Conditions | Yield |
---|---|
With nano-MnO2; graphite at 75℃; for 1.5h; Electrochemical reaction; Ultrasonic; | 91.6% |
With oxygen In water at 45 - 50℃; for 5h; Reagent/catalyst; | 91% |
With tert.-butylhydroperoxide; C56H62Cl2Mn2N6O10P2 In water; acetonitrile at 80℃; for 4h; Catalytic behavior; Green chemistry; | 44% |
Conditions | Yield |
---|---|
With oxygen In water at 60℃; Catalytic behavior; Reagent/catalyst; Autoclave; chemoselective reaction; | A 84.2% B 9.5% C 6.3% |
With oxygen In water at 60℃; under 760.051 Torr; for 4h; Catalytic behavior; | |
With Pt-MCM-41 catalyst; oxygen In water at 69.84℃; under 760.051 Torr; pH=Ca. 7; Kinetics; Catalytic behavior; Reagent/catalyst; Temperature; |
Conditions | Yield |
---|---|
With aluminum (III) chloride; tin(ll) chloride In water at 189.84℃; under 22502.3 Torr; for 2h; Catalytic behavior; Inert atmosphere; Autoclave; | A 81% B 5.2% |
rac-Glycerinaldehyd-2-phosphat Natriumsalz
B
Glyceraldehyde
Conditions | Yield |
---|---|
In aq. phosphate buffer at 60℃; for 23h; pH=7; | A 74% B 12% |
Conditions | Yield |
---|---|
With silver dodecamolybdophosphate; oxygen In water at 60℃; under 3750.38 Torr; for 5h; Catalytic behavior; Reagent/catalyst; Autoclave; | A 72% B n/a C n/a |
With phosphomolybdic acid; dihydrogen peroxide at 60℃; for 0.133333h; Catalytic behavior; | A 42% B n/a C n/a |
With MoO40W12(3-)*Cr(3+); oxygen In water at 60℃; under 7500.75 Torr; for 20h; Autoclave; | A 12.9% B 8.6% C 5.9% |
methanol
A
D-Mannose
B
(S)-Methyl lactate
C
2-methoxyethyl vinyl ether
D
methyl 2-hydroxybut-3-enoate
E
1,1-dihydroxyacetone
F
Glyceraldehyde
G
glycoaldehyde diethyl acetal
Conditions | Yield |
---|---|
With potassium carbonate at 160℃; for 16h; Reagent/catalyst; Flow reactor; | A n/a B 72% C n/a D n/a E n/a F n/a G n/a |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hydroxide In water; water-d2 for 59h; pH=5; | A 72% B 10% |
With hydrogenchloride; sodium hydroxide In water; water-d2 for 30h; pH=3; | A 17% B 29% |
Conditions | Yield |
---|---|
With perchloric acid In ethanol at 20℃; pH=1; Concentration; Reagent/catalyst; Electrochemical reaction; | A 9% B 70.6% |
With Pseudomonas putida HK-5 pyrroloquinoline quinone-dependent alcohol dehydrogenase; 4,4'-azobis(1-methylpyridinium) bis(methyl sulfate); NADH In aq. buffer for 6h; pH=7.1; Catalytic behavior; Time; Electrolysis; Enzymatic reaction; | A 53% B 15% |
With silica-supported platinum; oxygen In water at 89.84℃; for 24h; |
Conditions | Yield |
---|---|
With potassium hydroxide for 4h; Reagent/catalyst; Electrochemical reaction; | A 70% B 13% C 17% |
With dihydrogen peroxide In water at 60℃; for 4h; |
Conditions | Yield |
---|---|
With triethylamine In N,N-dimethyl-formamide at 120℃; under 15751.6 Torr; for 1h; Temperature; Pressure; Reagent/catalyst; Solvent; | A 63.52% B 23.12% |
With triethylamine In N,N-dimethyl-formamide at 100℃; under 3750.38 Torr; for 1h; Temperature; Pressure; Reagent/catalyst; Solvent; | A 25.17% B 38.23% |
With 5-methoxy-1,3,4-triphenyl-4,5-dihydro-1H-1,2-4-triazoline In various solvent(s) at 80℃; |
glycerol
A
LACTIC ACID
B
glyceric acid
C
dihydroxyacetone
D
acetic acid
E
Glyceraldehyde
Conditions | Yield |
---|---|
With oxygen In water at 60℃; under 3750.38 Torr; for 5h; Catalytic behavior; Autoclave; | A 45% B n/a C n/a D n/a E n/a |
