuryl)phosphanyl)ferrocene
525603-48-9

1-di(2-(5-methylfuryl)phosphanyl)ferrocene

Conditions
ConditionsYield
With aluminum (III) chloride In hexane at -10℃; for 3h; Temperature; Inert atmosphere;96%
recorcinol
108-46-3

recorcinol

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C30H48O2P2

C30H48O2P2

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 85℃; for 20h; Inert atmosphere;96%
2-Aminomethylthiophene
27757-85-3

2-Aminomethylthiophene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

thiophene-2-(N-dicyclohexylphosphino)methylamine
1588499-13-1

thiophene-2-(N-dicyclohexylphosphino)methylamine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 1.25h; Inert atmosphere; Schlenk technique;95.6%
1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride
1118072-24-4

1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

1-{3-chloro-2-[(dicyclohexylphosphanyl)oxy]propyl}-3-methylimidazolium chloride
1621393-73-4

1-{3-chloro-2-[(dicyclohexylphosphanyl)oxy]propyl}-3-methylimidazolium chloride

Conditions
ConditionsYield
Stage #1: 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride With n-butyllithium In hexane; dichloromethane at -78 - 20℃; for 1.5h; Inert atmosphere; Schlenk technique;
Stage #2: chlorodicyclohexylphosphane In hexane; dichloromethane at -78 - 20℃; for 4h; Inert atmosphere; Schlenk technique;		95.5%
Stage #1: 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride With n-butyllithium In hexane; dichloromethane at -78 - 20℃; for 1.5h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In hexane; dichloromethane at -78 - 20℃; for 2h; Inert atmosphere;		95.5%
Stage #1: 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride With n-butyllithium In hexane; dichloromethane; acetone at -78 - 20℃; for 1.5h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In hexane; dichloromethane; acetone at -78 - 20℃; for 2h; Inert atmosphere;		95.5%
Stage #1: 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol chloride With n-butyllithium In dichloromethane at -78 - 20℃; for 1.5h; Inert atmosphere; Schlenk technique;
Stage #2: chlorodicyclohexylphosphane In dichloromethane at -78 - 20℃; for 2h; Inert atmosphere; Schlenk technique;		94.8%
(S)-1-Pyrrolidin-2-yl-methanol
23356-96-9

(S)-1-Pyrrolidin-2-yl-methanol

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(CH2)3NP(C6H11)2CHCH2OP(C6H11)2
112150-34-2

(CH2)3NP(C6H11)2CHCH2OP(C6H11)2

Conditions
ConditionsYield
With triethylamine In benzene at 20℃;95%
chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexylphosphine oxide
14717-29-4

dicyclohexylphosphine oxide

Conditions
ConditionsYield
With water In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;95%
With water In tetrahydrofuran at 20℃; for 5h;86%
With water Ambient temperature;
Multi-step reaction with 2 steps
1: (i) nBuLi, benzene, hexane, (ii) /BRN= 956672/
2: H2O / CHCl3
View Scheme
With hydrogenchloride In water at 0 - 20℃; for 24h;
(RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene

(RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene

(RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene

Conditions
ConditionsYield
Stage #1: (RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene With sec.-butyllithium In tert-butyl methyl ether; cyclohexane at 0℃; for 1h;
Stage #2: chlorodicyclohexylphosphane In tert-butyl methyl ether; cyclohexane at 0 - 20℃; for 2h;		95%
Stage #1: (RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene With n-butyllithium In hexane; tert-butyl methyl ether at -5 - 0℃;
Stage #2: chlorodicyclohexylphosphane In hexane; tert-butyl methyl ether at 0 - 20℃;		95%
C30H31BrFe2NP

C30H31BrFe2NP

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(RC,SFC,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene

(RC,SFC,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene

Conditions
ConditionsYield
Stage #1: C30H31BrFe2NP With sec.-butyllithium In methyl tert-butyl ether (MTBE); cyclohexane at 0℃; for 1h;
Stage #2: chlorodicyclohexylphosphane In tert-butyl methyl ether; cyclohexane at 0 - 20℃; for 2h;		95%
3-chloro-N,N-diisopropylbenzamide
35306-66-2