glycerol
A
glycolic Acid
B
LACTIC ACID
C
dihydroxyacetone
D
Glyceraldehyde
Conditions | Yield |
---|---|
With dihydrogen peroxide In water at 60℃; for 1h; Reagent/catalyst; Temperature; Time; | A n/a B 36% C n/a D n/a |
Conditions | Yield |
---|---|
With triethylamine In N,N-dimethyl-formamide at 160℃; under 12001.2 Torr; for 1.66667h; Temperature; Pressure; Reagent/catalyst; Solvent; | 30.53% |
A
5-hydroxymethyl-2-furfuraldehyde
B
LACTIC ACID
C
1,1-dihydroxyacetone
D
Glyceraldehyde
Conditions | Yield |
---|---|
With zinc(II) chloride at 200℃; for 0.416667h; | A 22.6% B n/a C n/a D n/a |
Conditions | Yield |
---|---|
With perchloric acid In ethanol at 20℃; pH=1; Reagent/catalyst; Electrochemical reaction; | A 7% B 7.6% C 20.3% |
Conditions | Yield |
---|---|
With 3H(1+)*MoO40W12(3-); oxygen In water at 60℃; under 7500.75 Torr; for 20h; Autoclave; | A 16% B 14.9% C 8.4% |
A
5-hydroxymethyl-2-furfuraldehyde
B
LACTIC ACID
C
1,1-dihydroxyacetone
D
5-ketohexanoic acid
E
Glyceraldehyde
Conditions | Yield |
---|---|
With chromium chloride at 200℃; for 0.5h; | A 13% B n/a C n/a D n/a E n/a |
Conditions | Yield |
---|---|
With tin(ll) chloride In water at 109.84℃; under 22502.3 Torr; for 3h; Catalytic behavior; Inert atmosphere; Autoclave; | A 10% B 9.6% |
Conditions | Yield |
---|---|
With lead(IV) acetate; acetic acid Erwaermen des Reaktionsprodukts mit wss.Schwefelsaeure; |
2-Phenyl-4H-[1,3]dioxin
Glyceraldehyde
Conditions | Yield |
---|---|
With Perbenzoic acid; chloroform at 0℃; dann bei Raumtemperatur, und Verseifen des Reaktionsprodukts mit verd. Essigsaeure auf dem Wasserbad; |
3,3-diethoxypropane-1,2-diol
Glyceraldehyde
Conditions | Yield |
---|---|
With acetic acid dl-glyceraldehyde; |
(+/-)-erythronic acid
Glyceraldehyde
Conditions | Yield |
---|---|
die Reaktion des Kupfersalz.Electrolysis; |
Conditions | Yield |
---|---|
With sodium carbonate; sodium sulfite bei der Destillation; | |
With sodium carbonate; sodium sulfite |
Conditions | Yield |
---|---|
durch Oxydation; | |
With sodium decatungstate; oxygen In water at 24.84℃; under 760 Torr; Mechanism; Reagent/catalyst; Irradiation; | |
With zinc(II) oxide In water at 30℃; Kinetics; UV-irradiation; |
Conditions | Yield |
---|---|
With sodium chlorate; osmium(VIII) oxide; water at -8℃; zuletzt bei Raumtemperatur; | |
With osmium(VIII) oxide; barium chlorate; water at -8℃; zuletzt bei Raumtemperatur; | |
With osmium(VIII) oxide; sulfuric acid; acetic acid In water at 26.4℃; for 24h; | |
With thallium(III) sulfate In 1,4-dioxane; sulfuric acid at 17.5℃; Kinetics; Thermodynamic data; Mechanism; other acroleine concentration, other temperature, ΔH(excit), ΔS(excit); | |
With osmium(VIII) oxide; sulfuric acid; acetic acid In water at 26.4℃; for 24h; Rate constant; Thermodynamic data; Mechanism; no reaction with corresponding saturated organic compound (selectivity);absence and presence of acrylonitrile or acrylamide (no polimerization); negligible effect of added salts; variation of concn. of substrate; activation parameters; |
(1S,2S)-1,2-bis[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethane-1,2-diol
Glyceraldehyde
Conditions | Yield |
---|---|
With lead(IV) acetate; benzene Erwaermen des Reaktionsprodukts mit wss.Essigsaeure; |
Conditions | Yield |
---|---|
In water at 25℃; Equilibrium constant; |
formaldehyd
A
methanol
B
formic acid
C
dihydroxyacetone
D
Glycolaldehyde
E
Glyceraldehyde
Conditions | Yield |
---|---|
With calcium hydroxide; dihydroxyacetone In water at 50℃; Kinetics; Mechanism; other reaction partner, specific co-catalytic activities for the most important intermediates and products; |
Conditions | Yield |
---|---|
With triethylamine; 3-ethylbenzothiazolium bromide In ethanol at 65℃; for 6h; Product distribution; var. of base, solvent; | |
With triethylamine; 3-ethylbenzothiazolium bromide In ethanol at 65℃; for 6h; Yield given; |
formaldehyd
A
DL-dendroketose
D-mannose
Arabinose
glucopyranose
E
Glyceraldehyde
Conditions | Yield |
---|---|
With calcium hydroxide In water at 50℃; for 0.8h; Kinetics; Mechanism; Product distribution; homogeneous catalysis, other time, temperatures, reagent, conc. Ca(OH)2; | A 9.9 % Chromat. B 2.0 % Chromat. C 7.3 % Chromat. D 10.0 % Chromat. E 2.5 % Chromat. F 3.0 % Chromat. |
Conditions | Yield |
---|---|
With 1 wt% Au/TiO2; oxygen In water at 75℃; under 39547.2 Torr; for 3022h; Time; Flow reactor; | 100% |
With sodium chlorite; dimethyl sulfoxide In aq. phosphate buffer at 0 - 20℃; pH=4; | 93% |
With iodine; sodium carbonate |
Conditions | Yield |
---|---|
With tin containing MWW type β-zeolite In decane at 119.84℃; for 24h; Reagent/catalyst; | 99% |
With Y-zeolite H-USY-6 In water at 115℃; for 48h; Inert atmosphere; | 98% |
With Sn(salen) functionalized [OMIm]Br at 160℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction; | 91.7% |
Glyceraldehyde
LACTIC ACID
Conditions | Yield |
---|---|
With tin containing MWW type β-zeolite In water at 109.84℃; for 6h; Reagent/catalyst; | 96% |
With Y-zeolite H-USY-6 In water at 125℃; for 48h; Inert atmosphere; | 63% |
With oxygen In water at 149.84℃; under 3750.38 Torr; for 1h; Reagent/catalyst; | 42% |
Glyceraldehyde
rac-Glycerinaldehyd-2-phosphat Natriumsalz
Conditions | Yield |
---|---|
With diamidophosphate In aq. phosphate buffer at 20℃; for 4h; pH=4; | 96% |
Glyceraldehyde
3-Amino-1,2-propanediol
Conditions | Yield |
---|---|
With ammonia; active charcoal; palladium In water | 94.5% |
With ammonium hydroxide; hydrogen at 55℃; under 15001.5 Torr; for 6h; Autoclave; Green chemistry; |
Conditions | Yield |
---|---|
With E. coli BL21 (DE3) cells harboring pETDRhaD aldolase; sodium borate buffer In water; toluene at 37℃; for 16h; pH=7.6; | A n/a B 92% |
Conditions | Yield |
---|---|
In methanol at 25℃; for 96h; | 91% |
fructose 1,6-diphosphate
Glyceraldehyde
Conditions | Yield |
---|---|
With fructose 1,6-bisphosphate aldolase from S. carnosus; triose phosphate isomerase from rabbit muscle [EC 5.3.1.1] In water at 20℃; Addition; Aldol condensation; Enzymatic reaction; | 90% |
Conditions | Yield |
---|---|
In aq. buffer for 24h; pH=7; Reagent/catalyst; | 90% |
chloro-trimethyl-silane
bis(trimethylsilyl)phosphonite
Glyceraldehyde
C21H47O8PSi3
Conditions | Yield |
---|---|
With triethylamine In benzene 1.) 40-45 deg C, 15 min; 2.) reflux, 2 h; | 88% |
Conditions | Yield |
---|---|
In ethanol at 25℃; | 87% |
Conditions | Yield |
---|---|
With scandium tris(trifluoromethanesulfonate) In water; acetonitrile at 40℃; for 24h; | 87% |