3-chloro-N,N-diisopropylbenzamide

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

N,N-diisopropyl 3-chloro-2-dicyclohexylphosphinobenzamide
1053223-45-2

N,N-diisopropyl 3-chloro-2-dicyclohexylphosphinobenzamide

Conditions
ConditionsYield
Stage #1: N,N-diisopropyl 3-chlorobenzamide With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at -78℃; for 0.583333h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;		95%
9-dicyclohexylphosphino-9H-fluorene

9-dicyclohexylphosphino-9H-fluorene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C37H52P2

C37H52P2

Conditions
ConditionsYield
Stage #1: 9-dicyclohexylphosphino-9H-fluorene With n-butyllithium In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran at 0 - 20℃; for 18h; Inert atmosphere; Schlenk technique;		95%
(1R,2R)-N',N'-dimethyl-1,2-diphenylethane-1,2-diamine
320778-96-9

(1R,2R)-N',N'-dimethyl-1,2-diphenylethane-1,2-diamine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

(1R,2R)-N1-(dicyclohexylphosphino)-N2,N2-dimethyl-1,2-diphenylethane-1,2-diamine

(1R,2R)-N1-(dicyclohexylphosphino)-N2,N2-dimethyl-1,2-diphenylethane-1,2-diamine

Conditions
ConditionsYield
Stage #1: (1R,2R)-N1,N1-dimethyl-1,2-diphenylethane-1,2-diamine With n-butyllithium In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Inert atmosphere;		94.4%
8-quinolinol
148-24-3

8-quinolinol

bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

[Pd(C9H6N(O)P(C6H11)2)Cl2]
1219698-46-0

[Pd(C9H6N(O)P(C6H11)2)Cl2]

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran; dichloromethane quinoline was dissolved in THF, KH was added slowly, mixt. was stirred for 10 min, filtered, (C3H7)2PCl in THF was added dropwise, mixt. was stirred for 1 h, soln. of Pd complex in CH2Cl2 was added to filtrate, mixt.was stirred overnight; mixt. was filtered through celite, volatiles were removed under vac.; elem. anal.;94%
...Expand
2-bromo-pyridine
109-04-6

2-bromo-pyridine

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2-(dicyclohexylphosphino)pyridine
959264-38-1

2-(dicyclohexylphosphino)pyridine

Conditions
ConditionsYield
Stage #1: 2-bromo-pyridine With n-butyllithium In diethyl ether; hexane at -100 - -90℃; for 2h;
Stage #2: chlorodicyclohexylphosphane In diethyl ether; hexane at -90℃; for 2h;		94%
lithium cyclopentadienide

lithium cyclopentadienide

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

lithium (dicyclohexylphosphino)cyclopentadienide

lithium (dicyclohexylphosphino)cyclopentadienide

Conditions
ConditionsYield
Stage #1: lithium cyclopentadienide; chlorodicyclohexylphosphane In toluene at -80 - 20℃; Inert atmosphere;
Stage #2: With n-butyllithium In hexane; n-heptane at -40 - 20℃; Inert atmosphere;		94%

Dicyclohexylchlorophosphine Chemical Properties

Chemical Name: Dicyclohexylchlorophosphine
CAS No.: 16523-54-9
Molecular Formula: C12H22ClP
Formula Weight: 232.73 g/mol
Density: 1.054 g/mL at 25 °C(lit.)
Flash Point: 133.7 °C
Boiling Point: 297.5 °C at 760 mmHg
Sensitive: Air & Moisture Sensitive
Following is the structure of Dicyclohexylchlorophosphine (16523-54-9):


Product Categories about Dicyclohexylchlorophosphine (16523-54-9) are Chlorophosphines ; Phosphines ; Catalysis and Inorganic Chemistry ; Phosphorus Compounds ; Phosphorus Precursors
The chemical synonymous of Dicyclohexylchlorophosphine (16523-54-9) are Chlorodicyclohexylphosphine ; Dicyclohexylphosphinous chloride ; Dicyclohexylchlorophosphine ;  Dicyclohexylchlorophosphine, 98+% ; Chlorodicyclohexylphosphine,97%

Dicyclohexylchlorophosphine Safety Profile

Hazard Codes:
C: Corrosive
Risk Statements about Dicyclohexylchlorophosphine (16523-54-9):
R14 Reacts violently with water. 
R34 Causes burns. 
Safety Statements about Dicyclohexylchlorophosphine (16523-54-9):
S8 Keep container dry. 
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 
Attentions:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Handle under argon.

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