With Montmorillonite K10 at 20℃; for 0.5h; | 80% |
1.3-propanedithiol
Glyceraldehyde
(R)-1-(1,3-Dithian-2-yl)-2-hydroxy-1-ethanol
Conditions | Yield |
---|---|
With hydrogenchloride for 2h; | 86% |
Conditions | Yield |
---|---|
In ethanol at 25℃; | 86% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 86% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 86% |
Conditions | Yield |
---|---|
In water Ambient temperature; | 85% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 85% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 85% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 84% |
Conditions | Yield |
---|---|
With aluminium; tin(ll) chloride In methanol; water; acetic acid at 50 - 53℃; for 5h; | 82% |
Conditions | Yield |
---|---|
With tin In methanol; water; acetic acid 1.)room temperature, 2 h, 2.)electrolysis, 20 deg C; | 81% |
With tin In tetrahydrofuran; water Ambient temperature; Irradiation; | 55% |
With tin In water at 20℃; |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 81% |
methyl (triphenylphosphoranylidene)acetate
Glyceraldehyde
methyl (E)-4,5-dihydroxy-2-pentenoate
Conditions | Yield |
---|---|
In benzene Heating; | 80% |
2-isopropyl-5-methylcyclohexyl chloroformate
Glyceraldehyde
2,5-bis(Menthoxycarbonyloxymethylene)-3,6-bis(menthoxycarbonyloxy)-1,4-dioxane
Conditions | Yield |
---|---|
With pyridine In chloroform 1.) 0 deg C, 15 min, 2.) room temperature, 24 h, 3.) 40 deg C, 1.5 h, 4.) 60 deg C, 1 h;; | 80% |
Glyceraldehyde
ethyl (triphenylphosphoranylidene)acetate
ethyl (4RS,2E)-4,5-dihydroxypent-2-enoate
Conditions | Yield |
---|---|
In dichloromethane | 80% |
Conditions | Yield |
---|---|
With gold(III) tribromide In 2,2,2-trifluoroethanol at 60℃; for 24h; | 80% |
Molecular Structure of Dl-glyceraldehyde (CAS NO.56-82-6):
IUPAC: 2,3-dihydroxypropanal
Molecular Formula:C3H6O3
Molecular Weight:90.08
EINECS:200-290-0
Density:1.272 g/cm3
Melting Point:144-145oC(lit.)
Flash Point:106oC
Boiling Point:228oC at 760 mmHg
Storage temp.:2-8oC
Product Categories:Carbohydrate;Metabolic Pathways;Metabolites and Cofactors on the Metabolic Pathways Chart
SMILES:O=C[C@@H](O)CO
InChI:InChI=1/C3H6O3/c4-1-3(6)2-5/h1,3,5-6H,2H2/t3-/m1/s1
InChIKey:MNQZXJOMYWMBOU-GSVOUGTGBZ
Index of Refraction:1.454
Molar Volume:70.7 cm3
Surface Tension:53.3 dyne/cm
Molar Refractivity:19.16 cm3
Enthalpy of Vaporization:54.01 kJ/mol
Vapour Pressure:0.0146 mmHg at 25oC
1. | mmo-sat 100 µg/plate ABCHA6 47,2461,83 | |||
2. | ipr-rat LD50:2 g/kg | JPPMAB Journal of Pharmacy and Pharmacology. 17 (1965),814. |
Reported in EPA TSCA Inventory.
Mildly toxic by intraperitoneal route. Mutation data reported.
Safty informations about Dl-glyceraldehyde (CAS NO.56-82-6):
WGK Germany:3
RTECS:MA6475000
F:10-23
Dl-glyceraldehyde with cas registry number of 56-82-6 is also known as Glyceric aldehyde ; Glyceraldehyde ; Dl-glyceraldehyde ; (+-)-Glyceraldehyd ; 3-Dihydroxy-(+/-)-propana ; Dl-glyceraldehyd ; Dl-glycericaldehyde ; Dl-glyceraldehyde crystalline . It is a compound with the appearance of white crystalline powder. It is soluble in water. Dl-glyceraldehyde is used as an organic synthesis intermediate in synthesis of many useful compounds. It is also used in biochemical research.
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